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Growing media pH is a perennial subject the plant species being grown also affect tained pH like blood in your body? To
of interest in our industry. One reason is pH, the growing medium is the first thing build such a buffer system into a mix,
that unlike mineral soils where plants questioned when pH problems occur, be- first we should know what causes pH
grow naturally, peat mixes are not well cause pH changes occur right in the me- variation in mixes. So, we wanted to
buffered against pH changes. Another dium. explore this further in a quantitative
reason is that, again, unlike in natural manner.
conditions where plants can grow more Here, I present the latest research in the
roots in favorable pH zones, the limited area of growing media pH. The informa- In 2001, we initiated and partially sup-
volume of mix in containers exacerbates tion may fulfill your curiosity, your prac- ported a research study at North Caro-
pH effects. Drastic pH changes upset tical needs or just give you talking points lina State University. Soon Martin Ma-
plant quality (see an example in figure about how industry is striving to manage rietta Technologies joined the study.
1). materials to produce a better growing This company is a derivative of the
media. aerospace company but they are on the
ground in the limestone business and
Truck-wide variation probably produce most of the limestone
Peat is acidic and lime is added to neutral- in the world. Our idea was whether,
ize some of that acidity and raise its pH. with their resources, a horticultural lime
However, even when the same amount of could be devised. Though, like peat,
lime is added to the same amount of peat transport is a major factor in lime busi-
every time, the resulting mix pH is not the ness, a lime produced differently for
same every time. The pH variation can be, horticulture could have a good market.
as the famous remark goes— wide
enough for the truck carrying the mix to Peat dimensions
go thro— from 5.0 to 7.0. Remember that At first, when you joined the industry,
pH scale is logarithmic: a pH of 5 is 10 you thought all peats looked the same,
times more acidic than pH of 6 and 100 didn’t you? But you soon realized all
Figure 1: Calibrachoa in high pH mix times more acidic than 7. Therefore, the peats are not the same all the time.
(photo courtesy of Dr. Paul Fisher, variation is wide. If your blood pH varies Though it is called Sphagnum, there are
University of New Hampshire) by just 0.2, problems occur in your body. various species that make up this genus.
Don’t worry, your body is so efficient, its Further, within each species, peat can be
buffer system kicks in and brings blood at a different decomposition stage. Still
Though grower’s water, the fertilizer pH back to the original value in less than more— one would expect that the water
regime the grower is practicing and even a minute. Don’t you wish your mix main- (Continued on page 2)
Page 2 THE SUN GRO’er Volume 3, Issue 3
(Continued from page 1) are already saturated with bases vary. Further variation occurs over time as
peat has been in contact with during its The saturation is influenced by how the well. Because a field that has been
formation would influence its pH. The species existed with respect to the wa- harvested for a long time would have a
water could be groundwater or rain ter table. Sphagnum angustifolium,
water. All these differences can affect which is in the hollows, derives its
peat’s inherent acidity that has to be moisture from water that is in contact
neutralized. The question is which of with mineral soil. Such water has bases
these characters predict a peat’s re- like calcium, magnesium, sodium, etc.,
quirement of how much lime? which exchange places with hydrogen
on peat. Therefore, angustifolium has a
During late 2002, nearly 500 peat sam- higher percent of its sites saturated
ples were collected from different with bases— so, less hydrogen or acid
fields in Alberta bogs. In each sample, ions and higher pH. Sphagnum fuscum,
fuscum dominates
depth varies, usually on top of hummock
about
6-12” magellanicum Figure 3b: Harvesting flat-
tened peat (photo from Sun
angustifolium Figure 2—Sphagnum species in a natu- Gro archives)
in the hollow ral bog (drawing by Jean McDonald)
species were tedi- which is on top of the hummock de- different mix of species and different
ously separated and their percentages rives its moisture from precipitation decomposition stages than a newly
estimated. Their decomposition rate only and there are few bases in rain opened field. As an example, species
was also rated. The species content of water. Therefore, fuscum still has more content in different fields in a sample
Alberta peat varied. Why? hydrogen or acid ions, or lower pH. location are shown in figure 4. Such
diagrams drawn for different fields can
A natural bog is not flat. For example, What happens to pH as peat decom- be used to know the homogeneity of
Alberta bogs naturally have hummock- poses? Peats that are highly decom- peat and therefore predictability of pH
hollow type topography and have ma- posed have high pH. variation.
