CHEMISTRY -InterPart-2 2010 4. Circle the correct option. 1) Mark the correct statement from the following about the properties of elements in periodic table. a. Melting point of halogens first increases and then decreases down the group b. The ionization energy of calcium is higher than that of beryllium” c. Covalent character of metal halides increases from left to right in a periodic table d. Lu is bigger in size than Ce , 2) Lithium is the first member of group 1.4 of the periodic table, yet it shows deviation in physical properties from other members of its own family 17 a) Its smaller size b) Absence of d orbitals for bonding c) Having one electron in its valence shell d) Having high charge density 3) Which of the following is the end product when Boric acid is strongly heated? a) B,O, b) H,B,0, c) H,BO, 4) Sulphur forms three different compounds with chlorine. The type of hybridization shown by sulphur in SOF, .....0...2.. a) SP? D) Bid ete) SPY pe BSP Bie 5) Halogen acids act as reducing agents. Choose from the following the CORRECT order of reducing power’of these acids. a) HF > HCI < HBr < Hi b) HF < HCI < HBr < Hi HCI > HBr > Hi d) HF < HCI < HBr> HI 6) Which of the following compounds forms trigonal bipyramidal shape? ay 203 ins chee / eK | | F oe A ie B Fa Nay —f— Wy ch NHS ce WH, Nity ; oe c. iP ‘ I Seal ee Moa, ai ah Son ek “4 et 7) In isomerism, compounds have same molecular formula, but different structures. The possible isomers formed by pentane are ............ a) Five b) Four c) Three d) Two 8) Choose from the following the catalyst which is used for the partial hydrogenation of alkynes to form trans alkenes. a) £2. He(SO,) Quinoline cy) PE (Ba SO,) Quinoline 9) Which of the following compounds will be sulphonated most readily? a) Toluene b) Benzene c) Aniline d) Chiorobenzene 10) The rate of SN, mechanism depends upon ......... a) The concentration of nucleophile b) The concentration of substrate c) The concentration of substrate and nucleophile d) The concentration of catalyst 11) Alcohols react with con.H,SO, and give different products. What is the product as a result of the Equation 2C,H,—OH Conc.i7,SO, = b Pb (Hg SO,) Quinoline d) Na! Liquid NH, 140°C a) CH, =CH, b) CH, -—CH, ce CH.=0-C,F, d) CH=CH 12) Which of the following reagents will react with both aldehydes and ketones? a) Grignards reagent b) Tollen's reagent c) Benedict's reagent d) Fehling’s reagent 13) Given the genera! reaction: R-CH, —OH +[o) 9 —_> x el yz Select X, Y and Z from the following set of products: _ x ¥ | Dire aces A co, Alcohol Carboxylic acid B Aldehyde Carboxylic acid co, S Alcohol Aldehyde =: ie 5 5 None of these ae rock i oe, Alcohol Carboxylic acid B °-Aldehyde © Carboxylic-acid OE C i Alleohal., Abdel ess D oye 94) Which othe flowing the, the CORRECT formula ? oe of 1 cH, dat sinotieq 6M oa 8. aia vd aco 45) Which of the followingis pon-caiczrious? a) kime- b) Lime stone c) Sea shélise.d) rie drinking water? 16) Which of the disinfeets* #)PNH,CIrY by He] © ce) HOCT “dy NH,OH 17) Which of the following isan slectrophile? a) A,°0," b) H, ae c).c4, d) BF, 2. Attempt any 14 parts. A2 1) Oxidation state Is the charge which an.element ~ carry in the compound,. a. On what is different in ionic and covalent. compounds basis it, b. On what factors does.oxidation state of typical elements depend? _6. Transition elements show more than one "oxidation state. Why? 2) NaOH is prepared on large scale by the electrolysis of aqdéous solution of sodium chloride. a. What two problems are faced by a chemist this process? hea first problem being solved by chemist? ~ 3) Carbon and silicon belong to the same group of 1V.A of the periodic table. a. Why should there be a big difference in CO, and silicon dioxide? b. How is viterious silica formed from SiO, ? 