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Advanced Separations - Chapter 10: Equilibrium-Based Methods for Multicomponent Absorption, Stripping, Distillation, and Extraction

1. Calculate product compositions, stage temperatures, interstage vapor and liquid flow rates and compositions,
reboiler duty, and condenser duty with a process simulator for the following column specifications.
Feed (bubble-point liquid at 250 psia and 213.9°F):
Component (lbmol/h)
Ethane- 3.0
Propane- 20.0
n-Butane- 37.0
n-Pentane- 35.0
n-Hexane - 5.0
Column pressure = 250 psia; partial condenser and partial reboiler;
Distillate rate = 23.0 lbmol∕h; reflux rate = 150.0 lbmol∕h;
Number of equilibrium stages (exclusive of condenser and
reboiler) = 15;
Feed is sent to middle stage.
For this system at 250 psia, K-values and enthalpies may be computed
by the SRK EOS.

Top

Feed1 9

16

Bottom

17
Advanced Separations - Chapter 10: Equilibrium-Based Methods for Multicomponent Absorption, Stripping, Distillation, and Extraction

ChemSep Output:

Mass and Energy Balances

Stream / Apparatus Mass (kg/s) Energy (J/s) Exergy (J/s)

Feed1 0.765907 -107715 2306.08

Top -0.765899 -111593 -52500.2

Bottom -0.000007533 -0.763808 -0.41972

Qcondenser -252715 -63278.5

Qreboiler 472024 170600

----------- + ----------- + ----------- +

Balance 9.5866E-08 -0.03125 57127.1

Thermodynamic efficiency = 0.467702

Component discrepancies: absolute (kmol/s)


Advanced Separations - Chapter 10: Equilibrium-Based Methods for Multicomponent Absorption, Stripping, Distillation, and Extraction

ethane 3.2512E-12 8.6012E-09

propane 9.1195E-11 3.6189E-08

n-butane 1.8849E-10 4.0432E-08

n-pentane 2.5089E-10 5.6894E-08

n-hexane 2.6208E-11 4.16E-08

Liquid x composition profiles

Stage Ethane Propane n-butane n-pentane n-hexane

1 0.00739176 0.0854752 0.288691 0.489875 0.128567

2 0.00439704 0.0562156 0.230774 0.515572 0.193041

3 0.00397952 0.0487726 0.201301 0.501832 0.244115

4 0.00391718 0.0467076 0.187451 0.478382 0.283543

5 0.00390943 0.0460279 0.180909 0.455961 0.313193

6 0.00391089 0.0457447 0.177644 0.437725 0.334975

7 0.00391355 0.0455972 0.175875 0.42394 0.350673

8 0.00391584 0.0455079 0.174834 0.413923 0.36182

9 0.00313033 0.041112 0.169418 0.409387 0.376953

10 0.00072244 0.0143203 0.0963077 0.363801 0.524848

11 0.0001678 0.0048675 0.0519316 0.296052 0.646981

12 0.000039298 0.00163668 0.0272224 0.228802 0.7423

13 9.2685E-06 0.0005475 0.0140375 0.171212 0.814193

14 2.1981E-06 0.00018267 0.00716559 0.125451 0.867199

15 5.235E-07 0.000060868 0.00363409 0.0906357 0.905669

16 1.2505E-07 0.000020266 0.00183519 0.0648597 0.933285

17 2.9939E-08 0.000006745 0.0009241 0.0461108 0.952958


Advanced Separations - Chapter 10: Equilibrium-Based Methods for Multicomponent Absorption, Stripping, Distillation, and Extraction

Liquid x composition profiles


(wt)

