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JEE Advanced 2017 Solved Paper Brean CHAPTERS BASED ON CLASS 11" SYLLABUS ‘Some Basic Concepts of Chemistry Structure of Atom Classification of Elements and Periodicity in Properties ‘Chemical Bonding and Molecular Structure States of Matter Thermodynamics Equilibrium The s-Block Elements Organic Chemistry — Some Basic Principles & Techniques Hydrocarbons CHAPTERS BASED ON CLASS 12 SYLLABUS The Solid State & Surface Chemistry Solutions Electrochemistry Chemical Kinetics & Nuclear Chemistry General Principles and Processes of Isolation of Elements The p-Block Elements The d- and f-Block Elements & Co-ordination Compounds Haloalkanes and Haloarenes Alcohols, Phenols and Ethers Aldehydes, Ketones and Carboxylic Acids ‘Compounds Containing Nitrogen Carbohydrates, Amino Acids, Polymers & Miscellaneous Match the Following Analytical Chemistry 1-6 7-14 15-18 19-24 25-32 33-40 41-50 51-54 55-68 69-76 77-82 83 - 88 89 - 98 99 - 108 109 - 112 113 - 126 127 - 140 141-144 145 - 152 153 - 168 169 - 180 181 - 188 189 - 192aa BEX) 268 1, Some Basic Concepts of Chemistry 1-16 2. Structure of Atom 17-25 3. Classification of Elements and Periodicity in Properties 26-29 4, Chemical Bonding and Molecular Structure 30-43 5. States of Matter 44-54 6. Thermodynamics 55-64 7. Equilibrium 65-84 8. The s-Block Elements 85 - 88 9. Organic Chemistry — Some Basic Principles & Techniques 89 - 104 10. Hydrocarbons 105 - 117 11, The Solid State & Surface Chemistry 118 - 123, 12. Solutions 124-133, 13. Electrochemistry 134-148, 14. Chemical Kinetics & Nuclear Chemistry 149 - 161 15. General Principles and Processes of Isolation of Elements 162 - 164 16. The p-Block Elements 165 - 180 17. The d- and f-Block Elements & Co-ordination Compounds 181 - 197 18, _Haloalkanes and Haloarenes 198 - 203, 19. Alcohols, Phenols and Ethers 204 - 215 20. Aldehydes, Ketones and Carboxylic Acids 216 - 239 21, Compounds Containing Nitrogen 240 - 253 22. Carbohydrates, Amino Acids, Polymers & Miscellaneous Match the Following 254 - 260 23. Analytical Chemistry 261 - 268 + The chapters have been divided as per the Class 11° & 12 syllabus followed by the NCERT books. Some of the chapters which are spit in the class 11" & 12 syllabus in NCERT have been combined. There might be certain topis/ chapters which are not covered in NCERT but are a part of JEE Advanced/ITJEE syllabus. >_3021ee ar | PAPER-1 Soe ‘This section contains 7 questions. Each question has 4 options (A), (B), (©)and (D). ONE or MORE THAN ONE ofthese four ‘options is (ate) correct. 1. An ideal gas is expanded from (p,. V).;) to (P3. V>.T3) under different conditions, The correct tatement() among the following istare) (A). The work done on the gas is maximum when itis compressed irreversibly from (p. V3) t0 (Pi. V,) against constant pressure p, (B) If the expansion is carried out freely, it is simultaneously both isothermal as well as adiabatic (© The work done by the gas isles when its expanded reversibly fom V; to V; under adiabatic conditions as compared to that when expanded reversibly from YV, 10 V, under isothermal eonditions (D)_Thechange in internal energy of the gas is(i) zero, ifit is expanded reversibly with T = T, and (ii positive, ifitisexpanded reversibly under adiabatic conditions with Ty + Ty 2. Fora solution formed by mixing liquids L and M, the vapour pressure of L. plotted against the mole fraction of M in solution is shown inthe following figure, Here x, and Xyq represent mole fractions of Land M, respectively, in the solution. The correct statement(s) applicable to this system is(are) A Y ww 0 (A). ThepointZ represents vapour pressure of pure liquid ‘Mand Raoult’ law is obeyed from x,=0 t0x,=1 (B) The point represents vapour pressure of pure liquid Land Raoult's law is obeyed when x, -> 1 (©The point represents vapour pressure of pure liquid Mand Raoul’s law is obeyed when x, -> 0 (D) Attractive intermolecular interactions between L-L in pure liquid Land M-M in pure liquid M are stronger than those between L-M when mixed in solution, 3. The correct statement(s) about