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JEE MAIN ONLINE

EXAMINATION - 2017

QUESTION WITH SOLUTION

Test Date : 8 April 2017


JEE Online Paper _ Date [8-4-2017] (Page # 1)
[MATHEMATICS]
1. If ( 27)999 is divided by 7, then the remainder is :
(1) 3 (2) 1 (3) 6 (4) 2
Sol. 3
999
 28  1 28  1 28  7  1  1 7  4  1  6
=  =
7 7 7 7
 Rem =6

 0 cos x  sin x 
   
S   x  0, 2  : sin x 0 cos x  0 
2. If
 
, Then  tan  3  x 
 cos x sin x 0 
xS

(1) 4  2 3 (2) 2  3 (3) 2  3 (4) 4  2 3


Sol. 2
0(0 – cosx) – cosx(0 – cos2x) – sinx (sin2x – 0) = 0
cos3x – sin3x = 0
tan3 = 1  tanx = 1
3  tan x
 1 3

3 1 1 3 1 3  2 3 42 2 3
 1 
3 1 3
  2
=  2  3

 2  3

3. Let A be any 3 × 3 invertible matrix. Then which one of the folliwing is not Always true ?
(1) adj(adj(1)) = |A|2 . (adj(1))–1 (2) adj(adj(1)) = |A|. (adj(1))–1
(3) ajd(adj(1)) = |A|.A (4) adj(1) = |A|.A–1
Sol. 3
See theorey

 1  x 2  1  x2 
 , x  1 , x  0 , is equal to :
1
4. The value of tan  2 2
 1  x  1  x  2

 1   1 
(1)  cos 1 x 2 (2)  cos 1 x 2 (3)  cos 1 x 2 (4)  cos 1 x 2
4 2 4 4 2 4
Sol. 1
1
x2 = cos2 ;  = cos x 2
2
 1  cos 2  1  cos 2 
tan 1  
 1  cos 2  1  cos 2 

1  tan  
tan 1 
1  tan  

1   
= tan  tan     
  4 

 1
=  cos x 2
4 2

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5. The area (in sq. units) of the parallelogram whosed diagonals are along the vectors 8iˆ  6jˆ and

3iˆ  4ˆj  12kˆ , is :


(1) 20 (2) 65 (3) 52 (4) 26
Sol. 2
i j k
8 6 0
d 1 × d2 =
3 4 12

= 72iˆ   96  ˆj  50kˆ


= 5178 + 7056 + 2500
d1  d 2 = 16900 = 130
1 1
A= d1  d 2 =  130
2 2
= 65


4
8cos 2x
6. The integral   tan x  cot x 

3 dx equals :
12`

13 15 13 15
(1) (2) (3) (4)
256 64 32 128
Sol. 4


4
cos 2x 4

 1 
3
=
2
 cos 2x  sin 2x.sin  2x  dx

12  
 sin 2x  12

1
= sin 4x. 1  cos 4x  dx
4


4
14
=  sin 4x –
4
 sin 8x

12
12

7. Let z  C , the set of complex numbers. Then the equation, 2|z + 3i| – |z – i| = 0 a circle with
8
radius .
3
8 16
(1) a cirlce with radius (2) an ellipse with length of minor axis
3 9
16 10
(3) an ellipse with length of major axis (4) a circle with diameter
3 3
Sol. 1
2 x  i  y  3  = x  i  y  1

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2 2
= 2 x 2   y  3 = x 2   y  1
= 4x2 + 4( y + 3)2 = x2 + ( y – 1)2
= 3x2 = y2 – 2y + 1 – 4y2 - 24y – 36
= 3x2 + 3y2 + 26y + 35 = 0
26 35
= x2 + y2 + y + =0
3 3

169 35
=r= 0 
9 3

64 8
= =
9 3

8. If the um of the first n terms of the series 3 + 75 + 243 + 507 + ...... is 435 3 , then n
equals :
(1) 13 (2) 15 (3) 29 (4) 18
Sol. 2
3 1  25  81  69  ...... = 435 3
 
3 [ 1 + 5 + 9 + 13 +.....Tn] = 435 3
n
= 3   2   n  1 4  = 435 3
2
2n + 4n2 – 4n = 870
= 4n2 – 2n – 870 = 0
= 2n2 – n – 435 = 0
1  1  4  2  435
n=
4
1  59
=
4
1  59 1  59
= = 4;
4 4

9. The tangent at the point (2,–2) to the curve x2y2 – 2x = 4(1 – y) does not pass through the
point :
 1
(1) (–2,–7) (2) (8,5) (3) (–4,–9) (4)  4, 
 3
Sol. 1
x2y2 –2x = 4 – 4y
dy dy
2xy2 + 2y.x2. –2 = – 4.
dx dx
dy
dx
 2y.x 2  4  = 2– 2x.y2
dy 2  2 24 14 7
dx = 2  2   4  4 = =
2, 2 12 6

7
(y + 2) =  x  2   7x – 6y = 26
6

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10. Let f(x) = 210dx + 1 and g(x) = 310x – 1. If (fog)(x) = x, then x is equal to :
210  1 1  210 310  1 1  310
(1) (2) (3) (4)
2  310
10
310  210 3  210
10
210  310
Sol. 2
f(g(x)) = x
f(310x – 1) = 210(310.x – 1) = x
1
=
310  2 110
210(310x –1) + 1 = x
x(610 –1) = 210 – 1
210  1 1  210
x= =
610  1 310  210

11. The proposition (~p)V(P^~q) is equalvalent to :


(1) P ~q (2) P^~q (3) q  p (4) p v~ q
Sol. 2
(~p) V ( P ^ ~q)

p q ~ p ~ q p^ ~ q  ~ p  v  p^ ~ q 
T T F F F F
T F F T T T
F T T F F F
F F T T F F

