Adva PI Sol PDF

1
AITS-FT-V (Paper-1)-PCM(Sol)-JEE(Advanced)/14
From Classroom/Integrated School Programs 7 in Top 20, 23 in Top 100, 54 in Top 300, 106 in Top 500 All India Ranks & 2314 Students from
Classroom /Integrated School Programs & 3723 Students from All Programs have been Awarded a Rank in JEE (Advanced), 2013
FIITJEE JEE(Advanced), 2014
ANSWERS, HINTS & SOLUTIONS
FULL TEST – V
PAPER-1
Q. No. PHYSICS CHEMISTRY MATHEMATICS

1. A C C
ALL INDIA TEST SERIES
2. A A B
3. A D C
4. A A C
5. B B B
6. D C D
7. A C A
8. B A A
9. A, B, C B, C B, C
10. B, C B, C, D A, B
11. C, D B, D A, B
12. B, C, D A, B, D A, B, C
13. A, C, D A, B A, B, D
14. C C B
15. B B A
16. C B B
17. A C A
18. D C D
1. 3 9 9
2. 1 7 3
3. 2 6 4
4. 5 7 4
5. 1 8 0
6. 3 5 0
7. 1 6 0
8. 8 3 2
9. 5 5 7
10. 0 4 2
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
2
Physics PART – I
SECTION – A
9
2. intensity of S1 = 9 times of intensity S2
4
2
Intensity of maxima =  I1  I2  = 9 I2
 S2P – S1P = n for maxima
d2  n2  2
d2  x 2  x  n  x=
2n
   
3. sin  = 2
,  = sin1  2 
4y 0  4y0 
2mv 0 1  qE0  2
4.   t
qB0 2 m 
4m2 v 0
 t2
q2 E 0 B 0
2m v 0
x = v0 
q E0B 0
6. y1 = A sin 1t Ar
y2 = A sin 2t cycle
2A0
 (   1 )   ( 2  1 ) 
yr = 2A cos  2 t  sin t A0
2 2 1s
1/6 s
1/3 s
1/4 s
3/4 s
2/3 s
  
5/6s
Resultant amplitude Ar = 2A0|cos()t/2|
t  1
()   t = s
2 2 4
t  1
( )   t = s
2 3 6
In one cycle of intensity of 1/2s, the detector remain idle for
 1 1 1
2    s  sec
 4 6  6
 1 1
 In ½ sec cycle, active time is    = 1/3 sec
 2 6
1/ 3 
 In 12 sec interval, active time is 12  = 8 sec
(1/ 2)
7. Let 1 = 4eV, then 2 = 2eV

(E  ) represent kinetic energy of most energetic electron.
E  2 = 2(E  1)
 E = 6eV
3
8. Induced e.m.f. = Bv = 0.125 V +

0.5T
10 V 0.25 m
10  e 10  0.125 V 
current I =  0.5 N
R 2 2
V
 10  0.125 
Force BI = 0.5   0.25  0.5N (given) Q
 2 
Solving v = 16 m/s.
0 (a  x)a 0 xak 
11. C 
d d
 0 a[a  x  kx]
=
d x
 a
= 0 a  (k  1)x 
d
 aV 2
U= 0 a  (k  1)x 
2d
dU 0 aV 2 (k  1)
F= 
dx 2d
 aV 2 (k  1)
v 2  v 02  2Ax = v 20  0 x
md
1  aV 2 (k  1)x  aV 2
E  mv 20  0 + 0 a  (k  1)x 
2 2d 2d
1  a2 V 2 (2k  1)
Emax  mv 02  0
2 2d
12. P.D. same & electric field same

Charge will be kC ε
Energy will be ½ kC ε2
14. P0 + 0.8 wgh + wg(2h) + 1.2 wg(3h) = P0 + 1.2 wgh2

