1. Ejection of the photoelectron from metal in the photoelectric effect experiment can be stopped by applying 0.5 V when the radiation of 250 nm is used. The work function of the metal is: (2018) (@)45ev (b) 3 eV ()55eV @sev 2. Which of the following statements is false ? (@ Splitting of spectral lines in electrical field is called Stark effect. (b) Frequency of emitted radiation from a black body goes from alower wavelength to higher wavelength as the temperature increases (©) Photon has momentum as well as wavelength (@) Rydberg constant has unit of length Ge. cm) 3. A stream of electrons from aheated filament was passed between two charged plates kept at a potential difference V esu. Ife and m are charge and mass of an electron, respectively, then the value of h/ 2 (where A, is wavelength associated with electron wave) is given by (2016) (a) 2meV (b) vmeV (c) V2meV, (@) mev 4, Rutherford's experiment, whi established the nuclear model of the atom, used abeam of (2002) (@ B -patticles, which impinged on ametal foil and got absorbed () y-rays, which impinged on a metal foil and got scattered (©) helium atoms, which impinged on a metal foil and got scattered (@ helium nuclei, which impinged on a metal foil and got scattered 5. Rutherford's alpha particle scattering experiment eventually led to the conclusion that (4986) (@) mass and energy are related () electrons occupy space around the nucleus (©) neutrons are buried deep in the nucleus (@ the point of impact with manor can be precisely determined 6. The radius of an atomic nucleus is of the order of asss) (@) 10" cm (b) 103 cm (©) 1075 cm @) 10* cm 7. Bohr's model can explain 989) (@ the spectrum of hydrogen atom only () spectrum of an atom orion containing one electron only ) the spectrum of hydrogen molecule wa(@ the solar spectrum 8. The increasing order (lowest first) for the values of elm (charge/mass) for electron (e), proton (p), neutron (a) and alpha patticle (a) is a9s4) @epna ()n, prea (On, Prae @n,ape 9. Rutherford's scattering experiment is related to the size of the 4983) (@) nucleus () atom (©) electron (@) neutron 10. Rutherford's experiment on scattering of a-particles showed for the first time that the atom has gsi) (@ electrons () protons (©) nucleus (@) neutrons 11. The radius of the second Bohr orbit for hydrogen atom is (Planck's constant (h }= 6.6262 x 10 Js, mass of electron = 9.1091 x 103! kg ; charge of electron (e) 1.60210 x 10° C; permittivity of vacuum (Eo) = 8.854185 x 10 ?kg? m? A?) 017) ° @165A ° )4.76 A (0529 A o @22A 12. Pis the probability of finding the 1s electron of hydrogen atom in a spherical shell of infinitesimal thickness, dr, at a distance r from the nucleus. The volume of this shell is 4ar’dr. The qualitative sketch ofthe dependence of Ponris (2016) ? >| © © \ [Nas o 7 c 7 a ?| © @ 6 7 ° r 13, Which of the following is the energy of apossible excited state of hydrogen? (2015) (@+136ev ) -68eV (34ev @+68ev 14, The correct set of four quantum numbers for the valence electrons of rubidium atom (Z= 37) is (2013) @5,0,0,+4 v4©) 5,1,0,+4 Os Laek @5.0,1,+4 15. Energy of an electron is given by a 2 vrei s(3) ” ‘Wavelength of light required to excite all electron in an hydrogen atom from level n = 1 ton=2 will be (h= 6.62 x 10 Js and 3.0 x 10° ms) (2013) Ez (a) 1.214x107m (b) 2.816 x 107m (©) 6.500 x 107m (d) 8.500 x 107m 16. The kinetic energy of an electron in the second Bohr orbit of a hydrogen atom is [ao is Bohr radius] (2012) e