12. If all the words, with or without meaning, are written using the letters of the word QUEEN and
are arranged as in English dictionary, then the position of the word QUEEN is :
(1) 47th (2) 45th (3) 46th (4) 44th
Sol. 3
E,E, N, Q,U
(i) E......... = 24
4!
(ii) N ......... =  12
2
(iii) Q E........ = 3! = 6
3!
(iv) Q N ......= =3
2!
(v) Q U E E N = 1
Total = (i) + (ii) + (iii) + (iv) + (v) = 46th

13. The curve ssatisfying the differential equation, ydx – (x + 3y2)dy = 9 and passing through the
point (1,1), also passes through the point :
1 1  1 1 1 1 1 1
(1)  ,   (2)   ,  (3)  ,  (4)  ,  
4 2  3 3 4 2  3 3
Sol. 2
ydx – xdy – 3y2 dy = 0
dx x
=  3y
dy y

dx x
 = 3y
dy y

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1 1
I.f. = e   y dy = e–lnyy = y

 solution is
x 1
 3y. dy
y  y

x
y
= 3y + c

pass through (1,1)  1 = 3 + c ; c = –2


x = 3y2 – 2y
1 1 1 3
(i)  ,   =   1
 4 2  4 4
1 1 2 1
(ii)    = 
3 3 3 3

14. An unbiased coin is tossed eight times. The probabiity of obtaining at least one head and at
least one tail is :
127 63 255 1
(1) (2) (3) (4)
128 64 256 2
Sol. 1
1   P  All Head   P  All Tail 

1 1
1  8  8 
2 2 
1
= 1
27
1 127
= 1 =
128 128

15. If the arithmetic mean of two nubers and b,a, > b > 0. is five times their geometric mean,
ab
then is equal to :
ab

7 3 3 2 6 5 6
(1) (2) (3) (4)
12 4 2 12
Sol. 4
ab
 5 ab
2
ab
= 10
ab

a 10  96 10  4 6
 = =
b 10  96 10  4 6
Use C and D
ab 20 5 5 6
 = =
ab 8 6 2 6 12

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3x  3
16. lim is equal to :
x3
2x  4  2

1 1 3
(1) (2) (3) (4) 3
2 2 2 2
Sol. 1
3x  3
lim
x3
2x  4  2
Rationalize

 3x  9    2x  4  2 
lim
x3
 2x  4  2   3x  3
3  x  3 2x  4  2
lim 
= x3 2  x  3  3x  3 
3 2 2 1
=  =
2 6 2

17. The locus of the point of intersection of the straigh lines,


tx – 2y – 3t = 0
x – 2ty + 3 = 0  t  R  , is :
(1) A hyperbola with the length of conjugate axis 3
(2) a hyperbola with eccentricity 5
(3) an ellipse with the length of major axis 6
2
(4) an ellipse with eccentricity
5
Sol. 1
tx – 2y – 3t = 0
x – 2ty + 3 = 0

2 2
tx – 2y – 3t = 0 t x – 2ty – 3t = 0
2
tx – 2t y + 3t = 0 x – 2ty + 3 = 0
+ – – + –
2 2 2
y(2t –2) = 6t (t -1)x = (3t + 1)

6t 3t
y = 2
2 x = – 3sec2
2t  2 t 1
2y = 3(–tan2)
sec22 – tan22 = 1
x 2 y2
 =1
9 9/ 4
a2 = 9 ; b2 = 9/4

2 9/ 4 1 5
(T.A) = 6 ; e  1 = 1 ; e e 
9 4 2

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15 15 d2 y dy
If y   x  x  1  + y   x  x  1  , then (x2 – 1) 2  x
2 2
18. is equal to :
    dx dx
(1) 224y2 (2) 125y (3) 225y (4) 225 y2
Sol. 3

 
15 15
2
y = x  x 1  x  x 2 1 
14  x 
dy
dx
= 15 x  x 2  1  15  x 
14
x 2 1  1 


x2  1 

dy 15
 .y ...(i)
dx x2 1
dy
x 2  1. = 15y
dx
x dy d2 y dy
+ . x2  1 15
2 =
x  1 dx
2
dx dx

dy d2 y 2 15
x   x 2  1 2 = 15 x  1. 2 .y = 225y
dx dx x 1

19. The area (in sq. units) of the smaller portion enclosed between the curves, x2 + y2 = 4 and
y2 =3x, is :
1 4 1 2 1  1 2
(1)  (2)  (3) _ (4) 
3 3 3 3 2 3 3 2 3 3
Sol. 1
x2 + 3x – 4 = 0
(x + 4) ( x – 1) = 0
x = – 4, x = 1
1  1 1
 2
2

Area =   3. xdx  +    3. xdx   4  x .dx   2
0  00 1 
y2 = 3x
  x 3 / 2 1  x 2 
=4
1 x 
2

 2 y
3
=   3/ 2   2 4  x  2 sin   2 2 +
0  2 1  x
  

  2     3    
1 2
=  3  3    2. 2   2  3     2
       

 2 3 2 
   2
 3 2 3 

 1 2  1 4
=   2 = 
2 3 3  3 3
d

20. If the common tangents to the parabola, x2 + 4y and the circle, x2 + y2 = 4 intersect at the
point P, then the distance of P from the origin, is :

(1) 2  2 1  (2) 3  2 2 (3) 2 1 


(4) 2 3  2 2 
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Sol. 4
tangent to x2 + y2 = 4
y = mx ± 2 1  m 2
x 2  4y

x2 = 4mx + 8 1  m 2

x2 = 4mx – 8 1  m 2 = 0
D=0
16m2 + 4.8 1  m2 = 0 y

m 2  2 1  m2  0
or m 2  1  m2
m4 = 4 + 4m2
m4 – 4m2 – 4 = 0
x
4  16  16
m2 =
2

44 2
= P
2
m2 = 2  2 2

21. The line of intersection of the planes


 ˆ ˆ ˆ
 
r. 3i  j  k  1 and
 ˆ ˆ ˆ
r.  i  4j  2k   2 , is :

