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    Chemical Bonding Assignment PDF

    Uploaded by

    Raghvendra Pandey

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    © All Rights Reserved
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    Nedanth, 1. According to molecular orbital theory, (@) 3eOR and XeOR, which of the following will not bea feasible molecule? ais) @ E> () HP 6 () (1) ta hydrogen azide H-N.N.N (©) Hey @ Hy (above) the bond orders of bonds (I) and (are 2. Which of the following compounds oo Oo @ contain(s)mo covalent bonds)? 2018) @<2 >2 ()>2 >2 KCI, PHs, O2, BaHs, HaSO+ @>2 <2 @2 <2 (@)KCI, Balls (b) KCI, Balls, PHs 7. For Nat, Mg™, F-and O ; the correct (OKCI, HS order of nreasing intra s (Kel (@) 0% 4, Inthe molecular orbital diagram for the — paramagnetic molecularion, Nj, the number of (©) [N(CN)aP— tetrahedral; [NCO electrons in the op molecular orbital is ~ paramagnetic 018) (© [NiCl]* - paramagnetic ; [Ni(CO)4] - @o (2 tetrahedral (3 @l (q) [NiCls]?- — diamagnetic ; [Ni(CO)4] - square-planar 5, Identify the pair in which the geometry of the species is T-shape and square- 9. In graphite and diamond, the percentage pyramidal, respectively 018) of p-characters of the hybrid orbitals in (@ 101 and 10% hybridization are respectively: 2018) (@) 33 and 25 (b) 67 and 75 (®) 10; and 10,F; (©) 50nd 75, (@) 3 and 75 (© CIR, and 10; ma Nedanth, 10. The decreasing order of bond angles in BR, NH,, PF, Iris 018) @ I> BR > NH, > PR (b) BF, > I; > PF, > NH, (© BR > NE, > PR > Ip (®) Jy > NH, > PR > BE, 11, Which of the following arrangements shows the schematic alignment of ‘magnetic moments of antiferromagnetic substance? 018) @ OOOO © DOOOOD ° OD OOOO @ ® ®OOOOO 12. Among the oxides of nitrogen : (2018) N03, N20 and NOs ; the molecule(s) having nitrogen-nitrogen bond is/are (@) Nn03 and N20s (B)N2Os and N2Os (©)N203 and N20s (&) Only N2Os 13, Which of the following conversions involves change in both shape and hybridisation ? @H,O>H,O () BR BR (CH,>C,H, (@) NH, > NH; 14, In Wilkinson's catalyst, the hybridization of central metal ion and its shape are respectively ais) (@) sp°4, trigonal bipyramidal (®) dsp, octahedral (© dsp’ (d) sp°, tetrahedral , square planar 15. The incorrect geometry is represented by 018) (@) NF3 — trigonal planar (b) BF3 — trigonal planar (© AsFs trigonal bipyramidal (@)H20 bent 16. The intermolecular interaction that is dependent on the inverse cube of distance between the molecules is 015) (@)ion-ion interaction (b) ion-dipole interaction (© London force (@) hydrogen bond 17. The nodal plane in the n-bond of ethene is located in 2002) (@) the molecular plane m Nedanth, (b)a plane parallel to the molecular plane (c)a plane perpendicular to the molecular plane which bisects the carbon-carbon o- bond at right angle (d)a plane perpendicular to the molecular plane which contains the carbon-carbon o- bond 18, Amongst 20, HaS, HaSe and HaTe, the one with the highest boiling point is 000) (@) H20 because of hydrogen bonding (b) HaTe because of higher molecular weight (©) HaS because of hydrogen bonding (@) HaSe because of lower molecular weight 19. Arrange the following compounds in order of increasing dipole moment, toluene (D, m-dichlorobenzene (ID, 0- dichlorobenzene (IID, p-dichlorobenzene @) 4996) @IPaAs=Bi ()B>P>As>Bi (OB HCI > HBr >HI (0) CH3-F > CD3-F (©) S03> S02 (@) CH — CH = CHCl (cis) > CH - CH= CHC! (trans) 716. Which of the following is not correct? (@) Carbon-carbon bond length in CaC2 ‘will be more than that in CHCCH (b) 0 - 0 bond Length in NaO2 will be ‘more than that in KO2 (© O-O bond length in [PtFe] will be less than that In KO2 (@)N—0 bond Length in NO gaseous molecule will be smaller than that bond length in NOCT gaseous molecule ‘77. Correct order of bond length is @ 80} > 80?