I GATE - 1999 I u!

'M

It==:- CHEMICAL ENGINEERING

:.=::=====:=:J
SECTION A 3, 1,25
b I3
(75 Maltul)
c. 1,35
ONE MARKS QUESTIONS (1 - 35) d. I .2
For each of the followmg questions ( I IO 35 ), four Puru A in gQS phase ･ｾｵｲｳ＠ a reactor 5(\%

om
altemati"es - A. B, C and 0 arll pro1'ided. of Lhts A is con•ened to B Uuougl1 the
U1dicate the correct answer by writing A, B. C or tll{lction ａｾ＠ 3 B. Mole- fracnon of A .iu
0. ns npproprinte, !\£Dinst the corresponding the e.XLt streaQl iS
question number in the ｢ ｬ ｯ｣ｾ＠ 1n the ｾｴｓｉｈＺｲ＠ book.
1/2
(1,
I Marks : I ' 35 = 35)
b 1/3

.c
C, 1/4
The system of equations.
d. 1/5
2x + 4) e iO

ce
7 Which uf the folloWJII!l is true for Vtrinl
Sx + 10y = 25 equation of sUIto
n. bas no w1ique solullQn a. Vinal cocff:ictems are wnversal
b. has only one solution
ra COilS UlnLS
c. has only two solution:; b Virial coel'ficient B represents ｴｨｲｾ･＠
d. has mtuute solultons bod)' onteroctions
.2 , Four .fnir coins are tossed simulUlilcously c. V.r"11 coemcrents are funchons ol'
The probabi li\)' ｾｬ｡＠ nt least one head turns tempernturc only
m
up is d For some gases, Vi rial equations and
1L 1/ )6 ideal gas ｾｱｵ｡ｴｩ ｯ ｮｳ＠ are the s;une

b, ISf[(i 15. A g:rs mrxture of three componenLS ｴｾ＠

xa

c. 7/fl br·ought in c.ontact ｜ｾｬｨ＠ n dispcrston of an

organic phase in water. The degrees of
d. 1/R freedom or the system are
a. -1
.e

3. b. 3
'· 5
a. ll d, (i
w

b A pr.pe or I D 4 m is bifurcated mto Lwo

pipes of LD. 2 m each. If the m·erage
c. 2
w

velocity of warer nowwg through !he .main

d. 3 prpe IS 5 m/s. the average 1 elooi Ly through
T he hannonrcseries L-;;I
ｾ＠ the birurcared prpes 1s
w

rl JJ a 20 ruts
n. com'erges for p > 1 b. IiJ m/s
b. Jiv,;rges for p > I c, 5 ../2 m/s
c com•erges for r < l d 5 mls
d. ､ ｩ ｶ･ｲｧｾｳ＠ for p < I Ill, In centnfugal pumps. cantallon occurs
5 1\ solution of spec.fic gmvlly J.U consrS1s 1vben pressure of the impeller eye or vane
of 35% A by 11e1ght and the ceruaioing B becomes
1£ !he speci [tc gmvtt) of A is U7, !he Ｌｾ＠ Jess thnn nrmospheric pressure
specific gr:wtly ofB i> b. more tban liq·urd \'apour pressure
 c. ｬ ･ｾＤ＠ Otan IJquld vppour pre<sun: a. is oflow Yolntility
d. ono111 thlln ｾ ｴｭ ｯｳｰ ｢･ｲｬ ･＠ prcssuru b. ｦｯｴｭｾ＠ A low-bonln.g
uzco1rope
Lt. Fut IMlinnr l1o" thrOugh « pocked bed. c, forms • hiAh·boilioj!. l!Ztolrope
the prcssul'C dr9p 1$ proport.iona\ to (V, j, d. ｾ ｾ＠ nnl •11<:1' tbc t'Ciativt l'lllatility ur
the superficini Iｩｾ ｵｩ､＠ ｾ ､ ｯｾｩ ｴ Ｎｖ＠ :md Dv is thc- the original component!.
J>Ilrl ielc diameter)
18. The ｲｾｶ｣ｹ＠ of ponicillln from tb e
a.. V, /l)p' acidified fennent1>1ion broth is done hy
b, v/ D1,l 11; distil Iali on
C. \ ••, ' I'_.,I,J b. <:Vopomlion

om
d. \1 0 vD.' c. absorption
12. Por n tu<bin...agit.1t• d and ))all:led t.1nk:. d. liquid ･ｸ ｾ ﾷ ﾷ ･ ｾ ｯｮ＠
o perating at low Reynolds number Ｈ ｢ｾ ｳ･ ､＠
19. Pe:nclratioll tln:ury sla""' Utal the ｭ｡ ｓＭｾ＠
on m1pcll.:r dinm<rter). llw powe1· number tronsfer ｾＧｴｬ ｯｦｩ｣･ｮｬ＠ is equal lo (where D, is
(Np) ｶ ｯｲｩｾ＠ will1l'<R,. ｾｳ＠ diffu.,ivity and t is time)