jor species occurring as shown in fig-
ure 2. When the naturally undulating bog You might expect a peat starting at a
surface is made flat to allow for har- pH of 4.5 to reach a target of 5.8 with
The differences in species correlate to vesting, each pass of harvester picks up less lime than a peat starting at a pH of
differences in pH. Sphagnum fuscum variation in the species and decomposi- 3.5. You would think in the peat with
on top of the hummock generally has a tion, resulting in variation in peat pH pH 4.5, some acidity is already re-
pH of 3.5. Sphagnum fuscum is hor- (see figures 3a and 3b). duced by bases, so further neutraliza-
ticulturally a best peat, because it has tion requirement should be lower.
high water absorption capacity and There is some such relation between
decays slowly. Sphagnum megellani- higher starting pH and lower lime re-
cum also absorbs water fast and retains quirement but the relation is not strong
it well, but decomposes quickly. (just 20%). Why? A peat with a pH of
Sphagnum angustifolium that is in the 4.5 can still have a lot more number of
hollow has a pH of 4 to 5. There are sites available for bases than a peat
also non-Sphagnums like sedges or with pH of 3.5. Confusing? Let us take
debris, which not only have a higher an analogy of hotel vs. small motel.
pH, but also increase pH variability. Info like 25 rooms occupied in each
lodging (like pH value of each peat)
Why are there pH differences between gives you little information about how
Sphagnum species? All Sphagnum many rooms are still vacant— till you
species have sites loaded with ex- Figure 3a: Flattening of bog know the total capacity of each lodg-
changeable hydrogen (acid) ions but ing. Even when bases like calcium and
(photo from Sun Gro archives)
the number of sites and the percent that (Continued on page 3)
Page 3 THE SUN GRO’er Volume 3, Issue 3
(Continued from page 2) buffer capacity. acid, there were tremendous variations in
magnesium are extracted, a peat sam- dolomites coming from different sources.
ple can yield greater quantity of bases Finally, we generally think hydrogen is But there was very little or no variation
(= more number of guests) and still the source of acidity in peat. But inter- between calcitic limes (thus indicating it
have a lower pH (= lower percent oc- estingly iron is found in Alberta peat. is difficult to change dolomite sources
cupancy). Iron bonds with hydroxide in water and easier to change calcite sources).
leaving acidic hydrogen ions in the Smaller lime particles did react faster
Figure 4: Species and decomposition solution. Variations in peat pH could than larger particles. But the tremendous
differences in fields (drawing by Jean
McDonald)
be due to differing amounts of iron as variations in reaction rates were not fully
well. related to particle size alone. Particle size
accounted for only half of the reaction
Detritus Lime dimensions rate of lime. This finding gives an expla-
S. fuscum
A1 N S. angustifolium Lime costs <1% of the mix price. But nation of how mix pH can vary despite
S. magellanicum
Sedges
the value and the headaches it brings using limes having the same sieve analy-
Wood are well known. Most lime companies sis if these limes are coming from differ-
A1 MN Drepanocladus
primarily serve the construction market ent sources.
and to them agricultural lime is a by-
product. Consequently lime companies Same sized lime particles taken from
A2 N don’t have technical people knowl- different sources were reacted. Dolomites
edgeable of our industry. The burden is took longer time to react than calcites—
A2 M A3 M on us to decide whether their lime 4 times longer on average. So, is reaction
serves our purpose or not. slower because of the presence of mag-
A2 S
A3 S nesium carbonate in dolomite? When
Lime has to dissolve to act and neutral- limes were listed in the order of increas-
ize peat acidity. We generally agree ing magnesium carbonate content (which
Field Sample A1MN A1N A2M A2N A2S A3M A3S that the size of a lime particle affects is the same as decreasing calcium car-
Decomposition 2 2 3 3.5 2 3 2
Detritus 6 4 10 20 4 6 4 its solubility: smaller particles dissolve bonate content), magnesium carbonate
S. fuscum 85 40 87 4 94 5 84
S. angustifolium 8 1 86 10 faster. That’s how agriculture lime is content showed an influence on slowing
S. magellanicum +
Sedges + 53 1 75 1 2 2 characterized now. Unfortunately, this the reaction rate but again the reaction
Wood 1 3 1 1 1 1 +
Polytrichum is yet another time of getting into trou- rate was not fully related to magne-
Tomenthypnum
ble when agriculture perceptions are
transferred to horticulture. In agron-
omy, they have time. A slow rise in
To predict the lime requirement of a soil pH in 3-4 months and a residual
peat, one should determine the total lime effect that lasts for 3 years is ok in
capacity for base saturation and the field crops. In greenhouse growing, we
percent of that capacity already satu- want rapid rise— in days if not hours
rated with bases. The correlation be- and the residual effect for just 3-4
tween increasing percent of base satu- months. Our industry experience has
ration and decreasing lime requirement been that the same amount of lime with
is stronger (40%). The total capacity of the same sieve analysis (= particle size)
a peat to hold bases is based on its doesn’t always give same pH in mixes.
