1.

Aldehyde are more reactive than ketone Because OH gp contain lp of e which shows +m effect and activate the benzne
because reactive of aldehyde and Ketone depend upon positive charge on ring
carbonyl gp greater the Positive charge more is the reactivity since ketone has 14. Which is steam volatile ortho nitro phenol or para nitro phenol
less +ve charge because Of more +I effect Hence less reactive and also more ortho nitro phenol there is intramolecular hydrogen ond but para nitro phenol
stearic hinderance in ketone are held together by inter molecular hydrogen od thus less Steam volatile
2. Cyclohexanone is more reactive than 226-trimethylcyclohexanone 15. Acetic is more acidic than Phenol
Because reactive of aldehyde and ketone depend upon positive charge on Because acetic acid after loosing proton form acetate and phenol form
carbonyl gp , phenoxide ion but resonance of acetate Is more effective as negative charge
greater the Positive charge more is the reactivity oscillate between more EN element O and in phenoxide -ve charge oscillate
since 2,2,6 tri methyl Cyclohexanone ketone has less +ve charge because etween less electronegative carbon
of more +I effect Hence less reactive and also more stearic hinderance in 16. Tert butyl ether cannot be prepared
ketone Tert butyl ether after protanation form carbocation this tert butyl carbocation
3. NaHSO3 is used to purify aldehyde and ketone can't attack on other due to stearic hinderance
NaHSO3 react with Aldehyde and ketone to form ppt this ppt is filtered off 17. Ammonolysis is not a good method to prepare primary amine why
and when again treated with NaOH give back aldehyde and ketone Because when methyl chloride react with NH3 a mixture of 4 compound are
4. Aldehyde react with HCN 2 isomer are formed which can't be seperated formed
When Aldehyde with HCN 2 optical isomers are formed dextro and laevo CH3Cl + NH3 → CH3NH2 → CH3NHCH3 → (CH3)3N → (CH3)4N
hence can't be seperated 18. In Gabriel pthalamide process aniline can't prepared
5. In Esterification water should be remove as soon as it form because in order to prepare aniline pott pthamide must react with
Because esterification is reversible process in order make reaction one of Chlorobenzene which is not possilble due to resonance and formation of
the product must be removed partial double bond
CH3COOH + C2H5OH → CH3COOC2H5 + H2O 19. AgCl and CuSO4 dissolve in amine
6. There are 2 NH2 gp in semicarbazide only 1 involve in reaction with aldehyde because AgCl and CuSO4 react with amine to form complex compound
or ketone [Ag(NH3)2]Cl and [Cu(NH3)4]SO4
Ans beause NH2 gp which is directly attached to CO gp undergoes 20. CH3NH2 soluble in H2O but aniline not
resonance and lp get dispersed now lone pair is not available to attack on Because methyl amine can form hydrogen bond but aniline do not form due
carbonyl group to bulky phenyl group
7. Acetic acid is more reactive than Phenol 21. P amine acetylation but tertiary amine doesn't
Acetic acid and phenol both after releasing proton form anion which is P amine contain NH group thus HCl is formed but ter doesn't contain NH
resonance stabilized but the resonance of acetic acid is more effective as -ve group thus HCl is not formed
charge oscillate between more EN element O but in phenol -ve charge come 22. Benzene diazonium chloride is more stable than aliphatic diazonium salt
on carbon Because of resonance and formation of partial doule bond
8. Orthonitro phenol is more acidic than orthomethoxy phenol 23. Aniline do not give friedal craft reaction
Because nitro gp is electron withdrawing gp it dec -ve charge of phenol thus In aniline contain lp and FeCl3 is electron defecient gp they combined
can readily furnish H+ but methoxy gp is electron repelling gp is increases togather to form adduct
the -ve charge on O thus can't furnish proton readily 24. Aniline give meta nitro aniline sometimes on nitration
9. Phenol do not get protonation Because aniline on protonation sometime form anilium ion which is meta
Because phenol undergoes +m effect as a result O acquire + charge which directing
repels the proton 25. Methyl amine is basic
10. Ethanol is soluble in water than alkane Because it contain lp of electron and can accept proton thus called as base
Ethanol can form hydrogen bond but alkane can't form hydrogen bond 26. Aniline is weaker base than CH3NH2
11. Ethanol has high Bpt than ether Because lp involve in resonance and due to absence of lone pair it is unable
Ethanol can form hydrogen bond but ether can't form hydrogen bond to attract H+
12. Phenol is acidic than ethanol 27. PKb of aniline is more than CH3NH2
Phenol after loosing proton form phenoxide ion which is resonance stailizes Aniline is weaker base than CH3NH2 because lp involve in resonance and due
in order to become phenol readily looses proton thus strong acid but ethanol to absence of lone pair it is unable to attract H+ thus PKb of aniline is more
form ethoxide which is not stale due to resonance than CH3NH2
13. C6H5OH or benzene which is nitrated easily 28. Tert amine is insoluble in water
because of absence of NH gp it is unable to form Hydrogen ond with water
29. Alkyl chloride is insoluble in water
Because it can niether form hydrogen ond with watet nor it can break HB
existing in water molecule
30. Methyl chloride when react with AgCN produces isocynide why
AgCN is covalent molecule it can't furnish CN- hence it can't react with methl
group to form CH3CN and also Bond Between Ag and CN is weak thus it has
tendency to form weak bond ie it form CH3-NC
31. Grignard prepared anhydrous condition
Because grignard reagent react with water to form alkane
32. Dipole moment of chlorobenzene less
Because C in which Cl is attached undergoes SP2 hybridisation and % S
character is 33.3 such carbon is less EN less eager to donate electron and due
to less charge on Cl it is less polar
33. Aq KOH give substitution
Because the Bascicity of OH- dec due to water molecule and due to weak
Base it always give sustitution reaction
34. Paradichloro benzene high mpt
because it is symmetrical in a nature and tightly packed in crystal close
packing
35. Ambident nucleophile
CN and NC- are called as ambident nucleophile because it can react with
both the atoms
36. Which is more reactive C6H5CH2Cl or C6H5CHCl C6H5
C6H5CH2Cl < C6H5CHCl C6H5 with KOH because in latter carbocation form
is more resonance stabilizes thus latter looses Cl readily
37. Chlorobenzene and vinyl chloride do not give substitution reaction
Because of resonance and formation of partial double bond