y pista BU saa twt ek SE MARCH gurwt F SOP gas 81 2018 TUESDAY Weems] 026/279 bution law Asan twaporteant gonoradligetion by chhich pist* hetevogone> equilibrium Con be exam athe. distention... law exprener tne Yelatiow Hevent phases in equt nade belween ‘the concentyatti Ro over gabstone in eo cli Hibwiamn with ach other Let us tate two ammisarble [eet x pce A&B th aheakery selvent A selvent B ib get when a thule 'X’. Chick UW foleble iu beth solvents 4 added 'Fget added, distyiloutul ex portionsd behsesn TOMEI OB oe Dy 9 wow 1) 6 wt a dy nemic equilibrem establishes. WEEKS] 087/278 Forexample the distnibakiou of Auccmic acid been ety ahr ; between eftner & —— feeceeeeree Guceitic Aud. cone: of aed Concentyation Of acid nn 4 ere (C1) a eoaken Cee) covsbant: Cone of Kim9 10 11 12 13 14 fib 16 17:18 19 20 21 2 L 23.24 25 26 27 28 29 30 wang, 088277 hod F uated 4 Noevist's law whom bosd—* bhactieed The Tai tethubor oF “fevered Atietes boettueen clitfevent Saiteble paiws gf Kolyerhs « He gore goneriaakion hich —cyeverns tthe dite hcbey of o sdakee vetwerm tee immbeibale Kelvewk calle? Astaildion loc T+ Atala os, tha Sotete x chsteibsty “Azelf bebwee to fenmisecble gelvenh A 4 Bat -the Neve? (Leah) constant dempevetve and ¥ & in game meleculav Condihon fn bet tre bokent, — -= k ceneek xm BO ie ow Si, ac conc. of BIW A os & OG ene OF KIB ley ov 1€ fs Called the distaibetion oc Csnietioy yoko. rod sid Ko Hee a mite BOB mar 3()' c FRIDAY of benger § oodley . Affey “Ahatcing cool! andelleciug. WeERIST 0887276 stead plo ok oe Benrans loyev wer feud ® contain 0125 Of « avd co-efficient ov pavhou Co-eFfcied loo m of txt layer contain 0-225 of x Cel. ine nse dithitadsos coe tticieut 2 aamed ie enc of X m benzene (Cy, z OAR S003 9 mi! ; te conc of IM Wake to) = oa . Se 0002 gm" A covouy destrthtion Gaw, Cy ed ols 4 orco2 CQL: Tithe distoibubion oF Auccini® Acid bles Cher and corkiv aici Romcef etrevedd Payev conta o.0q2 9 ef acid. Find cat the clef te acid proed 5 iy Somt ef tre aqyrecus solution iy euciliniceny wit fe the ctigtnibubiew co-efficient for ducemic_ acd blo eatiy ethev th Se2- ds Let the Gt -°F Auceinic ackd PH Aayrecy Dosey be 9 Cone: agqueny Loy = wm g mt’ semew 82 345 6 7 MARCH 9 1011 12 13 14 16 17:18 19 20 21 SATURDAY 2324 25 26 27 28 30 Wee 20275 onc: } = 01092 - cere: Mm etueveal layey : 1 aor! © ee ae Xx . Ceoehen oe - _ ——__ by 20" a Cethey ooqe - 2 2 he Sox 0-04 AZ _SEeSOK OroV2 2 felqey Ge Lek, a [ c Ss. Chee Saud Sp ae the bea lihen ap eRe sake tre tuo solvent, 7 Sclalsliing eyo verenwtg conch vation) Efi Ab ose an oy Selebioy PED eB Containing arose gar! Asi _squili Loren aly See & ty Sdlafion eaten any ht The Sctubiliby of fedtme Fu woot a 2sc_is 0249 pif! fud the be ability of 08% mq cog Che aah _— kp cone: OF Jo} P conker Gyo) = 00816 9 git! cone soe 5 hee Clatqe) = Anetra pet! by Calcwlabion of Aolubilily . Get Fy is Ce OY Mila; Te iw yOEx Pleads ou OF clithoc ¥i2829 30 3) 0 “23 24 25 26 LESS sunny |! = EER 3276 Aon lacs Af enuiltbaun the Numb of maleculy of % PrrBing fven, Soluemt A inty BR th proportional to 4 conceuttation fia A and MIG versa? Ales, the vale of migrrtion of solute ~2 ard Bt A TH equals R he fener Ry = Nake of migrahen of KAvorn Ate & Rue ey Cy (te = comand) RekG Pyaveteee mordionl DOIG awe ()) molecales fyem Ate MONDAY % yes From BA (Wvezxerg| osz7273 Ro = ke Ch (te = contbet) - th sing Bince ab eauililorium Rye My DIG = Meg as G ob kK | HO _ enitetions s (The ‘Ta kept constant Hhvouggat sta ergorienet 8 BOE the Aalete Undrgers idociahon oY adbocahou the diceibubion lec ne longer hells geod: id @ The cones of the helat Srofed efter the equiliboiium bes been establish @ he Aisredbubor law valid only Sr dilufe cubs Be none misabilily of seluenty +FsiM i one ie 2018 amy at 15 (67 8 TUESDAY 15 16 0 19 2 2 22:23 24 2% 2B pa ¢ 28 29 30 31 CIFIED prisTRi@utiond Law es Nernat thet Cie; © conant oy if the oct by G0 the solute belvents « palvents ‘it b found ear po Aolude ex ish 4 — pivnple enolecales im undergoes abieciahon ey Association % one of the 3s nol constarte Tnlhese Cares, the ciclethuhon lac applies dimple moleciler the “wo sthet ley de that part of the Aolate which present as Naso Rat tou No change eo hen Adlut andevgou 4 present on pimple Solvent A Suppo The Aotetion ty moleccler X fn belvent A - Fr Solved By nm arociate 4o form xX, refeceles, th nx =x, nefeceter Of ¥ Absuming that a foo ng le mole cales % ave ale praret fn suet B tue enwilibova nat extch tn the to selvewh ave Aha 'n fy APRIL. cone of xt Advent A 201 weonespay WEERA 094/271 Arlvenk & DistMbution Ategiam chen The am than folete Th arseciated tor ovr solvent colverd 8 Aasociation Lat q be fhe (abe the emcek Im @ be the Conc eh Xy m fluent 3 Applying dstoihwbon tew de th eauillegien Xin Solvent AS Xm solve B we howe 6 ine flakes = 49 3 Applyivg regs law b te Chemical equilibotum ny = x= A On ie ov re}1415 16 17 18 19 (20) 21 22 23 24 25 26 (27, LD hil En Fi . 