Appendix TaBLe 1 ‘Tux terms a, b and c in the following table are the constants of the general formula of the temperature-function of the heat capacity, cyr) = @ + b.10-3.T + ¢.108. T-*. The standard values of enthalpy and entropy of various substances «re also given which are for solids except where otherwise stated as subscripts / or g for liquids and gases. Enthalpy and entropy of phase transformations are also given as subseripts with temperature. ep cal/deg /mol | | Temp. | | ASz0s cal ‘Substance 1 | Range | cas a op ow | \ i \ AL 494) 2-96 208-981 ° (ear Al 7-00 ARyon) | | | =25) | AIN | s-47| 7-80 208-900 | —76-5 5:0 ALO. lets} 308 | —s-20) 298-1800 400-0 122 ALSIO, | Sillimans |4009| 5-86 | —10:13| 208-1600 45-0 23-0 ‘Andalus* 46-24 =1255| 208-1600 -30-3 | BBB Kyanite™ 45-32] 234 | 16-00) 208-1700; —39-7 20-0 Casssadia 410| 102 | —210/ 298-2300 | ° 1-361 faa 5-65 | 11-44 | —0-46| 298-1500/ —17-89 445 co, 679| 0-08 | —o11, 298-2500| -264 | 47a COy) - |10:55| 216 | —204) 298-2500 | 9405 | S11 Ca, sal) 333 | | 298-713 ° | 05 oe tT ne) Ae ary Car T+ | | | 1128-1220 AHyi129) =21 | ro-40 -sor) aserao | “tat 168 | 1s-40 | 720-1876 | | | | 2498 -020) Beasio | 20- 298-800 | 10-20 | 1000 | 48-24 —s-00| 298-1373 CaSiOt | 26-64 —6-50 298-1450 | | (Wollastonit) ab chee | zs Sx ree cs “a r -0 2122 z & 20 | is Seyatn i =46 crc |ao03 5:58 | —r40/ gaatsoo | —21-0 20-4 crc [20:35 7-40 5:02 298-1700 16-4 253 erie, \3e06a4-sa | -10-12| 298-1500| 42-5 48-0 * ALSO, from Al.O, + Si0,. + from 8CaO + P.O. $ from CaO + Sid. $ from 2CaO + SiO. ¥ 325Temp. ‘Substance Range a o © S35 | | cn | 884 39 298-800 28:2 8-0 Gr0, {28-53 220 | -a-74 350-1800 -270-0 194 & faethe ee | Shiga. 3 fe Cur | 750 1857-1600 | AHy¢157) = 3-1 cuo e-27| 4-80 298-1250 871 10-2 Cu,0 14-90 5-70 | 298-1200, — 40-0 22-45 CuSO, |1s-77 17-20 | 298-900 184-0 25:3 Cu, 19-50 | 298-876 —19-6 28-5 CuSy 23-25 | | 876-628 AHy376) =0-02 cus 20-82 | exs-r400| aH 2” 418) 5-02 | 298-1033 ° o-49 9-0 | } 2038-2181 | As 6 1035 | rie | 84) 00 1181-1074 | py ie | | | o22 j105 | | | 1674-1808 | AH, 51674 | | | So-zi 10-0 | 1808-1873 | AHy SiO, fe, 3 298-1700 3 | 1700-1973 3 | 1978-2200 8/2Si +N, = 1/2Si. ‘90000 10 298-1680 =106700 |. 30 | 1680-1800 Si+c -sic —12770 3B 298-1680 | 24010 4 | 1688-2000 2Ti + 0. = 2710 | —244600 4 ‘600-2000 ‘Ti + 0; = Tid, | =217500 10 298-2080 4Tio. + 6, = 2Ti.0 | = 228300 4 298-2000 6Ti,0, + 0, = 4Ti.0. | =177000 3 700-2000 270, + 01 = 6TiO, —146000 3 298-2123 2Ti +N, = 2TiN 160500 | 4 298-1155 = 161700 | 4 | 1155-1500 Ti+c =7IC 43750 ie 13 298-1155 = 44600 | 3 | 1155-2000 2Vv +0, = 2v0 205900 } 8 900-1800 4/8V + O3 = 2/8V,0, —206800 10 298-1995 avo + 0, = 2,0, 175300 5 825-1385 2V,0, + 0, = 4V0. —102800 4 | 1020-1180 4V0, + 0, = 2V.0, — 64480 3 298-948 = 84300 4 943-1800 2V +N, — 2vN = 88300 10 298-1600 Ww +O. = Wo, 181600 5 298-1500 W +S: = WS; — 62360 10 | 298-1400 w4+c—we | —s100 | 3 | 298-2000 2Zn +S, = 2ZnS 121130 10 «| 298-693 = 128480 10 693-1189 =178330 | 10 | 1189-1500 2ZnO + SiO, = Zn,SiO. —7130 i. > ‘800-1800 Zr + On — ZrOs 256000 oar + Ny = 222N —174000 8 208-1185 =175850 B | 1135-1500 Zr + © = Zr 44100 8 ‘208-2200