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WASTEWATER
TREATMENT
NL4NUALS
PRIMARY,
SECONDARY ANL
TERTIARY
TREATMENT
document
contains '3t pages
WASTE WATER TREATMENT
MANUALS
Parts of this publication may be reproduced without further permission, provided the
source is acknowledged.
ISBN 1 899965 46 7
Price Ir15 1/97/400
CONTENTS i
TABLE OF CONTENTS
ACKNOWLEDGEMENTS viii
PREFACE ix
ABBREVIATIONS x
1.2 LEGISLATION 1
OF WASTE WATER
2.3 LABORATORYACCREDITATION 7
2.6 TELEMETRY 10
3.2 BACTERIALGROWTH 14
3.3 INHIBITION 16
4.1 PROCESSDESCRIPTION 19
4.2 PRIMARYSETTLEMENTTANKS 19
5.5 SLUDGESETTLEABILITY 28
5.6 RETURNACTIVATEDSLUDGE(RAS) 29
5.7 WASTEACTIVATEDSLUDGE(WAS) 30
5.10 SLUDGEAGE 31
5.16 FOAMING 39
5.18.2ASHING 42
5.18.3 PIN-POINT FLOC 42
5.18.4 FILAMENTOUS BULKING 42
5.18.5 NON-FILAMENTOUS BULKING 43
5.18.6 STRAGGLER FLOC 43
5.19 BIOLOGICAL ACTIVITY 43
5.19.1 MONITORING BIOLOGICAL ACTIVITY 43
5.20 ENERGY 45
5.21 LABORATORYEQUIPMENT 46
6.2 PERCOLATINGFILTERS 47
6.2.1 SHAPES ANDCONFIGURATIONS 47
6.2.2BIOLOGICAL SLIME 47
6.2.3MEDIA 48
6.2.4MASS TRANSFER ACROSS SLIME INTERFACES 48
6.2.5DISTRIBUTION OF FEED 49
6.2.6OUTFLOW COLLECTION (UNDERDRAINS) 49
6.2.7OXYGENSUPPLY 50
6.2.8FINALOR SECONDARY SETFLING 50
6.2.9RECIRCULATION 50
6.2.10 COLDTEMPERATURE OPERATION 50
6.2.11 CLASSIFICATION ANDCONFIGURATION OF FILTERS 51
6.2.12 COMMON OPERATING PROBLEMS 54
6.3 ROTATING BIOLOGICAL CONTACTORS 55
6.4 SUBMERGEDFILTERS 56
6.4.1 PRINCIPLE OF OPERATION 56
6.4.2 UPFLOW OR DOWNFLOW 57
6.4.3 MEDIA SELECTION 57
6.4.4 AERATION SYSTEM 57
6.4.5 LOADING RATES 57
/
6.4.6 BACKWASH REQUIREMENTS AIR SCOUR 59
6.4.7 OUTFLOW CHARACTERISTICS 60
6.4.8 RELATIONSHIP WITHOTHERUNITPROCESSES 60
6.4.9DISSOLVED OXYGENCONTROL 60
6.4.10 COMMONOPERATING PROBLEMS 61
6.4.11 NUISANCE 61
8. DISINFECTION 71
8.1 INTRODUCTION 71
8.4 ULTRA-VIOLETDISINFECTION 72
8.5 MEMBRANETECHNOLOGY 72
9.1 INTRODUCTION 73
9.3 HYDRAULICPROFILES 74
9.4 PUMPS 76
10.1 INTRODUCTION 79
10.3 NOISE 81
10.3.1 NOISE CONTROL 82
10.4 VISUALIMPACT 83
10.5 PESTS 83
11.3 pH NEUTRALISATION 87
11.5 ORGANICCONSTITUENTS 87
12.4 ORGANISATIONANDPERSONNEL 90
12.6 OPERATIONALCONTROL 90
12.7 ENVIRONMENTALMANAGEMENTDOCUMENTATIONANDRECORDS 90
REFERENCES 93
GLOSSARY 95
APPENDICES 101
LiST OF TABLES
Table2.1 Physicaland chemical characteristics ofwaste water and their sources 6
Table2.2 Typicalcharacteristics of urbanwastewater 9
Table3.1 Reported inhibition thresholdlevels 17
Table5.1 Typicalperformance data for selected aeration devices 26
Table5.2 Comparison betweenFIM ratio and sludgeage 32
Table5.3 Operating at a high FIM ratio (low sludge age) 32
Table5.4 Operating at a low F/M ratio (high sludge age) 32
Table5.5 Operational relationships betweenRAS and WAS 33
Table5.6 Loadingand operational parameters for activatedsludge processes 34
Table5.7 Applications of activated sludge process variations 39
Table5.8 Whitefoam 40
Table5.9 Excessivebrownfoams 40
Table5.10 Black foams 40
Table5.11 Classification of activated sludges 41
Table5.12 Sizeof micro-organisms used in wastewater treatment 43
Table5.13 Operating costsofKillarney wastewater treatment plantduring 1995 45
Table6.1 Classification of percolating filters 51
Table6.2 Ponding on percolating filters 54
Table6.3 Upflow or downflow submerged filters 59
Table7.1 Chemical phosphorus removal performance 66
Table7.2 Nutrient removal process selection and application 69
Table 8.1 Membrane type and application 72
Table9.1 Typicalheadlosses acrossvarious treatmentunits 75
Table 10.1 Odourthresholds of common odourous gases 79
Table 10.2 Odourpotential from wastewatertreatmentprocesses 80
Table 10.3 A-weighting adjustments 81
Table 10.4 Conversion ofoctave levels to A-weighted levels 82
Table 10.5 Approximate range ofnoisereduction 83
Table 11.1 Reported inhibition thresholdlevels 85
Table 11.2 Technologies available for the pretreatment of industrial discharges 86
Table 11.3 Pretreatment optionsfor selected discharges 88
CONTENTS vii
UST OF HGURES
Figure 1.1 Waste watertreatment plantoverview 3
Figure2.1 Growthrate of micro-organisms as a functionofpH 6
Figure 2.2 Typicalcomposition of urbanwastewater 7
Figure 2.3 Diurnaland seasonal flow variations to a treatment plant 8
Figure 3.1 Metabolism and transportmechanisms in bacterial cells 14
Figure 3.2 Examples ofprotozoa and rotifera 14
Figure 3.3 Relativepredominance oforganismsused in wastewater treatment 15
Figure 3.4 Bacterial growth curve 15
Figure 4.1 Settling theory 19
Figure 4.2 Circular radialflow settlement tank 20
Figure 4.3 Rectangular horizontal flow settlement tank 21
Figure 4.4 Imhofftank 21
Figure 4.5 Inclined settlement system 22
Figure 4.6 Dissolved air flotation 22
Figure 5.1 Activated sludge process 23
Figure 5.2 Aeration devices 25
Figure 5.3 Comparison of aeration efficiency and depth ofimmersion ofaerators 26
Figure5.4 Settling velocity v. time and initial MLSS concentration for goodsettlingmixed liquors 28
Figure5.5 Activated sludge growthcurve 34
Figure5.6 A-Bactivatedsludge process 35
Figure5.7 Completely mixed activated sludge system 35
Figure 5.8 Plug flow activated sludge system 36
Figure 5.9 Tapered aeration 36
Figure 5.10 Step feed 36
Figure 5.11 Pasveeroxidation ditch 37
Figure 5.12 Carouseloxidation ditch 37
Figure 5.13 Sequencing batchreactor 38
Figure 5.14 Deep shaft activated sludge 38
Figure 5.15 Predominance ofmicro-organisms in relationto operating conditions 44
Figure 5.16 Powerrequirements as a function of mixed liquorDO 45
Figure 5.17 Oxygenconsumption 45
Figure 6.1 Percolating filter 48
Figure 6.2 Transport mechanism acrossthe biofilm 49
Figure 6.3 Diffusion across the biofilm 49
Figure 6.4 Hydraulic effectofrecirculation on humustanks 50
Figure6.5 Configurations of percolating filters 52
Figure6.6 Rotating biologicalcontactor 56
Figure6.7 Sparge pipes for aeration 57
Figure6.8 Submerged biological aeratedfilters 58
Figure7.1 Biological pre-denitrification and the effectof recirculation ratio 65
Figure7.2 Biological post-denitrification 65
Figure7.3 Simultaneous biological nitrification and denitrification 65
Figure7.4 Dosing pointsforthe chemical precipitation ofphosphorus 67
Figure 7.5 Illustration ofcell mechanism for Prelease and luxury uptake 67
Figure 7.6 Phostripprocess 68
Figure 7.7 ModifiedPhoredox, A2/O,3-stage Bardenpho process 69
Figure 7.8 UCT,VIPprocess 69
Figure 9.1 Sourceof pumpingheadlosses 73
Figure 9.2 Pump systemhead curve 74
Figure 9.3 Hydraulic profilefor a secondary waste water treatment plant 75
Figure9.4 Types ofpumpsand applications 77
Figure9.5 Centrifugal pumpperformance curves 77
Figure 11.1 Methodsof flow balancing 87
Figure 12.1 Management systemof a waste water treatment plant 89
viii TREATMENT OF WASTE WATER
ACKNOWLEDGEMENTS
The Agency wishes to acknowledge those who contributed to and reviewed this manual. The Agency
personnel involved in the preparation and production of this manual were Gerry Carty, Gerard O'Leary and
Brian Meaney.
A review panelwas established by theAgency to assistin the finalisation of themanual and we acknowledge
below those persons who took the time to offer valuable information, advice and in many cases comments
and constructive criticism on the draftmanual.
Mr. JohnKilgallon,Forbairt
Mr. John O'Nynn, (representing the County and CityManagers Association), Waterford Co.Co.
The Agency also wishes to acknowledge the assistance of Engineering Inspectors of the Department of the
Environment and the Sanitary Services Sub-committee of the Regional Laboratory, Kilkenny, both of whom
commented on the draftmanual.
PREFACEix
PREFACE
The EnvironmentalProtectionAgency was established in 1993 to license, regulateand control activities for
the purposesofenvironmental protection. In Section 60 of the Environmental Protection Agency Act, 1992,
it is stated that "the Agency may, and shall if so directed by the Minister, specfy andpublish criteria and
procedures, which in the opinion of the Agency are reasonable and desirable for the purposes of
environmental protection, in relation to the management, maintenance, supervision, operation or use ofall
orspecified classes ofplant, sewers or drainagepipes vestedin orcontrolledor usedby a sanitaryauthority
for the treatment or disposalofany sewage or other effluent to any waters ". Criteria and procedures in
relation to the treatment and disposal of sewage are being published by the Agency in a numberof manuals
under the general heading: 'Waste Water Treatment Manuals'. Where criteria and procedures are published
by the Agency,a sanitary authority shall, in the performance ofits functions, haveregardto them.
This manual on Primary, Secondary and Tertiary Treatment sets out the general principles and practices
which should be followedby those involved in the treatment of urban waste water. It providescriteria and
procedures for the proper management, maintenance, supervision, operation and use of the processes and
equipment required for the secondary treatment of wastewater. The Agency hopes that it will provide
practical guidance to those involved in plant operation, use, management, maintenance and supervision.
Where reference in the document is made to proprietary equipment, this is intended as indicating equipment
type and is not to be interpreted as endorsing or excluding any particularmanufacturer or system.