6 5 4 5
x y x z
(1) 13  13  z (2) 7  y  7
2 7 13 2 7 13

6 5 4 5
x y x z
(3) 13  13  z (4) 7 y 7
2 7 13 2 7 13
Sol. 3
  
n  n1  n 2

ˆi ˆj kˆ
3 1 1
1 4 2

= ˆi(2)  ˆj(7)  k(13)


ˆ

n = 2iˆ  7ˆj  13kˆ


Now
3x – y + z = 1
x + 4y – 2z = 2
but z = 0
3x – y = 1×4
x + 4y = 2
13x = 6 x = 6/13

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y = 5/13
.... is
x  6 /13 y  5 /13 z  0
 
2 7 13
or
x  6 /13 y  5 /13 z
 
2 7 13

22. If a point P has co - ordinates ( 0,–2) and Q ia any point on the circle, x2 +y2 – 5x – y + 5 = 0,
then the maximum value of (PQ)2 is :
47  10 6 25  6
(1) 8  5 3 (2) (3) 14  5 3 (4)
2 2
Sol. 3
25
(x –5/2)2 +(y -1/2)2 – 1/4 + 5 = 0
4
= (x – 5/2)2 + (y –1/2)2 = 3/2
1
on circle Q = 5/2 + 3/ 2 cos Q, 2  3 / 2 sin Q

2 2
5  5 
PQ2 =   3/ 2 cos Q  +   3/ 2 sin Q 
2  2 
25 3
PQ2 = + + 5 3/ 2 (cos Q + tan Q)
2 2
= 14  5 3/ 2 (cos Q  sin Q)

manmr = 14  5 3 / 2 ( 2)
= 14  5 3

23. The mean age of 25 teaches in a school is 40 years. A teacher retires at the age of 60 years
and a new teacher is appointed in his place. if now the mean age of the teachers in this school
is 39 years, then the age ( in years ) of the newly appointed teachers is :
(1) 35 (2) 40 (3) 25 (4) 30
Sol. 1
x1  x 2  ...  x 25
= x  40
25
x1 +x2 + ... + x25 = 1000
x2 + x2 + ...+ x25 – 60 + A = x  25
1000 - 60 + A = 39 × 25 = 975
A = 975 – 940 = 35

24. Let p(x) be a quadratic polynomial such that p(0) = 1. if p(x) leaves remainder 4 when divided
by x – 1 and it leaves remainder 6 when divided by x + 1, then :
(1) p(–2) = 19 (2) p(2) = 19 (3) p(–2) = 11 (4) p(2) = 11
Sol. 1
p(x) = ax2 + bx + c
p (0) = 1 = c = 1
p(1)  4 
p(1)  6 
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a  b  c  4 a  4 

a  b  c  6  b  1
p(x) = 4x2 – x + 1
p(–2) = 16 + 2 + 1 = 19

25. consider an ellipse, whose centre is at the origin and its major axis is along the x - axis. if its
3
eccentricity is and the distance between its foci is 6, then the area ( in sq. units ) of the
5
quadrilateral inscribed in the ellipse, with the vertices as the vertices of the ellipse, is :
(1) 32 (2) 80 (3) 40 (4) 8
Sol. 3
e = 3/5, 2ae = 6, a(5) a = 5
b2 = a2 (1–e2)
b2 = 25 (1–9/25) b
a
b=4

area = 4 (1/2 ab)


= 2ab = 40

26. If two parallel chords of the a circle, having diameter 4 units, lie on the opposite sides of the
1  1 
centre and subtend angles cos   and sec–1(7) at the centre respectively, then the distance
7
between these chords, is :
8 16 4 8
(1) (2) (3) (4)
7 7 7 7
Sol. 1
cos 2Q = 1/7 = 2cos2Q – 1 = 1/7
= 2 cos2Q = 8/7
cos2Q = 4/7
cp 2 4
= =
4 7

4
= Cp =
7

1
sec2Q = 7 = 7
2
2 cos Q  1
2 p1
 Cp 2  1
= 2  1  7
 2  Q 2
r
2
 Cp 2  8 2
= 2   Q1 Q1 2
 2  7
p2
4
= Cp2 
7

4 4 8
 =
7 7 7

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27. The number of real values of  for which the system of linear equations
2x + 4y – z = 0
4x + y + 2z = 0
x + 2y + 2z = 0
has infinitely many solutions, is :
(1) 3 (2) 1 (3) 2 (4) 0
Sol. 2
 0

2 4  2 4
4  z 4 0
 z 2  z
= – (32 + 8 –  3) = 0
=  3 + 4  – 40 = 0
=

28. The coodinates of the foot of the perpendicular from the point (1, – 2,1) on the plane contain-
ing the lines,
x  1 y 1 z  3
  and
6 7 8
x 1 y  2 z  3
  , is :
3 5 7
(1) (2, – 4, 2) (2) (1, 1, 1) (3) (0,0,0) (4) (–1, 2, –`=1)
Sol. 3
n  n1  n 2

ˆi ˆj kˆ
6 7 8
=
3 5 7

= (9, –18, 9)
= (1, –2, 1)

1(x+1)–2 (y–1) + (2–3) = 0


= x  2y  z  0
foot to z
x 1 y  2 z 1 [1  4  1]
= = =
1 2 1 6
x  0, y  0, z  0
10,000

29. Three persong P, Q and R independently try to hit a target. If the probabilities of their hitting
3 1 5
the target are , and respectively, then the probability that the target is hit by P or Q
4 2 8
but not by R is :
39 21 9 15
(1) (2) (3) (4)
64 64 64 64

