Professional Documents
Culture Documents
1. Calculate product compositions, stage temperatures, interstage vapor and liquid flow rates and compositions,
reboiler duty, and condenser duty with a process simulator for the following column specifications.
Feed (bubble-point liquid at 250 psia and 213.9°F):
Component (lbmol/h)
Ethane- 3.0
Propane- 20.0
n-Butane- 37.0
n-Pentane- 35.0
n-Hexane - 5.0
Column pressure = 250 psia; partial condenser and partial reboiler;
Distillate rate = 23.0 lbmol∕h; reflux rate = 150.0 lbmol∕h;
Number of equilibrium stages (exclusive of condenser and
reboiler) = 15;
Feed is sent to middle stage.
For this system at 250 psia, K-values and enthalpies may be computed
by the SRK EOS.
Top
Feed1 9
16
Bottom
17
Advanced Separations - Chapter 10: Equilibrium-Based Methods for Multicomponent Absorption, Stripping, Distillation, and Extraction
ChemSep Output:
K-value profiles
Stage 9 9 9 1 17
Vapour std.vol.flow
0.0304052 0.0268246 0.298493
(m3/s)
Liquid std.vol.flow
0.00118011 0.00119383 1.1398E-08
(m3/s)
Vapour:
Heat capacity
127140 127140 150545
(J/kmol/K)
Liquid:
Heat capacity
170764 170764 277635
(J/kmol/K)
Column C:\USERS\DELL\DESKTOP\SUCCESS1.SEP
Components:
Ethane
Advanced Separations - Chapter 10: Equilibrium-Based Methods for Multicomponent Absorption, Stripping, Distillation, and Extraction
Propane
N-butane
N-pentane
N-hexane
Operation:
Complex Column
17 Stages
Feeds to stages 9
+----+
+------>-----+---->-
| |1 | |
+--|------+ +--|-+
| | +----<---+
|--|---|--|
|--|---|--|
|--|---|--|
|--|---|--|
----->----9-|--|---|--|
|--|---|--|
|--|---|--|
|--|---|--|
|--|---|--|
| +---|-----<----+
+------|--+ +--|-+
Advanced Separations - Chapter 10: Equilibrium-Based Methods for Multicomponent Absorption, Stripping, Distillation, and Extraction
+--->------+--->-
17+----+
Properties:
EOS K model
Soave-RK Enthalpy
[Soave-RK Data]
1 2 -0.0022 ethane/propane
1 3 0.0052 ethane/n-butane
1 4 0.0056 ethane/n-pentane
1 5 -0.0433 ethane/n-hexane
2 3 0 propane/n-butane
2 4 0.0233 propane/n-pentane
2 5 -0.0022 propane/n-hexane
3 4 0.0204 n-butane/n-pentane
3 5 -0.0111 n-butane/n-hexane
4 5 0 n-pentane/n-hexane
Reactions:
Advanced Separations - Chapter 10: Equilibrium-Based Methods for Multicomponent Absorption, Stripping, Distillation, and Extraction
Specifications:
Column pressure
Feed 1
Name Feed1
Stage 9
Enthalpy (J/kmol)
Vapour fraction ( )
ethane 3.77E-04
propane 2.51E-03
n-butane 4.66E-03
n-pentane 4.40E-03
n-hexane 6.29E-04
Condenser
Duty: Qcondenser
Initialization guess: *
Advanced Separations - Chapter 10: Equilibrium-Based Methods for Multicomponent Absorption, Stripping, Distillation, and Extraction
Reboiler
Duty: Qreboiler
Initialization guess: *
Product streams:
Solve options:
Automatic Initialization
Newton's method
Accuracy = 0.000001
Maximum iterations = 30
Iteration log(Err/Tol)
0 3.3658
1 4.3738
2 3.5318
3 1.5758
Advanced Separations - Chapter 10: Equilibrium-Based Methods for Multicomponent Absorption, Stripping, Distillation, and Extraction
4 -2.5234
Run level: Report
Convergence obtained in 4 iterations
Time 12 milliseconds
Cleanup called with T
FixMem driver done
O'Connell efficiency
Stage Efficiency Angle
2 0.787923 0.000000
3 0.792689 0.000000
4 0.795181 0.000000
5 0.796747 0.000000
6 0.797825 0.000000
7 0.798592 0.000000
8 0.799142 0.000000
9 0.801925 0.000000
10 0.822882 0.000000
11 0.842020 0.000000
Advanced Separations - Chapter 10: Equilibrium-Based Methods for Multicomponent Absorption, Stripping, Distillation, and Extraction
12 0.858065 0.000000
13 0.871228 0.000000
14 0.881727 0.000000
15 0.889862 0.000000
16 0.896006 0.000000
Advanced Separations - Chapter 10: Equilibrium-Based Methods for Multicomponent Absorption, Stripping, Distillation, and Extraction
Stage T Hv Hl Sv Sl Q Sirr
Stage Vapour Liquid Vapour Liquid Vapour Liquid Vapour Liquid Vapour Liquid Surface
Density Density Viscosity Viscosity Molecular Molecular Heat Heat Thermal Thermal tension
kg/m3 kg/m3 N/m2.s N/m2.s kg/kmol kg/kmol J/kmol/K J/kmol/K J/s/m/K J/s/m/K N/m