The Agency welcomes any suggestions whichusers ofthe manual wishto make. Theseshouldbe returnedto
the Environmental Management and Planning Division at the Agency headquarters on the enclosed User
Comment Form.
x TREATMENT OF WASTE WATER
ABBREVIATIONS
[..] concentration of.. parameter
Agency Environmental Protection Agency
BOD biochemical oxygen demand
BOD5 five-day biochemical oxygendemand
cm centimetre
COD chemical oxygendemand
°C degreesCelsius
d day
DAF dissolved ar flotation
dB(A) decibels (A-weighting filter that simulates the subjective response of the
human ear)
DO dissolved oxygen
DWF dry weatherflow
EC50 concentration of toxin required to cause a specified effect on 50% of the
test organisms
EPA Environmental Protection Agency
FIM food to micro-organism ratio
FOG fats, oils and grease
g gram
h hour
Hz hertz
IPC Integrated Pollution Control
ISO International Standards Organisation
kg kilogram
K, oxygentransfercoefficient
km kilometre
kP kilopascal
litre
m metre
mg milligram
MLSS mixed liquor suspended solids
MLVSS mixed liquor volatile suspended solids
mm millimetre
rn/s metresper second
N Newton
NAB National Accreditation Board
OC oxygenation capacity
ABBREVIATIONS xi
Pa Pascal
p.e. population equivalent
PHB polyhydroxyl butyrates
ppm parts per million
RAS return activated sludge
RBC rotatingbiological contactors
s second
SCFA short chain fatty acids
S.I. statutory instrument
SSA specific surface area
SS suspended solids
SSVI specific sludge volumeindex
SVI sludgevolume index
TOC total organic carbon
TSS total suspended solids
UWWT urban wastewater treatment
WAS waste activated sludge
xii TREATMENT OF WASTE WATER
1 TREATMENT OF WASTE WATER 1
Biological treatment of waste waters takes place meeting the standards for sensitive waters
in fixed media or suspended growth reactors whereprescribed;
using activated sludge, biofiltration, rotating
biological contactors, constructed wetlands or minimising odours and thus avoiding
variantsof these processes. nuisance complaints;
Collection network
StormWaterReturn
SludgeLiquors Return
r
Pretreatment works
and stormwater overflow
+
Stormwater Primarysedimentation — —
balancing/storage
I
Biological treatment
Process RAS
recycle
Sludge
*___
%
J treatment/storage
• Secondary settlement
or clarification
4
— i
Nutrient removal
r--+ Sludgere-use/disposal
— — — —
Sludge
Receiving water
Wastewater
Processes described
in this manual
FIGuRE1.1 WASTEWATERTREATMENTPLANTOVERVIEW
4 TREATMENT OF WASTE WATER
2 GENERAL CONSIDERATIONS 5
pH: This is theconcentration of hydrogen ions in Total phosphorus: This parameter is normally
solution and indicates the level of acidity or divided into threefractions,namely:
alkalinity ofan aqueous solution. If the pH ofthe
waste water is outside the range 5-10, there may orthophosphate: dissolved inorganic
be considerable interference with biological phosphate (P043)
processes. Figure 2.1 illustrates the effect of pH
on bacterialgrowth. polyphosphates: complexcompounds
generally derived from
detergents
Water
99.9%
100% 4
800 mg/I Dissolved
solids
1000mg/i
Non-settleable
70mg/I
4 solids (colloidal)
200 mg/i
130 mg/I
and operation of both the collection system and (Water Pollution) Acts 1977 and 1990 or the
thetreatment plant. IPC licence issued under the EPA Act, 1992.
Alternatively, an industry's metered water
For large scale treatment plants, it is common to consumption figurescan be used:
design the plant for a maximum 3 times Dry infiltration:
Weather Flow (DWF). On smaller plants, the
scale of plant and the cost implications of a surface water and storm water (except in
higher design coefficient are less significant and separate systems).
the figure is normally taken as 4 to 6 times DWF
depending on whether the sewerage system is The flow entering a plant can vary from hour to
combined or partially separate. This approach is hour. day to day, week to week and season to
generally followed for treatment plants up to season. Figure 2.3 illustrates an example of
2,000p.e. and may wellbe desirable up to at least diurnalflow variation.
5,000p.e.
Appendix B contains a summary table of the
2.4.1 HYDRAULIC LOADING characteristics of some common industrial
discharges.
The flow entering an urban waste water treatment
plant includes: 2.4.2 ORGANIC LOADING
domestic waste water; The organic loading entering the waste water
treatment plant will be determinedby the volume
industrial waste water discharges: data can be
and strength of the industrial waste water in
obtained from discharge licences issued in addition to the population served.
accordance with the Local Government
120
100
80
60
40
20
nteter
0 I I I I I I I I I I I
00:00 02:00 (1)4:00 06:00 08:00 10:00 12:00 14:00 16:00 18:00 20:00 22:00
Hours
New cells -
ftO jProductsof
respiration
Free
particle
organics
MECHANISMSIN BACTERIALCELLS
FIGURE 3.1 METABOLISMAND TRANSPORT
(CRS Group, 1978)
Bacterialand protozoan populations do not exist animals important to waste water treatment and
in isolation; they interact, causing modifications their relative abundance.
to each other's population and activities.
Although protozoa remove bacteriaby predation, 3.2 BACTERIALGROWTH
treatment of waste water occurs at a faster rate
whenboth classesofmicro-organism are present. Under batch conditions bacterial growth can be
k
predicted usingthe growth curve illustratedin
1
Higher life forms
Lower life forms
uspended& dissolved
Tganic matter
Percolating filter
process
I- Conventional Extended
aeration zone aerationzone
Contact time
Rotary sludge
scraper
Part H
Stilling box Reduces the velocity and distributes flow radially through the tank.
Outflow weir Ensuresequal flow along the periphery of the outflow channel.
Outflow channel Collectsthe outflow and carries it to the next treatment stage.
Rotary sludge scraper Moves the sludge downthe floor slopeto the collection hopper.
Scumbaffle Extends above the watersurface and prevents floating material from reaching the
outflow channel. The collectedscum is directed by a surface skimmer to a scum
box from whereit is typicallydischarged withthe excess sludge.
The efficiency of the primary settlement tank is return liquors from other treatment stages
dependent on a numberof factors, including: (e.g. sludge dewatering) which may contain
suspended solids with varying settlement
• the type of solids present inthe waste water: qualities.
this will typically be influenced by the type
and quantity of industrial waste entering the Notwithstanding the above, primary sludge lends
itself well to anaerobic digestion and resource
plant; recovery as well as to the production of well
• the length of time the waste water is in the stabilised sludges. Resource recovery (i.e.
collecting system: degradation of the waste methane gas) is economically viable because of
water can generate gas bubbles (H2S) as a the high level of substrate available as opposed to
result of anaerobic conditions and this can waste activated sludge where the substrate has
affect the settlementof solids; already been substantially digested.
• design criteria being exceeded: the most 4.3 SEPTIC TANKSAND IMHOFF TANKS
important criteria being the retentiontime in
the tank which is usually about 2 hours at The oldest type of primary treatment is the septic
maximum flow, the overflow (surface tank which has been often used to provide waste
loading) rate which is typically 28.8-36 water treatment for single houses and small
m3/m2/day (at peak flow) and the weir communities. The conventional system consists
overflow rate measured in m3/mlday; of a septic tank and a percolation area.
Percolation areas are also known as seepage
• sludge withdrawal: sludge should be fields or beds, subsurface areas or soil absorption
removed regularly to prevent septicity which systems.
can cause floating sludge: and
4 PRIMARYTREATMENT 21
Outflow
weir
Influent
Inlet baffle Scum baffle
Ii Outflow
__ J jnei
direction flow
Sludge
outlet
— HD Sludge scraper mechanism
H
Sludge
- hopper—
A
Part Purpose
Inlet baffle Distributes the inflow evenly and prevents short-circuiting along the tank
surface.
Outflow weir Ensures equal flowalong the length ofthe outflow channel.
Outflow channel Collects the outflow and carries it to the nexttreatmentstage.
Sludge scraper Moves the sludge alongthe floor to collection hopper.
Scumbaffle Extends above the water surface and preventsfloating material from reaching
the outflow channel. The collectedscum is directed by a surface skimmerto a
scum box from whereit is typically discharged withthe excess sludge.
The main function of a septic tank is to act as a aluminium sulphate (alum), ferric chloride, lime
primary settlement tank removing some of the and polymercan be added to the incoming waste
BOD and the majority of the suspended solids water to produce a floc, which will form an
from the waste water; the removal of suspended insoluble compound that adsorbs colloidal matter,
solids significantly reduces the extent of clogging attracts non-settleable suspended solids and
in the subsurface percolation area. encourages settlement.
Inclined surfacesin a settlement tank increase the Dissolved air flotation (DAF) involves the
effective surface area available for settlement and dissOlution of air in waste water by pressurising it
also increase efficiency by more closely in a pressure vessel. When the air saturated waste
approximating to ideal settlement theory. The water is released to the flotation tank, the sudden
increased surface area is provided by a series of decreasein pressure causes the air to come out of
inclined plates (lamellae) or tubes (which may be solution as micro-bubbles which will attach
circular, square, hexagonal or other) occupying themselves to solid particles in the waste water
up to 70% of the tank depth and lying less than 30 and make them float. The result is a floating mat
cm beneath the water surface. Typical tube size of sludge on the surface which is skimmed off.
or diameter is 25-50mm. They are set at an angle Clarified waste water exits under a solids
greater than 40° so that settled sludge falls to the retention baffle. DAF tanks can be circular or
base ofthe tank from where it may be removed by rectangular in shape. As in a gravity settlement
conventional methods of desludging. Providing tank, the retention period must be long enough to
an increased available surface area can result in: allow for adequate separation of the solid and
liquid fractions.
the use of a smaller tank thereby saving
capital costs; and A variation on the process called dispersed air
flotation does not use expensive pressure vessels
an increased capacity in an overloaded tank by and pumps to entrain air in the waste water.
retrofitting. Instead, mechanical devices such as rapidly
Ettlertt rotating impellers incorporating air sparges
provide small bubbles which will attach
themselves to solid particles. This method is
cheaper to purchase and operate and is generally
available on a smaller scale for use in package
plants.
DAF is not commonly applied for the routine
Lmdi ttk, Oprtoool nebooio.bo
separation of solids and liquids in urban waste
water but is more frequently used on difficult
FIGURE 4.5 INCLINED SETTLEMENTSYSTEM wastes or for the pretreatment of effluents, for
Some drawbacks of tube and lamella settlers example. in the removal of fats, oil and grease.
include: Other applications have included the thickening
of mixed liquor wasted directly from the activated
• a tendency to clog due to an accumulation of sludge aeration basin.
fats and grease. These materials should be
thickened
removed upstream; drretronel belt nlndge
Si Se
SR
the control and disposal of scum and The theoretical oxygen requirement can be
supernatants. calculated by assuming that the biodegradable
matter is converted to carbon dioxide, water and
5.2 MIXEDLIQUOR SUSPENDED SOLIDS energy.
The solids present in the aeration tank of an If the simple sugar glucose is the only compound
activated sludge process are termed mixed liquor in the waste water, it is possible to estimate the
suspended solids (MLSS) while the liquid exact oxygen requirement by writing down a
suspension is called mixed liquor. MLSS balanced equation:
concentrations are measured and used by
operators to monitorthe biomass levels present in C6H1206 + 6O — 6C02 + 6H20
the aeration tank. Different activated sludge
processes operate at different MLSS values for To completely oxidise one glucose molecule, 6
different process objectives. molecules of oxygen are required. In reality
however, such theoretical calculations become
5 ACTIVAtED SLUDGE 25
: .. . :
•: •'.
•-
.
• submerged diffusion usingair blowers; and . •..• . • •
• combinations of mechanical and diffused
______ —
air
systems.
V
•0 0 •• •
aerator. This is controlled by raising or lowering by recording the DO at regular intervals. The
theaeratoror the liquid surface level. oxygen transfer coefficient (KLa) may then be
determined.
To alter the liquid surface level, the outlet weir
TABLE 5.1 TYPICAL PERFORMANCEDATA FOR
may be adjusted either manually or automatically
(in response to a signal from a dissolved oxygen SELECTEDAERATIONDEVICES
probe). Power consumption typically increases
with the depth of immersion of the aerator. Aeration Device Oxygen
TransferRate,
However, as Figure 5.3 shows, a point will be
reachedwhere the oxygentransferwill not always kgO2/kWh
increase in tandem with an increase in power. In
the example, after two thirds immersion no Fine bubblediffusers 2.0 - 2.5
appreciable increase in oxygen transfer occurred
but the power consumption increased by a further Coarsebubblediffusers 0.8- 1.2
30%. Aeration equipment is a significant energy
user, therefore the aerator should be checked to Vertical shaft aerators up to 2.0
ensure that the depth of immersion does not
exceedthe required oxygentransfercapacity. Horizontal shaft aerators up to 2.0
<ontal aerator
temperature:
mixing intensity;
-
tankgeometry; and
Aerator immersion,mm
characteristics of the water.
K (tapwater)
. 5.3.4 PRACTICAL APPLICATION
EQUATION5.5
EQUATION5.3 _____ ____
OD = 0.75 Q (BOD - BODe)
C20(waste water)
__________________ • total demand carbonaceous
oxygendemand
-
C520(tapwater) .
