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KSCE Journal of Civil Engineering (2017) 21(2):546-553 Design Optimization and Applications in Civil Engineering

Copyright ⓒ2017 Korean Society of Civil Engineers


DOI 10.1007/s12205-017-1580-z pISSN 1226-7988, eISSN 1976-3808
www.springer.com/12205
TECHNICAL NOTE

Experimental Investigation on Compaction and Atterberg Limits Characteristics


of Soils: Aspects of Clay Content using Artificial Mixtures
Zhang Kunyong* and Charkley Nai Frederick**
Received September 11, 2016/Revised 1st: October 12, 2016, 2nd: November 2, 2016/Accepted November 3, 2016

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Abstract
The influence of different proportions of clay minerals on the moisture density relationship and index properties of clay soils are
not clearly understood because of the different factors that come into play in natural soil formation. This study used 11 different
remolded samples prepared by combining double mixtures of commercially available powdered kaolinite, montmorillonite and
quartz in proportions of 30%, 50%, 70% and 100% based on dry unit weight to investigate the relationship between different
proportions of clay minerals with index properties and compaction characteristics of clay soils. The results described the influence of
different proportions of clay minerals on the liquid limit, plastic limit and plasticity index measured using the fall cone penetration
test. Also, the variation of maximum dry density and optimum moisture content with different clay mineral proportions has been
analyzed. In addition, equations are presented with significant correlations to show the relationship between Atterberg limits,
compaction parameters and the proportion of clay minerals. Knowledge on the effect of the different clay minerals on the moisture
density relationship and index properties can be used to predict the behavior of compacted clay soils encountered in engineering
practices and reduce the time and effort needed for assessing the suitability of clay soils and clay liners for engineering use.
Keywords: clay, atterberg limit, maximum dry density, optimum moisture content
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1. Introduction compression index and liquid limit for a variety of clay soils.
Other authors (Pandian et al., 1997, Blotz et al., 1998; Gurtug
The evaluation of basic engineering properties of soils through and Sridharan, 2002; Sharma and Bora, 2003; Sridharan and
laboratory testing is very important in understanding and interpreting Nagaraj, 2005; Sivrikaya et al., 2008; Di Matteo et al., 2009;
how soils will behave in the field. Atterberg limits and laboratory Noor et al., 2011) have also showed strong associations between
compaction have been found to be very reliable in characterizing, compaction parameters and index properties. For example,
predicting and explaining the behavior of fine grained soils for Pandian et al. (1997) in a study on compaction characteristics of
engineering use (Wesley, 2003; Ramesh et al., 2010; Calik and 3 soils observed that the shape of the soil compaction curve
Sadaglu, 2014). These two tests are internationally relied on could be predicted by determining the liquid limit, the water
because they depend on the same factors such as type and content, and the coarse fraction. He came to the conclusion that
proportion of clay mineral, shape and grain size distribution for a practical range of liquid limit-water contents, the entire path
(Korfiatis and Manikopolous, 1982; Mitchell, 1993), which vary of compaction behavior can be determined using discrete dry
in space and time depending on different natural soil formations. density-water content data and the liquid limit value. Blotz et al.
In literature, a number of studies have been undertaken to relate (1998) described an empirical method for estimating optimum
Atterbeg limits and compaction parameters with a combination moisture content and maximum dry density using 22 clay soils at
of all the various factors that influence their plasticity. Jumikis any rational compaction energy. He concluded that variations
(1946) was among the early researchers to propose methods to employing the liquid limit and the logarithm of compaction
estimate optimum dry density and maximum dry density from energy were more precise. Gurtug and Sridharan (2002) on the
Atterberg limits. Using a number of compaction tests, Joslin other hand proposed correlations based on plastic limit to
(1959) was able to develop 26 different compaction curves based determine optimum moisture content and maximum dry density
on which a soils’ compaction curve could be wholly plotted from at varying compaction energy. Maximum dry density was 0.98
a single proctor test using dry unit weight and water content. times the dry unit weight at plastic limit and optimum moisture
Terzaghi and Peck (1967) suggested correlations between content was 0.92 times the plastic limit. Sridharan and Nagaraj

