5 393.

3033 Antoine coefficients for: log10(Psat[mmHg])=A-B/(T[oC]+C)

A B C Psat bar
c5h12 72 3.97786 1064.84 -41.136 0.5 8.998779
c6h14 86 4.00139 1170.875 -48.833 0.3 4.002495
c6h12 84 3.93002 1182.774 -52.532 0.2 2.878372

105 64.37042
h2 90
c1 3 6.6438 395.74 266.681 369.4732
c2 2.5 6.82915 663.72 256.681 76.03333
c3 1.5 6.80338 804 247.04 21.91616
nc4 1.5 6.80776 935.77 238.789 6.921825
nc5 1.5 6.85296 1064.84 232.012 2.395277
 V/F
k 1
1.799756 0.277815456
0.800499 0.374766248
0.575674 0.347418643
1.000000348

0.008526
0.034524
0.071865
0.227541
0.657544
1
t 330 K
p 100 mpa
v 44.67082
tc 191.15 k
pc 4.641 mpa
w 0.0115
r 8.314413 J/mol k
a 248853.9
b 26.64244
alpha 0.76884
tr 1.726393
 Composit CompoundTc(K) Pc(MPa) w TR PR
90 h2
R 8.314472 3 METHANE 190.6 4.604 0.011 1.731375 2.308862
T 330 K 2 ETHANE 305.4 4.88 0.099 1.08055 2.178279
P 10.63 MPA 1.5 PROPANE 369.8 4.249 0.152 0.892374 2.501765
1.5 n-BUTANE 425.2 3.797 0.193 0.776105 2.799579
0.75 ISOBUTAN 408.1 3.648 0.177 0.808625 2.913925
0.75 n-PENTANE 469.7 3.369 0.249 0.702576 3.155239
0.5 ISOPENTA 460.4 3.381 0.228 0.716768 3.14404

METHANE
3 2 1.5 1.5 0.75 0.75 0.5 kij
k1
k2
k3
k4
k5
k6
k7

a
191540.2
579347.8
1086331
1751699
1634938
2596693
2438305

3
2
1.5
1.5
0.75
0.75
0.5
 z3+a2z2+a1z+a0=0
KAPPA ALPHA a ( Mpa c b cm3/gmoA B a2 a1 a0 z1

0.391572 0.767963 191540.2 26.77811 0.270456 0.103744 -0.89626 0.030678 -0.01618 0.003612
0.524678 0.958985 579347.8 40.4801 0.818042 0.156829 -0.84317 0.430598 -0.09984 0.393617
0.602827 1.067839 1086331 56.29535 1.533905 0.218101 -0.7819 0.954999 -0.2766 0.343874
0.662242 1.163869 1751699 72.43442 2.473406 0.280627 -0.71937 1.675897 -0.59325 0.383464
0.639164 1.132957 1634938 72.36093 2.308539 0.280342 -0.71966 1.512079 -0.54656 0.394958
0.741927 1.254501 2596693 90.18035 3.666541 0.349379 -0.65062 2.601587 -1.1163 0.444737
0.712244 1.23042 2438305 88.08105 3.442897 0.341246 -0.65875 2.41106 -1.01869 0.440071

k1 k2 k3 k4 k5 k6 k7
0 -0.0026 0.014 0.0133 0.0256 0.023 0
-0.0026 0 0.0011 0.0096 -0.0067 0 0
0.014 0.0011 0 0 -0.0078 0 0.011
0.0133 0.0096 0 0 0 0 0
0.0256 -0.0067 -0.0078 0 0 0 0
0.023 0 0 0 0 0 0
0 0 0.011 0 0 0 0

191540.2 579347.8 1086331 1751699 1634938 2596693 2438305

172.3862 200.3912 202.3954 257.1919 122.6875 155.0306 102.5098
199.8715 232.3416 234.6654 298.1987 142.2489 179.7487 118.854
205.2691 238.6161 241.0026 306.2517 146.0904 184.6029 122.0637
260.6587 303.004 306.0344 388.8903 185.5112 234.4159 155.0012
125.9108 146.3657 147.8295 187.8529 89.61094 113.2343 74.87312
158.6802 184.4586 186.3034 236.7433 112.933 142.7045 94.35949
102.5098 119.163 120.3548 152.9397 72.95637 92.18922 60.95763

191540.2 579347.8 1086331 1751699 1634938 2596693 2438305

5.171585 4.007823 3.03593 3.857879 0.920156 1.162729 0.512549 18.66865
5.996145 4.646833 3.51998 4.472981 1.066867 1.348115 0.59427 21.64519
6.158074 4.772322 3.615039 4.593775 1.095678 1.384522 0.610318 22.22973
7.81976 6.06008 4.590516 5.833354 1.391334 1.758119 0.775006 28.22817
3.777325 2.927314 2.217443 2.817794 0.672082 0.849257 0.374366 13.63558
4.760406 3.689172 2.794552 3.551149 0.846997 1.070284 0.471797 17.18436
3.075293 2.38326 1.805322 2.294095 0.547173 0.691419 0.304788 11.10135
 mixture
z2 fugacity b=sum(xibia A B a2 a1

-0.01608 -0.01608 Err:502 0.803343 0.01217 0.020159 -0.97984 -0.02937

-8.62E-07 -8.62E-07 5.065461 0.809602
-1.45E-07 -1.45E-07 2.041631 0.84443
-1.4E-07 -1.4E-07 0.759632 1.086516
-9.07E-08 -9.07E-08 1.004804 0.542707
-2.23E-07 -2.23E-07 0.287069 0.676353
-1.63E-07 -1.63E-07 0.358023 0.440405
5.203357 8618.864
a0 z1 z2 z3 fug vapor fug liq

0.000169 0.004926 1.008786 9.28E-07 -7.26E-08 0.000169 1.027414 Err:502

1.035671 Err:502
1.045292 Err:502
1.055186 Err:502
1.055183 Err:502
1.066225 Err:502
1.064934 Err:502