+2VA. MLSS
where C20 is the saturation concentration of endogenous oxygen demand
oxygen at 20°C. Values may vary from 0.7 to +4.3Q(Ammi-Amme)
0.98 with a valueof 0.95 being commonly used.
nitrification oxygen demand
To predict the oxygen transfer rates for - 2.83 Q [(Amm, - Amm)- Nel
mechanical surface aerators based on field
measurements the following relationship is used: oxygen derived from denitrifiation in
ananoxiczone
EQUATION5.4 where: OD= mass ofoxygen required(g/h)
BOD= inflowBOD(mg/I)
OTRf =
C 0T-20.a BOD, = outflow BOD(mg/I)
SOTR[CS
C520 )
Amm, = inflowammoniacal nitrogen (mg/I)
where: Amen. = outflow ammoniacalnitrogen(mg/I)
5.4 CLARIFICATION OF MIXED LIQUOR valuesgreaterthan 120 ml/g indicate poor settling
characteristics.
The purposeof a secondary settlement tank is to:
• remove suspended solids; and
MISS 1518) mg/i
• returnsettledsludge to the aerationtank.
6
out underquiescent conditions and therefore does to changes in inflow loading rates by adjusting
not mirror the hydraulic conditions in the RAS flowratesis vital to good plant performance.
settlement tank where there is always some Typically, RAS flow rates are 50 to 100% of the
degree of turbulence and flocculation- of the waste water flow rate (DWF) for large plants and
sludge solids. At MLSS concentrations in excess up to 150% of DWF for smallerplants. All RAS
of 2500 mg/I, wall effects may occur in the flowrates should be adjustable either manually or
measuring cylinder, resulting in interference in by using inverter driveson variablespeed pumps.
the rate of settlement. Other problems with the Having up to 150% of DWF in RAS pumping
test include denitrification of the sludge and capacity will improve the flexibility of a plant in
flotation of the sludge solids. To overcome these responding to varying operating conditions.
problems the stirred specific volume index
(SSVI), traditionally used in design studies, Many techniques are employed to determine the
should be used. Settlement is measured in a return sludge rate. The control strategies are
special settling column where wall effects are based on either maintaining a target MLSS
reducedby a stirrer rotating at one revolution per concentration in the aeration tank or a target
minute. The mixed liquor is maintained at a sludge blanket level in the secondary settlement
constant temperature. The test gives a better tank. The more common controltechniques are:
simulation of the settling pattern in the
settlement tank due to reduced walleffectsat high • observation ofthe sludge blanketheight;
MLSS. • the sludgesettleability test;
Depending on the density of a settled sludge • maintaining a solids balance across the
(which is indicated by the SVI or SSVI), the aeration tank; and
volume of return activated sludge will needto be
• maintaining a solids balance across the
altered in order to maintain the desired mass of
secondary settlement tank.
sludge solids in the aeration tank.
Ifthesludge blanketlevel is used as a control, the
The visibility depth is a useful guide in assessing operatorwill be required to adjustthe RAS rate to
the performance of a secondary settlement tank. maintain a targetlevel in the secondary settlement
It measures the turbidity of the liquid by dipping tank. To successfully use this control the
a graduated disc to a depth at which it is no operatorwill haveto be awareofthe variations in
longervisible. diurnal flow, sludge production variations and
changes in the settling characteristics of the
Many process problems are caused by secondary sludge.
settlement tanks not performing efficiently.
Instrumentation has been developed to monitor
Using the sludgesettleability test, the return flow
their performance. Theseinstruments measure: rate is based on the sludge volume index (SVI).
The RAS flow rate (QR), in m3/day, may be
• the level ofthe sludge blanket;
calculated from the following equation:
• the concentration of suspended solids;
EQUATION5.7
• the returnactivated sludge flowrate;
• the turbidity ofthesupernatant; and = Settled sludgevolume(ml/ I) xQ(m3 / day)
R
/
l000ml I—Settledsludgevolume(ml/1)
• theconcentration ofdissolved oxygen.
A solids balance across the aeration tank may be
5.6 RETURN ACTIVATED SLUDGE(RAS) used to determine the sludge return rate:
The purpose of RAS is to maintain an adequate EQUATION5.8
numberof micro-organisms in the aeration tank to
Solids entering = Solidsleaving
deal with the load (food) entering the plant. The
the aeration theaeration
sludge returned contains micro-organisms that
have the ability to feed on organic matter in the tank tank
wastewater. -
A solids balance across the secondary settlement maintaining a constant Food to Micro-
tank may also be used to determine the sludge organisms ratio (FIM): or
returnrate. In other words:
maintaining a constantsludge age.
EQUATION 5.10
5.9 SOLIDS LOADING RATE (F/M RATIO)
Solids entering Solids leaving
thesecondary thesecondary The solids loading rate or the food to micro-
settlementtank settlement tank organism ratio is defined as the ratio between the
mass of food entering the treatment plant and the
or, referringto Figure5.1: massof micro-organisms in the aeration tank.
MLSS (Q + QR) = QR .SR+ Qw Sw + (Q - Qw) S EQUATION 5.12
BOD(mg/1)xQ
rearranged to determine the RAS flow rate (QR) where: kgBOD / day =
1000
in m3/day:
and MLSSVA
EQUATION5.11 kgMLSS= 1000
MLSS.Q-Qw.Sw The F/M ratio is an important control parameter
QR = — MLSS
SR as the quantity of biomass present will influence
the removal efficiency. The F/M ratio relates to
5.7 WASTEACTIVATED SLUDGE (WAS) the biological state of the plant and is
independent of the size of the aeration tank.
Excess activated sludge generated as a result of Hence, two different activated sludge processes
biological activity has to be removed from the can havethe same process efficiency by operating
system to maintain the desired MLSS in the at the same FIM ratio. If the operatoris aware
aeration tank. Concentrated sludge is generally of the load entering the plant he can ensure that
removed from the secondary settlement tank or sufficient biomass (micro-organisms) is present in
from the return sludge line. Mixed liquor can the aeration tankto react with the load.
also be extracted directly from the aeration tank.
Where the optimum FIM ratio has been
Typically, 1AS and WAS pumps are located in
the same chamber. determined, the optimum or desired mass of
MLSS may be calculated by re-arranging
Equation 5.12:
:
EQUATION5.13
Aeraonrnnk Seondr
_______________ tIiog rnnk
kgMLSS = kgBOD/day
F/M
the amount of sludge wasted from the system. If needs to be wasted on a daily basis in order to
the actual mass of MLSS is greater than the maintain this can be quantified using the formula:
desired mass of MLSS then a proportion of the
mixed liquor must be wasted from the system. EQUATION 5.18
= MLSS(VA + Vc)
The wastage rate may be calculated from the
following mass balance: Sludge age x
EQUATION 5.14
Actual — Desired = mass of sludge Sludge age measures the length of time (in days)
solids to be that the sludge solids are held within the system.
kgMLSS kgMLSS
Sufficient time must be allowed for the micro-
wasted, kg
organisms in the system to react with the waste
The WAS flow rate (Qw) is then computed using water, otherwise the qualityof the outflow will be
thefollowing relationship: affected. Conversely, iftoo much time is allowed
the micro-organisms tend to die off and the
EQUATION 5.15 outflow will contain "fine" solids because large
massof sludgesolids wasted x 1000 portions of the floc will be inactive.
Q SW
5.11 COMPARISON BETWEEN F/M
where mass of sludge solids wasted is in kg/day, RATIOANDSLUDGE AGE
S is in mgIl and Qw is in m3/day.
Waste water treatment plants can be operated
5.10 SLUDGEAGE using eitherthe FIM ratio or the sludge age. Both
methods rely on regulating the rate of growth and
Sludge age is defined as the total mass of sludge metabolism of the microbial population.
contained in the aeration tank divided by the total Maintaining a constant F/M ratio requires fewer
mass ofsludgewasted daily, including suspended analytical results at the treatment plant in
solids discharged with the outflow. Sludge age comparison to•use of the sludge age technique.
and mean cell residence time are taken to mean However, both methods are interrelated and
the same and relate to the length of time the changing one control affects the other control.
bacterial celllfloc remainsin the activatedsludge Table5.2 sets out a comparison of FIM ratio and
system. It is calculated from the quantity of sludge age.
active solids in the system divided by the daily
loss ofactive solids from the system: 5.12 ADVANTAGES OFHIGH ANDLOW
F/M RATIOS
EQUATION5.16
( MLSS(VA+Vc)
Table 5.6 outlines the operating parameters
associated with various modes of operating an
Sludge age=
w 5w+ (Q_QW)Se J activated sludge plant and shouldbe referredto in
determining what is a high or low F/M ratio.
The concentration of suspended solids in the
outflow is normally small compared to the A plantoperating at the high end of the F/M ratio
concentration in the WAS and so the term (Q- spectrum is characterised by a low concentration
Qw)Secan be ignored, i.e. of MLSS and a low sludge age. The advantages
and possible problemsof operating in this mode
EQUATION5.17 are outlinedin Table5.3.
changes in the process or the inflow to the plant. the BUD load (including variability) and
The operating F/M of a plantis influencedby:
temperature (ambient and waste water) and
thedesired mode of operatiom seasonal changes.
Control Constant load: select the desired Waste a percentage of total solids
MLSS and maintain it by wasting regularly.
the correctamount ofsolids.
e.g. to controlsludge age to 5 days,
Variable load: maintain a constant 20% of the solids will have to be
ratio by adjusting MLSS as inflow removed daily.
changes.
Measurements required kg of MLSS, inflow BOD. kg of MLSS and kg of sludge
concentration and dailyflowrate. wasted.
Sludge return The return ratio is dependenton the The return ratio is the same as in
MLSSand the RAS concentrations. the F/MRatio.
TABLE 5.3 OPERATINGATA HIGH F/M RATIO TABLE 5.4 OPERATINGAT A LOW FIM RATIO
(LOW SLUDGEAGE) (HIGH SLUDGEAGE)
Maintaining the
required dissolved
oxygen concentration
can be difficult.
5 ACTIVATEDSLUDGE 33
As a general rule of thumb, a higher MLSS • increase WAS and hold RAS constant; or
should be maintained in the aeration tank during
the winter than during the summer. This is • decreaseRAS and increase WAS.
because of decreased biological activity due to
lowertemperatures. 5.13 PROCESS VARIATIONS IN
ACTIVATED SLUDGE
Operation at a desired F/M ratio or sludge age is
dependenton the controlof mixed liquorsolidsin The activated sludge process is classified into
thesystem. By adjusting thesolidsconcentration, threebroad categories: low rate, conventional and
the desired F/M or sludge age can be achieved. high rate. The divisions are based on the organic
The solidsconcentration can be modified by more and hydraulic loading rates and retention times.
than one method. How&ier, the operator should Subdivisions within these categories are based
be aware that by changing the solids mainlyon flow and methodof aeration.
concentration other aspects of the process may be
affected. Table 5.6 gives a summary of the operating
parameters foreach of the processesdescribed.
Table 5.5 outlines changes in the operational
procedures which will affect the process 5.13.1 CONVENTIONAL AERATION
operation. The operator has various optionsopen
to the modify the sludgeage and the MLSS: Conventional aeration is preceded by a primary
settlement stage and operates at loading rates
To increase the sludge age and the FIM ratio the greater than 0.2 kgBOD/kgMLSS.day. A high
operatorcan: quality outflow is produced and nitrification is
possible. Greater nitrification is achieved at
• increase RAS flow rate and leave WAS lowerloading ratesand longersludge ages.
constant; or
• decrease WAS flow rate and leave RAS Sludge production is 0.5-1.0 kg dry solids/kg
BOD removed and the RAS has a concentration
constant; or of 8,000-12,000 mg/I MLSS. This is equivalent
• increase RAS and decreaseWAS. to 0.8-1.2% dry solids and requires thickeningor
dewatering prior to recovery or disposal.