the oxoacids, HCIO, and HCIO,istare) (A). The central atom in both HCIO, and HICIO is sp? hybridized 8) HCIO, is more acidic than HCIO because of the resonance stabilization ofits anion © CIO, is ormed in the reation between Cl, and 1,0 (D) The conjugate base of HCIO, is weaker base than 1,0 Thecolow ofthe Xp molecules of group 17 element changes gradually from yeliow to violet dow the group. This isdue to (A). Thephysicl state ofX, atroom temperature changes from gas to solid down the group (®) Decrease in ionization energy down the group (©, Decrease in x* ~0* gap down the group {B)_Dezrease in HOMO-LUMO gap down the group Addition of excess aqueous ammonia to pink coloured aqueous solution of MCI; 6H,0(X) and NH,Cl gives an octahedral complex Y in the presence of at. In aqueous solution, complex Y behavesas 1:3 electrolyte. The reaction of X with excess HICI at room temperature results in the formation ofa blue coloured complex Z. The calculated spin only magnetic moment of X and. is 3.87 B.M., whereas itis zer0 for complex Y. Among the following options, which statement()isfare)corret? (A)_ Addition of silver nitrate to ¥ gives only two equivalents ofsilve chloride (8) Thebybridization ofthe central metal ion in Y is sp? ©. Zisatetrahedral complex (D) When XandZare in equilibrium at 0°C, the colour of the solution is pink ‘The IUPAC name(s) ofthe following compound is(are) (A)_{-chloro-4-methylbenzene ®) 4-chlorotoluene (© 4-methyichlorobenzene ©) L-methyi-4-chlorobenzene ‘The correct statement() forthe following addition reactions istare) Ee aprcnc a {Mand N vo oH HG Cth c ayycwc w s+ OntOand Pare identical molecules (B) (Mand O)and (N and P) are two pairs of diastereomers (©) (Mand O)and (N and P) are two pairs ofenantiomers Bromination proceeds through trans-addition in both, the reactions SEs Tt 'S questions. The answer to each question isa SINGLE DIGIT INTEGER ranging ftom 0109, both inclusive, 8. A crystalline solid of a pure substance has a face-centred ‘cubic structure with a cell edge of 400 pm. Ifthe density of ‘the substance in the crystal is 8 gcm3, then the number of atoms present in 256 g ofthe crystal is N * 10°. The value of Nis 9, The conductance of 0.0015 M aqueous solution ofa weak monobasic acid was determined by using a conductivity cell consisting of platinized Pt electrodes. The distance between the electrodes is 120 cm with an area of cross section ‘of I em?, The conductance ofthis solution was found to be 5 x 10°98, The pHof the solution is 4. The value of limiting molar conductivity (AS) ofthis weak monobasic acid in 10. 2, JEE Advanced 2017 Solved Paper ‘aqueous solution is Z 10? em"! mol"! . The value of Z is ‘The sum ofthe number of lone pais of electrons on each central atom inthe following species is [TeBrg}*, [BrF,]*, SNF, and [XeF]- (Atomic numbers: N= 7, F=9, Xe=54) “Among Hp, Hey*, Lip, Bey, By, C;,Np,Oz and F, the number of diamagnetic species is (Atomicnumbers: H= 1, He: N=7,0=8, Among the following, the numberof aromatic compound(s) ‘OAAOO OOCO LD Eocene This section contains 6 questions of MATCHING TYPE, contains two tables each having 3 columnsand 4 rows, Based on each table, there are three questions, Each question has four options (A), (B), (C) and (D) ONLY ONE ofthese four option is correct (Qs. 13-15) : By appropriately matching the information given inthe three columns ofthe following table. ‘The wave function, pm is a mathematical function whose value depends upon spherical polar coordinates (r, 0, 4) of the electron and characterized by the quantum numbersn, land m,. Here's distance from nucleus, 0 iscolatitude and 6 is azimuth. Inthe ‘mathematical functions given inthe table, Zisatomic number and ays Bohr radius ColsmaT Column? Caen 2 {2 2 tse © vam (Ze ° o> © 2sorbiat (®)Oneria nade (© Prbailiy density at mules «1 3 So (a 2} lis) oc! Gi vam <(Z]P re) coso—()Prabatitiy desis maximamat nus % iv) 34,2 orbital (iv) xy-plane isa nodal plane (8) _ Energyneeded to excite electron from n=2 n state ton =4 state is > times the energy needed to excite electron from n=6state state 10 GP_3021