Examen 1.

Diseño de una Secuencia de Destilación para la Sereparación de u

Mezcla de Pentano-Hexano-Heptano, usando el metodo de FUG.

Secuencia directa

TD=120ºF
PD=21.7676 psia
Torre 1

C5=32.666
C6=0.6666
C7=0 TD=120ºF
PD=14.7 psia
TF=180.59ºF
PF=29.267 psia
Comp lbmol/h
C5 33.33 C5=0.6666
C6=32.0101
C6 33.33 C7=0.6666
C7 33.33
TF=332.44ºF
PF=22.2 psia
C5=0.6666
TB=240.8ºF C6=32.666
PB=31.7676 psia C7=33.333
C5=0
C6=32.6334
C7=0.6532
TB= 127.80ºF
PB=24.7 psia

TD= 120 ºF 48.8888888889 ºC

LK= 0.98
HK= 0.02

Componente lbmol/h Fracción A B C

C5 33.33333333 0.3333333333 6.84 1060.8 231.54
C6 33.33333333 0.3333333333 6.88 1175.81 224.86
C7 33.33333333 0.3333333333 6.9 1267.82 216.82
∑ 100

Recuperación en el domo Recuperación en el fondo

Componente lbmol/h Componente lbmol/h
C5 32.66666667 C5 0.6666666667
C6 0.666666667 C6 32.666666667
C7 0 C7 33.333333333
∑ 33.33333333 ∑ 66.666666667
 �=(𝐵/(𝐴−𝑙𝑜𝑔𝑃))+�
PD= 21.76760539 psia
PF= 29.26760539 psia TC5= 524.22284
PB= 31.76760539 psia TC6= 96.0137191
1642.853845 mmHg TC7= 127.284775

Componente lbmol/h zi T T*Zi PmmHg

C5 0.666666667 0.01 524.222840296 5.242228403 6124.72119
C6 32.66666667 0.49 96.0137190702 47.046722344 2690.08246
C7 33.33333333 0.5 127.284774527 63.642387263 1229.9504
TB= 115.93133801 ºC
240.682 ºF
Ecuación de Fenske TF= 180.59 ºF
�_𝑚𝑖�=𝑙𝑜𝑔[(𝑑_𝑖⁄𝑑_𝑗 )(𝑏_𝑗⁄𝑏_𝑖 )]/(𝑙𝑜𝑔[(𝛼_(𝑖,𝑗) )_� (𝛼_(𝑖,𝑗) )]^(1/2) )

di,C5= 0.98 bi,C5= 0.02

dj,C6= 0.02 bj,C6= 0.98

(αi,j)N= 2.9678135 (αm)= 2.5994332407

(αi,j)= 2.276778232

Aplicando ecuación de Fenske

Nmin= 8.147905445 Numero minimo de etapas teoricas

Calculando componentes no clave:

𝑑_�=(�_� (�_�⁄�_� ) (∝_(�,�) )_�^(�_��� ))/(1+(�_�⁄�_� ) (∝_(�,�) )_�^(�_��� ) )
𝑏_𝑖=𝑓_𝑖/(1+(𝑑_𝑟⁄𝑏_𝑟 ) (∝_(�,�) )_𝑀^(�_𝑚𝑖� ) )

br= 32.66666667 dr= 0.6666666667

Componente A B C
C7 6.9 1267.82 216.82

TD= 48.88888889 ºC --> 120 F T B= 115.931338

PD= 21.76760539 psia PB= 31.7676054
 PsatC7= 2.599698887 PsatC7= 23.7833566
Psat ref= 7.433130719 Psat ref= 52.0176998

α= 0.349744809 α= 0.45721662

(αi,j)M= 0.3998864063
TD= 120
bC7= 32.6662860208 TF= 180.59
dC7= 0.0003884141 T B= 240.682

Ecuación de Underwood
𝐹⁄𝐹)[((𝐷𝑋_(𝐿𝐾, 𝐷) ))/((�_� �_(��, 𝐹) ) )−(�_(��,��) )_𝐹 ((��_(��, �))/(�_� �_(��, �) ))]/((�_(��,��) )_�−1)

Alimentación
TF= 180.59 ºF α= 2.4550946764
PF= 29.26760539 psia

(Lꝏ)min= 63.97508847
Rmin= 1.919252654 ; R= 2.4950284502

Ecuación de Gilliland
(�−�_𝑚𝑖�)/(�+1)=1−𝑒𝑥𝑝[((1+54.4�)/(11+117.2�))((𝑋−1)/𝑋^0.5 )]

X= 0.164741376

Sustituyendo en la ecuación de Gilliland

(�−�_���)/(�+1)= 0.491561223

Despejando N
N= 17.19639066 Etapas reales

Ecuación de Kirkbride
_𝑅/�_𝑆 =[(𝑍_(�𝐾,𝐹)/𝑍_(𝐿𝐾,𝐹) ) (𝑋_(𝐿𝐾,𝐵)/�_(��,𝐷) )^2 (𝐵/𝐷)]^0.206

�_�/�_� = 0.8669375635
NR= 7.9853752538 Aprox= 8

Calculando NF :
NF= 9.19639066 Plato de alimentación
n para la Sereparación de una
etodo de FUG.