*Associate Professor, Key Laboratory of Ministry of Education for Geomechanics and Embankment Engineering, Nanjing, 210098, China; Geotechnical
Research Institute, Hohai University, Nanjing, Jiangsu P.R. China 210098 (E-mail: ky_zhang@hhu.edu.cn)
**Ph.D. Student, Key Laboratory of Ministry of Education for Geomechanics and Embankment Engineering, Nanjing, 210098, China; Geotechnical
Research Institute, Hohai University, Nanjing, Jiangsu P.R. China 210098 (Corresponding Author, E-mail: fredioz@yahoo.com)

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Experimental Investigation on Compaction and Atterberg Limits Characteristics of Soils: Aspects of Clay Content using Artificial Mixtures

(2005) carried out detailed investigation using standard proctor 2. Materials and Methods
compaction to determine which index property correlated well
with compaction parameters. Based on his result and results 2.1 Materials
gathered from about 54 sources, he predicted that the plastic For this study, commercially processed powdered sodium
limit bears good correlation with compaction parameters better montmorillonite (SD1090B) supplied by Zhejiang Sanding
than liquid limit and plasticity index. The work of Noor et al. Technology Company, spheswhite kaolin from Shanghai IMERYS
(2011) on 106 fine grain soils from India also suggested Mineral Company and fine quartz from Anhui Shengli quartz
correlations for predicting compaction parameters from specific factory were used. The general properties of the kaolin and
gravity, plasticity and plastic limit. More recently, Nagaraj et al. montmorillonite are summarized in Table 1. Specific gravity
(2015) used the concept of predicting compaction characteristics determined from water pycnometer method gave values of 2.65
from varied proportions of fines less than 425 μm to correlate for quartz, 2.6 for kaolin and 2.69 for montmorillonite. Particle
compaction parameters of natural soils with modified plastic size analysis was performed using BT9300H laser particle size
limits and Farooq et al. (2015) proposed predictive curves for analyzer. The results of particle size distribution curves for
quick estimation of maximum dry density and optimum kaolin, montmorillonite and quartz are shown in Fig. 1.
moisture content based on liquid limit, plasticity index and The curve shows that all three minerals contained appreciable
compaction energy without performing laboratory compaction quantities of fines. About 90% of both kaolin and montmorillonite
tests. contained clay size particles (particles smaller than 0.005 mm).
The previous studies in literature have showed that researchers However, majority of the quartz fell within the silt range (0.005
focused on correlating the compaction parameters as a function mm and 0.075 mm).
of Atterberg limits for fine grained soils, particularly natural
soils, whilst limited publications mentioned the impact of the 2.2 Methods
clay mineralogy. And for the few literature that attempted to In order to obtain clay soils of different properties, reconstituted
study the influence of clay content, the results of their study soil mixtures were prepared base on dry unit weight from
were not always in agreement (Polidori, 2007). This is because varying combinations of kaolinite, montmorillonite and quartz.
external factors have strong influence on the Atterberg limits Sivapullaiah and Sridharan (1985), Pandian et al. (1995), Ziegler
and compaction characteristics depending on the type and et al. (1998) and Tiwari and Ajmera (2012) used such mixes to
proportion of clay minerals. For instance, as the concentration of obtain a wide range of correlations between the properties of fine
salt increases, the liquid limit of montmorillonite decreases soils. The double mixture proportions used in this study were
sharply, while the liquid limit of kaolinite is not significantly
affected (Di Maio and Fenelli, 1994). It is thought that the Table 1. General Properties of Kaolin and Montmorillonite Used in
presence of clay minerals even in small quantities can alter the the Present Study
behavior of the whole soil mass (Holtz and Kovacs, 1981). The Values
Physical properties
influence of clay soils on compaction and consistency limits goes a Kaolin Montmorillonite
long way to affect the capacity of foundations, slope stability of Principal mineral Kaolinite
Sodium
embankments and design of earth retaining structures as Montmorillonite
highlighted in literature (Lupine et al., 1981; Georgiannou, Specific gravity 2.6 2.56
1988; Yin, 1999). However, the role of different clay minerals Liquid limit 55 328.2
on the fundamental properties such as moisture density Plastic limit 27 33.5
Plasticity index 28 294.7
relationship and index properties is not clearly understood
Clay (< 0.005 mm) 90% 90%
because of the different environmental factors that come into
Maximum dry unit weight (g/cm3) 1.38 1.2
play. In light of this and the fact that compaction and Atterberg
Optimum moisture content (%) 32.6 38.3
limits require a lot of time and energy to obtain in the laboratory,
the present study investigated the relationship between clay
mineralogy, index properties (liquid limit, plastic limit,
plasticity) and compaction characteristics (optimum moisture
content, maximum dry density) using 11 artificially remoulded
clay mixtures. By using artificial soils, the effect of spatial
variability that occurs in natural clay soils is reduced and the
influence of only the clay minerals can be investigated. The aim
was to establish empirical correlations for compaction
parameters and Atterberg limits based on various proportions
and types of clay minerals. Knowledge of this will reduce the
time and effort needed for assessing the suitability of clay soils
and artificial clay liners for engineering use. Fig. 1. Grain Size Distribution of Kaolin, Montmorillonite and Quartz