-> $0, m9 Nedanth, (b) So} > $0} > SO, (© 80, > SO} > So} (@ None of these 78, Which of the following is paramagnetic? @O (CN (co (NOt 79. Gaseous SOs molecule (@) is planner triangular in shape with three bonds from sp” -p overlap and three n- ‘bonds formed by two px — px overlap and one pa- do overiap. (b) is planner triangular in shape with three o-bonds from sp?- p overlap and three x- bonds formed by one pr — pr overlap and two pa — dr overlap (O)isa pyramidal molecule with one double bond and two single bonds (@) planner triangular in shape with two double bonds between $ and O and one single bond 80. Among the following, the pair in ‘which the two species are not isostructural is (@) 10; and 20, () APH, and PH} (© ASFy and SF, (@ SiR, and SeF, 81, The correct order of C-N bond length in the given compounds is: P: CH3CN; Q: HNCO; R: CHsCONH: @P>QoR ()P=Q=R (OR>Q>P (@R>P>Q 82. The correct order of increasing s character (in percentage) in the hybrid orbitals in below molecules / ions is (assume all hybrid orbitals are exactly equivalent) @ coy () eR ay (Vv) NCh, () Bet, (g) @U HS > HaSe > HaTe (b) CaHa > Cals > CHy > NH (© SFo HO > H2S > SFs nt Nedanth, 91. The correct order of stability to form ionic compounds among Si**, AP*, Mg** and Na is @ Si*> AP*> Mg > Nat (0) AY > Sift > Mg > Nat (Nat > Sit > Mg > at (6) Nat Mg > ABY> sift 92. The correct order of hybridisation of the central atom in the following species ‘NF3, BF3, PFs, and [SiFs]” is @) sp? sp, spe, spd (b) sp°, sp?, spd, spi? (sp, sp°, spd, spe? (@ sp*, sp”, spe, spi? 93. Which of the following arrangements is correct on the basis of the increasing p- character of the hybrid orbitals of the central atoms in the following (Dclox (CS: (UD SnCly @l>u>m (> I> Mt (>> mt (@Ul>1> 0 94. Which of the following are isostructural? (Nox (a cos* (up clos (Iv) S03, (V) Xe0s @ @Mand(y) (©) ID and (V) (© (ID) and (IV) (@) UV) and”) 95, Which of the followingisa square planar molecule? (@ XeOsF2 (b) XeOFs (OXF ()XeFe 96. Which one of the following represents the INCORRECT decreasing order of ‘bond angles? (@) CO: > BF3 > CHa > FO (b) NO3* > NO > NOx (OBCh > PCls > AsCl > BiCls (@) IOs > BrOs > Clos 97. The number of P—O—P bonds in tricyclic metaphosphoric acid is (@) zero (b) two (© three @ four mm Nedanth, 98. In which of the following molecule / (10D The hybridisation of boron In BF3 is ion all the bonds are equal ? the same which nitrogen has in CINO @sr molecule (Fr ocr: @) Only (D & (11) (@ PCls ap (© Only () & (1) 99. Which of the following options with ©. ey respect to increasing bond order is comrect? (@)NO ()NO os (os 4 Nm 8 108. Arrange the following compounds in increasing order of their ionic character () Niki is pyramidal about each atom SnClp, SnCl, SiCls, SnFs, SaF (A) NH,OH is pyramidal about the N atom (1) SnF < SnCh < SnF4 < SnCle < SiCle and bent about the O atom (2) SnF: < Sn < SnF4 < SiC < SnClt (ID) CHaCOCTis trigonal planar about the (B) SiCle < SnChs < SnFs < SnCh < SnF2 carbon atom (attached to O and CD). 105. Which of the following statements are correct ? (4) SnCle < SnFs < SnCh < SnF2 < SiCle nly (1) & (I @) only & CI) 109. The shape of SFs can be (b) only (11) 2 & epee ve (© only (D) & (ID. Dy bal | 5 . @@, dD & ap rT F F k 106. Which of the following statements (@) lonly isfare true? (0) [and Il only (@) Based on VSEPR theory, the number (OW only of 90 degree F - Br—F angles In BrFsis four. (@) I, Wand UT (b) Molecular geometries of both (CHs)sN and (SiFis)3N are trigonal planar. 