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Sol. 2
 3   1   3   1  1   3   3  1  3 
      +          
 4   2   8   4  2   8   4  2  8 
12  9
=
64
27
=
64

 
30. The integral 1  2cot x  cos ecx  cot x dx  0  x   is equal to :
  2
(where C is a constant of integration )
 x  x  x  x
(1) 2log  sin   C (2) 4log  sin   C (3) 4 log  cos   C (4) 2 log  cos   C
 2   2  2  2
Sol. 1
 2 cot x cos ecx  cos ec 2 x  cot x  dx
  

 cos | x  cot x | dx
 (cos ec  cot x)dx
 cos ec dx
2log(log(x 2 )  c

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[PHYSICS]
1. A compressive force, F is applied at the two ends of a long thin steel rod. It is heated, simultaneously,
such that its temeprature increass by T. The net change in its length is zero. Let l be the length
of the rod, A its area of cross-section, Y its Young's modulus, and  its coefficient of linear
expansion. Then, F is equal to -
AY
(1) lA Y T (2) A Y T (3) (4) l2 Y T
T
Sol. 3
Net change in length = 0
Thermal Exp. = l  t
F/A
y=
l / l

l F
=
l Ay

Fl
l =
Ay

Fl
= l  t
Ay
F = Ay  t

2. A potentiometer PQ is set up to comapre two resistances as shown in the figure. The ammeter A
in the circuit reads 1.0 A when two way key K3 is open. The balance point is at a length l1 cm from
P when two way key K3 is plugged in between 2 and 1, while the balance point is at a length l2 cm

R1
from P when key K3 is plugged in between 3 and 1. The ratio of the two resistance R , is found
2

to be -

A E2 Rh2 K2

R1 2 3
R2
K3
G 1

P Q

E1 Rh1 K1

l1 l2 l1 l1
(1) l  l (2) l  l (3) l  l (4) l  l
1 2 2 1 1 2 2 1

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Sol. 1
When key is at point
V1 = iR1 = xl1
when key is at (3)
V2 = i (R1 + R2) = xl2
R1 l1
R 1  R 2 = l2

R1 l1
R 2 = l2  l1

3. A signal of frequency 20 kHz and peak voltage of 5 volt is used to modulate a carrier wave of
frequency 1.2 MHz and peak voltage 25 volts. Choose the correct statement.
(1) Modulation index = 5, side frequency bands are at 1400 kHz and 1000 kHz
(2) Modulation index = 0.8, side frequency bands are at 1180 kHz and 1220 kHz
(3) Modulation index = 0.2, side frequency bands are at 1200 kHz and 1180 kHz
(4) Modulation index = 5, side frequency bands are at 21/2 kHz and 18.8 kHz
Sol. 3
Vm
Modulation idex = m = V
0

1
= = 0.2
5
Frequency = 12 × 103 kHz
F = 12.00 kHz
F1 = 1200 – 20 = 1180 kHz
F2 = 1200 + 20 = 1220 kHz

4. A single slit of width b is illuminated by a coherent monochromatic light of wavelength . If the


second and fourth minima in the diffraction pattern at a distance 1 m from the slit are at 3 cm and 6
cm respectively from the central maximum, what is the width of the central maximum ? (i.e.,
distance between first minimum on either side of the central maximum)
(1) 4.5 cm (2) 1.5 cm (3) 6.0 cm (4) 3.0 cm
Sol. 4
min.
f sin  = n
n
sin  =
6
n=2
2 x
sin  = = tan 1 = 1
6 D
x=4
4 x
sin 2 = = 2
6 D

4 2 2
x 2 – x1 = – = = 3 cm
6 6 6

2
width of central max = = 3 cm
6

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5. A 1 kg block attached to a spring vibrates with a frequency of 1 Hz on a frictionless horizontal


table. Two springs identical to the original spring are attached in parallel to an 8 kg block placed
on the same table. So, the frequency of vibration of the 8 kg block is -

1 1 1
(1) 2 Hz (2) Hz (3) Hz (4) Hz
4 2 2 2
Sol. 4

1 k
F= =1
2 m

k m=1kg
42 = m= 1
m
k = 42
In parallel keq = 2k

1 K2
F=
2 8 k
1 8kg
= Hz
2

6. A magentic dipole in a constant magnetic field has -


(1) maximum potential energy when the torque is maximum
(2) zero potential energy when the torque is maximum
(3) zero potential energy when the torque is minimum
(4) minimum potential energy when the torque is maximum
Sol. 2
PE = – PE cos 
 = PE sin 
max when  = 90°
PE = 0

7. If the earth has no rotational motion, the weight of a person on the equation is W. Detrmine the
speed with which the earth would have to rotate about its axis so that the person at the equator
3
will weight W. Radius of the earth is 6400 km and g = 10 m/s2.
4
(1) 0.63 × 10–3 rad/s (2) 0.28 × 10–3 rad/s
(3) 1.1 × 10–3 rad/s (4) 0.83 × 10–3 rad/s
Sol. 1
g' = g – 2R cos2 
3g
= g – 2R
4

g
w 2R =
4

g
w=
4R

10
=
4  64  103

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1
=
2  8  100

1 1
= = × 10–2 = 0.6 × 10–3
1600 16

8. An object is dropped from a height h from the ground. Every time it hits the ground it looses 50%
of its kinetic energy. The total distance covered as t   is -
5 8
(1) 2h (2)  (3) h (4) h
3 3

1 1 1
Sol. mv'2 = v2
mv
2 2 2

v
v' =
2
v = eu
1
e=
2

 1  e2 
H=  2 
1e 

 1 
1 2 
= h  1  = 3h
1 
 2 

9. The energy stored in the electric field produced by a metal sphere is 4.5 J. If the sphere contains 4C
charge, its radius will be :