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Zhang Kunyong and Charkley Nai Frederick

Table 2. Summary of Atterberg Limit Results 2 mm respectively. The plasticity index was determined from the
Samples
Plastic limit Liquid limit Plasticity
Soil Type
numerical difference between the liquid limit and plastic limit.
(%) (%) (%)
K30Q70 19.7 30.5 11 CL (lean clay) 2.2.2 Compaction Test
K50Q50 21.1 36.0 15 CL(lean clay) The standard compaction test method was used to estimate the
K70Q30 27.0 48.1 21 CL(lean clay) relationship between the optimum moisture content and maximum
K100 27.4 55.3 28 CH(lean clay)
dry unit weight of the mixtures. Approximately 2.3 kg of each
M30Q70 22.8 103.1 80 CH (fat clay)
sample with the appropriate designated mineral composition by
M50Q50 24.2 167.5 143 CH(fat clay)
weight was measured. The two minerals were thoroughly mixed in
M70Q30 29.5 238.8 209 CH(fat clay)
the dry state by hand until a fairly even distribution of the particles
M100 33.5 328.2 294 CH(fat clay)
was obtained. A minimum of 5 specimens were prepared at
M30K70 26.8 114.8 88 CH(fat clay)
predetermined water content for each sample by adding distilled
M50K50 33.1 176.1 143 CH(fat clay)
water while continuously stirring by hand. The amount of water to
M70K30 33.1 238.5 205 CH(fat clay)
be added was computed from Eq. (1). Based on visual observation
and the satisfaction that all clogged particles have been crushed, the
specimens were put in plastic bags and kept in air tight containers
30%, 50%, 70% and 100% by dry weight. Table 2 shows the for 24 hours to allow for uniform distribution of the water before
basic index properties of the 11 different samples obtained from the commencement of the compaction process.
laboratory tests conducted in accordance to procedures outlined mwater = msoil × ( mf – mi ) (1)
in Chinese standard GB/T 50123 (1999). The initial letters K, M
and Q represent kaolin, montmorillonite and quartz respectively Where mf = Final water content desired and
whiles the proceeding numbers denote the percentage of that mi = Initial water content of soil
mineral in the mixture. From the Atterberg limits results msoil = Total mass of soil (in grams);
presented in Table 2, the soil mixtures were all classified based mwater = Mass of water to be added (in grams)
on the China Classification System for liquid limit values read at After curing, the samples were compacted into a 102 mm
17 mm penetration. All the mixtures were classifed as CH (fat diameter proctor mould layer by layer for a total of three layers.
clay) with the exception of K30Q70, K50Q50 and K70Q30 Each layer received 25 blows by dropping a 24.4N rammer from
which fell in the class of CL (lean clay). a height of 305 mm. The detailed procedure can be found in the
To carry out this study, double mixtures of the various minerals Chinese standard GB/T 50123 (1999) for soil compaction. After
were subjected to Atterberg limit tests and standard proctor each test, the specimen was carefully extracted from the mould
compaction test. The Atterberg limits investigated were liquid using a jacking apparatus.
limit and plastic limit using fall cone penetration. Maximum dry
density and optimum moisture content were obtained from 3. Results and Discussion
compaction by preparing a minimum of five samples for each
mineral mixture at different water contents. 3.1 Atterberg Limits Characteristics

