Vedantu, 1. NO, decomposes to NO,and O, and follows first order kinetics. After 50 minutes, the pressure inside the vessel increases from 50 mm Hg to 87.5 mm Hg. ‘The pressure of the gaseous mixture after 100 min at constant temperature will be (@ 136.25 mm Hg (b) 106.25 mm Hg (©) 175.0 mm Hg @ 116.25 mm Hg 2. At 518°C, the rate of decomposition of a sample of gaseous acetaldehyde, initially at apressure of 363 Torr, was 1.00 Torr s*, when 5% had reacted and 0.5 Torr s? when 33% had reacted. The order of the reaction is @o (b)2 ©3 @1 3. If 50 % of areaction occurs in 100 second and 75 % of the reaction occurs in 200 second, the order of this reaction is @2 ()3 (©) Zero @t 4, The rate of reaction A doubles on increasing the temperature from 300 to 310 K. By how much, the temperature of reaction B should be increased from 300 K, so that rate doubles if activation energy of the reaction Bis twice to thet of reaction A (984K (b)492K (245K @19.67K 5. The rate of a reaction quatruples when the temperature changes from 300 to 310 K ‘The activation energy of this reaction is (Assume activation energy and pre- exponential factor are independent of temperature; In2=0.693;R=8.314 J mol*K) (@ 107.2 AF mol (b) 53.6 kJ molt (© 268k mol (@ 214.4 kv mol 6. Two reactions, Rand R, have identical preexponential factors. Activation energy of ‘R, exceeds that of R, by 10 k/ mol" If ‘ky and kare sate constants for reactions R and Ryrespectively at 300 K, then In(, /) is equal to (a12 (b) 6 @4 @s 7. Decomposition of H2O> follows a first order reaction. In fifty minutes, the concentration of H2O2 decreases from 0.5 to 0.125 Min one such decomposition. When the concentration of H2O2 reaches 0.05 M, the rate of formation of O2 will be (@) 6.93 x 10? mol min? (b) 6.93 « 10 mol min (©) 2.66 L min? at STP (d) 1.34 « 10? mol min? 8. 200 g water is heated from 40°C to 60°C. Ignoring the slight expansion of water, the change in its intemal energy is close to (Given specific heat of water=4184 J/kg/K) @ 84k (0) 4.2K (16.7 (@) 1674 kt 9. The rate law for the reaction below A+B — Productis given by the expression, k [A][B] 2Ifthe concentration of B is increased from 0.1 to 0.3 mole, keeping the value of A at 0.1 mole, the rate constant will be @k (b) K/3 (3k @ 10. Higher order (>3) reactions are rare due to (@ Low probability of simultaneous collision of all the reacting species. (b) Increase in entropy and activation energy as more molecules are involved (© Shifting of equilibrium towards reactants due to elastic collisions (@ Loss of active species on collision 11, The reaction 2N,O,(g) + 4NO,(g) + O,(g) follows first order kinetics. The pressure of avessel containing only V,0, was found to increase from 50 mm Hg to 87.5 mm Hg in 30 min. The pressure exerted by the gases after 60 min, will be (Assume temperature remains constant): (2) 106.25 mm Hg (b) 116.25 mm Hg (©) 125 mm Hg (@ 150 mm Hg 12. A+ 2B — C, the rate equation for this reaction is given as Rate =k [AJ[B]. Ifthe concentration of A is kept the same but that of Bis doubled, what will happen to the rate itself? (@ halved () the same (©) doubled @ quadrupled 13. For the non-stoichiometric reaction, 2A + BC+ D, the following kinetic data were obtained in three separate experiments, all at 298 K. Vedantu, Tnitial Tnitial Tnitial Concentration | Concentration | rate of @ ®) formation ofC (mol L* 5!) vim viM 12x10 01M 02M 12% 105 02M 01M 234x107 ‘The rate law for the formation of C is ac = =H ALI @ 4 7 MAl dc dt ac at ac @ Al 14, In the following sets of reactants which two sets best exhibit the amphoteric character of Al,0,.xH,07 Set-1: Al,0,.x#7,0(s) and OH-(ag) Set-2: ALO, xHf,0(6) and H,0(0) Set-3: Al,O,.xHf,0(s) and H” (aq) Set-4: Al,0,.x#f,0(s) and NH, (ag) (@ land? (b) 2and 4 (land 3 (@)3and4 15, Which of the following statements about Na,O,is not correct? (@ Na,O, oxidises Cr?