a) —_. © nal R 1627maj, ® RB © 32n°mag RB 64n°map @ 17. The number of radial nodes in 3s and 2p respectively are (005) (@)2 and 0 (b) O and 2 (land? (@ 2 and1 18, Which hydrogen like species will have same radius as that of Bohr orbit of hydrogen atom? 2004) @a=2, Le @)a=2, Be (@a=2, Het Lit @a 19. Ifthe nitrogen atom had electronic configuration 1s’, it would have energy lower than that of the normal ground state configuration Is? 2s? 2p?, because the electrons would be closer to the nucleus, yet Is? is not observed, because it violates (2004) (@ Heisenberg uncertainty principle (&) Hund’s rule (©) Pauli exclusion principle (@) Bohr postulate of stationary orbits 20. The quantum numbers ++ and —1 for the electron spin represent (2001) (@ sotation of the electron in clockwise and anticlockwise direction respectively () rotation of the electron in anti- clockwise and clockwise direction respectively (©) magnetic moment of the electron pointing up and down respectively wsNedanti, (@ two quantum mechanical spin states which have no classical analogue 21. The wavelength associated with a golf ball weighing 200 g and moving at a speed of $ mbhr is of the order 2001) (a) 10 m (b) 107° m (c) 107m @ 10% m 22. The number ofnodal planes in a px orbital is 2001) (@) one (b) two (©) three (@ zero 23. The electronic configuration of an element is Is?, 2s? 2p8, 3s? 3p® 3d, 4s! This represents its (2000) (@ excited state (b) ground state (©) cationic form (@) anionic form 24. The electrons, identified by quantum numbers n and I, @n=4, 1=1, @in=4, 1=0, Gi) n=3, 1=2, @v) n= 3, /=1 can be placed in order of increasing energy, from the lowest to highest, as a9) @ @w) < @) < Gi) <@ v8 (®) @) < @v), © < Gu) O@<@i)<@<@) @ i) <@<@)< G) 25. The energy of an electron in the first Bohr orbit of H-atom is —13.6 eV. The possible energy value(s) of the excited state(s) for electrons in Bohr orbits of hydrogen is (are) (4998) @—34ev )—42ev @—61ev @+68ev 26. For ad-electron, the orbital angular momentum is 4997) @v ( OR (2) © (3) of) 27. The first use of quantum theory to explain the structure of atom was made by (as97) (@ Hatsenberg () Bohr (© Planck (@ EinsteinNedanti, 28. Which of the following has the maximum number of unpaired electrons ? (1996) (@ Me* wm ev @ Fe* 29. The orbital angular momentum of an electron in 2s-orbital is 4996) @it (b) zero 30. Which of the following relates to photons both as wave motion and as a stream of particles? (4992) (@ Interference () E=me* (©) Diffraction @E=hy 31. Which of the following does not characterise X-rays ? cag92) (@) The radiation can ionise gases (b) It causes ZnS to fluoresce (©) Deflected by electric and magnetic fields (@) Have wavelengths shorter than ultraviolet rays 32. The correct set of quantum numbers for the unpaired electron of chlorine atom is ags9) olm a lom @210 ®211 @311 @3 00 33. The correct ground state electronic configuration of chromium atom is (1989) (@ [Ar] 3d° 4st (b) [Ar] 3d 45? (© [Ar] 306 43° (d) [Ar] 405 4s! 34, The outermost electronic configuration of the most electronegative element is (1988) (@ as? np? (b) ns? np* (C) ns? np* (@) ns? np® 35. The orbital diagram in which the ‘Anfoau’s principle is violated (2988) @ wNedanti, WJ U4 36. The wavelength of a spectral line for an electronic transition is inversely related to (agssy (@ the number of electrons undergoing the transition () the nuclear charge of the atom (©) the difference in the energy of the energy levels