1 42.5842 478.083 9.8039E-06 0.000079929 60.7871 67.1939 150545 203693 0.0294471 0.0769217 0.00422007
2 44.2557 473.998 9.8725E-06 0.000078497 64.0749 69.8575 161800 217406 0.0301187 0.0748822 0.00387016
3 44.827 472.731 9.9118E-06 0.00007797 65.4459 71.2136 166524 222967 0.0304421 0.0740476 0.00373944
4 45.0375 472.382 9.9375E-06 0.000077638 66.1224 72.0215 168843 226043 0.030631 0.0736162 0.00368115
5 45.1265 472.306 9.9552E-06 0.00007738 66.5111 72.5485 170171 228071 0.0307542 0.0733498 0.00366185
6 45.1708 472.302 9.9676E-06 0.000077174 66.7581 72.9077 171014 229494 0.0308386 0.0731696 0.0036593
7 45.1965 472.313 9.9764E-06 0.000077015 66.9239 73.1568 171581 230503 0.0308975 0.0730435 0.00365743
8 45.213 472.322 9.9826E-06 0.000076894 67.0379 73.3301 171972 231216 0.0309387 0.0729545 0.00365602
9 45.6568 471.152 0.00000999 0.000076292 67.7518 73.7747 174591 233572 0.0310328 0.0725087 0.00360265
10 49.4015 461.655 0.00001006 0.000072293 73.7747 77.7276 197479 234547 0.0317916 0.0699599 0.00312333
11 51.9925 455.71 0.000010105 0.000067543 77.7276 80.3517 213516 249694 0.0322024 0.0670591 0.00276999
12 53.757 451.965 0.000010137 0.000063396 80.3517 82.1313 224635 259689 0.0324513 0.0649873 0.00253831
13 54.9718 449.512 0.000010159 0.000060025 82.1313 83.3565 232404 266382 0.0326155 0.0635052 0.00238867
14 55.8175 447.852 0.000010176 0.000057402 83.3565 84.2069 237869 270920 0.0327286 0.0624463 0.00229181
15 56.4097 446.705 0.000010188 0.000055426 84.2069 84.7995 241723 274023 0.0328081 0.0616922 0.00222854
Advanced Separations - Chapter 10: Equilibrium-Based Methods for Multicomponent Absorption, Stripping, Distillation, and Extraction
16 56.8254 445.906 0.000010197 0.000053969 84.7995 85.2133 244441 276158 0.0328643 0.0611572 0.00219335
17 57.1171 445.346 0.000010203 0.000052912 85.2133 85.5024 246355 277635 0.0329041 0.060779 0.00216699
Advanced Separations - Chapter 10: Equilibrium-Based Methods for Multicomponent Absorption, Stripping, Distillation, and Extraction
ChemSep
5
Stage
10
15
etha
propane
n-but
n-pe
n-h
0.0 0.2 0.4 0.6 0.8 1.0
ChemSep
5
Stage
10
15
etha
propane
n-but
n-pe
n-h
0.0 0.2 0.4 0.6 0.8 1.0
K-value profiles
ChemSep
5
Stage
10
15
etha
propane
n-but
n-pe
n-h
0 1 2 3 4 5
K-value
Advanced Separations - Chapter 10: Equilibrium-Based Methods for Multicomponent Absorption, Stripping, Distillation, and Extraction
Temperature profile
ChemSep
5
Stage
10
15
T
400 420 440 460 480
Temperature (K)
Advanced Separations - Chapter 10: Equilibrium-Based Methods for Multicomponent Absorption, Stripping, Distillation, and Extraction
Flow profiles
ChemSep
5
Stage
10
15
V
L
0.000 0.005 0.010 0.015 0.020 0.025 0.030
Flow s (kmol/s)
Advanced Separations - Chapter 10: Equilibrium-Based Methods for Multicomponent Absorption, Stripping, Distillation, and Extraction
Advanced Separations - Chapter 10: Equilibrium-Based Methods for Multicomponent Absorption, Stripping, Distillation, and Extraction
ChemSep
5
Stage
10
15
etha
propane
n-but
n-pe
n-h
-0.002 0.000 0.002 0.004
Stripping factors
ChemSep
5
Stage
10
15
etha
propane
n-but
n-pe
n-h
1 10
ChemSep
5
Stage
10
15
key ratio-1-2
key ratio-2-3
key ratio-3-4
key ratio-4-5
0.01 0.1 1
key ratio
Advanced Separations - Chapter 10: Equilibrium-Based Methods for Multicomponent Absorption, Stripping, Distillation, and Extraction
Relative volatility
ChemSep
5
Stage
10
15
alpha-n-pe-n-h
1.4 1.5 1.6 1.7 1.8 1.9
alpha-n-pe-n-h
Advanced Separations - Chapter 10: Equilibrium-Based Methods for Multicomponent Absorption, Stripping, Distillation, and Extraction
2. Find the solution of the system of equations using the Newton -Raphson Method:
1 0.1415 0.8394
2 0.2806 0.9073
3 0.2984 0.9026
4 0.2994 0.9030
1 0.4901 1.0235
2 0.4999 1.0002
3 0.5000 1.0000
1 0.9091 0.6914
2 1.0720 0.2987
3 0.9727 0.5500
4 1.1633 -0.0252
5 1.0511 0.3321
6 0.9512 0.6053
7 1.0876 0.2072
Advanced Separations - Chapter 10: Equilibrium-Based Methods for Multicomponent Absorption, Stripping, Distillation, and Extraction
8 1.0042 0.4451
9 0.7160 1.2837
10 0.6514 0.9886
11 0.5135 1.0452
12 0.5045 1.0008
13 0.5001 1.0001
14 0.5000 1.0000