To decrease the MLSS concentration, the Conventional aeration sludge digests reasonably
operatorcan: well as there will be some unoxidised organic
matter remaining. It digests best howeverwhen
• decrease RAS flow rate and hold WAS mixed with primary sludge.
constant; or
34 TREATMENT OF WASTE WATER
Extended 0.05 -0.15 0.25 -0.3 20- 30 20- 30 2000- 90- 95 0.5 -0.6
aeration 6000
Highrate 1.0-2.5 1.6- 16 2.5 -3.5 0.5 - 10 5000- 60-70 0.8- 1.2
activated 8000
sludge
Deep shaft 0.5 - 5.0 3.7 - 6.6 0.5 - 5.0 4 -5 2000- 0.5 - 0.85
6000
1990). There is no primarytreatment of inflow so soluble BOD are uniform throughout. Uniform
the load to the A-stage can be highly variable. distributionensures that the outflow mixed liquor
High floc loading (FIM) to the A-stage is identical to the mixed liquor in the aeration
contributes to good sludge settling and tank. An advantage ofa completely mixed tank is
dewatenng characteristics. The lower loading that shock loads are rapidlydispersed and diluted.
rates to the B-stage result in good BOD removal Completely mixed tanks are generally square or
and nitrification at sludge ages of up to 25 days. rectangularin shape with a length to width ratio
Overall, the organic loading rate to an A-B less than5:1.
system may be 50% greater than that to a
comparably sized single stage activated sludge
Even oxygen demand
plant. Absorption (A) stages can be retro-fitted to Uniformconcentration ofsubstrate and MLSS
existing plants; in new plants, the omission of
primary settlement tanks can save capitalcosts.
Completely mixed activated sludge systemsare Plug flow activated sludge plants allow for easy
the simplest; the concentration of available modification to provide contact, anoxic and
substrate and MLSS are the same throughout the anaerobic tanks for control of filamentous
tank. In this mode, the inflow is rapidly mixed bulking, denitrification and biological phosphorus
throughout the wholetank so that DO, MLSS and removal respectively.
36 TREATMENT OF WASTE WATER
High FIM
High oxygen demand
-
Low oxygen demand
length:wid
Overflow weir
An oxidation ditch possesses properties and seededwith new waste water and RAS and is
attributable to both completely mixed and plug aerated until the BUD is satisfied. Aeration is
flow reactors. In one respect, due to its closed stopped to allow the mixed liquorto settleand the
loop circulation, it acts as a completely mixed clear supernatant is decanted off. New waste
system. On the other hand, due to poor water and seed (if necessary) is added and the
longitudinal mixing, DO and substrate gradients cycle repeats itself. Hydraulic and organic
are evident downstream from surface aerators, as loading rates and sludge ages can be controlled in
in a plug flow tank; as the flow progressesfrom SBRs so a full range of treatment objectives can
one aerator to another, dissolved oxygen and be achieved. Biological or physico-chemical
substrate are consumed. These gradients allow nutrientremoval are possible.
for the incorporation of naturally occurring
anoxicor low DO zones in nitnfyingplants at the 5.14.8 HIGH INTENSITY SYSTEMS
design stage. With the addition of separate In treatment plants with a constant or periodic
anaerobic tanks, an oxidation ditch can be
modifiedfor biological phosphorus removal. high loading, there may be deficiencies of DO
where the potential rate of reaction by the micro-
5.14.7 SEQUENCINGBATCH REACTORS organisms cannot be achievedbecause of a lack
of oxygen. High intensity systems such as pure
Most activated sludge plants perform the two oxygen and deep shaft increase the amount of
fundamental aspects of the activated sludge available oxygen so that this demand can be
processin two tanks, one for aeration and one for satisfied. These systems are generally used on
solids separation. Sequencing batch reactors high strength industrial wastes and tend to be of
allow for both processesto be carried out in one high capitaland/oroperating cost.
tank (Figure 5.13). The tank is firstly charged
38 TREATMENT OF WASTE WATER
High intensity systems can be operated, like whereas open systems must have an efficient gas
conventional aeration, at various points on the transfer mechanism to ensure maximum
bacterial growth curve and sludge production dissolution of gas prior to dispersal to the
depends on how theyare operated. atmosphere. Pure oxygen has found application
as permanent or partial systems. Permanent
systems operate using pure oxygen constantly.
Partial systems are where the pure oxygen maybe
switched on on demand during periods of high
inflowwaste water
loading.
Return
Inflow
Outflow
WAS
Ashing The presence of dead cells, sludge particles and grease on the
surface of the secondary settlement tank. If the 30 minute cone
test releasesbubblesafter it has been stirred, denitrification, not
ashing, is occurring.
Pin point floc Small dense sludge particles suspended in the secondary
settlement tank; often seen in plants operating between
conventional and extendedaeration.
Bulking sludge Filamentous hulking: light brown, grey or white in colour with
poor settling characteristics (SVI >150mug).
Straggler floe This can occur during periods of low MLSS and appears as
small, transparent, fluffy sludge particles in the secondary
settlement tank.
42 TREATMENT OFWASTE WATER
• high temperature: rising sludges are often a decreasing the sludge age;
summer phenomenon;
maintaining dissolved oxygenabove 2 mg/I
* the sludge blanket in the secondary (i.e. 2 -4 mg/I); or
settlement tank will have a low dissolved
as a remporan'measure, adding a flocculating
oxygen (<0.5 mg/I); and
agent.
* the sludge blanket will contain nitrate 5.18.4 FILAMENTOUS BULKING
concentrations in excess of5 mg/I.
Filamentous bulking occurs when filamentous
A similarcondition calledsludge clumping occurs organisms extend in significantnumbers from the
when plants are operated at low F/M's and floc into the bulk solution. Thoughthe quality of
nitrification takes place. Clumps of sludge may supernatant may still be good, the major problem
appear on the surface of the secondary settlement with this form of bulking is poor consolidation of
tank when the sludge is being retained in the sludge. Maintaining the desired F/M ratio in the
secondary settlement tank for too long a period. aeration tank can be difficult because thinner
Clumping sludge may also occur during the RAS reducesthe MLSS concentration.
summerwhen temperatures are high.
Filamentous bulkingcan be caused by:
Rising and clumping sludge maybe resolvedby:
low F/M ratio;
• increasing the return activated sludge flow
rate; or low dissolved oxygen concentration in the
aeration tank;
• decreasing the sludge age which reduces
nitrification. insufficient levels of P, N or other nutrients.
This mayoccur if industrial loadsenteringthe
5.18.2 ASHING treatment plant are deficient in these nutrients
and dilute the nutrient concentration in the
Ashing is occasionally associated with dead cells aeration tank, e.g. brewery waste can promote
and other sludge particles or grease floating on the growth of Thiorhrix spp. and Sphaerotilus
the surface of a settlement tank. The dead cells natans;
will not settle; the sludge may settle but not
flocculate. too high or low pH values. Fungi predominate
at low pH;
The possible causesare: high wastewater temperatures;
• extremely low F/M (less.than 0.05);and widely fluctuating organic loading rates;
a
industrial wastewaterswith high BOD; or
MLSS containing high grease concentrations.
industrial waste waters with a high sulphide
The problemmaybe resolved by: content, e.g. tannery waste or septic waste
water, which can promote the growth of
• increasing the F/M ratio and decreasing the Thiotrix spp. and Beggiatoa spp.
sludge wasting rate; and Iffilamentous bulkingis taking place on a regular
monitoring the inflow for fats, oils and grease basis, the type of filamentous organism may have
to establish whetherunusually high levels are to be identifiedin order to understand the nature
present. Also, check that grease removal of the problem. For example, the presence of
equipment, such as baffles, is operating fungi will indicate a low pH industrial discharge.
efficiently.
5 ACTIVATEDSLUDGE 43
Thiotrix spp. may indicatethat septic conditions It is difficult to isolate a particular species of
are prevalentin the collecting system. micro-organism as being responsible for a
particular function in waste water treatment.
Where low F/M bulking has been a problem, However, as a group, the identification of the
selector or contact zones have been used to types of micro-organisms present, the
restrict the growth of filamentous bacteria by predominance of each type, the diversity of the
providing floc forming bacteria with a communities and the mobility of the micro-
competitive edge that makes them more organisms are invaluable guide to the health and
ctominant. An extra zone is provided before an status of a plant and to predicting operational
aeration tank where the RAS and inflow are problems in the early stages. The micro-organism
mixed for a short hydraulic retentionperiod (15- population will reflect their environment and be
30 minutes based on the average flowrate). A influenced by the contents of the mixed liquor
high FIM ratio results which favours the floe and thus the incoming waste water. This can be
formers. The high FIM ratio at the start of a plug used by the operator to provide the optimum
flow tank is the reason that this configuration is conditions for growth.
more successful than completely mixed systems
in preventing the development of filamentous The micro-organisms can be observed using a
bacteria. Anoxic selector zones have been microscope with a magnification between 100X
appliedto certain bulking/foaming conditions. and 400X. Figure 5.15 illustrates the relative
predominance of micro-organisms versus FIM,
5.18.5 NON-FILAMENTOUS BULKING sludge age and SVI. It can be seen that
flagellates (lower life forms) predominateat high
Bulking can occur without filamentous organisms FIM or low sludge age whenthe floes are light or
being present. This can occur in certain high F/M dispersed. At longersludge ages, the rotifers and
situations. If such a situationexists the operator worms (higher life forms) become more
shoulddecrease sludge wasting. predominant and this can sometimes indicate a
poorer effluent quality and an over-oxidised
5.18.6 STRAGGLER FLOC sludge.
Straggler floe is characterised by small, 5.19.1 MONITORING BIOLOGICAL
transparent and fluffy sludge particles in the ACTIVITY
settlement tank. The causes of straggler floc are:
An experienced operator can assess an activated
• over aeration, particularly during process sludge plant by examining daily the microbial
start-up; population of the mixed liquor. Each plant will
• low MLSS, which mayresult from too high a operate under differentconditions and individual
characteristics will be empirically established
sludge wasting rate; and with time. For example, an examination of the
• batchsludge wasting. mixed liquormay yield47% rotifers, 26% stalked
ciliates and 23% free swimming ciliates; this can
The problem maybe resolved by: indicatea long sludge age.
• decreasing the sludge wasting rate, thereby The identification of the micro-organisms present
increasing the MLSS and the sludge age; and in a sample ofmixed liquorand thebeneficial use
of this information requires a lot of experience
• not wasting sludge during periods of high and reference shouldbe madeto standard texts.
organic loading.
TABLE 5.12 SIzE OFMICRO-ORGANISMSUSED
5.19 BIOLOGICAL ACTIVITY INWASTEWATERTREATMENT
The factors which affect the performance of the (Standard Methods, APHA, 1992)
activated sludge processinclude:
Micro-organismgroup J Size,inn
• micro-organisms; Rotifers 400
•
Free swimming ciliates .100-300
oxygen; and Stalked ciliates 40-175
______
• food. Flagellates 5-60
Amoeboids 10-30
44 TREATMENT OF WASTE WATER
Good settling
Rotifers Nematodes
Stalked
0 ciliates
Freeswimming Rotifers Nematodes
0 ciliates Free Stalked
swimming ciliates
ciliates
Rotifers
Free Stalked ciliates
swimming Freeswimming
Flagellates ciliates ciliates
Flagellates Flagellates Flagellates
Amoeboids Amoeboids Amoeboids Amoeboids
V
• dissolved oxygen concentrations; V
Urban waste water treatment plants are normally FIGURE 5.16 POWERREQUIREMENTSASA
FUNCTIONOFMIXED LIQUORDO
designed to take account of future growth and
seasonal factors.
Figure 5.17 shows the oxygen consumed during
TABLE 5.13 OPERATING COSTSOFKILLARNEY carbonaceous BOD removal nd
nitrification.
WASTEWATERTREATMENTPLANTDURING 1995 The figure shows that carbonaceous removal
requires about 30-40% less power than the power
required to satisfy both carbonaceous and
nitrogenous BOD. If nitrification is not required,
Unit Cost, £ % oftotal
operating at a sludge age between 6-10 days will
satisfy the carbonaceous oxygen demand. Care
Power 48,432 22 should be exercised in reducing the sludge age as
this can be accompanied by a higher SVI and the
Labour 66,000 30 production ofmore waste sludge.
Sludge disposal
25,287
43,677
11.6
20
:
Laboratory
Other
2,788
7,689
1.3
/ 5-dayBOO
15
packed media (percolating filters and some Two shapes of percolating filter exist: circular
submerged filters); and and rectangular. Rectangular filters are more old-
fashioned and were used on largetreatment plants
moving or buoyant media (rotating biological where activated sludge or submerged filtration
contactors and other submerged filters). would typically be applied today. Rectangular
deep bed filters are often used now as high rate
Biofilm processes are usually preceded by filters. Circular percolating filters offer better
primary settlement to remove gross settleable distribution of waste water and are less
solids which may interfere with oxygen transfer cumbersome and have more easily maintained
to the micro-organisms, block the filter media or mechanical parts.
result in high solidsyields.