P(120ºF) zdomo zfondo

22.0601456942 0.98 0.01
7.4331307185 0.02 0.49
2.5996988867 0 0.5

Alimentación Destilado Fondo

PmmHg Psia PmmHg Psia PmmHg Psia
C5 2901.51011322 56.1060429 1140.8349706 22.0601457 6124.72119 118.432767
C6 1135.29352714 21.9529917 384.402514022 7.43313072 2690.08246 52.0176998
C7 462.42352202 8.94181063 134.44278402 2.59969889 1229.9504 23.7833566

Calculando valores de ki para:

Alimentación Destilado Fondo
 ki ki ki
C5 1.9170014823 1.01343925 3.72809864
C6 0.7500781626 0.34147673 1.63744479
C7 0.3055190375 0.11942971 0.74866696

Ppsia
118.432766593
52.0176998099
23.7833566349

82.55 ºC
 ºF 48.8888888889 ºC
ºF 82.55 ºC
ºF 115.931338011 ºC

�,��) )_�−1)
 Torre 2
TD=120ºF
PD=21.7676 psia

C5=32.666
C6=0.6666 TD=120ºF
C7=0
PD=14.7 psia
TF=180.59ºF
PF=29.267 psia
Comp lbmol/h C5=0.6666
C5 33.33 C6=32.0101
C6 33.33 C7=0.6666
C7 33.33
TF=332.44ºF
PF=22.2 psia
TB=240.8ºF C5=0.6666
PB=31.7676 psia C6=32.666
C7=33.333
C5=0
C6=32.6334
C7=0.6532
TB=127.80 ºF
PB=24.7 psia

T B= 120 ºF 48.8888889 ºC
LK= 0.98
HK= 0.02

Componente lbmol/h A B C P(120ºF) zi

C5 0.6666666667 6.84 1060.8 231.54 22.0601457 0.01
C6 32.666666667 6.88 1175.81 224.86 7.43313072 0.49
C7 33.333333333 6.9 1267.82 216.82 2.59969889 0.5
∑ 66.666666667

PD<14.7= 14.7 psia

Recuperación en el domo Recuperación en fondo

Componente lbmol/h Componente lbmol/h
C5 0.66666667 C5 0
C6 32.0133333 C6 0.65333333
C7 0.66666667 C7 32.6666667
∑ 33.3466667 ∑ 33.32

�=(𝐵/(𝐴−𝑙𝑜𝑔𝑃))+�
 �=(𝐵/(𝐴−𝑙𝑜𝑔𝑃))+�
PD = 7.62892406 14.7 psia
PF= 22.2 psia TC7= 551.0119
PB= 24.7 psia TC6= 86.7210882
1277.35438 mmHg TC5= 52.5758206

Componente lbmol/h zB T T*zB PmmHg

C5 0 0 551.0119 0 1303.43418
C6 0.65333333 0.01960784 86.7210882 1.7004135 448.817324
C7 32.6666667 0.98039216 52.5758206 51.5449222 160.511578
TB= 53.2453357 ºC
127.841605 ºF
TF= 332.44 ºF
Ecuación de Fenske 166.911 ºC
�_𝑚𝑖�=𝑙𝑜𝑔[(𝑑_𝑖⁄𝑑_𝑗 )(𝑏_𝑗⁄𝑏_𝑖 )]/(𝑙𝑜𝑔[(𝛼_(𝑖,𝑗) )_� (𝛼_(𝑖,𝑗) )]^(1/2) )

di,C7= 0.02039984 bi,C7= 0.98039216

dj,C6= 0.97960016 bj,C6= 0.01960784

(αi,j)N= 0.34974481
(αi,j)= 0.35763231 (αm)= 0.35366657

Aplicando ecuación de Fenske

Nmin= 7.48858515 Aprox: 8 Numero de etapas minimas

Calculando componentes no clave:

𝑑_𝑖=(𝑓_𝑖 (𝑑_𝑟⁄𝑏_𝑟 ) (∝_(𝑖,𝑟) )_𝑀^(�_𝑚𝑖� ))/(1+(𝑑_𝑟⁄𝑏_𝑟 ) (∝_(𝑖,𝑟) )_𝑀^(�_𝑚𝑖� ) )
𝑏_𝑖=𝑓_𝑖/(1+(𝑑_𝑟⁄𝑏_𝑟 ) (∝_(𝑖,𝑟) )_𝑀^(�_𝑚𝑖� ) )

br= 0.66666667 dr= 32.6666667

Componente A B C
C5 6.84 1060.8 231.54

TD= 48.8888889 ºC T B= 53.2453357

PD = 14.7 psia PB= 24.7
 PsatC5= 22.0601457 psia PsatC7= 25.2043009
Psat ref= 7.43313072 psia Psat ref= 8.67870972