Stage Ethane Propane n-butane n-pentane n-hexane

1 0.00330778 0.0560931 0.249715 0.526 0.164884

2 0.00189263 0.0354849 0.192006 0.532484 0.238133

3 0.0016803 0.0302004 0.164295 0.508423 0.295402

4 0.00163543 0.0285973 0.151274 0.479229 0.339264

5 0.00162033 0.0279764 0.144935 0.45345 0.372018

6 0.00161295 0.0276673 0.141618 0.43317 0.395932

7 0.00160855 0.0274842 0.139731 0.418101 0.413076

8 0.00160569 0.0273655 0.138575 0.407256 0.425198

9 0.00127586 0.0245732 0.133473 0.400366 0.440313

10 0.00027948 0.00812414 0.0720157 0.337691 0.581889

11 0.000062797 0.00267123 0.0375645 0.265831 0.693871

12 0.000014387 0.00087872 0.0192646 0.200994 0.778849

13 3.3434E-06 0.00028963 0.00978793 0.148193 0.841726

14 7.8494E-07 0.000095661 0.00494591 0.107487 0.88747

15 1.8563E-07 0.000031651 0.00249083 0.0771148 0.920363

16 4.4128E-08 0.000010487 0.00125174 0.0549161 0.943822

17 1.0529E-08 3.4786E-06 0.00062818 0.0389096 0.960459

Vapour y composition profiles

Stage Ethane Propane n-butane n-pentane n-hexane

1 0.0300002 0.200002 0.370002 0.350002 0.0499936

2 0.018398 0.141229 0.328275 0.421782 0.0903156


Advanced Separations - Chapter 10: Equilibrium-Based Methods for Multicomponent Absorption, Stripping, Distillation, and Extraction

3 0.0168497 0.126149 0.298491 0.435043 0.123467

4 0.0166854 0.122617 0.283677 0.427694 0.149326

5 0.0167108 0.121898 0.276991 0.415412 0.168988

6 0.0167545 0.121832 0.274004 0.403795 0.183614

7 0.0167909 0.121899 0.272609 0.394417 0.194283

8 0.0168177 0.121975 0.271903 0.387366 0.201938

9 0.0134697 0.111139 0.267365 0.391447 0.216579

10 0.00313034 0.0411122 0.169418 0.409388 0.376951

11 0.00072245 0.0143204 0.0963081 0.363802 0.524847

12 0.0001678 0.00486751 0.0519317 0.296053 0.64698

13 0.000039298 0.00163668 0.0272225 0.228803 0.742299

14 9.2686E-06 0.0005475 0.0140375 0.171213 0.814193

15 2.1981E-06 0.00018267 0.00716561 0.125451 0.867199

16 5.2351E-07 0.000060868 0.00363409 0.0906358 0.905669

17 1.2505E-07 0.000020266 0.00183519 0.0648597 0.933285

Vapour y composition profiles


(wt)

Stage Ethane Propane n-butane n-pentane n-hexane

1 0.0148399 0.145084 0.35378 0.415422 0.0708736

2 0.0086338 0.097193 0.297776 0.474931 0.121466

3 0.00774157 0.0849965 0.265087 0.479601 0.162573

4 0.00758762 0.0817715 0.249354 0.466675 0.194612

5 0.00755479 0.0808166 0.242054 0.450625 0.218949


Advanced Separations - Chapter 10: Equilibrium-Based Methods for Multicomponent Absorption, Stripping, Distillation, and Extraction