6.2.2 BIOLOGICAL SLIME
Biofilm processesare categorised as follows:
The basic bacterial unit in bioflimprocessesis the
percolating or trickling filters: these are biological slime layer that grows on the support
made up of beds of packed media. The
medium. The slime layer is characterised by
medium provides support for the growth of
zoogleal growth which is viscous and jelly-like
micro-organisms and applied waste water and contains bacteriaand other micro-organisms.
flowing in a downward direction through a As the bacteria grow in numbers, the film
medium provides food for these micro-
increases in thickness and any excessis removed
organisms. Thus, the micro-organisms feed by one oftwo mechanisms:
upon and remove the substances contained in
the waste water. The media used are highly • the passage of liquid between the media
permeable; the word "filter" does not imply causes a continuous erosion of small amounts
any straining or separation of solid material. • of biofilm. The level of erosion is dependent
Many variations on the arrangement of on the rate of liquidflow over the biofilmand
structure, media and distribution systems are on the thickness of thebiofilm. Thus, the size
available. and thickness of the slime layer is partly
controlled by the liquid flowing through the
rotating biological contactors (RBC): these medium;or
units allow the growth of a biofilm on large
diameter discs or structured modules. A • sloughing of biofilm is a rapid loss of large
central horizontal shaft rotates the discs or quantitiesof biofilmwhichis most noticeable
modules thereby exposing the biofilm when the biofilm has become thick. It is
sequentially to the waste water and to the typically The result of anoxic or anaerobic
atmosphere. conditions arising deep within the biofilm
which can cause gas production and reduce
submerged (aerated) filters: these units the ability of the biofilm to adhere to the
have been commercially developed over the medium.
last ten years with claims ofhigh loading rates The bacterial population resident in the slime
and efficiencies and low land area layer depends on a number of factors including
requirements. They are intensive biofilm the nature and loading rate of the applied waste
processes where large quantities of biomass water. At normal loading rates heterotrophic
are supported inside a tank through which the carbonaceous bacteriaand fungipredominate. On
waste water is passed. A submerged aeration more lightly loaded plants or near the base of
systemis requiredin aerobicprocesses. The bacteria beds, slow growing nitrifying bacteria
48 TREATMENT OF WASTE WATER
will developand compete with the faster growing liquid pathswhichdo not easily clog.
heterotrophs. Photosynthetic algae and bacteria Modern media tend to be engineered plastics
will reside near the surface of a percolating filter.
On maturetreatment plants, ciliated protozoa will designed to maximise specific surface area2
(SSA) and hence bacterialpopulation. SSAs are
consume any free suspended bacteriain the liquid
film and so clarify the outflow, which would highly variable and range in size from 50 m2/m3
otherwise be turbid. Higher life forms which up to 600 m2/m3 for some of the most specialised
media.
grazeon the slime are represented successively by
rotifers, nematode and annelidworms,larvae and Random packed media are made up of very large
adult dipteran flies (e.g. Psvchoda), midges and numbers of individual pieces which sit on a filter
other insects. In consuming slime, the grazing floor with no ordered pattern. The liquid flow
fauna decreasesludge production and increase the path is random but intricate and good shapes will
settleability of sludge solids. The food chain is maximise contact between the liquid and the
topped by birds which consume the insects and biofilm. Although smaller sizes will provide a
worms near the surface of a bacteria bed. The greater SSA for bacterial growth. the voids tend
grazing fauna are most active during the warmer to clog more easily which limits the passage of
months and this accounts for the drop-off in liquid and air.
activity ofpercolating filters duringthe winter.
Structured mediaare usually supplied as bales up
to I m3 in size which are fitted like bricks into a
filter. They are constructed of corrugated sheets
bonded together to form long intricate flow paths
for the liquid. The surface is often roughenedto
maximise retention of biomass and to prevent
complete sloughing of the surface. Different
channel widths are available for different
applications and bacterial growth rates.
1/
Biofilm:
Anaerobic and aerobic layers
Atmosphere
• worms,insects and other mobile invertebrates Percolating filters are generally classified based
migrateto the warmerdepths ofthe bed. on either their physical configurations, on their
loading rates or on a combination of both.
Thus,the activity ofa percolating filter decreases; Examples of some of these configurations are
however, on a well sized and maintained plant described in Table 6.1 and illustrated in Figure
this shouldnot result in a deterioration in outflow 6.5.
quality. Nitrification does decrease significantly
below about 10°C so ammonia concentrations in 6.2.11.1 Single stagefiltration
the outflow may increase. With the arrival of
spring the above changes reverse, but not at the At low organic loading rates, a single pass
same rate. Thus, bacterial metabolism, through a bacteriabed is sufficient to ensure full
particularlyat the highly loaded top part of the carbonaceous oxidation. Loading rates are also
bacteria bed, increases and the biofilm increases sufficiently reducedin the bottom of the bed to
in thickness. This excess biomass, combined allow nithfying bacteria to grow; hence
with the increasing activity of higher life forms, nitrification is generally good. Due to the extent
causes a slough which can continue for up to 4 of treatment, sludge tends to be well stabilised
weeks at the beginning of spring. This is and endogenous respiration is not uncommon.
commonly called the spring slough and occurs to
a greater or lesser extent on all percolating filter
Dosing siphons are used to ensure the distributors
plants. keep turning. Bed depths are about 2.0-2.5 m,
which is deep enough for nitrification to occur,
6.2.11 CLASSIFICATION AND and the medium, usually stone, is generally no
CONFIGURATION OF FILTERS
larger than 40-50 mm. Due to long retention
The outflow quality from percolating filters is periods and low biofilm removal rates, odours
and filter flies are common sources of nuisance,
dependent on their hydraulic and organic loading
rates which are in turn governed by the inflow, particularly during mild weather. Few modern
the plant configuration and recirculation rates. plants are constructed to operate at such low
loading rates due to costconstraints.
Organic loading 0.08 - 0.32 0.24 - 0.48 0.48 - 0.96 0.8 - 1.6
kg BOD/m3.d —
Notes:
m3/m2.d m3 applied flow/day per m2 bed surface area
kg applied BUD/day per m3 bed volume(totalbed volume ifusingmultiplestages)
kgBOD/m3.d
kgTSS/kgBOD.d kg total suspended solidsproduced/day perkg BODremoved
52 TREATMENT OF WASTE WATER
Alterna ye
Multi-stage filtration
Filter1
Filter 1 leads
Filter2 Filter2 leads
Alternatingdouble filtration
Mediumtoo small or not Becomes blocked by Manually dig or rake Replace medium.
uniform in size*. biofilmgrowth or medium to redistribute it
smallerpiecesfill voids and remove excessive
between larger pieces. biofilm. Increase
Breaksup too easily or hydraulic load
Medium unsuitable.
periodically.
cements/degrades under
chemical attack.
Excessivegrowthof Accumulates in the voids Manually dig out the Increaserecirculation to
insect larvaeor snails. between the media. excess or wash out by avoid larvalbuild-up.
increasing flow.
* On olderplants,this may be due to the breakdown ofmedia overyearsor decades.
6 BIOFILMS 55
Hydraulic flow problems other than ponding can the knock-on effects are often seen at the humus
be caused by the clogging of distribution arms, tanks due to poor settleability or carry over of
vent pipes or collection underdrains. It is solids. Shock loads are best dealt with prior to
important that these are inspected regularly and the percolating filter plant; recirculation rates can
any rags, leaves or other debris removed. be increased to dilute incoming organic loads or
Recirculation pump failure during periods of high toxins. However, the maximum hydraulic load to
flow can increase the effective organic load to a a humustank must not be exceededin doingthis.
percolating filter and, while treatment efficiency
may suffer in the short term, if repairs are Floating sludge in a humus tank is generally
promptly carried out, long term effects such as causedby gasification or denitrification occurring
ponding are unlikely. in the consolidated sludge at the bottom of the
tank. The problem is often remedied by
6.2.12.2 Humustanks increasing the frequency of sludge withdrawal
from the tank so that dissolved oxygen does not
High suspendedsolids in a humus tank outflow become depleted thus preventing anoxic
can be caused by a numberofconditions: conditions from developing in the firstplace.
• heavysloughing ofbiomass from thefilters;
6.3 ROTATING BIOLOGICAL
• high hydraulic loading or short-circuiting CONTACTORS
through the humus tank;
The rotating biological contactor (RBC) is a
• shock organic,hydraulic or toxic loads; and biofllm process in which the biofilm support
• sludge floatedby denitrification. medium is cycled between being submerged
where it comes into contact with the waste water
High solidsloads which adversely affect a humus and being emergedwhere the biofllm is exposed
tank and which are associated with increased to air. Anaerobic biofilms do not adhere to the
sloughing of a percolating filter may be solved support medium very well.
by:
There are a large varietyof support mediaon the
• minimising the solids washed out by operating market but the characteristic unit consists of
a higher recirculation rate before increased closely spaced (20-30 mm apart) plastic discs 1-3
sloughing of biomass occurs; m in diameter rotating around a horizontal shaft.
• ensuring there is no short-circuiting through The rotation of the discs is driven either by a
the tank;and geared motorconnected directly to the shaft, by a
peripheral drive on the discs or by air bubbles
• removing settled solids as frequently as actingtangentially on vanes attached to the discs.
possible while still allowing for good Other RBC media use textured or otherwise
consolidation to occur. modified surfaces with one common purpose: to
increase the specific surface area of the medium
Highhydraulic loads result ifthe tank is too small and thus reduce the overall plant size and cost.
for the flow being passed through it; that is, the Not all RBC media are discs; there are many
flow is not slowed down enough for all of the variations on the market supplied by numerous
settleable solids to fall from suspension. It may manufacturers.
be that recirculation rates are too high. If the
outflow is recirculated from a point between the Most RBCs are supplied as proprietary package
percolating filter and the humus tank, then the plants often in conjunction with package primary
latter is unaffected by the increased hydraulic and secondary settlement tanks and thus plants
loads. Short-circuiting may be caused by a build- can easily have additional units put on-line or
up of consolidated solids in the cornerof tanks or taken off-line. This flexibility of operation of
by poor inflow distribution or by uneven outflow RBCs has been a major selling point particularly
weirs (all weirs shouldbe set to the same height). with smaller customers.
Proper design and maintenance of the tank and
particularly the outflow weirs should prevent this Loading rates to RBCs shQuld not exceed 5 g
from happening. soluble BOD/m2.d (expressed in terms of the total
surface area of media, free and immersed) for
All unit processes shouldbe protected from shock settled waste water or 7.5 g total BOD/m2.d for
loads. Percolating filters are less susceptible to raw waste water. Refer to manufacturers'
shock loads than other biological processes but literature for significant variations.
56 TREATMENT OF WASTE WATER
.
1
collection
-l Dirty waste water
to further Medium
treatment Aerationinlet
Cleaned waste water
I Waste water
—inlet
Air
Sludge
Sludge outlet
Some reactors combine a relatively low organic increased head loss can be used as a trigger for
loading rate with nitrification while othersrequire backwash to take place. Moreusually,backwash
additional reactors operated in series in order to takes place on a timed basis with headloss being
nitrify. Other downflow reactors use a raised used as an override in abnormal hydraulic or
aeration grid such that the bottom of the bed is organic loads.
unaerated and acts as a physical filter. Upflow
systems with a raised aeration grid will allow Variations in the sequence for backwashing
denitrification if a carbon source is applied. Most granular media exist depending on the
biological submerged filters require a solids manufacturer and type of process but the basic
removal stage to remove any residual suspended sequence is as follows:
solids from the outflow. Submerged gravel or
sand filters are often used. These do not need to • inlet flow stops; the bed remainssubmerged;
be as large as the biological reactors becauseof •
the higher hydraulic loading rates that are air flow is increased by 2-3 times to expand
the medium and dislodge excessive attached
possible. or interstitial solids. This is called the air
scour;
6.4.6 BACKWASH REQUIREMENTS / AIR
SCOUR • backwash water is introduced (either upflow
or downflow) and, combined with the air
Excessive bacterial slime growth (as in scour, washes the loosened solids from the
percolating filters) can cause clogging of the reactor;
medium. Using tightly packed granular media,
• air scour is' stopped. Backwash water
hydraulic erosion during normal operation does
not occur so backwashing of the medium bed continuesflushing out the bed;
clears it of excessive growth. As biomass builds • water scourstops and the medium settles back
up on the medium and it becomes more clogged, into place;and
the hydraulic head loss acrossthe bed increases; it
may completely block the bed in time. The
60 TREATMENT OF WASTE WATER
6.4.10.2 Mediumloss
Some medium loss takes place from almost every
proprietary submerged filter system on the
market. The designer or operatorshouldassess:
• whetherthe manufacturer has quantified this?