1
[Take : 4 = 9 × 109 N – m2/C2]
0

(1) 32 mm (2) 16 mm (3) 28 mm (4) 20 mm


Sol. 2
Q2
Energy of sphere =
2C

16  10 12
4.5 =
2C

16  10 12
C= = 40R
9

16  10 12 1
R= × 4
9 0

16
= 9 × 109 × × 10–12
9
= 16 × 10–3 = 16 mm

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10. A uniform disc of radius R and mass M is free to rotate only about its axis. A string is wrapped
over its rim and a body of mass m is tied to the free end of the string as shown in the figure. The
body is released from rest. Then the acceleration of the body is -

M Wall

2Mg 2Mg 2mg 2mg


(1) (2) (3) (4)
2m  M 2M  m 2M  m 2m  M
Sol. 4
mg – T = ma
RT = I
MR 2 a
RT = .
2 R

Ma
T=
2

Ma
mg – = ma
2

M 
mg = a  2  m 
 

 M  2m 
mg = a  2 
 

2mg
a=
M  2m

11. An engine operates by taking n moles of an ideal gas through the cycle ABCDA shown in figure. The
thermal efficiency of the engine is - (Take Cv = 1.5 R, where R is gas constant)

B C
2P0

P0 P D
0
A

V0 2V0
V

(1) 0.24 (2) 0.15 (3) 0.32 (4) 0.08

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Sol. 2
w = P0V0
Heat given = QAB = QBC
= nCVdTAB + nCPdTBC
3 5
= (nRT
TB – nRTA) + (nRT
TC – nRTB)
2 2

3 5
= (2P0V0 – P0V0) + (4P0V0 – 2P0V)
2 2

13
= P0V0
2

w 2
n=
Qgiven = 13 = 0.15

12. Time (T), velocity (3) and angular momentum (h) are chosen as fundamental quantities instead
of mass, length and time. In terms of these, the dimensions of mass would be -
(1) [ M] = [ T–1 C–2h] (2) [M] = [T C–2h]
–1
(3) [M] = [T C h ]–2 –1 (4) [M] = [T–1 C2h]
Sol. 1
M  Tx vy hz
M' L0T0 = (T')x (L1T–1)y (M1L2T–1)z
M1L0T0 = Mz Ly+2z + Tx-y-z
z=1
y + 2z = 0 x–y–z=0
y=–2 x+2–1=0
x=–1
M  T–1 C–2 h1

13. In an experiment a sphere of aluminium of mass 0.20 kg is heated upto 150°C. Immediately, it is put
into water of volume 150 cc at 27°C kept in a calorimeter of water equivalent to 0.025 kg. Final
temperature of the system is 40°C. The specific heat of aluminium is -
(take 4.2 Joule = 1 calorie)
(1) 434J/kg-°C (2) 378J/kg-°C (3) 315J/kg-°C (4) 476J/kg-°C
Sol. 1
Q given = Q used
0.2 × S× (150 – 40) = 150 × 1 × (40 – 27)
+ 25 × (40 – 27)
0.2 × S × 110 = 150 × 13 + 25 × 13
13  25  7
S=
0.2  110
S = 434
14. There is a uniform electrostatic field in a region. The potential at various points on a small sphere
centred at P, in the region, is found to vary between in limits 589.0V to 589.8 V. What is the potential
at a point on the sphere whose radius vector makes an angle of 60° with the direction of the field ?
(1) 589.4 V (2) 589.5 V (3) 589.2 V (4) 589.6 V
Sol. 1
V = E.d
0.8 = Ed (max)
V = Edcos = 0.8 × cos 60
= 0.4
589.4

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15. Magnetic field in a plane electromagnetic wave is given by



B  B0 sin(kx  t) ĵ T
Expression for corresponding electric field will be

(1) E  B0c sin(kx  t) k̂V / m

(2) E  B0c sin(kx  t) k̂V / m

(3) E  B0c sin(kx  t) k̂V / m

 B
(4) E  0 sin(kx  t) k̂V / m
c
Sol. 3
E0
C=
B0
E = CB0
= CB0
= CB0 sin (kx + t) î

16. According to Bohr's theory, the time averaged magnetic field at the centre (i.e. nucleus) of a
hydrogen atom due to the motion of electrons in the nth orbit is proportional to :
(n = principal quantum number)
(1) n–3 (2) n–2 (3) n–4 (4) n–5
Sol. 2
0I
B=
2r

0qt
=
2r
r  n2
B  m–2

17. Moment of inertia of an equilateral triangular lamina ABC, about the axis passing through its centre
O and perpendicular to its plane is I0 as shown in the figure. A cavithy DEF is cut out from the lamina,
where D,E,F are the mid points of the sides. Moment of inertia of the remaining part of lamina about
the same axis is -

F E
O

A D B

15 3I0 7 31I0
(1) I (2) (3) I (4)
16 0 4 8 0 32

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Sol. 1
I0 = kml2 BC = l

2
m l
IDEF =K  
4 2

k
= ml2
16

0
IDEF =
16

I0
Iremain = I0 =
16

15I0
=
16

18. The maximum velocity of the photoelectrons emitted from the surface is v when light of frequency n
falls on a metal surface. If the incident frequency is increased to 3n, the maximum velocity of the
ejected photoelectrons will be -

(1) more than 3 v (2) equal to 3 v

(3) v (4) less than 3 v


Sol. 2
E1 = hn – 
E2 = 4hn – 
E2 = 3 (E1 + ) – 
E2 = 3 E1 + 2V

m0 x 3 y

19. What is the conductivity of a semiconductor sample having electron concentration of


5 × 1018 m–3, hole concentration of 5 × 1019 m–3, electron mobility of 2.0 m2 V–1 s–1 and hole
mobility of 0.01 m2 V–1 s–1 ?
(Take charge of electron as 1.6 × 10–19 C)
(1) 1.83 (-m)–1 (2) 1.68 (-m)–1
(3) 1.20 (-m)–1 (4) 0.59 (W-m)-1
Sol. 2
s = e (nee + nnn)
= 1.6 × 10-19 (5 × 1018 × 2 + 5 × 1019 × 0.01)
= 1.6 × 10–19 (1019 + 0.05 × 1019)
= 1.6 × 1.05
= 1.68