110. In terms of polar character, which of () The C —C bond length in C2 is bigger the following order is correct ? than © — O bond length in O2 @Niy <1,0 < HF H30)> HF > HS (0) HF > Hy03 > H20 > HS (QHF > H30 > HS > H202 (@) HF > H:0 > H202 > aS 116. In which of the following metal to metal bond is present? (@) Cupric chloride (b) Stannous chloride (© Mercurous chloride (@) Mercuric chloride 117. What is not true about ice? (@) Ithas open cage like structure (b) It has less density than water (© Each O atomis surrounded by 4H atoms (@) Each O atom has four H-bonds around it 118. Give the correct order of initials T or F for following statements. Use T If statement is true and F if itis false: (D The order of repulsion between different pair of electrons is Ip — Ip > h— bp > bp — bp 16 Nedanth, (ID) In general, as the number of lone pair of electrons on central atom increases, value of bond angle from normal bond (IID The number of lone pair on O in H20 is 2 while on N in NH is 1 (IV) The structures of xenon fluorides and xenon oxyfluorides could not be explained on the basis of VSEPR theory. (@) TTTF (b) TFTF (9 TFIT () TFFF 119. Consider the following statements 1 A sigma (0) bond is formed when two o- orbitals overlap IL A pi(a) bond is formed when two n- orbitals overlap axially IIL A o-bond is weaker than x-bond ‘Which of the above statements is/are correct? (@) Iand IT (b) Wand IIT (o)Talone (@ Malone 120. Match list I with List ITand select the correct answer using the codes given below the lists List I List IT @CS (p) Bent (i) S02 (@) Linear ii) BFs (©) Trigonal planar (iv) NEG (9) Tetrahedral (® Trigonal pyramidal Codes © @ G Ww @ gq por it (o) pPoqorot © qopotios @ pPoaqotos 121, Match list I (Hybridisation) with List II (shapes) and select the correct answer using the codes given below the lists: List I List I @ip? (p) Square planar @ sp (q) Tetrahedra, (iit) Psp? (®) Octahedral Gv) sp'd (s) Trigonal bipyramidal Codes © @ G @ q porios (o) sq or op © pPoroqiss @ sor oq ep 122, Identify the correct sequence of increasing number of -bonds in the structure of the following molecules (FDS206 (I) H2S203 (UD HaSi0s @ I, Mand I (®) H, tand IT (QU, Mand! 0 Nedanth, (D1, Mand 123, The hybridization of the central atom will change when (@) NH combines with H* (b) H3BOs combines with OF (©) NH forms NHY (120 Combines with H* 124. Which of the following is the most ionic? (@PsOw (C103 (b) MnO (@Mm0r 125. Among LiCl, BeCls, BCls and CCl, the covalent bond character varies as (@LICIBCb > CC (b) LICI > BeCh BeCh >BCh > CC 126, Ina metallic crystal the (@) Valence electrons remain within the fields of influence of their own kemels (b) Valence electrons constitute a sea of mobile electrons (©) Valence electrons are localised between the two kemels (@) Kemels as well as the electrons move rapidly 127. Polarisation involves the distortion of the shape of an anion by an adjacently placed cation. In this context, which of the following statements is correct? (@) Maximum polarisation is brought about bya canon of high charge (b) Minimum polarisation is brought about bya cation of low radius. (OA large cation is likely to bring about a high degree of polarisation. (@) The polarising power ofa cation is less than that ofan anion 128. Which of the following is required for the formation of an ionic bond? (@) An electron from the more electronegative element should be transferred to the less electronegative (b) The total energy of the resulting molecule should be less than the total energy of the reactants (©) The lattice energy of Me resultant molecule should beas lowas possible. (@) The ionic potential of the reactants should be identical 129. AICIis covalent while AIF3 is ionic This can be justified on the basic of (@) The valence bond theory (b) Fajan’s rules (© The molecular orbital theory d Hydration energy 130. Which of the following oxyacids of phosphorous are monoprotic (monobasic)? (@) HsPOs (©) HsPOs (© HsPO2 (HPO rm Nedanth, 131, Which of the following has greater ‘bond Length? (@P-0 (gcl-o (b) 8-0 (®0=0 132, Which of the following has been arranged in order of increasing covalent character? @ KCl < CaCl

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