6 0.0075465 0.0804744 0.238557 0.436403 0.237019

7 0.00754415 0.0803191 0.236755 0.425212 0.25017

8 0.00754336 0.0802326 0.23574 0.416899 0.259584

9 0.005978 0.0723345 0.229364 0.416852 0.275471

10 0.00127586 0.0245733 0.133473 0.400367 0.44031

11 0.00027948 0.00812417 0.072016 0.337692 0.581888

12 0.000062797 0.00267124 0.0375647 0.265831 0.69387

13 0.000014387 0.00087873 0.0192647 0.200994 0.778848

14 3.3434E-06 0.00028963 0.00978796 0.148193 0.841726

15 7.8494E-07 0.000095661 0.00494593 0.107487 0.88747

16 1.8563E-07 0.000031652 0.00249084 0.0771149 0.920362

17 4.4128E-08 0.000010487 0.00125175 0.0549161 0.943822

K-value profiles

Stage Ethane Propane n-butane n-pentane n-hexane

1 4.05861 2.33988 1.28165 0.714472 0.388854

2 4.18419 2.51227 1.4225 0.818086 0.467856

3 4.23411 2.58647 1.48281 0.866911 0.505773

4 4.25953 2.62521 1.51334 0.894043 0.526645

5 4.27449 2.64834 1.53111 0.91107 0.539565

6 4.28406 2.66331 1.54243 0.922486 0.548143

7 4.29044 2.6734 1.55001 0.93036 0.55403

8 4.29478 2.68032 1.55521 0.935842 0.558118

9 4.30296 2.70332 1.57814 0.956178 0.574552

10 4.33296 2.8709 1.75913 1.12531 0.718209

11 4.30521 2.94204 1.85452 1.22884 0.811225


Advanced Separations - Chapter 10: Equilibrium-Based Methods for Multicomponent Absorption, Stripping, Distillation, and Extraction

12 4.27014 2.97402 1.90768 1.29393 0.871588

13 4.23997 2.98937 1.93928 1.33637 0.911698

14 4.21648 2.99711 1.95901 1.36478 0.938877

15 4.19896 3.00118 1.97178 1.38412 0.957523

16 4.18616 3.0034 1.98023 1.39741 0.97041

17 4.17695 3.00465 1.98592 1.40661 0.979355

Stream Feed1 V.Feed1 L.Feed1 Top Bottom

Stage 9 9 9 1 17

Pressure (N/m2) 1723600 1723600 1723600 1723600 1723600

Vapour fraction (-) 0.0898662 1 0 1 0

Temperature (K) 374.206 374.206 374.206 397.742 466.897

Enthalpy (J/kmol) -8548000 8856700 8668900

Entropy (J/kmol/K) -29287.1 15730.4 13098.3

Total molar flow


0.0125998 0.0011323 0.0114675 0.0125997 8.8109E-08
(kmol/s)

Total mass flow (kg/s) 0.765907 0.0607237 0.705183 0.765899 7.5335E-06

Vapour std.vol.flow
0.0304052 0.0268246 0.298493
(m3/s)

Liquid std.vol.flow
0.00118011 0.00119383 1.1398E-08
(m3/s)

Mole flows (kmol/s)

etha 0.00037799 0.00010062 0.00027736 0.00037799 2.6379E-15

propane 0.00251996 0.00040116 0.00211879 0.00251996 5.943E-13

n-but 0.00466192 0.00040556 0.00425636 0.00466192 8.1421E-11


Advanced Separations - Chapter 10: Equilibrium-Based Methods for Multicomponent Absorption, Stripping, Distillation, and Extraction

n-pe 0.00440993 0.00021018 0.00419975 0.00440993 4.0627E-09

n-h 0.00062998 0.000014754 0.00061523 0.0006299 8.3964E-08

Mole fractions (-)

Ethane 0.03 0.088869 0.0241873 0.0300002 2.9939E-08

Propane 0.2 0.354296 0.184765 0.200002 0.000006745

n-butane 0.37 0.358178 0.371167 0.370002 0.0009241

n-pentane 0.35 0.185627 0.36623 0.350002 0.0461108

n-hexane 0.0499999 0.0130302 0.0536503 0.0499936 0.952958

Mass flows (kg/s)

Ethane 0.0113659 0.00302573 0.00834019 0.0113659 7.9321E-14

Propane 0.111119 0.0176897 0.0934295 0.111119 2.6206E-11

n-butane 0.270961 0.0235723 0.247389 0.270961 4.7324E-09

n-pentane 0.318171 0.0151646 0.303007 0.318171 2.9312E-07

n-hexane 0.0542895 0.00127143 0.0530181 0.0542823 7.2356E-06

Mass fractions (-)

Ethane 0.0148398 0.0498278 0.011827 0.01484 1.0529E-08

Propane 0.145082 0.291315 0.13249 0.145083 3.4786E-06

n-butane 0.353778 0.388189 0.350815 0.353782 0.00062818

n-pentane 0.415417 0.24973 0.429685 0.415421 0.0389093

n-hexane 0.0708827 0.020938 0.0751835 0.0708739 0.960459

Combined feed fractions


(-)