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20. The V-I characteristic of a diode is shown in the figure. The ratio of forward to reverse bias
resistance is :

1(mA)

20

15
10
–10
.7 .8 V (volt)

(1) 100 (2) 106 (3) 10–6 (4) 10


Sol. 3
0.1
f.B = l = 10
10  10 3

10
RB = = 107
10 6
fB
= 10–6
RB

21. Which graph corresponds to an object moving with a constant negative acceleration and a positive
velocity ?
Velocity

Velocity

Velocity

Velocity

(1) (2) (3) (4)

Distance time Distance time

Sol. 3
a = –C
VdV
=–C
dx
VdV = – CdX
V2
= – Cx + k
2

V2 K
x=– +
2C C

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22. A small circular loop of wire of radius a is located at the centre of a much larger circular wire loop of
radius b. The two loops are in the same plane. The outer loop of radius b carries an alternating
current I = I0 cos (t). The emf induced in the smaller inner loop is nearly ?

a2  0I0 a2
(1)  0I0  sin(t) (2) .  cos(t)
b 2 b

 0I0b2  0I0 a2
(3)  cos(t) (4) .  sin(t)
a 2 b
Sol. 4
e = MdI
 0a2
dT M=
2b

 0a2
= = I0 lt
2b

23.

A1
A2 A3
B V
9V

A 9 V battery with internal resistance of 0.5  is connected across an infinite network as shown
in the figure. All ammeters A1, A2, A3 and voltmeter V are ideal.
Choose correct statement.
(1) Reading of A1 is 18 A
(2) Reading of V is 9 V
(3) Reading of V is 7 V
(4) Reading of A1 is 2 A
Sol. 4

1
A
x 4 x
B
1

4x
x= +2
4x

8  6x
x=
4x
4x + x2 = 8 + 6x
x2 – 2x – 8 = 0

2  4  4(1)(8) 2  36
x= =
2 2

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26
= =4
2

9
A' = =2
4  0.5
A' = 9

24. Let the refractive index of a denser medium with respect to a rarer medium be n12 and its critical
angle be C. At an angle of incidence A when light is travelling from denser medium to rarer
medium, a part of the light is reflected and the rest is refracted and the angle between reflected
and refracted rays is 90°. Angle A given by -

1 1
(1) tan–1 (sin C) (2) tan1(sin  ) (3) cos–1 (sin C) (4) cos1(sin  )
C C

Sol. 1

A A
90

R sinic
=  =
D sin 90

R
D = sin ii

R sin A
=  =
D sinr

sin A sin A
= =
sin(90  A) cos A

R
D = tan A
tan A = sin C
A = tan–1 (sin C)

25. The ratio of maximum acceleration to maximum velocity in a simple harmonic motion is 10 s–1.


At, t = 0 the displacement is 5 m. What is the maximum acceleration ? The initial phase is .
4

(1) 500 m/s2 (2) 750 2 m/s


2 (3) 750 m/s2 (4) 500 2 m/s
2

Sol. 4
fmax = a
vmin = a

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a
= 10
a
w = 10
x = a sin ( + /4)
at f = 0
5 = a sin (/4)
a= 5 2
max acc. = w2a
= 100 × 5 2

= 500 2

26. Two wires W1 and W2 have the same radius r and respective densities 1 and 2 such that 2 = 41.
They are joined together at the point O, as shown in the figure. The combination is used as a
sonometer wire and kept udner tension T. The point O is midway between the two bridges. When
a stationary waves is set up in the composite wire, the joint is found to be a node. The ratio of the
number of antinodes formed in W1 to W2 is -

W1 W2

(1) 4 : 1 (2) 1 : 2 (3) 1 : 1 (4) 1 : 3


Sol. 2
n1 = n2
T  same
r  same
l  same

p T
n=
2l r 2d
n1 = n2
p1 p2
=
d1 d2

p1 1
p2 = 2

27. An ideal gas has molecules with 5 degrees of freedom. The ratio of specific heats at constant pressure
(CP) and at constant volume (CV) is
7 7 5
(1) (2) 6 (3) (4)
5 2 2
Sol. 1
Cp 2
f= C =1+
a 1
= 7/5

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28. Two deuterons udnergo nuclear fusion to form a Helium nucleus. Energy released in this process is :
(given binding energy per nucleon for deuteron = 1.1 MeV and for helium = 7.0 MeV)
(1) 23.6 MeV (2) 25.8 MeV (3) 30.2 MeV (4) 32.4 MeV
Sol. 1
2 1 4
1H + 1H  2Hc
initiate  1.1 × 4 = 4.4
final  4 × 7 = 28
release  28 – 4.4 = 23.6

29. In a certain region static electric and magentic fields exist. The magnetic field is given by
 
   
B  B0 î  2 ĵ  4k̂ . If a test charge moving with a velocity   0 3î  ĵ  2k̂ experience no force in
that region, then the electric field in the region, in SI units, is -
 