6.4
 1.2 h2 = h[0.8 + 2 + 3.6] = 6.4 h  h2 = h
1.2
P0 + 0.8 wgh + wg(2h) = wgh1 + P0
 h1 = h[0.8 + 2]  h1 = 2.8 h
h2/h1 = 40/21
1
15. P0 +  w v 2 = P0 + 0.8wgh + wg(2h)
2
v2
  gh[0.8  2]
2
v = 2  9.8  0.28  2.8 = 3.92 m/s
16-18. In the time interval t = 0 sec to t = t0 sec, till the time. The relative velocity is not zero the nature
of friction will be kinetic.
4
 N
uAB  0iˆ  (20i)
ˆ = 20 m/sec (i)ˆ
N = 100 N  Fk = 0.25  100 = 25 N
 

a A  4m / sec 2 î , aB  0m / sec 2 î  F = 15 N
10 kg
  
a AB  a A  aB  4m / sec 2 î  10 g
Fk
   
VAB  uAB  a AB t  0
 t = 5 sec
When the relative motion between block A and belt conveyor will be zero, the nature of friction will
be static and its magnitude will equal to magnitude of unbalanced external force acting on the
block A and its direction will be I the opposite direction of unbalanced external force.
ˆ  kinetic in nature Friction force
 25N(i)
 Fr  Frictional force   25 N
15N( î)  Static in nature 5sec
O t
15 N
SECTION –C
1 3ˆ y
1. p̂  ˆj , n̂  aiˆ  bjˆ  î  j a
2 2 r̂1 p̂
i b
rˆ1  nˆ  2(nˆ  p)p
ˆ ˆ n̂ (90i) ( i)
= (aiˆ  bj)ˆ  2( b)jˆ  aiˆ  bjˆ O
r n̂
nˆ  pˆ  cos(   i)  b
3
cos i = b =  i = 30
2
 = cot i = 3
4. For collision the relative velocity of A with respect to B should be along the line AB
6. Using condition of equilibrium

KL = (m1 + m2)g
Using COME
1 2
KL  m1g(2L)
2
KL (m1  m2 )
 m1 = 
4g 4
 3m1 = m2 = m2/m1 = 3
Q
8. If we place another similar cone on this one, net flux =
0
Q 3Q 2Q 8Q
 Flux with the upper cone =  =  . This
0 50 50 200
must also be the flux associated with the lower cone when the 2H
charge is raised through a height 2H because of symmetry. H
+Q
5
9. Velocity of first block before collision,

v12  12  2(2)  0.16
= 1 - 0.64
v1 = 0.6 m/s
By conservation of momentum, 2  0.6 = 2 v1 + 4 v2
also v 2  v1 = v1 for elastic collision
It gives v2 = 0.4 m/s
v1 = -0.2 m/s
Now distance moved after collision
(0.4)2 (0.2)2
s1 = & s2 =
2 2 22
 s = s1 + s2 = 0.05 m = 5 cm.
10. By symmetry, no current will flow in arm along x-axis.
6
Chemistry PART – II
3. More activated ring undergo EAS.
4. Br Me H
Br2 2NaNH2 Na/Liq.NH3
Me  CH  CH  Me 
CCl4
 Me CH CH Me   Me  C  C  Me  
H Me
Br
st
5. 1 titration
1 1
Meq. of NaOH Meq. of Na2CO3 = Meq. of HCl = 50  =5
2 10
2nd titration
1 1
Meq. of Na2CO3 = Meq. of HCl = 10  1
2 10
 Meq. of NaOH = 5 – 1 = 4
Meq. of NaOH  Equivalent weight
Wt. of NaOH 
1000
4  40

1000
= 0.16 g
6. CHO CHO
 3
i O NaOH dil.

 ii Zn/H O
 


2
CHO Intramolecular aldol condensation
7. 8NH3  excess   3Cl2  6NH4 Cl  N2

6NaOH  hot and conc.  3Cl2 
 5NaCl  NaClO3  3H2O
Fe  2HCl   FeCl2  H2
Liberation of H2 prevents the formation of FeCl3.
Bond dissociation of F – F is less than that of Cl – Cl.
8. (CH3)3SiCl is used to stop the growth of polymerisation of linear polymer formed from the
hydrolysis of (CH3)2SiCl2.
9. Configuration of (B) is (2R, 3S)

Configuration of (C) is (2R, 3S)
10. CH3 O O O
2HIO4
H3C C CH CH2   H3 C C CH3  H C OH  H C H
OH OH OH
11. 1. Addition of inert gas at constant pressure shifts the equilibrium in that direction which has
more number of gaseous moles.
2. Increasing the volume of the container shifts the equilibrium in that direction which has more
number of gaseous moles.
12. Chemisorption unimolecular layer.
7
13. [Cu(NH3)4]2+ → dsp2