Ethane 1 0.266211 0.733789 1 6.9788E-12

Propane 1 0.159196 0.840804 1 2.3583E-10


Advanced Separations - Chapter 10: Equilibrium-Based Methods for Multicomponent Absorption, Stripping, Distillation, and Extraction

n-butane 1 0.086995 0.913005 1 1.7465E-08

n-pentane 1 0.0476617 0.952338 0.999999 9.2127E-07

n-hexane 1 0.0234195 0.97658 0.999867 0.00013327

Vapour:

Mole weight (kg/kmol) 53.6288 53.6288 60.7871

Density (kg/m3) 38.8997 38.8997 42.5842

Std.density (kg/m3) 2.26373 2.26373 2.56589

Viscosity (N/m2.s) 9.6533E-06 9.6533E-06 9.8039E-06

Heat capacity
127140 127140 150545
(J/kmol/K)

Thermal cond. (J/s/m/K) 0.0278916 0.0278916 0.0294471

Liquid:

Mole weight (kg/kmol) 61.4941 61.4941 85.5024

Density (kg/m3) 486.1 486.1 445.346

Std.density (kg/m3) 590.69 590.69 660.911

Viscosity (N/m2.s) 0.000083839 0.000083839 0.000052912

Heat capacity
170764 170764 277635
(J/kmol/K)

Thermal cond. (J/s/m/K) 0.0818193 0.0818193 0.060779

Surface tension (N/m) 0.00486924 0.00486924 0.00216699

Column C:\USERS\DELL\DESKTOP\SUCCESS1.SEP

Title: Problem 10.15

Components:

Ethane
Advanced Separations - Chapter 10: Equilibrium-Based Methods for Multicomponent Absorption, Stripping, Distillation, and Extraction

Propane

N-butane

N-pentane

N-hexane

Operation:

Complex Column

Partial (Vapour product) Condenser

Partial (Liquid product) Reboiler

17 Stages

Feeds to stages 9

+----+

+------>-----+---->-

| |1 | |

+--|------+ +--|-+

| | +----<---+

|--|---|--|

|--|---|--|

|--|---|--|

|--|---|--|

----->----9-|--|---|--|

|--|---|--|

|--|---|--|

|--|---|--|

|--|---|--|

| +---|-----<----+

+------|--+ +--|-+
Advanced Separations - Chapter 10: Equilibrium-Based Methods for Multicomponent Absorption, Stripping, Distillation, and Extraction

+--->------+--->-

17+----+

Properties:

EOS K model

Soave-RK Cubic EOS

Soave-RK Enthalpy

Enthalpy reference state Vapour

Enthalpy reference temperature 298.150 (K)

Formation enthalpies Excluded

Exergy surroundings temperature 298.150 (K)

Thermo data (J/mol):

[Soave-RK Data]

i j kij Component Component

1 2 -0.0022 ethane/propane

1 3 0.0052 ethane/n-butane

1 4 0.0056 ethane/n-pentane

1 5 -0.0433 ethane/n-hexane

2 3 0 propane/n-butane

2 4 0.0233 propane/n-pentane

2 5 -0.0022 propane/n-hexane

3 4 0.0204 n-butane/n-pentane

3 5 -0.0111 n-butane/n-hexane

4 5 0 n-pentane/n-hexane

Reactions:
Advanced Separations - Chapter 10: Equilibrium-Based Methods for Multicomponent Absorption, Stripping, Distillation, and Extraction

Specifications:

Column pressure

Condenser pressure 1.7236E+06 (N/m2)

Top pressure 1.7236E+06 (N/m2)

Default efficiency = 1.00000 (-)

Feed 1

Name Feed1

Stage 9

Pressure (N/m2) 1.72E+06

Enthalpy (J/kmol)

Vapour fraction ( )

Temperature (K) 374.206

Component flows (kmol/s)

ethane 3.77E-04

propane 2.51E-03

n-butane 4.66E-03

n-pentane 4.40E-03

n-hexane 6.29E-04

Condenser

Duty: Qcondenser

Heat duty of condenser = -252715 (J/s)