2.2.1 Atterberg Limit Test 3.1.1 Liquid Limit


The liquid limit, plastic limit and plasticity index was used in A graph of the liquid limit verses the proportion of montmorillonite
this study in an attempt to define the water content behavior or kaolin (i.e. 30, 50, 70, and 100 %) is presented in Fig. 2. The
relationship of different clay minerals. Atterberg limits test were liquid limit of montmorillonite and kaolin were 328 and 55
conducted on particles passing the 0.5 mm diameter sieve. respectively. The results generally indicate that as the proportion
Instead of the regular Cassagrande method, the fall cone penetration of montmorillonite and kaolin increases, the liquid limit also
was adopted on the basis that it produces consistent and more increases in all soil mixtures. This confirms the assertion that the
reliable results (Ladeira and Oliveira, 1995; Leroueil and Le liquid limit of a soil is primarily controlled by its clay content
Bihan, 1996). The fall cone penetration test was conducted in (Seed et al., 1964) and is in agreement with the trend of liquid
accordance with the procedures outlined in Chinese standard limits results reported by Tiwari and Ajmera (2011) using similar
GB/T 50123 for determination of liquid limit and plastic limits. minerals. That notwithstanding, it was also observed that the
Firstly, dried samples of the minerals were mixed with water and increase in liquid limit in montmorillonite dominated soil
stored in plastic bags for 24 hours to ensure uniform distribution (montmorillonite-quartz and montmorillonite-kaolin mixtures)
of moisture. After homogenization, distilled water was gradually was more significant than in the kaolin dominated soil (kaolin-
added to determine the penetrations at 3-4 mm, 7-9 mm and 15- quartz mixture). The high affinity for water can be attributed to
17 mm and their corresponding moisture contents. A curve of the high specific surface area of montmorillonite clay minerals
penetration against the water content was plotted. The liquid compared to kaolin (Young, 2012). Therefore an increase in
limit and plastic limit correspond to penetrations at 17 mm and montmorillonite content increases the water holding capacity of

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Experimental Investigation on Compaction and Atterberg Limits Characteristics of Soils: Aspects of Clay Content using Artificial Mixtures