α= 2.9678135 α= 2.904153

(αi,j)M= 2.9358107

bC7= 1.01121969 Fondo

dC7= 65.655447 Domo

Ecuación de Underwood
𝐹=(𝐿_𝐹⁄𝐹)[((𝐷𝑋_(𝐿𝐾, 𝐷) ))/((𝐿_𝐹 𝑋_(𝐿𝐾, 𝐹) ) )−(𝛼_(𝐿𝐾,�𝐾) )_𝐹 ((𝐷𝑋_(�𝐾, 𝐷))/(𝐿_𝐹 𝑋_(�𝐾, 𝐹) ))]/((𝛼_(𝐿𝐾,�𝐾) )_𝐹−1)

Alimentación
TF= 166.911 ºC α= 1.99048452
PF= 22.2 psia

(Lꝏ)min= 69.7313821 lbmol/h

Rmin= 2.09110502 ; R= 2.71843653

Ecuación de Gilliland
(�−�_𝑚𝑖�)/(�+1)=1−𝑒𝑥𝑝[((1+54.4𝑋)/(11+117.2𝑋))((𝑋−1)/𝑋^0.5 )]

X= 0.16870841
Sustituyendo en la ecuación de Gilliland
(�−�_𝑚𝑖�)/(�+1)=
0.48797326

Despejando N
N= 16.6672687 Aprox. = 17 etapas

Ecuación de Kirkbride
�_𝑅/�_𝑆 =[(𝑍_(�𝐾,𝐹)/𝑍_(𝐿𝐾,𝐹) ) (𝑋_(𝐿𝐾,𝐵)/𝑋_(�𝐾,𝐷) )^2 (𝐵/𝐷)]^0.206

�_𝑅/�_𝑆 =
0.75459079
 NR= 7.31113116

Calculando NF :
NF= 9.35613755 Plato de alimentación
 C5=0
C6=32.6334
C7=0.6532

zD zB
0.019992 0
0.96001599 0.01960784
0.019992 0.98039216

Alimentación Destilado Fondo

PmmHg Psia PmmHg Psia PmmHg Psia
C7 15055.327435 291.122489449 1140.83497 22.0601457 1303.43418 25.2043009
C6 7563.6496107 146.257098262 384.402514 7.43313072 448.817324 8.67870972
C5 3945.2174514 76.2880469294 134.442784 2.59969889 160.511578 3.10378703

Calculando valores de ki para:

−𝑙𝑜𝑔𝑃))+� Alimentación Destilado Fondo
−𝑙𝑜𝑔𝑃))+�
ki ki ki
ºC C5 13.1136256509 1.50069018 1.02041704
ºC C6 6.5881575794 0.50565515 0.35136477
ºC C7 3.4363985103 0.17685026 0.12565939

Ppsia
25.2043009
8.67870972
3.10378703

apas minimas

𝑟 ) (∝_(𝑖,𝑟) )_𝑀^(�_𝑚𝑖� ) )

ºC
psia
 psia
psia

((𝛼_(𝐿𝐾,�𝐾) )_𝐹−1)

Fracción de alimentación Vaporizada: 0.092496

F= 66.6666667
(αC6,C7)F = 0.52160236
D = 33.3466667
LF = 60.5002667
XLK,D = 0.96001599
XLK,F = 0.49
XHK,D = 0.019992
XHK,F = 0.5
 R=2.53 Comp lbmol/h zi
N=9
C5 32.666 0.98
C6 0.6666 0.02
Recuperación 0.98 C7 0 0

Comp lbmol/h zi C1 TD=120ºF

PD=21.7676 psia
C5 33.33 0.333
C6 33.33 0.333 NF=4
C7 33.33 0.333
100 1
TF=180.67ºF
PF=29.267 psia

Comp lbmol/h zi
C5 0.6666 0.01
C6 32.666 0.49
C7 33.333 0.5

TB=240.8ºF
PB=31.7676 psia
Comp lbmol/h zi
C5 32.666 0.98
C6 0.6666 0.02
C7 0 0

TD=120ºF
PD=21.7676 psia

R=2.17
N=8

Recuperación 0.98

Comp lbmol/h zi
C2
lbmol/h zi C5 0.6666 0.01 NF=4
0.6666 0.01 C6 32.666 0.49
32.666 0.49 C7 33.333 0.5
33.333 0.5

0.8ºF TF=332.44ºF
.7676 psia PF=22.2 psia
Comp lbmol/h zi
C5 0.6666 0.019
C6 32.0101 0.96
C7 0.6666 0.019

TD=120ºF
PD=14.7 psia

Comp lbmol/h zi
C5 0 0
C6 32.6334 0.019
C7 0.6532 0.9809

TB=127.80 ºF
PB=24.7 psia