• what is the acceptable loss of medium before
replacement becomes necessary? and
• where does the lost medium go to and what
effect will it haveon other unit processessuch
as primary settlement tanks, pumps and other
equipment? Will it be discharged with the
plantoutflowand affectthe effluent quality?
Most media are lost during backwash and
therefore end up in the waste sludge system. If
themedium is buoyant it may end up floating on
the surface of primarysettlement tanks or sludge
thickeners. If it is not buoyant, it may settle in
pipes or tanks and cause blockages. If the
medium settles in the primarysedimentation tank,
it maycause damage to pumpsor other equipment
because of its grittynature.
62 TREATMENT OF WASTE WATER
7 NUTRIENTREMOVAL 63
by passing the gas through a filter for shock loads and hydraulic washout mean that
biological removal, or nitrifiers require more stable conditions and
longer hydraulic and solids retention times than
by passing the gas through a scrubber to re- heterotrophic carbonaceous bacteria.
dissolve the ammonia in water which can be
treated separately to the mainprocess stream. Denitrification is an anoxic process which takes
7.3.1.2 Ion exchange place in the absence of dissolved oxygen. The
nitrate and nitrite produced during nitrification
Zeoliteshavebeen found effective in many water, become the oxygen source for heterotrophic
waste water and industrial applications as bacteria which utilise the available BOD. In
molecular filters which can distinguish molecules essence, what is required are: bacteria, oxidised
at the ionic level. For example, the natural zeolite nitrogen as the oxygen source and a carbon
clinoptilolite is selective for the ammonium ion in source.
preference to other ions present in solution. A
filtered waste water can be passed through a bed In percolating filter processes, these conditions
of zeolite to effecta 90-97% ammonium removal. will be providedin a separate reactor which may
precede or succeed the biofilters themselves.
7.3.1.3 Breakpoint chlorination Conventionally, if the reactor precedes the
biofilter, settled sewage is used as the carbon
By addingchlorine to a waste water, a stepwise source and recirculated nitrified biofilter effluent
reaction takes place which results in the
(either settled or unsettled, depending on the
conversion ofanimonium to nitrogen gas.
Mechanical mixers are generally requiredto keep i.e. only half of the flow is recirculated. If the
the mixed liquorin suspension. recycle ratio is 3:1, then a 75% removal is
possible. Obviously, the recycle ratio becomes
Biological denitnfication processes generally limitingdue to hydraulic constraints on the plant
recirculate nitrified effluentas a source of nitrate. and allowances must be made for periods of high
This means that 100% removal can never be flow. As many plants are designed for a
achieved. Only the nitrate contained in the throughput of no more than 3 DWF, there are
recirculated stream will be removed; thus, practical limitations on the amount of NO3
referring to Figure 7.1, if the recycle ratio is 1:1, removal possible.
then a maximum 50% NO3 removal is possible,
Q,m3Id
II A
Q,m3/d
I
Nitrified
C-source andrecycle Aeration
-
jinlet
Effluent
Biologicaltreatment Unaerated
denitriftcation Anoxic
reactor (unaerated)area
7.4 MECHANISM AND APPLICATION OF The Fe3 oxidation state is the active form of the
PHOSPHORUS REMOVAL iron salts. Fe2 must therefore be oxidised to Fe31
before it becomes viable. Therefore, if Fe2 is
7.4.1 CHEMICAL PHOSPHORUS dosed into a primary settlement tank, it will
REMOVAL gradually become oxidised as it passes through
the treatment plant. Active Fe3 is thus available
Phosphorus exists in three main forms in waste after the biological stage to react with any newly
water; ortho-phosphate, polyphosphate and available ortho-phosphate. This can avoid the
organic phosphate. During aerobic treatment, the need for expensive -metering equipment and
latter two forms are converted to ortho-phosphate dosing of chemicals near an effluent discharge
which is the easiest form to precipitate using point. Chemical dosing immediately before a
chemical addition. Metal salts are generallyused percolating filter plant may cause a buildup of
for the precipitation of phosphate according to the insoluble precipitate on the surface of the filter
reaction: bed which can cause ponding. Adequate
hydraulic loading rates will reduce the effects of
M3 + P043 —÷ MPO4 ponding.
Suiphates and chlorides of ferric (Fe3), and Phosphorus removal chemicals can be corrosive
ferrous (Fe2) iron and aluminium are most and hazardous substances and due regard must be
suitable (Table 7.1). Ferric sulphate has been paid to the appropriate health and safety
commonly applied although ferrous sulphate is literature. Tanks for liquid storage must be
increasingly being used. The metal salt can be constructed and bunded to the appropriate
appliedat a numberof different points: building regulations and chemical deliveries by
contractors should be fully supervised.
prior to primary sedimentation;
at the biological stage; or Dosing pumps are generally of the adjustable
diaphragm or peristaltic type and are themselves
priorto the secondary clarification stage. bunded or contained within the bounds of the
tank bund.
Figure 7.4 illustrates the most commonly used
dosing locations. Effluent phosphate A control system for chemical dosing may be
concentrations of 0.1 mg/I P are theoretically to ensure the process performs
required
possible depending on the chemical used and on satisfactorily and to minimise overuse of the
the dosing point, although a concentration of 0.2 chemical. The control regime can use the
mg/i is more likely to be achievedin practice. following criteria:
.SCFAs _—
fermentation
Organicmatter
system and maxiniising the P release. The anaerobic zone, it is nitrate free thus ensuring
BardenphofPhoredox process requires a maximum P release. A multi-celled (at least 2
COD:Total N ratio greater than 10 to ensure cells per zone) version of the UCT is marketed in
complete denitrification and a COD:P ratio the USA as the VIP (Virginia Initiative Plant).
greaterthan40 to maximise phosphorus removal.
Anoxic
Arroxic Anaerobic
Anaerobic
WAS [J Aerobic
WAS 0 Aerobic
Biological V' V V V
nitrification
Additional capacity orupgradeson separate units generallyrequired
Biological V V I' V
denitrification
separate reactor separate reactor
usingsewageas
C-source requiredwith required with
recirculation recirculation
.1
Biological V V V V
denitrification unusual separate reactor separate reactor
using external
C-source . required required
ChemicalP V V V V
precipitation
8. DISINFECTION
8.1 INTRODUCTION 8.2 CHLORINE DISINFECTION
Disinfection of urban waste water is the Chlorine is widely used in drinking water
destruction of disease bearing micro-organisms or treatment for the disinfection of surface and
pathogens. It is distinct from sterilisation which groundwater. It is a strong oxidisingagent and
involves the complete destruction of all reacts with any organic matter present in the
organisms in the liquid being treated. water. As a result of the large concentrations of
Disinfection has not been extensively practised in organic matter in waste waters, higher doses are
Europe to date; in the USA a large proportion of required (than in drinking water treatment) in
discharges are disinfected using chlorine. order to achieve similar levels of disinfection.
However, in order to comply with EU directives Chlorine may be applied in a number of forms
such as: such as chlorine gas, sodium hypochlorite or
chlorine dioxide. On contact with water,
• the shellfish directive (79/923/EEC), as elemental chlorine is hydrolysed and ionises to
implemented by S.I. 200 of 1994, and hypochiorous acid (HOCI) and the hypochiorite
• the bathing water directive (76/160/EEC), as ion (OCI). HOCI is by far the more potent
implemented by S.!. 155 of 1992 and S.I. 230 disinfectant, therefore the lowerthe pH, the more
of 1996, effective is the process. Chlorine will also react
rapidly with ammonia in the waste water to
sanitaryauthorities mayin futurehaveto consider produce a series of chloramines in solution as
theuse of disinfection. follows:
agent and rapidly forms free radicals on reaction hardness salts. Periodic cleaning of the lamps is
with water. It is generated on-site in ozone therefore required.
generators by passing dry air or oxygenthrougha
high voltage electric field. The gas is bubbled 8.5 MEMBRANE TECHNOLOGY
through the water being treated and any
remaining ozone in,the off-gas is destroyed either Membrane technology is an emerging technique
catalytically using metal oxide catalysts or in a for the removal of bacteria and viruses. The
furnace heated to 300°C. Ozone reacts with membrane pore size dictates the particle sizes
organic matterin the waste water and this ozone whichwill be removed and will also influence the
demand must be satisfied before efficient capital and operating costs. Table 8.1 details the
disinfection commences. Disinfection is typically uses of sometypesofmembranes.
achieved within5 minutesat dosage ratesof 5-50
TABLE 8.1 MEMBRANETYPE AND APPLICATION
mg 0311, depending on the level of treatment
received by the waste water (that is, on how much
organic matteris remaining).
Membrane type Size Suitable to
The advantages ofozonedisinfection include: (Mm) remove
• theelimination ofodours; Microfiltration 0.1-1 bacteriaand
• the oxidation of residual organic compounds; someviruses
• the 8-hour occupational exposure limit Ultrafiltration 0.001-0.1 bacteriaand
(OEL) of ozone in air is 0.1 ppm. The odour viruses
thresholdof ozone has been reported at 0.02
ppm. This means that a person working near Reverse osmosis <0.001 bacteria, viruses
an ozone handling area should be able to and inorganic
smell ozone at concentrations far below the ions
OEL; and
• ozone can be generated from air, making its Operators should initially decide on the level of
supply dependent only upon a source of disinfection required and then examine the
power. removal efficienciesof the various options. For
example, microfiltration will remove most viruses
The disadvantages of using ozone as a and therefore the additional expense of
disinfectant include: ultrafiltration may not be justified.
• the high costofproduction; and
• the potentialto cause localisedair pollution.
8.4 ULTRA-VIOLET DISINFECTION
A fluid will flow through a section of pipe or Figure 9.1 illustrates the head to be overcome by
channel only when a driving force is applied. differenttypes ofpumpingsystems.
This force is the pressure difference over that
section of pipe or channel. Pressure is measured
in terms ofheight of water, calledthe head, and is
H
hfS I H
pump
reservoir
hd is the static discharge headwhichis the height of water standing abovethe pump.
h is the static suction head or the height of liquid between the reservoirand the pump. With
suction lift (when the source is below the centre line of the pump) this term is positive; with
suction head (when the source is abovethe centre line of the pump) it is negative as it helps the
pump.
Qasim (1994) outlined the basic principles that • the total head loss through connecting
must be considered when preparing a hydraulic pipework, channels and attachments is the
profile through a plant and these are summarised sum of the head losses due to entrance, exit
as follows: contraction, enlargement, fittings, gates,
valves and meters. The head loss over weirs
• profiles are prepared at peak flow (which and other hydraulic controls, the weir free-
accounts for the largest head loss through a fall allowance and the head allowance for
treatment unit), average flow and minimum future expansions of the treatment facility
flow; should be included;
• profilesare prepared for all flow paths;
to
outfall
Top ofwall
el. 23.16
heightsnot to scale
w.s. = water surface
el. = elevation in metres
the total head loss through a treatment plant Examples of positive displacement pumps are
is the sum of the headlosses in the treatment diaphragm, rotary lobe, piston or ram and
units and in the connecting pipework and progressive cavity pumps. Their operation is
attachments; characterised by a cavity which cyclically
operates as a suction and discharge chamber.
a minimum velocity (normally taken as Positive displacement pumps are often self-
O.3m/s) in connecting piping and conduits priming and some can be allowedto run dry for
shouldbe maintained to ensure that solids do short periods of time. Macerators are often
not settleout;
required upstream of these pumps in order to
friction losses in pressure conduits must be protect them from large objects that may block
included; the pump. The volume that can be pumped is
governed by the size ofthe pumpand its speedof
themaximum levels in thereceiving water at rotation. Positive displacement pumps are not
theoutfall must be established; and usually submersible but can be operated using
the depth and grade of open channel is kept variable speed drives.
in such a way that the water surface at the
The flowrate of a pump can be checked by the
design flow corresponds to the hydraulic
profile: following methods:
install a flowmeter; or
9.4 PUMPS
-: measure the time it takes to fill a vessel or a
Pumps used in waste water treatment fall into two tank of known volume where all other inputs
main categories: centrifugal and positive and outlets have been isolated. To ensure a
displacement. Centrifugal pumps are more constant fixed head on the pump, the inlet
commonly used in pumping waste water while • should discharge at or above the top water
positive displacement pumps are frequently used level of the vessel. What is being measured is
forpumpingsludge. the time it takes to fill or drain a known
volume; (e.g. if it takes 5 minutesto fill 1000
Centrifugal pumps rely on the force imparted to a litres,then the flowrate is 1000 litres/S mm or
fluidby a rotating impellerto drive it towardsthe 3.33 Lls).
pump discharge. The size, speed and
configuration of the impeller all have an influence
on the amount of liquid a pump can handle. The
characteristic pumpcurve
Di
Hoist
-Discharge
Discharge
EEE
E
Ce
30cm 1750 rpm
25cm 1500rpm
20cm
Discharge, lIs -*
1250rpm
Discharge, 115 -
FIGUIu9.5 CENTRIFUGALPUMPPERFORMANCECURVES
(WPCF, 1990)
78 TREATMENT OF WASTE WATER
1 0 CONTROL OFNUISANCE 79
Partial V V
enclosure
Complete i/ V V V V V
enclosure
Attenuators V V V V V V
— 1
V V,
adequate landscaping;
. maintenance of a neat and tidy site;
• protection of exposed surfaces from
splashing, lichen, algal or fungal growth;
• maintenance of site fencing and boundary
screening in goodcondition;
• prevention of aerosols and foaming from the
aeration tank;and
• regular painting of gates, doors and
buildings.