* to CrO}-in acid medium, () It is diamagnetic in nature (©) Itis the super oxide of sodium (@ Itis a derivative of H,0, “4Vedantu, 16. The standard enthalpy of formation (A, xq) for methane, (CH,) is -74.9 15 mol"? In order to calculate the average energy given out in the formation of a C-H bond from this itis necessary to know which one of the following is correct? (@ the dissociation energy of the hydrogen molecule, Ho (b) the dissociation energy of He and enthalpy of sublimation of carbon (graphite) the first four ionisation energies of ‘bon and electron affinity of hydrogen (@ the first four ionisation energies of carbon 17. Which type of ‘defect’ has the presence of cations in the interstitial sites ? (@ Metal deficiency defect (b) Schottky defect (©) Vacancy defect (@ Frenkel defect 18. For a first order reaction, A — P, the temperature (T) dependent rate constant (k) ‘was found to follow the equation: logk = 20 6.0 the pre-exponential factor A and the activation energy Es, respectively, are (a) 1.0 « 108 s? and 9.2 kJ mol? (b) 6.0 s-1 and 16.6 ki mol? (©) 1.0 x 108 s and 16.6 kI mot? (@ 1.0 « 106 $4 and 38.3 kJ mol? 19. Under the same reaction conditions, initial concentration of 1.386 mol d? ofa substance becomes halfin 40 s and 20 s through first order and zero order kinetics (i) respectively. Ratio | K | ofthe rate Ve) constants for first order (kn) and zero order (ke) of the reaction is (2) 0.5 mol dm? (b) 1.0. mol dex? (c) 1.5 mol dm? (d) 2.0 mol dm? 20, Consider a reaction, aG + bH > products. When concentration of both the reactants G and His doubled, the rate increases by eight times, However, when concentration of G is doubled keeping the concentration of H fixed, the rate is doubled The overall order of the reaction is @a 1 2 @3 21, Which one of the following statement(s) is incorrect about order of reaction? (@ Order of reaction is determined experimentally (b) Order of reaction is equal to sum of the power of cementation terms in differential rate law (©) Itis not affected with stoichiometric coefficient of the reactants (@) Order cannot be fractional 22, (A) follows first order reaction, (4) + product. Concentration of A, changes from 0.1 M to 0.025 M in 40 min. Find the rate of reaction of A when concentration of 4 is 0.01 M. (@ 3.47% 104 M min? (b) 347 10% M min? (©) 1.73 x 10 M min? (d) 1.73 « 10% M min? 23. In a first order reaction, the concentration of reactant decreases from 800 mol/dm? to 50 mol/dm? in 2 x 10* s. The rate constant of reaction in sis (@)2* 10 (b) 3.45 x 10% 6Vedantu, (©) 1.386 = 10 @2« 104 24. Consider the chemical reaction, Na(g )+ 3H2(g) > 2NHs(g). The rate of this reaction can be expressed in terms of time derivatives of concentration of N2(g), Ho(g) or NH3,(g). Identify the correct relationship amongst the rate expressions @ paew - 21M] tel) ales] at ) a[Ns] Rate de ratee . 0%] 1d[NH,] at 2 at @ race — $(t]__ales) ales) dt dt dt 25. IfTis the intensity of absorbed light and Cis the concentration of AB for a photochemical process, then AB + hy —> AB", the rate of formation of AB" is directly proportional to @c I or @ci 26. The rate constant for the reaction, 2N2Os > 4NO2 + Oris 3.0 x10% s?. Ifthe rateis 2.40 x 10% mol L's then the concentration of N2Os (in mol L") is @14 12 (0.04 @os 27. The half life period of a radioactive clement is 140 days. After 650 days, one gram of the element will reduce to @te 1 ©) 78 ol Oe 1 @ ye 28. A catalyst is a substance which (@ increases the equilibrium concentration of the product (b) changes the equilibrium constant of the reaction (©) shortens the time to reach equilibrium (@ supplies energy to the reaction 29. The specific rate constant of a first order reaction depends on the (@ concentration of the reactant (b) concentration of the product 6Vedantu, tume @ temperature 30. The rate constant of a reaction depends on (@ temperature (b) initial concentration of the reactants (©) time of reaction (@ extent of reaction 31. For the first order reaction, 2NOs(g) —> AN2(g) + Ox(G). (@ the concentration of the reactant decreases exponentially with time (b) the half-life of the reaction decreases with decreasing temperature (©) the halflife of the reaction depends on the initial concentration of the reactant (@ the reaction proceeds 98.6% completion in eight halflife duration 32, The following statement (s) is are correct (@ A plot of log K vs ¢ is non-linear (b) A plot of log [X] vs time is linear for a first order reaction, x p (©) Aplot of log p vs ; is linear at constant volume @ Aplot ofp vs z is non-linear at constant temperature 33. For the first order reaction, (@ the degree of dissociation is equal to (e*) (b) a plot of reciprocal concentration of the reactant vs time gives anon-straight line (©) the time taken for the completion of 75% reaction is thrice the half-life of the reaction (@ the pre-exponential factor in the Asthenius equation has the dimension of time, T? 34. A catalyst (@ decreases the average kinetic energy of reacting molecules (b) decreases the activation energy (©) alters the