 
(1) E   0B0 î  ĵ  7k̂  
(2) E   0B0 3î  2 ĵ  4k̂
 
(3) E   B 14ˆj  7kˆ 
0 0 (4) E   B 14jˆ  7kˆ 
0 0

Sol. 4
Fe = Fn = 0
Fe = –Fm
 

= – q v B 
 
= – 0v0 3 î  ĵ  2k̂  î  2 ĵ  4k̂ 
= – 0v0 14î  7k̂ 
30. In a physical balance working on the principle of moments, when 5 mg weight is placed on the left
pan, the beam becomes horizontal. Both the empty pans of the balance are of equal mass. Which
of the following statements is correct ?
(1) Every object that is weighted using this balance appears lighter than its actual weight
(2) Left arm is shorter than the right arm
(3) Both the arms are of same length
(4) Left arm is longer than the right arm
Sol. 2

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[CHEMISTRY]
1. If the shortest wavelength in Lyman series of hydrogen atom is A, then the longest wavelength
in Paschen series of He+ is :

5A 36A 36A 9A
(1) (2) (3) (4)
9 7 5 5
Sol. 2
Shortest wavelength is corresponding to best ine
 nL = 1 (Lyman series)
nH =  (infinite)

1  1 1
= r × (1)2    = R
A 12 2 
Longest wavelength  1st Line
 =3 nH = 4

1 1 1  r7
= r × (2)2  2  2  =
  3 4  36

36A
=
7

2. Among the following, the essential amino acid is :


(1) Valine (2) Alanine (3) Serine (4) Aspartic acid
Sol. 1

3. Identify the pollutant gases largely responsible for the discoloured and lustreless nature of marble
of the Taj Mahal.
(1) SO2 and O3 (2) O3 and CO2 (3) SO2 and NO2 (4) CO2 and NO2
Sol. 3
SO2 and NO2

4. Which of the following compounds will not undergo Friedel Craft's reaction with benzene ?
Cl COCl
(1) (2) Cl (3) (4)
Cl
O
Sol. 1
Formation of carbocation is not possible in case of CH2 = CHCl
5. Which of the following is paramagnetic ?
(1) CO (2) NO+ (3) O22 (4) B2
Sol. 4
No of e–
CO = 14, NO+ = 14
O2 = 18
2–
B2 = 10
According to MOT
B2 is paramagnetic

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6. The rate of a reaction A doubles on increasing the temperature from 300 to 310 K. By how much,
the temperature of reaction B should be increased from 300 K so that rate doubles if activation
energy of the reaction B is twice to that of reaction A.
(1) 4.92 K (2) 9.84 K (3) 19.67 K (4) 2.45 K
Sol. 1

Eq  1 1 
2=    ...(i)
R  300 310 

Ea  1 1
2 = e2    ...(ii)
R  300 T 

2Ea  1 1 E  1 1 
   = a   
R  300 T  R  300 310 

1 1 2 300  310
+ =  T = ×2
300 310 T 610
= 304.92

7. A solution containing a group-IV cation gives a precipitate on passing, H2S. A solution of this
precipitate in dil. HCl produces a white precipitate with NaOH solution and bluish-white prcipitate
with basic potassium ferrocyanide. The cation is :
(1) Mn2+ (2) Zn2+ (3) Ni2+ (4) Co2+
Sol. 2

HCl NaOH
ZnS ZnCl2 Zn(OH)2

k4[Fe(CN)6]

Zn2[Fe(CN)6]

8. Which of the following statements is not true about partition chromatography ?


(1) Stationary phase is a finely divided solid adsorbent
(2)Separation depends upon equilibration of solute between a mobile and a stationary phase
(3) Paper chromatography is an example of partition chromatography
(4) Mobile phase can be a gas
Sol. 4

9. Excess of NaOH (aq) was added to 100 mL of FeCl3 (aq) resulting into 2.14 g of Fe(OH)3. The
molarity of FeCl3(aq) is :
(Given molar mass of Fe = 56 g mol–1 and molar mass of Cl = 35.5 g mol–1)
(1) 0.3 M (2) 0.2 M (3) 0.6 M (4) 1.8 M
Sol. 2
3NaOH + FeCl3  Fe (CH)3 + NaCl
100 ml 2.14 gm
m=?
2.14
Moles of Fe(CH3) = = 2 × 10–2 mol
107
moles FeCl3 = 2 × 10–2 mol
2  102
M= × 1000 = 0.2 M
100
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10. 5 g of Na2SO4 was dissolved in x g of H2O. The change in freezing point was found to be 3.82°C.
If Na2SO4 is 81.5% ionised, the value of x
(Kf for water = 1.86°C kg mol–1) is approximately :
(molar mass of S = 32 g mol–1 and that of Na = 23 g mol–1)
(1) 25 g (2) 65 g (3) 15 g (4) 45 g
Sol. 4
Na2SO4  2Na+ + SO24
x = 1 + (3 – 1) 0.815 = 2.63
5  1000
3.82 = 1.86 × 2.63 ×
142  x
1.86  2.63  5000
x=
142  3.82
= 45 gm

11. Consider the following standard electrode potentials (E° in volts) in aqueous solution :
Element M3+/M M+/M
Al –1.66 + 0.55
TI + 1.26 –0.34
Based on these data, which of the following statements is correct ?
(1) T3+ is more stable than A3+ (2) A+ is more stable than A3+
(3) T is more stable than A
3+ 3+
(4) T+ is more stable than A+
Sol. 4
G is –ve

12. The major product expected from the following reaction is :


CH2OH O
HO2C
NH2 HCl(g)/CCl4

OH
O
HO2C O
(1)
Cl
O
HO2C O
(2)
OH
O
O
O
NH 2
(3)
OH
CH2OH O
HO2C
NH 2
(4)
Cl

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Sol. 3

13. Among the following, the incorrect statement is :


(1) At low pressure, real gases show ideal behaviour.
(2) At very low temperature, real gases show ideal behaviour.
(3) At Boyle's temperature, real gases show idela behaviour.
(4) At very large volume, real gases show ideal behaviour.
Sol. 2