[Ni(CN)4]2- → dsp2
[CuCl4]2- → sp3
2- 3
[NiCl4] → sp
14.–15.
CHO CHO H3C
i O3

ii Zn/H2 O
  C O
Me
H3C
CH C CHO
A Me
B  C
H3C H3C OH
 i KCN/H
C O  ii H3 O

 C
H3C H3C CO2H
C
CHO COONa
NaOH 50%  
H /

   O
CHO CH2OH
D  O
16.–18.
ZnS  H2 SO4  ZnSO4  H2 S
A   C B 
 White 
3H2 S  K 2 Cr2 O7  4H2SO 4  K 2 SO 4  Cr2  SO4 3  3S  7H2O
 D
S  O 2  SO 2
 D E 
2H2 S  SO2 
 2H2 O  3S
ZnSO4  2NaOH  Zn  OH2  Na2 SO4
Zn  OH 2  2NaOH  Na2 ZnO2  2H2 O
 Solub le 
SECTION – C
1. A present in corners and face centre.
B present in alternate tetrahedral voids.
1 1 15
No. of A per unit cell = 6   6  
8 2 4
No. of B per unit cell = 4 – 1 = 3
15
x:y :3  5: 4
4
x+y=5+4=9
2. All the compounds undergo hydrolysis.
3. Let the number of -particles emitted be x and the number of -particles emitted be y.
4x = 238 – 206 = 32
x=8
2x – y = 10
2 × 8 – y = 10
y = 6.
8
4. Cl CH2Cl
H3C Cl
CH3 Cl CH3 H
H H H Cl
d   d  
Total number of isomers = 7.
5. H3C CH CH2 CH2 CH3  2

OH
H2C CH CH2 CH3  2
OH CH3
CH3
H3C CH HC  2
OH CH3
H3C CH CH2 CH3  2
OCH3
6. PCl3  3H2 O  H3PO3  3HCl

 dibasic 
Number of moles required to neutralise H3PO3 = 2
Number of moles required to neutralise HCl = 3
Total number of moles of NaOH required to neutralise the solution = 5.
 12 
7. C xH12  g   x   O2  g   xCO2  g  6H2O  g 
 4 
Initial moles of gaseous reactant taken = 1 + (x + 3) = x + 4
Final moles of product formed = x + 6
Number of moles increased = 2
Pressure  Number of moles.
2 2
% of pressure increased   100 , 20   100 , x = 6.
 x  4  x  4
8. N2O, NO and CO are neutral oxides remaining are acidic oxides.
9. The following compounds give positive iodoform test

O O OH
H3C CH CH3 , H3C CH2 OH , H3C C CH3 , C CH3 , CH CH3
OH
10. In the following compound sulphur has +6 oxidation state

H2S2O7, H2SO4, H2SO5, H2S2O8
9
Mathematics PART – III
SECTION – A
2. Let origin be centre of larger circle and O’ be the centre of smaller circle.
Equation of (1): x 2  y2  2
Equation of (2):  x  2 2  y 2  1
5 7 y
 A  , 
4 4  (1)
A (2)
x  xC y  yC
xB  A , yB  A
2 2
2 2
 xC  yC  2 x
O B O’
2 2
 5   7
 x C    yC  
 4 2  4  1

 2   2  C
   

7
 AC 
2
3. Let B (0, 0), C (a, 0), A (h, k) and P  ,   . A

d  A, BC  k

d P, BC   P
Equation of AC is kx   h  a  y  ka  0 B
(0, 0) C (a, 0)
d  B, AC  ka
 
d  P, AC  k   h  a    ka
Equation of AB is kx  hy  0
d  C, AB  ka

d  P, AB  k  h
ha k
Solving,   , 
3 3
4. Ortho–centres of triangles formed by three tangents and corresponding normals to a parabola are
equidistant from axis of parabola.
5. Number beginning with 2 and not divisible by 5 is 6! – 120 = 600

Number beginning with 3 and not divisible by 5 = 600
Number beginning with 5 and not divisible by 5 = 720
Total = 1920
Number beginning with 6 2 and not divisible by 5 is 120 – 24 = 96
 Total = 2016
 2017th number is 6325789
6. PQ T  QTPT  QP  PQ
PQ is symmetric
10
 PQP 1  QPP 1  Q
 P 1PQP 1  P 1Q
 QP 1  P 1Q
T T
P Q 
1
 