Therefore the plasticity index, which is the numerical difference


between the liquid limit and the plastic limit, also increased
drastically with increase in montmorillonite content. The increase in
the kaolin-quartz mixture was quite slight. De Magistris et al.
(1998) also reported similar results. The relationship between the
Plasticity Index (PI) and proportion of clay minerals for
montmorillonite dominated soils and kaolin dominated soils
related to this study are shown by Eqs. (4) and (5) respectively.
An R2 value of 0.99 was obtained for both Eq. (4) and (5) which
is a reasonably confirmation in geotechnical engineering that the
Fig. 2. Variation of Liquid Limit with Percentage of Montmorillonite
linear relationship is good.
or Kaolin
PI = 3.0319α – 6.9834 (4)
the resulting mixture more rapidly and hence liquid limit PI = 0.2474β + 3.2112 (5)
increases. Thus, a relationship between the Liquid Limit (LL)
Regarding plasticity, Table 2 generally revealed that with the
and proportion of clay minerals for the montmorillonite dominated
decrease in quartz in both montmorillonite-quartz and kaolinite-
soils and kaolin dominated soils used in this study were
quartz mixtures, the plasticity increases. This can also be
investigated and given as:
explained by the increase in intermolecular attraction force as
LL = 3.1614α + 14.632 (2) clay content increases and quartz decreases. Nath and Dalal
(2004) observed similar trend in plasticity and associated it with
LL = 0.37β + 19.353 (3)
the increase in liquid limit as clay content increases.
In which LL is the liquid limit, α is the proportion of
montmorillonite by weight in percentage and β is the proportion 3.2 Compaction Characteristics
of kaolinite by weight in percentage. Eq. (2) can estimate the The compaction test was conducted to obtain the optimum
liquid limit of montmorillonite dominated soils and Eq. (3) can moisture content and dry density relationship of the mixtures.
be used to estimate the liquid limit of kaolin dominated mixtures. The relationship between the parameters has been illustrated in
To know if the correlation was good and reliable, the study Fig. 4 for all three mixture groups. The results depict typical
checked the correlation coefficient. Values of R2 for Eqs. (2) and curve characteristics for all compaction tests. For all mixtures,
(3) were 0.99 and 0.97 respectively. the dry density increased with increase in moisture content until
optimum, and then began to decrease with any further increase in
3.1.2 Plasticity Index moisture. It can be observed that as the proportion of
The plot of plasticity index with varying proportions of montmorillonite and kaolin were increased in the
montmorillonite and kaolin is displayed in Fig. 3 to further prove montmorillonite dominated mixtures (montmorillonite-quartz
the influence of clay minerals on Atterberg limits. and montmorillonite kaolin mixtures) and kaolin dominated
The trend is similar to observations made by Tiwari and mixtures (kaolin-quartz) respectively, the maximum dry density
Ajmera (2011). The experiment result showed that as the decreased and optimum moisture content increased. In the
quantity of montmorillonite is increased in the montmorillonite montmorillonite-quartz mixture, the dry density decreased from
dominated mixtures, the liquid limit increased considerably; 1.56 g/cm3 to 1.2 g/cm3 and the optimum moisture content
however the plastic limit increased very slightly (see Table 2). increased from 22.1% to 38.3%. The maximum dry density in
the kaolin-quartz mixture decreased from 1.68 g/cm3 to 1.38 g/
cm3 and the optimum moisture content increased from 17.4 g/
cm3 to 32.6 g/cm3. A similar trend was observed in the
montmorillonite-kaolin mixture. The reduction in density may
be attributed to the decrease in the proportion of quartz (silt
particles) which possesses a higher density. Furthermore, as the
clay content increases, it occupies the pore spaces and interferes
with the inter-particle bondage of the silt particles thus reducing
the density. Also, with the addition of more fine clay particles,
the specific surface area is increased and a lot of water is required
to reach the maximum dry unit weight (Holtz and Kovacs,
1981). The high water content separates the high density quartz
Fig. 3. Variation of Plasticity Index with Percentage of Montmoril- particles from each other and as a result the maximum dry
lonite or Kaolin density decreases. The correlation between maximum dry

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Zhang Kunyong and Charkley Nai Frederick

Fig. 4. Relationship between Dry Density and Moisture Content: (a) Kaolinite-quartz Mixure, (b) Montmorillonite-quartz Mixture, (c)
Montmorillonite-kaolin Mixture

dominated mixtures is below the line of best fit for kaolinite


dominated mixtures. This is because montmorillonite has a
relatively higher specific surface area than kaolinite.
From Fig. 5, it is also clear that there is a high correlation
between maximum dry density and optimum moisture content
for both kaolin and montmorillonite dominated soils. The
evidence of this is the high correlation coefficient (R2) obtained
for the linear regression plots. The relationship between Maximum
Dry Density (MDD) and Optimumum Moisture Content (OMC)
can be expressed by regression Eqs. (6) and (7) for kaolin
Fig. 5. Relationship between Maximum Dry Density and Optimum
Moisture Content
domintaed soils and montmorillonite dominiated soils used in
this study respectively.
MDD = – 0.0194 ( OMC ) + 2.0125 (6)
density and optimum moisture content is depicted in Fig. 5. It
can be observed that the line of best fit for montmorillonite MDD = – 0.0191 ( OMC ) + 1.947 (7)

Fig. 6. Relationship between Compaction Parameters and Plastic Limit: (a) Maximum Dry Density, (b) Optimum Moisture Content

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Experimental Investigation on Compaction and Atterberg Limits Characteristics of Soils: Aspects of Clay Content using Artificial Mixtures

Fig. 7. Relationship between Compaction Parameters and Liquid Limit: (a) Maximum Dry Density, (b) Optimum Moisture Content