involved in the transition (@ the velocity of the electron undergoing the transition 37. The ratio of the energy of a photon of 2000 A wavelength radiation to that of 4000 A radiation is (4986) 1 @; 4 © t @2 38. Which one of the following sets of quantum numbers represents an impossible arrangement? ag86) no looms @3 2 2 & ® 4 0 oF % @3 2 3 aR @5 3 Oo AR 39. Electromagnetic radiation with maximum wavelength is 98s) va (@ ultraviolet () radio wave () X-ray (@ infrared 40. Which electronic level would allow the hydrogen atom to absorb a photon but not to emit a photon? (1984) @3s ©» (2s @Is 41. Correct set of four quantum numbers for the valence (outermost) electron of rubidium (Z= 37) is a9s4) @5,0,0, +t O50, at OSuiat @60,0, 44 42. The principal quantum number of an atom is related to the (4983) (@ size of the orbital () spin angular momentum (©) orientation of the orbital in space (@ orbital angular momentum 43. Any p-orbital can accommodate upto (4983)@ four electrons () six electrons (©) two electrons with parallel spies (@) two electrons with opposite spins 44, Spin only magnetic moment of 2sMn™* ionis V15 B.M. Then, the value of xis @1 (2 ©3 @4 45. The spin only magnetic moment of Cr* in aqueous solution would be (a) VI3 B.M (b) VIS B.M. (©) V8. BM. (d) 35 BM. 46. y?=0 represent (@)node () orbital (©) zero amplitude of wave (@) wave function 47. Observe the following statements regarding isotones i °K and “Ca areisotones ii, Nucleides having different atomic number(Z) and mass numbers (a) but same number of neutrons (a) are called isotones iii, °F and Na are isotones. The correct answer is: (@)i, ii and iii are correct (&) Only i and ii are correct (©) Only i and iii are correct, (@) Only it and iii are correct 48. Ifn, and ny are the boundary value principal quantum numbers of a portion of spectrum of emission spectrum of H atom, determine the wavelength (in metre) corresponding to Last line (longest 2.) Given: m +n =7, m2-m=3 and R= 1.097 x 107m‘. (Give your answer in multiple of 10°) @s @)4 (10 @1s 49. What is the potential energy of an electron present in N-shell of the Be ion ? @-34ev )-272eV ()-136ev @—88ev 50. In which of the following transition, the wavelength will be minimum: @n=6ton=4 )n=4ton ()n=3ton=1 @n=2ton va51. The ratio of kinetic energy and potential energy of an electron in a Bohr orbit of a hydrogen-like species is @12 wn @1 @-a 52. Total Number of unpaired electrons in d-orbitals of an atom of element of atomic number 29 is: (a) Ten (b) One (©) Zero (@ Five 53. Photons of minimum energy 496 kJ. mol" are needed to ionize sodium atoms Calculate the lowest frequency of light that will ionize a sodium atom. (a) 1.24x 104s? (b)1.24 x 10 (2) 2.48 x 10! st (d) 2.48 x 10% 5? 54. According to Bohr's model, ifthe kinetic energy of an electron in 2™ orbit of Het is x, then what should be the ionisation energy of the electron revolving in 3rd orbit of M* ion @= (b) 4x (x4 @ 2x 55. Last line of Lyman senies for H—atom ° has wavelength 1, A, ™ line of Balmer a series has wavelength 22, A then 16 9 ear 16 3 oF iy 16 3 d) 2 OF a 56. Wave function vs distance from nucleus graph of an orbital is given below: ‘The number ofnodal sphere of this orbital is @1 2 ©3 @4 57. Number of nodal planes (planes of zero electron density) in the dy orbital is @! ®2 @o0 @4 18058. The uncertainty in position and velocity of the particle are 0.2 nm and 10.54 x 1077 ms? respectively then the mass of the particle is (h = 6.625 x 10 