 QT P 1  P1Q
8. P  ui   i2  2

 P  ui   k i2  2 
u1, u2, …….., un are mutually exclusive events.
 P  u1   P  u2   ........  P un   1
 k 12  2  22  2  32  2  .......n2  2   1
6
k
n  n  1 2n  1  12n
A  event of drawing a white ball
2 4 6 2n

P  A   k 12  2  
2n  1

 k 22  2 .
2n  1

 k 32  2 . 
2n  1
  
 .....  k n2  2 .
2n  1
k 2 2 2 2
 1 .2  2 .4  3 .6  .....  n .2n  2.2  4.2  6.2  .....  2n.2 
2n  1  
2.k
 13  23  33  ........  n3  2 1  2  3  .....  n  
2n  1  
2
2k  n  n  1 
2
   n  n  1 
2n  1  4 
 
2
2.6 n2 n  1  4n n  1 
  
4  2n  1 n  n  1 2n  1  12n 
2
 1  1 1 
3 1    4  2  3 
 n n n  3
Lt P  A   Lt 2

n n
 1  1  2 1  4
 2    1    12  2  3 
 n   n  n n 
 
sin cos
9. 12  12  2
sin x cos x
10. |z1| = |z2| = 1; |z1 + z2| = 1

  z1  z2  z1  z2   1
|z1 + z2| = |z1| |1 + ei| = 1
|z2 – z1| = |z1| |ei – 1|
100
11.  x1  x100   1
2
50
 x1  d  x100   1
2
11
12. Let y < x

y x
 
x xy
1
 R
1 R
13. (a + b) = x, then x 3 – 21x + 20 = 0

Which has roots 1, 4, –5
SECTION – C
8. 2 1  3  5  7  ......  a   2 1  3  5  7  ......  b   2 1  3  5  7  ......  c 

  a 1   a 1   b 1   b 1   c 1   c 1
 2    1 2  2    1 2    2   2  1 2 2
  2   2   2   2    
2 2 2
  a  1   b  1   c  1
 a  6 and a  b  c  21
 a = 7, b = 5, c = 9
ab  2
3
C1  8P6  3
C1  8P6  3P2  7P5 7
9. p 9

P7 12
 a11 a12   1 1  1 1 a11 a12 

10. a    
 21 a22   2 1 2 1 a21 a22 
 a11  2a12  a11  a21 ..... (i)
a11  a12  2a12  a22 ..... (ii)
a21  2a22  2a11  a21
a21  a22  2a12  a22
 From (ii), a11  a22
a21  2a12
2 2
 a11a22  a21a21  a11   2  a12 
 a11  2a12

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1

Q. No. PHYSICS CHEMISTRY MATHEMATICS

7. Let 1 = 4eV, then 2 = 2eV

8. Induced e.m.f. = Bv = 0.125 V +

12. P.D. same & electric field same

14. P0 + 0.8 wgh + wg(2h) + 1.2 wg(3h) = P0 + 1.2 wgh2

6. Using condition of equilibrium

9. Velocity of first block before collision,

10. By symmetry, no current will flow in arm along x-axis.

3. More activated ring undergo EAS.

7. 8NH3  excess   3Cl2  6NH4 Cl  N2

9. Configuration of (B) is (2R, 3S)

12. Chemisorption unimolecular layer.

13. [Cu(NH3)4]2+ → dsp2

2. All the compounds undergo hydrolysis.

5. H3C CH CH2 CH2 CH3  2

6. PCl3  3H2 O  H3PO3  3HCl

9. The following compounds give positive iodoform test

10. In the following compound sulphur has +6 oxidation state

Mathematics PART – III

3. Let B (0, 0), C (a, 0), A (h, k) and P  ,   . A

5. Number beginning with 2 and not divisible by 5 is 6! – 120 = 600

10. |z1| = |z2| = 1; |z1 + z2| = 1

12. Let y < x

13. (a + b) = x, then x 3 – 21x + 20 = 0

8. 2 1  3  5  7  ......  a   2 1  3  5  7  ......  b   2 1  3  5  7  ......  c 

 a11 a12   1 1  1 1 a11 a12 

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