DEA (diethanolamine) absorption is used to remove H2S from the
recycled gas in recycle gas absorber V-04. H2S gas is absorbed by the DEA solution because of the chemical reaction of DEA with H2S. Typical properties of DEA are shown in Table 8-19. The amount of H2S that can react depends on the operating conditions. The low temperature, high pressure, and high H2S concentration in the H2S absorber favor the reaction. In the DEA regeneration facilities, high temperature and low pressure are used to reverse the reaction and strip H2S from the DEA solution. About 90% of the H2S formed by the desulfurization reactions is removed from the recycled gas in a high-pressure absorber by scrubbing the gas with aqueous diethanolamine solution. The absorber is a vertical vessel packed with stainless steel ballast rings. Recycled gas flows through a support plate and upward through the packing. A lean DEA solution from the DEA regenerator enters the top of the absorber through an inlet distributor and flows downward through the packing. Rich DEA from the bottom of the absorber is sent to the H2S recovery unit.
RECYCLE GAS COMPRESSOR
Recycled gas is circulated by recycle gas compressor C-Ol, driven by
a steam turbine. The largest portion of the recycled gas stream joins the oil feed stream upstream of feed effluent exchangers. A portion of the gas stream from the recycling compressor flows on temperature control to interbed quenching.
DISTILLATION SECTION
The purpose of distillation section (see Figure 3-4) is to remove H2S
and light ends from the first-stage reactor effluent and fractionate the remaining effluent into naphtha, kerosene, and diesel cuts. The bottom stream is either fed to the second stage of the hydrocracker, recycled to extinction with the fresh feed, or withdrawn as product. Hydrocarbon liquid flows to H2S stripper V-Il from stripper preflash drum V-IO. The preflash drum removes some of the light ends and H2S from the low-pressure separator oil before it is stripped and fractionated. The stripper column contains packed sections below the feed plate and two sieve trays above the feed inlet. Stripping is achieved with steam,