Fig. 8. Relationship between Compaction Parameters and Proportion of Clay Minerals: (a) Maximum Dry Density and Clay Content, (b)
Optimum Moisture Content and Clay Content

3.3 Correlation between Compaction Parameters, Attter- Fig. 6. Therefore, the parameter that best predicts the maximum
beg Limits and Clay Proportions dry density and optimum moisture content is the plastic limit for
In order to develop correlations, the experimental data was compacted clay soils and given by Eqs. (8) and (9). This
quantitatively analysed by various combinations of maximum observation confirms that plastic limit bears better correlation
dry density, optimum moisture content, Atterberg limits and with compaction parameters than liquid limit and plasticity index
proportion of clay minerals. (Sridharan and Nagaraj, 2005).
Figure 6 and Fig. 7 represent the relationship between compaction OMC = 1.4497 ( PL ) – 10.094 (8)
parameters (maximum dry density and optimum moisture content)
and Atterberg limits (plastic limit and liquid limit). In Fig. 6 the MDD = −0.0322(PL) + 2.2826 (9)
correlation coefficient was 0.91 for maximum dry density with As Atterberg limits can be used to predict compaction
plastic limit and 0.86 for optimum moisture content with plastic parameters and it has been shown that the proportion of clay
limit. With regards to the correlation between optimum moisture minerals bears good correlation with Atterberg limit, then there
content and plastic limit, Leroueil et al. (1992) suggested that must exist, a relationship between the compaction parameters
optimum moisture content was approximately equal to the plastic and the proportion of clay minerals. Fig. 8 shows the relationship
limit for clay soils which is consistent with the almost 1:1 between maximum dry density, optimum moisture content and
correlations presented in this study. The correlation of several the proportion of clay minerals.
published data results between optimum moisture content and It is evident in Fig. 8(a) that the addition of montmorillonite
plastic limit and between maximum dry density and plastic limit as and kaolin steadily decreases the maximum dry density. This
presented by Howell et al. (1997) and Nagaraj (2015) respectively, implies that the high density of the quartz is compromised by the
further endorses the relationship obtained in this study. addition of kaolinite and montmorillonite. Fig. 8(a) also shows
In Fig. 7 the correlation coefficient was 0.62 for maximum dry that the average maximum dry density values of kaolin quartz
density with liquid limit and 0.45 for optimum moisture content mixtures are higher than the corresponding values in
and liquid limit. The plots reveal that, even though there is montomorillonite-quartz mixtures. This can be explained by the
somewhat correlation between compaction parameters and high specific gravity of the kaolinite minerals compared with the
liquid limit in Fig. 7, the R2 values are relatively small compared montmorillonite. Also, montmorilonite has high water absorption
with the R2 values obtained for correlations with plastic limit in capacity than kaolin, enabling it to store more water and reduce

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Zhang Kunyong and Charkley Nai Frederick

the inter particle locking and friction in the quartz. The trend in because of the high specific surface area of montmorillonite.
maximum dry density versus the proportion of clay in Fig. 8(a) is 4. Maximum dry density and optimum moisture content are
consistent with the results of sand clay mixtures by Howell et al better predicted with plastic limit than liquid limit.
(1997), who reported an increase in optimum moisture content 5. Compaction parameters and Atterberg limits can be pre-
and decrease in maximum dry density as the amount of clay dicted from the proportion and type of clay minerals present
increases beyond 20% clay content for one day curing period. to reduce the time and effort spent on accessing the suitabil-
The conclusion is also somewhat consistent with the findings ity of soils for engineering use.
presented by Kenney et al. (1992) for bentonite content beyond
16%:they reported an increase in maximum dry density up to Acknowledgements
16% bentonite content and afterwards a decrease in maximum
dry density with increasing bentonite content which is similar to The authors appreciate the financial support provided by the
the range of clay proportions considered in this study. National Science Foundation of China (No.51578214) and
In Fig. 8(b), there is a steady increase in optimum moisture Fundamental Research Funds for the Central Universities (No.
content with the addition of kaolin and montmorillonite. The 2015B17714).
linear relationships produced significant correlation coefficient
that can be used to predict compaction parameters from the References
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