Initialization guess: *
Advanced Separations - Chapter 10: Equilibrium-Based Methods for Multicomponent Absorption, Stripping, Distillation, and Extraction

Reboiler

Duty: Qreboiler

Boilup ratio = 328181 (-)

Initialization guess: *

Product streams:

Top (from 1): Top

Bottom (from 17): Bottom

Solve options:

Automatic Initialization

Newton's method

Flow Step limit 0.500000 (-)

Temperature Step limit 10.0000 (K)

Composition Step limit 1.00000 (-)

Flux Step limit 1.00000 (-)

Accuracy = 0.000001

Maximum iterations = 30

Feeds type = Stage below

Trace treshold = 0.000000 (-)

ChemSep (TM) - COL2 7.41


Copyright (c) 1988-2018 Harry Kooijman and Ross Taylor
License: 2100- 6 LITE free license
Build: e2abdf100026
Checking data file C:\PROGRA~1\CHEMSE~1\1015~1.SEP
Reading configuration
Advanced Separations - Chapter 10: Equilibrium-Based Methods for Multicomponent Absorption, Stripping, Distillation, and Extraction

Reading component property libraries


1 74-84-0
2 74-98-6
3 106-97-8
4 109-66-0
5 110-54-3
Reading thermodynamic property options
Reading physical property options
Reading thermodynamic property data
Reading reaction data
Reading specifications
Checking Component Data
74-84-0 Ethane
74-98-6 Propane
106-97-8 N-butane
109-66-0 N-pentane
110-54-3 N-hexane
Determining feed conditions
Solving TP flash
Run level: Initialization
Generating initial flow profiles
Generating initial composition profiles
Init 44 milliseconds
Run level: Complete model

Iteration log(Err/Tol)
0 3.3658
1 4.3738
2 3.5318
3 1.5758
Advanced Separations - Chapter 10: Equilibrium-Based Methods for Multicomponent Absorption, Stripping, Distillation, and Extraction

4 -2.5234
Run level: Report
Convergence obtained in 4 iterations
Time 12 milliseconds
Cleanup called with T
FixMem driver done

O'Connell efficiency
Stage Efficiency Angle

2 0.787923 0.000000
3 0.792689 0.000000
4 0.795181 0.000000
5 0.796747 0.000000
6 0.797825 0.000000
7 0.798592 0.000000
8 0.799142 0.000000
9 0.801925 0.000000
10 0.822882 0.000000
11 0.842020 0.000000
Advanced Separations - Chapter 10: Equilibrium-Based Methods for Multicomponent Absorption, Stripping, Distillation, and Extraction

12 0.858065 0.000000
13 0.871228 0.000000
14 0.881727 0.000000
15 0.889862 0.000000
16 0.896006 0.000000
Advanced Separations - Chapter 10: Equilibrium-Based Methods for Multicomponent Absorption, Stripping, Distillation, and Extraction

Stage T Hv Hl Sv Sl Q Sirr

(K) (J/kmol) (J/kmol) (J/kmol/K (J/kmol/K (J/s) (J/kmol/K)

1 397.74 8856700 -6566000 15730.4 -21846.4 -252715 8.57455

2 408.35 10706000 -4814000 20664.9 -16502.2 5.86939

3 413.18 11590000 -3986000 23144.1 -13844.6 1.87946

4 415.81 12078000 -3530000 24588 -12307.5 0.850201

5 417.43 12383000 -3247000 25511.1 -11331.1 0.435884

6 418.5 12586000 -3058000 26130.5 -10680.2 0.226685

7 419.23 12725000 -2927000 26555.1 -10236.5 0.115817

8 419.74 12823000 -2836000 26848.5 -9931.48 11.8074

9 421.68 13225000 -2442000 27784.6 -8923.41 77.2005

10 438 16858000 1108500 35874.8 -393.238 31.9058

11 448.24 19414000 3588000 40860.4 4931.96 19.3184

12 454.88 21197000 5308600 43894.5 8244.08 12.3352

13 459.32 22448000 6512000 45719 10307 8.17099

14 462.34 23329000 7358100 46787 11584.6 5.53341

15 464.44 23951000 7954100 47383.3 12364.5 3.7956

16 465.89 24389000 8373700 47690.7 12829.8 2.62225

17 466.9 24697000 8668900 47826.3 13098.3 472024 0.973432


Advanced Separations - Chapter 10: Equilibrium-Based Methods for Multicomponent Absorption, Stripping, Distillation, and Extraction