28.29 30 31 wes 5270 UJ) Thus, chon cuseciahion occurs mone Aclved tne dutribebioy co modifedn Gu Cae Ko @ chen pelute undergees iocttioy Serppore the Adlute present or novmeR, molecular xin aclyent A andi disseciates~into A+bin Solvent B. The equilibela get-up 4 Pa toa soo. Aclventy ave chown inte Sig. X =Aty Let cy be the concentration of xfn achent A ad @ be the tote concartration & «(Aisociaded undigsociate®) ay aclven! g - TS 2018 ar 06 Selveut A sven! Dierodiahoy FRIDAY 1K x on Ss p F - in the cheqvee of (WEEKI14) 036/269 CoC -%) ax Gu dintodidion 44 duet Q G An-4), ie the concentration fF UNdiAseciuted moleculerin Aolvent @ Arrlding distribution lew, G1. gi) A care of ths type ayise In the distetibution of a aate aie G3 succinic Aad ov oxalic add) blip etev am citer e C 2G cum be cetevmined by Aivect titration of the hoo layers against Alandevd alia’? Sélution., The Velecof 7. Can be feund by meosunteg letnica® conductance of the AMdafioy t Avert yTt > oy o 1 2 sAtunee: 49 20S uses stein pp veaction 1 rw Ba 2 yais 6 17 18 19 [20 ? 78 29 30 a = corslant for de 0 oe peteverinalio ™ mg me Kew a of squcilibeosicny aes eo MP Le solvent - Garhi betion “Tang hetps mm chetewnin ane veackants % bein foe tram in cbt for instante» klt+L = wa Gun be Caried ak Mm ealar, Anile jodine tx soluble on tolabl hell, eatin and berpons- protons: cp Te Bedeck be Hin olen an® bevsant tae haven 2 he concentyabion %F J. ites layews Ss -thom pend thichuMphals Maken = Thus doSbedion coethctent of Tp + Ta“ bottle. detexminad hy Fitrfion, seat then 08 SUNDAY cone: Of Ds in onl = Ke cone. ef Tp. ™™ bengeut. stra Veber ot K- Oe fren me evulliiw canine at A pluion OF 1S of Concunbeaion’ a? 2018 ae 09 ina fooltle. Fotnin add wea oan yer «id Ty ttl E vzs js Ahaiceu Hh Lo home bengaus 9 Phale-es OF stoning thee enincture seporeter Po poo laquws Ane eesti ria. ttnak awe feb ep ave Shown fate Re Te concentvation of Ty te determined hy . in The te leyews by Athcbow against shuBard © tricnwtphate dotesion Let 'b’ bethe cone-of Tz m bergene layer, ‘che the cone of Ip Mn wilir Gaye Ahich le ' veely. the toh FE Teneo at, Concotyation of freed, & ITs Ths = tone oF Tz Wn wey 2 Cre OT, i benzeur eae tt Tater) tr wily Layers Kxb 2 KK a. we, Conc. OF kets fr eather Dayey = CHI (cone. ef Ein aeter Sayer = a —(c. me = —(c- eb) = a-CtKLM 12 3 4 5 8 7 8 9 1011 1289 er A 1415 16 17 18 19 20 21 22 23 24 25 26 27 2018 TUESDAY Y 2829 30 31 (WOEEKGS] 100766 We Can row Seay thet the eguilibsium constant ofthe veachou Tae ker SS ict, woe hes tte (J J canc+eb) (eb) Sinay ett te quantitin on the Vighthen®d 81 Con be colewlated. Paes de ave Kream, the Appkation of distoubuhon (20+ rem owe numeveus appheetiens of distribution Daw tn te Labevadovy as Well od iy tacshy, QD. Selvent exhachow 5 rt js tne procenf used fey The Aeparehon of erganic Aabstances from aguects 6oludions. Zn a seprvedery fennel “the aquest bc\ukion fs shaven cotth an _vamiscible ovganie Advent ach 04 eh ov bengont. Mest ef the ovganie pubstance pastes inte the ethereal Lager dus 42 nen ndurg. APRIL The efisverl Qoyer TH sepevdd aD ether 2cis WEDNESDAY 11 BHIEd — offweratlBin Ayorrhien oF agente falgfence- ) porttion _ Chemetsgy 2 TINS is @ modern Techniqte. 4 mivture of Pgente Aubstancs Cou be separated cut. A porte of the mixhue is o Tn adding stove ep suspension hich tums blue. A grealey serethut, can be Cbtaied by Using chat we may Call ‘Dishibution Traietev’. A few Svops tf an tmmiscible evgonie sdvent such oy cHely (ev cele) is added.to te SPAY The belie of ony Ncdue Preeat poses Thte the ovganic Leer ane Bmparb APRIL eois MONDAY “on 6! WEEK 16, 105/259 fatemse viele cstey tovt.