reaction mechanism (@) increases the frequency of collisions of reacting species Passage Based Questions Passage Carbon-14 is used to determine the age of organic material. The procedure is based or the formation of “C by neutron capture in the upper atmosphere u Wien atc pt MC is absorbed by living organisms during photosynthesis. The ¥C content is constant in living organism once the plant or animal dies, the uptake of carbon dioxide by it ceases and the level of 'C in the dead being, falls due to the decay which C-I4 undergoes wVedantu, foi n+pt ‘The half-life period of “C is $770 yr. ‘The decay constant (4) can be calculated by 0.693 ‘using the following formula 4 = "6 An ‘The comparison of the f° activity of the dead matter with that of the carbon still in culation enables measurement of the period of the isolation of the material from the living cycle. The method however, ceases to be accurate over periods longer than 30,000 yr. The proportion of ¥C to 8C in living matter is 1: 107 35. Which of the following option is comrect? (a) In living organisms, circulation of ¥C_ from atmosphere is high so the carbon content is constant in organism (b) Carbon dating can be used to find out the age of earth crust and rocks (©) Radioactive absorption due to cosmic radiation is equal to the rate of radioactive decay, hence the carbons content remains constant in living organisms (@ Carbon dating cannot be used to determine concentration of “C in dead beings 36, What should be the age of fossil for meaningful determination of its age? @oyr (&) 6000 yr (©) 60,000 yr (@) It can be used to calculate any age 37. A nuclear explosion has taken place leading to increase in concentration of C™ in nearby areas. C™ concentration is C1 in nearby areas and C2 in areas far away. If the age of the fossil is determined to be Ti and Ta at the places respectively then (@ the age of fossil will increase at the place where explosion has taken place and 1, G 7-7, =n iB agine (b) the age of fossil will decrease at the place where explosion has taken place and non tind a (©) the age of fossil will be determined to be the same TG a 2G OF G 38. An organic compound undergoes first order decomposition. The time taken for its decomposition to 1/8 and 1/10 ofits initial concentration are tye and tino respectively. What is the value of fel 107 ony2=0 3) @7 @)s 9 (10 8Vedantu, 39. The concentration of Rin the reaction R > P was measured as a function of time and the following data is obtained: 075 0.05 040 0.12 0.10 0.18 [R] Gola) [10 T (min) 00 The order of the reaction is @o OR ©? @1s 40. For the given reaction, A+B > Products Following data are given Initial Initial Initial cone rate (a/L) | ql) [mLts"] [As] [Bo] o1 OL 0.05 02 OL ol o1 02 0.05 (@ waite the rate equation i) Calculate the rate constant @ka], 1s? (&) KA], 1.557 © kA], 057 @ kA], 0.57 41. “Cu (half-life = 12.8 h) decays by B emission (38%), B* emission (19%) and electron capture (43%). Write the decay products and calculate partial half-lives for each of the decay processes. (30h (b) 29h (©) 29.76 @ 28h 42. The rate of first order reaction is 0.04 mol Ls? at 10 min and 0.03 mol L's? at 20 min after initiation. Find the half-life of the reaction. (@ 20 min (b) 25 min (© 30 min (@ 35 min 43, A hydrogenation reaction is carried out at S00 K. Ifthe same reaction is carried out in the presence of a catalyst at the same rate, the temperature required is 400 K. Calculate the activation energy of the reaction if the catalyst lowers the activation barrier by 20 kJ mol (a) 10 kJ mol (b) 100 J mol ? (©) 100 ks mol (d) 1 kJ mol? 44, The rate constant for an isomerisation reaction, A» Bis 4.5 « 10° min. Ifthe initial concentration of Ais 1 M, calculate the rate of the reaction after Ih. (a) 3.42x 10? mol L? min? 0Vedantu, (b) 3.42 x 10° mol L? mir (©) 3.42 mol L? min? (@) 3.42 x 107 mol L? min? 45. One of the hazards of nuclear explosion is the generation of Sr° and its subsequent incorporation in bones. This nucleide has a halflife of 28.1 yr. Suppose one microgram was absorbed by anew-bom child, how much S:°° will remain in his bones after 20 ye (@)6x107g (b) 69x107g ()5.6x107g (@61x107gVedat, Chemical Kinetics Answer Key Tb ]2b |3d [4b [5d |Ge |7b |8e [9b |la la [a [ad [ise [se [ied [i7d [is d]i9a [204 Md [22a [23 [24a [2d [26d [27d [28 ]29.a [300 3La [32.6 [33a [34b [35 [366 [370 |38c [39a [40d ae [426 [ae [44a [45a For solutions, login to your Vedantu student dashboard a