Total entropy production = 191.615 (J/kmol/K)


Advanced Separations - Chapter 10: Equilibrium-Based Methods for Multicomponent Absorption, Stripping, Distillation, and Extraction

Stage Vapour Liquid Vapour Liquid Vapour Liquid Vapour Liquid Vapour Liquid Surface

Density Density Viscosity Viscosity Molecular Molecular Heat Heat Thermal Thermal tension

weight weight capacity capacity conductivity conductivity

kg/m3 kg/m3 N/m2.s N/m2.s kg/kmol kg/kmol J/kmol/K J/kmol/K J/s/m/K J/s/m/K N/m

1 42.5842 478.083 9.8039E-06 0.000079929 60.7871 67.1939 150545 203693 0.0294471 0.0769217 0.00422007

2 44.2557 473.998 9.8725E-06 0.000078497 64.0749 69.8575 161800 217406 0.0301187 0.0748822 0.00387016

3 44.827 472.731 9.9118E-06 0.00007797 65.4459 71.2136 166524 222967 0.0304421 0.0740476 0.00373944

4 45.0375 472.382 9.9375E-06 0.000077638 66.1224 72.0215 168843 226043 0.030631 0.0736162 0.00368115

5 45.1265 472.306 9.9552E-06 0.00007738 66.5111 72.5485 170171 228071 0.0307542 0.0733498 0.00366185

6 45.1708 472.302 9.9676E-06 0.000077174 66.7581 72.9077 171014 229494 0.0308386 0.0731696 0.0036593

7 45.1965 472.313 9.9764E-06 0.000077015 66.9239 73.1568 171581 230503 0.0308975 0.0730435 0.00365743

8 45.213 472.322 9.9826E-06 0.000076894 67.0379 73.3301 171972 231216 0.0309387 0.0729545 0.00365602

9 45.6568 471.152 0.00000999 0.000076292 67.7518 73.7747 174591 233572 0.0310328 0.0725087 0.00360265

10 49.4015 461.655 0.00001006 0.000072293 73.7747 77.7276 197479 234547 0.0317916 0.0699599 0.00312333

11 51.9925 455.71 0.000010105 0.000067543 77.7276 80.3517 213516 249694 0.0322024 0.0670591 0.00276999

12 53.757 451.965 0.000010137 0.000063396 80.3517 82.1313 224635 259689 0.0324513 0.0649873 0.00253831

13 54.9718 449.512 0.000010159 0.000060025 82.1313 83.3565 232404 266382 0.0326155 0.0635052 0.00238867

14 55.8175 447.852 0.000010176 0.000057402 83.3565 84.2069 237869 270920 0.0327286 0.0624463 0.00229181

15 56.4097 446.705 0.000010188 0.000055426 84.2069 84.7995 241723 274023 0.0328081 0.0616922 0.00222854
Advanced Separations - Chapter 10: Equilibrium-Based Methods for Multicomponent Absorption, Stripping, Distillation, and Extraction

16 56.8254 445.906 0.000010197 0.000053969 84.7995 85.2133 244441 276158 0.0328643 0.0611572 0.00219335

17 57.1171 445.346 0.000010203 0.000052912 85.2133 85.5024 246355 277635 0.0329041 0.060779 0.00216699
Advanced Separations - Chapter 10: Equilibrium-Based Methods for Multicomponent Absorption, Stripping, Distillation, and Extraction

Vapour phase composition profiles

ChemSep

5
Stage

10

15
etha
propane
n-but
n-pe
n-h
0.0 0.2 0.4 0.6 0.8 1.0

Vapour mole fraction


Advanced Separations - Chapter 10: Equilibrium-Based Methods for Multicomponent Absorption, Stripping, Distillation, and Extraction