10.5 PESTS
The fly Psychoda is the chief nuisance insect
associated with some biofilm processes. These
flies require an alternative wet and dry
environment for growth and are normally
associated with low rate systems. Controls
include:
84 TREATMENT OF WASTE WATER
11 PRETREATMENTOF INDUSTRIAL WASTE 85
Sulphide 25 - 30
ensure that the operation of a waste water
treatment plant and the treatment of sludge Anthracene 500
are not impeded;
Benzene 100-500, 125-500
ensure that discharges from treatment plants
do not adversely affect the environment or 2-Chlorophenol 5
prevent receiving waters from complying
with otherCommunity Directives; and Ethylbenzene 200
• ensure that sludge can be disposed of safely Pentachlorophenol 0.95,50
in an environmentally acceptable manner.
• Phenol 50-200, 200
As mentioned in section 1.1 of this manual, safety •Toluene
•
200
procedures (acceptable to the Health and Safety
Authority) should be adopted when operating Surfactants 100-500
urban wastewater treatment plants and nothing in
this manual should be construed as advice to the
contrary. This advice is also applicablefor work
carriedout on the collection system. Potential problems from industrial waste water
may be associated with hydraulic overloads,
temperature extremes and with excessiveamounts
of:
86 TREATMENT OF WASTE WATER
Appendix C lists some of the toxic and non-toxic alternating flow diversion, where the total flow
parameters that are commonly associated with from the process is collected in alternate tanks
various industrial sectors. All industrial waste and allowed to equalise. While one tank is
discharging to the foul sewer should be fully filling, anotheris being discharged;
characterised. In addition, where significant
levels of toxicity are suspected, data on the intermittent flow diversion, where significant
respiration rate, algal and microbial inhibition periodic variations in the discharge are diverted
potential shouldbe obtained. and subsequently allowedto bleed back into the
process stream at a controlled rate;
Table 11.2 lists the technologies which are
commonly used to remove industrial pollutants
priorto discharge to a sewer.
completely mixed combined flow systems, petrol stations. Other techniques include
where multiple streams are combined in order to dissolved air flotation, centrifugation, filtration,
reduce their variance. This assumescompatibility biological removal and ultrafiltration. There is
between the constituents in each stream; and wide scope for the reuse-of FOG which has been
recovered by gravity settlement. For example,
completely mixed flow system, where a FOG recovered from restaurants can be purified
completely mixed holding basin is employed and and reused as animal feed.
provides a constant discharge to the treatment
plant. 11.3 pH NEUTRALISATION
The different designs are illustrated in Figure A strongly acidic or alkalinewaste may seriously
11.1. affect the collection system as well as the
treatment process,thereforeneutralisation prior to
entry to the collection systemmaybe required.
ualisation basinI
lflfl_JIl_Jatn_ Outflow
The most common bases used to neutralise acidic
wastes are lime (which may come in the form of
Alternatingflowdiversion
high-calcium hydrated lime, calcium oxide,
r_00Ji [n]__
Inflow Outflow
dolomitic quicklime, dolomitic hydrate, high-
calcium limestone, dolomitic limestone, calcium
carbide and calcium hydroxide), caustic soda
Intermittent flowdiversion
Inflow2 (sodium hydroxide), sodium bicarbonate, sodium
carbonate and magnesium hydroxide. Acids used
Treatment
Inflow1 Outflow to rieutralise alkaline wastes include sulphuric
fMixingj__J plant -
acid, carbon dioxide (as carbonic acid),
Inflow3
hydrochloric acid and nitric acid.
Completely mixed combined flowsystem
11.4 HEAVY METALS
reatmen
In Outflow
The primary effect of heavy metals on the
Completely mixed fixedflowsystem
treatment process is decreasedbiological activity
FIGURE 11.1 METHODS OF FLOW BALANCING
of the micro-organisms. The toxicity of
individual metals varies and certain metals
(WEF, 1994) become more toxic when combined with others.
11.2 FATS, OILSAND GREASE (FOG) Also, certain metals can combine with organic
compounds and cause mutagenicity (changing of
The term FOG includes materials of vegetable, the genetic makeup) and/or teratogenicity
animal and mineral origin. Pretreatment of FOG (abnormal tissue development in embryos).
from industrial processes may be required to
avoid blockages in the collection system, High levels of heavy metals in waste water may
pumpingstationsand at the treatment plant. prohibitsludge from being used in agriculture.
The effect of FOG on the treatment system Though technologies exist for the removal of
depends on the type of FOG present. Animal heavy metals from waste water, industry should
and vegetable oil tend to be broken down in the be encouraged to recover as much as is
treatment system but oils of mineral origin economically viable. Recovery systems include
typically degradeslowly. This slow degradation evaporation, reverse osmosis, electrodialysis,
can affect the activity of micro-organisms at the electrolytic recovery and ion exchange.
plant by preventing the transfer of oxygen or
slowing down the degradation of other organic 11.5 ORGANIC CONSTITUENTS
material. FOG can affect the operation of
monitoring equipment such as dissolved oxygen Industrial wastes can contain high levels of
probes, pH probes and other instrumentation organic matter and/orlow levels of nuthents and
requiredto effectively control the process. may require some form of treatment prior to
discharge to the collection system. As a guide,
The simplestform of removal of FOG is gravity Appendix B lists the waste water characteristics
separation. This may be appropriate for waste from the mainindustrial categories.
water emanating from restaurants, hotels and
88 TREATMENT OF WASTE WATER
12.6 OPERATIONALCONTROL
The operational controls are a set of documented
practices, procedures and systems to ensure that
the activities of the plant operatorwhichhave an
impact on the waste water treatment plant
performance are carried out in accordance with
specified procedures. This would typically be
achievedunderthree sub-sections:
control procedures to ensure activities take.
place within parameter limits;
verification, measurement and testing to
ensure that the control procedures are
effective; and
SUGGESTED FURTHER READING 91
• Gray, N.F., Activated Sludge, Theory and Practice, Oxford University Press, 1990.
• Metcalf& Eddy, Wastewater Engineering, Treatment,Disposal and Reuse, McGraw and Hill
Publishing Company, 3rd Ed., 1991.
•
REFERENCES
a Bowman,J.J., Lough Ree: an investigation of eutrophication and its causes,Environmental Protection
Agency, 1996.
• Cooper, P., Day, M., Thomas, V., 1994, Process optionsforphosphorus and nitrogen removal from
wastewater,J.IWEM, 8, 1, 84-92.
a Day, M., (editor), WasteWaterand Sludge Treatment Processes, WRc Publication no. NS1O2, 1995.
• Day,M., Cooper, P.F., Guideon NutrientRemoval Process Selection, FWRPublication no. FR0253,
1992.
• Foot, R.J., Robinson, M.S., Forster, C.F., Operational aspects of three 'selectors' in relationto aeration
tankecologyand stable foam formation. J.IWEM, 1993, 7, 304-309.
• Gray, N.F., Activated Sludge, Theory and Practice, Oxford University Press, 1990.
• Skrentner, R.G., Instrumentation handbook for water and wastewater treatment plants, 1989.
*
Tchobanoglous, G., Schroeder, E.D.,Water Quality, Addison-Wesley Publishing Co., 1985.
• U.S.EPA, Operation of Wastewater TreatmentPlants, Field Study Training Program, 4th Ed., Voli
& 2, 1992.
• Upton,J., Stephenson, T., BAF - Upflowor Downflow - The Choice Exists, Paperpresentedat
Symposium, Waste WaterTreatmentby Biological Aerated Filters- LatestDevelopments,Cranfi
University, 20Jan 1993.
• Wheatley, A. D., 1985, Wastewater treatment and by-product recovery. In Topics in Wastewater
Treatment. Criticalreports on appliedchemistry 11. Blackwell Scientific Publications, Oxford.
GLOSSARY 95
GLOSSARY
Activated sludge.A flocculent microbial mass of bacteria, protozoa and other micro-organisms with a
significant proportionof inert debris, producedwhensewageis continuously aerated.
Adsorption. A surface phenomenon involving the adhesion of molecules to interfaces with which they are
broughtinto contact.
Aerator. A mechanical device used for dissolvingoxygen in water. The oxygen is generally supplied for
use by aerobic micro-organisms.
Aerobic. A condition in whichelementary oxygen is availableand utilised in the free form by bacteria.
Anaerobic. A condition in which oxygen is not available in the form ofdissolvedoxygen ornitrate/nitrite.
Anoxic. A condition in which oxygen is available in the form of oxidised inorganic compoundssuch as
nitrate, nitriteand sulphate.
Bacteria. Micro-organisms, of simple structure and very small size (average 1 Jim diameter); typically
unicellular rods or rounded cells (cocci), occasionally filamentous.
Baffle. Used to check eddies and promote a more uniform flow through a tank. A scum baffle is used for
retainingscum.
Bioflim. A layerof micro-organisms and their productsattached to a support medium.
Biological oxygen demand. The BOD is a measure of the rate at which micro-organisms use dissolved
oxygen in the bacterial breakdown of organic matter (food) under aerobic conditions. The BOD5 test
indicates the organic strength of a waste water and is determined by measuring the dissolved oxygen
concentration before and after the incubationof a sample at 20°Cfor five days in the dark. An inhibitormay
be added to prevent nitrification from occurring.
Biotower. A configuration of percolating filter using a high loading rate designedfor the removal of the
easily biodegradable BOD. May be constructedof structured bales of plastic media stacked up to 12 m in
height.
Bulking. The inability of an activated sludge to settle causing it to float on the settlement tank surface or to
be carriedover with the outflow.
Carbonaceous oxidation. The oxidation of carbon basedcompoundsultimately to CO2 and H20; generally
quantified by the Biological OxygenDemand (BOD)parameter.
Chemical oxygen demand. COD is a measure of the amount of oxygen consumed from a chemical
oxidising agent under controlled conditions. The COD is generally greater than the BOD as the chemical
oxidising agentwill often oxidise more compounds than is possible underbiologicalconditions.
Clarifier or settling tank or sedimentation tank. A solids-liquid separation stage used in primary and
secondary treatment in which heavier material sinks to the bottom and lighter material floats to the water
surface.
96 TREATMENT OF WASTE WATER
Consolidation. The squeezing out of water held between flocs or particles caused by the weight of further
settlement of particles above.
Conventional aeration. An activated sludge process whereby the waste water is subjected to periods of
aeration of 5-14 hours at F/M ratios between0.2 and 0.5; the mixed liquoris returned at rates similar to the
incoming flow with the object ofremovingBODand sometimes nitrogen.
Denitrification. The reduction of nitrate to molecular nitrogen (N2) under anoxic conditions. The nitrate is
used as an oxygensource by heterotrophic bacteriain the absenceof molecular oxygen. A source of carbon
must be added.
Drysolids content (of sludge). The weightof drysolidsper unit weight of sludge, expressed as a percentage
or as mg/kg. Also used to express the quantity of biomass produced per quantity of BOD removed (kg dry
solidsproduced per kg BOD removed)
Dry-weather flow (DWF).When the sewage flow is mainly domestic in character, the average daily flow to
thetreatment worksduring seven consecutive days withoutrain (excluding a period which includes public or
local holidays) following seven days during whichthe rainfall did not exceed0.25 mm on any one day. With
an industrial sewage the dry-weather flow should be based on the flows during five working days if
production is limitedto that period. Preferably, the flows during two periods in the year, one in the summer
and one in the winter, shouldbe averaged to obtain the average dry-weather flow.