cation exchange capacity, where This result makes one suspect that par- Figure 5: Limes from different
cations (positively charged ions like ticle size alone may not characterize sources (photo courtesy of Dr. Rick
hydrogen, calcium, magnesium) are horticultural lime sufficiently. Vetanovetz, Sun Gro)
swapped for one another.
Nine lime samples from our production sium/calcium content.
A high cation exchange capacity gen- plants (some shown in figure 5) and 40 What other character of lime is influenc-
erally imparts a high buffer capacity. from Martin Marietta quarries were ing its neutralization capacity? Surface
During growing, a peat with high gathered. Among these limes, there area of lime particles was measured.
buffer capacity will have great ability were dolomites (contain calcium and Same size lime particles from different
to trade other cations for hydrogen ions magnesium carbonates) and calcites sources had different surface areas— up
that are coming from plants, fertilizers, (contain just calcium carbonate). These to 5-fold difference. This tells that the
microbial action, etc. Thus, that kind of samples were tested. exposed area on some lime particles is
peat resists pH drifts, which is a prop- not just on the geometric surface and
erty we desire in a mix. Sphagnum When these limes were reacted to find there is considerable internal surface.
fuscum seems to be a species with high out how fast they react and neutralize (Continued on page 4)
Page 4 THE SUN GRO’er Volume 3, Issue 3
Matching peat-lime
The goal of the research is to find out
which characters determine neutrali-
zation capacity of lime and which
characters determine neutralization Figure 6: Microscopic digital images of same sized lime particles from different
requirement of peat and then match sources (courtesy of Dr. Janet Rippy)
them suitably. Like what the eHar-
tween companies. During some of
mony guy says on the radio about
those times, following the explana-
profiling different dimensions of men Research & further research tions and remedies suggested by well
and women before matching soul People in the industry should under- meaning participants was like follow-
mates! stand that large randomized, controlled ing the moves of mouse in a maze,
research trials like this one are slow and due to lack of good information.
Continuing on the matchmaking anal- frustrating at times. This study began in Working in the field we especially
ogy, you might be wondering: What 2001, and conclusions after going know how lack of good information
about the chemistry after marriage— through the vigilance of peer review, are adds uncertainty to our interpretation
pH drift during growing? The proper- just coming out. But imagine 500 peat of a situation. New insights from
ties mentioned above give informa- samples, 50 lime samples sieved into 8 research will reduce the uncertainty.
tion to predict pH changes during fractions, each sample studied in repli-
growing as well. For example, differ- cations for many different characters. The research initiated by Sun Gro,
ent reaction rates of limes give infor- Just devising a test on how to measure a NC State University and Martin Ma-
mation on balancing initial pH of the character took time. For example, how rietta branched into different angles.
mix with pH maintenance during its to measure the surface area of lime par- In 2004, Dr. Paul Fisher of the Uni-
use. For simplicity, I presented here ticle (dinitrogen gas was used as absor- versity of New Hampshire, got the
the effect of one factor at a time, as if bate because the gas accesses the same remains of the large collection of
other factors remain the same. In the areas of the particle as water does), what Alberta peat samples to find out
real world, as you can imagine, the type of base to use to disassociate hy- whether plants can mine the iron in
peat-lime reactions occur in multifac- drogen ions from peat, etc. some of those peats (like people do
eted dimensions in space and time.
in Caribou Mountains in Alberta).
But since the whole effect is a sum of Still, we should support research. Just His research is supported by a con-
its parts, depending on the situation, on the subject of pH, we know pH sortium of grower organizations and
we can select and add or subtract rele- brought on contentions, disputes and
(Continued on page 5)
vant factors and evaluate the effect. even litigations between people and
Page 5 THE SUN GRO’er Volume 3, Issue 3