14. The pair of compounds having metals in their highest oxidation state is :
(1) MnO2 and CrO2Cl2 (2) [Fe(CN)6]3– and [Cu(CN)4]2–
(3) [NiCl4] and [CoCl4]
2– 2–
(4) [FeCl4]– and Co2O3
Sol. 1
MnO2 = + 4
CrO2Cl2 = + 6

15. The IUPAC name of the following compound is

(1) 2-Ethyl-1, 1-dimethylcyclohexane


(2) 1, 1-Dimethyl 1-2-ethylcyclohexane
(3) 2, 2-Dimethyl-1-1-ethylcyclohexane
(4) 1-Ethyl-2,2-dimethylcyclohexane
Sol. 1

1
6 2

5 3
4

16. A mixture containing the following four compounds is extracted with 1 M HCl. The compound that
goes to aqueous layer is :

(1) IV (2) II (3) I (4) III


Sol. 2

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17. Consider the following ionization enthalpies of two elements ‘A’ and ‘B’.

Element Ionization enthalpy (kJ/mol)


st nd rd
1 2 3
A 899 1757 14847
B 737 1450 7731

Which of the following statements is correct?


(1) Both ‘A’ and ‘B’ belong to group-1 where ‘A’ comes below ‘B’.
(2) Both ‘A’ and ‘B’ belong to group-2 where ‘A’ comes below ‘B’.
(3) Both ‘A’ and ‘B’ belong to group-1 where ‘B’ comes below ‘A’.
(4) Both ‘A’ and ‘B’ belong to group-2 where ‘B’ comes below ‘A’.
Sol. 4

18. sp3d2 hybridization is not displayed by :


(1) SF6 (2) BrF5 (3) PF5 (4) [CrF6]3–
Sol. 3
SF6 = Sp3d2 BrF5 = SP3d2
[CrF6] = sp d
3– 3 2
PFs = sp3d

19. The number of S = O and S–OH bonds present in peroxodisulphuric acid and pyrosulphuric acid
respectively are :
(1) (2 and 4) and (2 and 4) (2) (4 and 2) and (4 and 2)
(3) (4 and 2) and (2 and 4) (4) (2 and 2) and (2 and 2)
Sol. 2
Peroxodisulphuric acid

O O
H2S2O8 HO—S—O—O—S—OH
O O

Pyrosulphuric acid

O O

H2S2O7 : HO—S—O—S—OH
O O

20. Among the following, correct statement is :


(1) Sols of metal sulphides are lyophilic.
(2) Brownian movement is more pronounced for smaller particles than for bigger-particles
(3) One would expect charcoal to adsorb chlorine more than hydrogen sulphide.
(4) Hardy Schulze law states that bigger the size of the ion is, the greater is its coagulating
power.
Sol. 3

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21. The major product of the following reaction is :

(1) (2)

(3) (4)

Sol. 1

22. What is the standard reduction potential (E°) for Fe3+  Fe ?


Given that :
Fe2+ + 2e–  Fe; EFe2 / Fe  0.47 V

Fe3+ + e–  Fe2+; EFe3 /Fe2  0.77 V


(1) –0.057 V (2) + 0.30 V (3) – 0.30 V (4) + 0.057 V
Sol. 1

23. The reason for “drug induced poisoning” is :


(1) Binding irreversibly to the active site of the enzyme
(2) Binding at the allosteric sites of the enzyme
(3) Binding reversibly at the active site of the enzyme
(4) Bringing conformational change in the binding site of enzyme
Sol. 2

24. The major product of the following reaction is :

(1) (2)

(3) (4)

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Sol. 1

25. The major product of the following reaction is :

(1) CH3CH = CH – CH = CHCH3 (2) CH2 = CHCH = CHCH2CH3


(3) CH3CH = C = CHCH2CH3 (4) CH2= CHCH2CH = CHCH3
Sol. 1

26. In which of the following reactions, hydrogen peroxide acts as an oxidizing agent ?
(1) HOCl + H2O2  H3O+ + Cl– + O2
(2) I2 + H2O2 + 2OH–  2I– + 2H2O + O2
(3) PbS + 4H2O2  PbSO4 + 4H2O
(4) 2MnO4– + 3H2O2  2MnO2 + 3O2 + 2H2O + 2OH–
Sol. 3
PbS + 4H2O2  PbSO4 + 4H2O
+2 +4

27. For a reaction, A(g)  A(); H = –3RT.


The correct statement for the reaction is :
(1) H = U = 0 (2) |H| < |U|
(3) |H| > |U| (4) H = U  0
Sol. 3

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28. The enthalpy change on freezing of 1 mol of water at 5°C to ice at –5°C is :
(Given fus H = 6 kJ mol–1 at 0°C,
Cp(H2O, ) = 75.3 J mol–1 K–1,
Cp (H2O, s) = 36.8 J mol–1 K–1)
(1) 6.00 kJ mol–1 (2) 5.81 kJ mol–1
(3) 5.44 kJ mol–1 (4) 6.56 kJ mol–1
Sol. D

29. Addition of sodium hydroxide solution to a weak acid (HA) results in a buffer of pH 6. If ionisation
constant of HA is 10–5, the ratio of salt to acid concentration in the buffer solution will be :
(1) 10 : 1 (2) 4 : 5 (3) 5 : 4 (4) 1 : 10
Sol. 1

30. A metal ‘M’ reacts with nitrogen gas to afford ‘M3N’. ‘M3N’ on heating at high temperature gives
back ‘M’ and on reaction with water produces a gas ‘B’. Gas ‘B’ reacts with aqueous solution of
CuSO4 to form a deep blue compound. ‘M’ and ‘B’ respectively are :
(1) Li and NH3 (2) Na and NH3 (3) Ba and N2 (4) Al and N2
Sol. 1
Li + N2  Li3N

H2O

LiOH + NH3

COSO4

[Cu(NH3)4] SO4

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