4) Nitrogen forms two oxyacids. [ Draw electronic structures of these two acids and write their names. b. Zinc combines differently with one of the above mentioned acids depending upon the concentration of an acid. Write equations for the reactions between Zine and that acid when: i) Acid is very dilute ii) Acid is very concentrated 5) Keeping in view the systematic rules for the nomenclature of oxyacids: a) Name the following: t HCIO, HCIO,, HEIO,, HC!IO, b) What is iodized salt? Why is it used in diet? 6) a. What is Paramagnetism? b. What is the cause of Paramagnetism? 7) The quality of gasoline is ‘improved by the process called Reforming. a. What happens when the spark plug fire ignites low quality gasoline in the engine of automobile b. How is the octane number of n-octane improved. €. Write the formula of T.E.L. 8) Halogenation is believed to proceed through free radical mechanism in alkanes. a. Write the names of steps involved in this process with examples. b. Complete the conversion of CH, —C/ to CCI, during one of the above steps in detail. 9) Complete the following using given hints: a. Propene aM 1 POE cy Alchokolic b. Propyne—“*>? c. Ethane —» Ethene — Ethyne 10) Nitratation of benzene takes place as follows: : NO, (oO) +HNO, _ng._{O) +H,0 a. Which is the nitrating agent & how it is generated b. Write complete mechanism for the above conversion upto the formation of nitrobenzene. 11) Alkyl halides are considered amongst the most reactive class of organic compounds. Consider the equation: Base eee ee (Cee ee (CH), -€ Polar Solvent (CH), a. Suggest the name and mechanism involved for the above conversion. b. What will happen to the configuration of alkyl halide during the process? c. Write rate equation for this reaction. 42) Ethanol is prepared on industrial scale world over. a. Name the process, temperature and enzymes used _ for the above process, when ethanol is prepared from the residue of sugar with.equations: » ~, bd. wer ee 13) Thovaactions ‘in which two molecules combine + to form new compounds with or without elimination of a small molecule is called® a. What type of condensation will be shown by i) CH, —GHO: il) C;H,+CHO _b.. Write.chemical equation along with mechanism for the conversion of CH, — CHO into products. 14) Esters formed-carboxylic acids give different flavours. What type of flavours is given by Amylacetatey| Isobuty! formate and Benzylacetate. 15) Polymers have animportantutitity imour daily fe. a. How is the molecular mass’efithe polymers - determined? Give an example: b. What type.of polymerization: is: shown. by the mutual reaction of two functional yet Give example. 16) Proteins are complicated molecules of living organism. How many levels of structural are shown by proteins?, - Explain by drawing structures if any... 17) What is Smog? Which, pollutants are the main cause of smog? Explain. 18) Gonents is an extraordinary stable molecule. Justify the truth with the help of example. _19) What is modern periodic law? ' “Write briefly about blocks in the periodic table. Attempt any TWO questions. 26 d) HBO, 3. Nitrogen and phosphorous belong to the group V.A of the periodic table. a. Write down the names and draw molecular structure of any two allotropic forms of US. What major properties are shown Which is the most stable one. - b. Phosphoric acid converts itself into other acids “». 3@n-heating: Write down the names of products >and equations of this conversion.- ." P,O,is strong dehydrating agent”. Prove this statement giving examples. 4-Lipids are essential for the growth of animals. a, i). What are Lipids? : __ Write their main characteristics. fi) How are these lipids classified? Draw the . structure and composition of fats and oils. 'b. Describe the reactions between carbonyl with the following compounds: i) 2,4~DNPH]: ii) NH, — NH, ? 3 3 6 Also mention general mechanism for their ientiekin 5. a) Define Reasonance. Draw all the possible resonating structures shown by a benzene. What structure would you suggest best for iting benzene? 6 5. b) Write structural formuta of the following __ compounds and name them a¢cording to 1.U.P.A.C. system of nomenclature: i) T.N.T. ii) Chloroprene iii)Mustardgas 3 5. c) How will you bring about the conversions? 4 i) Propanone into 2 —Propanol ii) Ethanol into Ethanoic acid