Liquid phase composition profiles

ChemSep

5
Stage

10

15
etha
propane
n-but
n-pe
n-h
0.0 0.2 0.4 0.6 0.8 1.0

Liquid mole fraction


Advanced Separations - Chapter 10: Equilibrium-Based Methods for Multicomponent Absorption, Stripping, Distillation, and Extraction
Advanced Separations - Chapter 10: Equilibrium-Based Methods for Multicomponent Absorption, Stripping, Distillation, and Extraction

K-value profiles

ChemSep

5
Stage

10

15
etha
propane
n-but
n-pe
n-h
0 1 2 3 4 5

K-value
Advanced Separations - Chapter 10: Equilibrium-Based Methods for Multicomponent Absorption, Stripping, Distillation, and Extraction

Temperature profile

ChemSep

5
Stage

10

15

T
400 420 440 460 480

Temperature (K)
Advanced Separations - Chapter 10: Equilibrium-Based Methods for Multicomponent Absorption, Stripping, Distillation, and Extraction

Flow profiles

ChemSep

5
Stage

10

15

V
L
0.000 0.005 0.010 0.015 0.020 0.025 0.030

Flow s (kmol/s)
Advanced Separations - Chapter 10: Equilibrium-Based Methods for Multicomponent Absorption, Stripping, Distillation, and Extraction
Advanced Separations - Chapter 10: Equilibrium-Based Methods for Multicomponent Absorption, Stripping, Distillation, and Extraction

Mass transfer rates

ChemSep

5
Stage

10

15
etha
propane
n-but
n-pe
n-h
-0.002 0.000 0.002 0.004

Mass transfer rates (kmol/s)


Advanced Separations - Chapter 10: Equilibrium-Based Methods for Multicomponent Absorption, Stripping, Distillation, and Extraction

Stripping factors

ChemSep

5
Stage

10

15
etha
propane
n-but
n-pe
n-h
1 10

Stripping factor (Si = Ki.V/L)


Advanced Separations - Chapter 10: Equilibrium-Based Methods for Multicomponent Absorption, Stripping, Distillation, and Extraction
Advanced Separations - Chapter 10: Equilibrium-Based Methods for Multicomponent Absorption, Stripping, Distillation, and Extraction

Key ratio profiles

ChemSep

5
Stage

10

15

key ratio-1-2
key ratio-2-3
key ratio-3-4
key ratio-4-5
0.01 0.1 1

key ratio
Advanced Separations - Chapter 10: Equilibrium-Based Methods for Multicomponent Absorption, Stripping, Distillation, and Extraction

Relative volatility

ChemSep

5
Stage

10

15

alpha-n-pe-n-h
1.4 1.5 1.6 1.7 1.8 1.9

alpha-n-pe-n-h
Advanced Separations - Chapter 10: Equilibrium-Based Methods for Multicomponent Absorption, Stripping, Distillation, and Extraction

2. Find the solution of the system of equations using the Newton -Raphson Method:

a.) Starting guess: x1 = 0.4 ; x2 = 0.9


Iteration x1 x2

Start 0.400 0.900

1 0.1415 0.8394

2 0.2806 0.9073

3 0.2984 0.9026

4 0.2994 0.9030

b.) Starting guess: x1 = 0.6 ; x2 = 0.9


Iteration x1 x2

Start 0.600 0.900

1 0.4901 1.0235

2 0.4999 1.0002

3 0.5000 1.0000

b.) Starting guess: x1 = 1 ; x2 = 1


Iteration x1 x2

Start 1.000 1.000

1 0.9091 0.6914

2 1.0720 0.2987

3 0.9727 0.5500

4 1.1633 -0.0252

5 1.0511 0.3321

6 0.9512 0.6053

7 1.0876 0.2072
Advanced Separations - Chapter 10: Equilibrium-Based Methods for Multicomponent Absorption, Stripping, Distillation, and Extraction

8 1.0042 0.4451

9 0.7160 1.2837

10 0.6514 0.9886

11 0.5135 1.0452

12 0.5045 1.0008

13 0.5001 1.0001

14 0.5000 1.0000

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