Effluent. As applied to sewage treatment, a liquid which flows out of a process or system, but more
particularly the domesticor industrial wastewater, treated to a greater or lesserextent, which flows out of a
section ofthe treatment plant, or from the treatment worksas a whole.
Endogenous respiration or cryptic growth. A stage in bacterial growth where dead bacterial cells are
consumed in the absence ofother organic substrates.
Erosion. The removal of attached biofilmgrowth by the washing action ofa flow of liquid. Used in biofilm
processes to control the thicknessof biofilm on the medium.
Eutrophication. The over enrichment of a water body by nutrients such as nitrate and phosphate causing,
amongst other things, excessiveplant growth and oxygendepletion.
Extended aeration. An activated sludge process wherebythe waste water is subjected to prolonged aeration
at F/M ratios less than 0.15; the mixed liquor is returned at a high rate with the aim of bringing about
considerable oxidation and aerobicdigestion of the organic matterin the activated sludge.
Filamentous bacteria. Organisms that grow in a thread or filamentous form. Common types are thiothrix
and actinomycetes. A common cause of sludge bulkingin the activated sludge process.
Food I
— kg BOD day
Microorganisms kg MLSS
Foul sewer. A sewerconveying sewage, i.e. wastewater of domestic or industrial origin,excluding fainwater
or surface water.
Grease. In sewage treatment, grease includes fats, oils, waxes, free fatty acids, calcium and magnesium
soaps,mineraloils, and other non-fatty materials. The typeofsolvent used for its extraction shouldbe stated.
GLOSSARY 97
Grease trap. A receptacle designedto collect and retaingrease and fatty substances in kitchen wastes or in
an industrial wastewater and installed in the drainagesystembetweenthe point ofproduction and the sewer.
Grit. The heavy mineral matter in sewage, such as silt, sand, gravel, cinders, ashes, metal and glass. It is
abrasive in character and may vary in composition seasonally. Soil originating from vegetablewashing and
preparation is also classified as grit.
Head. The total head against which a pump is to deliver is made up of the static head, plus friction head,
plus velocityhead. The static head is the actuallift, from the minimum level of the liquidin the wet well to
the point of discharge. Thefriction head is the energy lost by friction in the suction and the delivery pipes,
including losses at bends and obstructions. The velocity head is the energy per unit weightof liquid being
pumped due to its velocity.
Humus tank. A secondary settlement stage succeeding the percolating filter process. Namedafter the nature
ofthehumussolids separated.
Hydraulic load. The volumetric flow in relation to the hydraulic capacity of the collecting system or
treatmentplant.
Imhoff tank. A primary settlement tank incorporating an integral sludge storage tank. Not normally
constructed nowadays.
Longitudinal mixing. The back-mixing of liquid in the opposing directionto the main flow as it moves
through a pipeor vessel.
Metabolism. The utilisation by micro-organisms of nutrients (organic matter, compounds of nitrogen and
phosphorus, inorganic matter, trace elements) necessary to sustain life and to proliferate.
Milligrams per litre (mg/I). Used for expressing concentration of impurities in a wastewater or effluent. In
SI units the equivalent is gm/m3.
Mixed liquor suspended solids. The suspension of bacterial flocs or solids in an activated sludge plant
which firstly adsorband then metabolise organic matter.
Nitrification.The sequential oxidation of ammonia and ammonium firstly to nitriteand then to nitrateby the
autotrophic bacteriaNitrosomonas and Nitrobacter.
Nutrients. Compounds (typically of nitrogen and phosphorus) which cause enrichment of water bodies
whenpresent in sufficient concentrations. Enrichment causes eutrophication.
Organic load. The mass of organic polluting matter discharging from a sewer expressed as kg organic
matterper m3 offlow.
Outfall. The site of discharge of a liquid from a pipe. Applied particularly to the point at whicha sewer or
the effluent from a treatment plantdischarges into a receivingwater.
Percolating filter. A biologicalwaste water treatment method using an immobile support medium for the
growthofa bacterial slime that consumes organic matterunderaerobic conditions.
Photosynthesis. A mechanism by which plants synthesise materials (mainly carbohydrates) from carbon
dioxide,water and inorganic salts usingsunlight as a source ofenergy. Oxygenis also produced.
Plugflow. A configuration of activated sludge plant whereby there is (theoretically) no longitudinal mixing
between influent and effluent flows. A pipe/channel length to width ratio of at least 12:1 is normally
required.
98 TREATMENT OF WASTE WATER
Pollutant. A material or compound whichhas a detrimental effect on the environment (aquatic, air or land)
Ponding. The blockage of the interstices between the medium on a percolating filter caused by the
excessive growth of bacterialslime. The term is also applied to the effect of a blockage caused by inert
substances appliedto a bed.
Population equivalent. The volume and strength of a waste water expressed in terms of an equivalent
population, assuming a production of 0.060kg BODper capitaper day; the population equivalent of a waste
wateris therefore calculated usingthe relationship:
Preliminary treatment. The removal or disintegration of gross solids in sewage and the removal of grit.
Also sometimes the removal ofoil and greasefrom sewage, prior to sedimentation.
Pretreatment. The treatment which an industrial wastewater receives at the source before discharge into the
public sewer. Pretreatment ofa sludge refers to conditioning before dewatering.
Primarytreatment. The first major stage of treatment following preliminary treatment in a sewage works,
usually involving removal ofsettleable solids.
Protozoa. A group of motile microscopic animals (usually singlecelled and aerobic) that sometimes cluster
into colonies and often consumeas an energy source.
Receiving water. A body of water, flowing or otherwise, such as a stream, river, lake, estuary or sea into
which an outfalldischarges.
Recirculation.The re-introduction oftreatedeffluentto a treatment stage with the objective of reducing the
concentration of pollutants in incoming waste water in order to protect the process from overloading or
clogging due to excessivebiomass growthor from toxicity.
Return activated sludge (RAS). Closing the activated sludge loop by drawing bacterial floc from
secondary settlement tanks to be mixed with incoming waste water. The waste water providesthe food for
the bacteria.
Returnliquors. Water separated in sludge dewatering processes which is typically high organic strength
and is returnedto the maintreatment plant inlet.
Rotating biologicalcontactor. An attached growth biofilmprocess using rotating support media. Typically
used in smallschemes and package plants.
Scum. A layer of fats, oils, greaseand soaps together with particles of plastic and sludge which floats on the
surface of settlement tanksor digesters.
Scumbaffle. A plate orboard whichdips below the surface of sedimentation tanks to prevent scum flowing
out with the effluent. Alsotermeda 'scum board'.
Septic. A condition produced by lack of dissolved oxygen and oxidised nitrogen (nitrate or nitrite).
Putrefaction can occur.
GLOSSARY 99
Septic tank. A waste water treatment system whereby the settlement of heavy material and flotation of
lighter material occurs in a tank. The liquid overflow is then distributed over a percolation area for
dispersion in the natural environment. Septic tanks are sometimes used as precursors to small scale
biologicalwaste water treatment systems. They are desludged 2-4 timesper year.
Settlement. A physical solid-liquid separation process in which solid particles sink when the velocity of
flow decreases belowa critical value. Canbe aided by using chemicals to coagulate and flocculate the solid
particles to increase their density.
Sludge age. The total mass of sludgecontained in an activated sludge aerationand settlement tank divided
by the total massof sludge wasteddaily, including suspended solids discharged with theoutflow.
Sound power and sound pressure. A sound source radiates power and this results in a sound pressure.
Soundpower is the cause and soundpressureis the result. Sound power is independent ofthe environment
in which it is located. The sound pre'ssure which we hear is dependent on thedistance from the sources and
theacoustic environment (or soundfield)in which thesoundwaves are present.
Submerged filter. A submerged fixed film biological waste water treatment systemdeveloped mainly within
thelast fifteen yearswith claimsfor low footprintand high treatment intensities.
Substrate. A (food) substance that becomes changedby enzymes duringa bacteriological process. In waste
water treatment processes, it normally comprises the soluble biodegradable organic fraction of the waste
water. -
Surcharge. A condition where flow backs up in a pipe or channel due to a lack of hydraulic capacity
downstream.
Telemetry. A system of remote monitoring of plant and equipment using radio links and central control
rooms. Particularly valuable foralarm situations.
Waste activated sludge (WAS). A portion of the sludge drawn from the secondary settlement tank whichis
wasted due to the continuous growth of new micro-organisms during the activated sludge process. Used to
control the MLSS in the aeration tank atthe requiredconcentration.
100 TREATMENT OF WASTE WATER
APPEt'DICES 101
APPENDICES
APPENDIX A: STANDARD FORMS
This appendixprovidesexamplesof the forms which operators are encouraged to use to standardise
sampling and reporting. Those included are:
Sample/s from:
Sample Description
Sample Time
BODmg/102 .
COD mg/l 02
Suspended Solidsmgfl
MLSS mg/l
Temperature °C
Ammoniamg/I N
Total Nitrogenmg/I N
Comments: Signed:
(PrintedName ofanalyst)
APPENDICES 103
NameofPlant:
Laboratory No:
Container Marking:
Sample Description:
SamplingLocation:
Temperature °C:
Sample takenby:
Personcontacted:
GRAB SAMPLES:
FLOWMEASUREMENT
Meterreading Units
COMPOSITE SAMPLE
Start
Finish
COMMENTS:
104 TREATMENT OF WASTE WATER
On
Off
Duplicate
Sample No.
QC N/A* 1/50
Standard**
Parametersotherthan BOD, COD, Total Phosphorus, Total Nitrogen, pH,andAmmonia which may
be presentin an industrial discharge and which may affecttheoperation of secondary treatment
plant.
• Zinc a Tin
• Copper • Lead
• MineralOil (Interceptors) ELECTROPLATING
• MineralOil (Biological treatment) • Oils,Fats and Grease
• Organochionne pesticides • Mineral Oil (Interceptor)
• Benzene, Toluene and Xylene • Mineral Oil (Effluent treatment)
• Mothproofing agents(as Cl) • Organohalogens
• Organophosphorus pesticides • Phenols
• Aldrin,Dieldrin, Endrin, Isodrin • Mercury
• Sulphide a Nickel
SLAUGHTERING • Silver
• Oils, Fats and Grease a Lead
• MineralOil (Interceptor) a ChromiumVI
MANUFACTURE OF SYNTHETICFIBRES • Total Chromium
• Oils, Fats and Grease a Cadmium
• MineralOil (Interceptor) a Tin
• Phenols • Zinc
• Cyanide a Copper
• MineralOil (Biological treatment) a EC List 1 (76/464/EEC)
PROCESSING OF ASBESTOSOR • Cyanide
MANUFACTUREOR PROCESSING OF
MANUFACTURE OF VEGETABLE AND
ASBESTOSBASED PRODUCTS
MANUFACTUREOF GLASS FIBRE OR ANIMAL OILS AND FATS
MINERAL FIBRES, AND PRODUCTION OF a Oils, Fats and Grease
GLASS
a Mineral Oil (Interceptor)
• MineralOil (Biological treatment)
a Mineral Oil (Biological treatment)
• Phenols
PROCESSING OF IRON AND STEEL IN
• Lead FORGES, DRAWING PLANTS AND
• Arsenic ROLLINGMILLS
• Fluoride
a Oils, Fats and Grease
a Lead
• EC List 1 (761464/EEC)
MANUFACTURE OF INTEGRATED a Nickel
CIRCUITS AND PRINTEDCIRCUIT a Zinc
BOARDS
• Chromium VI
• Oils, Fats and Grease a Total Chromium
• MineralOil (Interceptor)
• Copper
• Chromium VI
• MineralOil
• TotalChromium
• Arsenic
• Fluoride
• Copper
110 TREATMENT OF WASTE WATER
Ten areas are designated as sensitive in the the Urban WasteWaterTreatment Regulations. Article5(6) of
the Urban WasteWaterTreatment Directive(9l/271IEEC)requiresthat the identification of sensitive areas
is reviewed atintervalsofno more than four years.
By: Temperature °C
Sample Location:
Amoebae
Flagellates
Free swimmingciliates .
Stalked ciliates .
Rotifers
Worms
Relative predominance
Method
CONTENTS:
STYLE:
INFORMATION:
NAME ORGANISATION
ADDRESS
Phone: Fax:
ENVIRONMENTAL
PROTECTION AGENCY