Js) (@) 48.86 (b) 30.86 g (©) 24.86 gm @ 100g 59. A particle initially at rest having charge q coulomb. & mass m kgis accelerated by a potential difference of V volts. What would be its KE & de Broglie wavelength respectively after acceleration bh aqVm h agVm h mV @av, ® av Oa, h d) — av Ow? 60. The number of possible lines of Paschen series when electron jumps from P excited state to ground state Gn hydrogen like atom) is: @2 5 @4 @3 61. AIR service on Vividh Bharati is transmitted on 219 m band. What is its transmission frequency in Hertz? (@) 1.37 x 10° Hz (b) 1.37x 105 Hz (1.3710? Hz (@) 2.74 x 108 Hz 62. Calculate the maximum and minimum number of electrons. Which may have magnetic quantum number m =+ 1 and spin quantum number s = Chromium (Cr). @3, (0) 6, ©4 @21 63. In the emission spectrum of H-atom from energy level ‘n’ to ground state in one or more step, no line belonging to the Brackett series is observed. The wave number of lines belonging to Balmer series maybe @ ® => @®>— 64. The ionisation energy of His 13.6 eV. Calculate the ionization energy of Li* ions. @544ev (b) 1224 ev 181(2) 244.8 eV (108.8 eV 65. If Photon having wavelength 6.2 nm was allowed to strike a metal plate having work function 50 eV then calculate wavelength associated with emitted electron: ()ix10%m (b) 2x10 m (3x10 m (d)4x10%m 66. The number of nodal planes in ape orbital is (@) one (b) two (©) three @ four 67. The wave number of electromagnetic radiation emitted during the transition of electron in between two levels of Li* ion whose principal quantum numbers sum is 4 and difference is 2 is @35R aR (O8R 8 @ SR 68. The correct order of wavelength of Hydrogen (1H), Deuterium (iH?) and ‘Tritium (1H) moving with same kinetic energy is @ dun> >> dt (0) An= Ao = Ar (© dns do < dt (@ dn < Ao > dt 69. Spin angular momentum for unpaired electron in sodium (Atomic No. = 11) is (4) None of these 70. The distance between 4th and 3rd Bohr orbits of He" is (a) 2.645 x 10m (b) 1.322x10%m (c) 1.851 x10" m (@) None 71. What is the frequency of revolution of electron present in 2nd Bohr's orbit of H- atom ? (a) 1.016 x 10% s? (b) 4.065 x 10% 5? (c) 1.626 x 10% s (d) 8.13 x 10's? 72. According to Bohr's atomic theory. which of the following is correct? 1822 (@ Potential energy of electron oc 2 2 (b) The product of velocity of electron and principle quantum number (n) « Z? (©) Frequency of revolution of electron in 2 an orbit «= 2 (@) Coulombic force of attraction on the 2 electron ac = a 73. If In Bohr's model, for uni-electronic atom, time period of revolution is represented as Ta,2 where n represents shell no. and Z represents atomic number then the value of 71,2: Ta,1 will be @s1 @is @iet (@1:32 74, Be. and a proton are accelerated by the same potential, their de-Broglie wavelengths have the ratio (assume mass of proton = mass of neutron) @i:2 @)1:4 @iet (@ 1-33 75. Ifthe ionization energy of He* is 19.6 x 107° J per atom then the energy of Be* ion in the second stationary state is (@)-4.9x10%5 (o)-44.1x 10%) (11.025 x 1025 (@)-194x10%)Ta [2b 3c [4d [5b [6b [7b 8d 19a 10. Ind /i2e Bc [laa [Ia [lec [Iza [8b [19.c | 20. Qe |[22.a [23.b [24a a [26a |27.b [28d [29.6 |30. Ble [32.¢ 33.a [34.c b [36c [37d [38c¢ [39.6 | 40. ala [42a [43.d]44d [45.b [46a [47.0 [48> [49.b | 50. Sib [52a [53.b/54b [55.b [56a [57.b [58c [59a [60 Gla |62.a |[63.c[64b [65.a [66a [67.b [68a [69.b | 70. Td [72 Bd [74a [75d For solutions, login to your Vedantu student dashboard 184