.c
Ｚｾ＠ ｾＧｴ＠ \'l NJU • · (D,I)' ｾ＠
IJ. N, a ,fN._: b. Ｈｄｊ ｴ ｻｾ＠

ce
c N,- ><:ostanl .:. (-ID,I(nt)) U2
1
d. N0 11IINo. d. (4D.,Ill "

13. Gibbs pluts« rule finds oppli"ation whon 20. A n alka1inesolullon is reduce ｴｬ ｾＺ＠ used lo
heottr•nsfer occurs by
ra concentntion of cnrbon dioxide in o
3, oondnction
slrcaru !rom I 0° • In 0. H o by obsorption
wilh irTeversible chemical renclion. The
｢ ｾ＠ convec_tion ovem ll number of lmru;J'e.- units based on
C. J'>ldi3tiOli g.. phase is
m
d. c:andt:usntion •. 9,2 1
14. As the dill'w•enc:.: between Ute wall b. 4.605
tcmporoturc ond the bu"' tempcrnllll\l c. I()()
xa

ｬｯ｣ｲ･ＮＱ ｾ ･ｳ Ｎ＠ tha- boiling he.lt lrJmfi!r

d. 0.00 1
CA>eJiicicnl
2 1. (n.,rnll ordl!l' of reaction for which nle
a. continues IQ increnst:" conslanl ｨ｡ ｾ＠ units of(mol L) ｾ Ｎ｜ＧＥ ＠ ｾ･｣ Ｇ Ｑ＠ is
b. conli ouef\ to decrease
.e

•. - 3'2
c g<JCS throush ll minimum
b. 112
cl ｳ ｾ＠ thw ug h • maximum
c. 312
15. tn pipe llow. bc.1t ｾ＠ itonsf=od lrom hut
w

\1 all In the liquid by

d. 512
ｵ ｾ＠ condoctinn only
22 Forlhet'eactionA 1D _,.2B 1C.
ll, I"ａ ｾ＠ lb
w

b. forecd ｾＱ Ｐ｜ Ｇ ｃｾＺ ｴｩ ｯｮ＠ unly

e. .foJ'ced ｾＮＺｯ ｶ｣ ｴｩ ｯｵ＠ nud condut:t.iou b. rA = -1'fl
rl. fret: lind CmeeJ cOnyj:ctino "' r, ｾ＠ 2 l'fl
r,
w

16. tlcot IIant ler uccun; by nawrnl corwcetion d. = l'fl •2

becnuse chanJ!,C In U.'tl\l'trnmre Couse• 'I he .:xi1 uge dislribuli<m cun'e l;(fl) fvr :m
djfferCJ1ces in ｩ､ｾｵｬ＠ C'S'fR Willi I!Jt UVcr:tge residence
n, ｶ ｩ ｳｾｮ ｩｴ ｹ＠
lime'<. is g.lvcn by
b. density a. e"1'
ll. lltcmJill i!l>ndud i1i1y b. ( I t )e ｾ＠
c._ ｬ｟ｴＺ［ ｾ＠
d. heat ""pacily
l7 So lvent used in o.xttoulive distillati.oro d. 1- ( Ut)o·l/<
 3 ｵｻｾ＠
An ･ｮ､ｯｴｨｲｭｩｾ＠ second-order rea..:tion l> 30. HMtcUoy C is d .good m:rtwl ot'
l!lllrled out ln •n adi:tbatic plug flo\\ construction In cllamica l process industry
rcttetor. The rule nl'btalgcnerallon ｩｾ＠ sin.:e it is.
ｾ Ｎ＠ maximum althc inlet oflhc ｲ｣｡ｾ ｬ ｣ｯｲ＠ a. high ly ･ｯｲｴｾｩｮﾷｦｃｬｳ＠ ll'lld is
b, ｭ｡Ｎｾ ｩ ｭｵ＠ at thce;(fl oflhe reactot r<:-'ltlily tabticaled
"· mxximum at the ｾ･ｮｴｲ＠ or 1ｨ･ｲ｡ｾｴｯ＠ b. ｲ･ｬ｡ｴｩｶ Ａ ｾ＠ inc.xpcn•ive alllitl"!!h it con
IL c<Jnst3nl throughout the ｲｾ｣ｬｯ＠ l>t>fallcicotcd witl1 """c di.Jljc.ulty
c. corrosioo·rcsisl3nl lo rnosl nlkalis,
2 5. rbe LapL!co lran.Com> of ｾ ｰ Ｈ｡ｬＩ Ｌ＠ where n
pnrticu!ttrly because of ｩｴ ﾷ ｾ＠ ru CClnlent
ｾ＠ 0. is ｩｬ｣Ｚｦｮｾ､＠ rm ly Cor th.: !,•place

om
parnmolcr. S > ct. since d. ligltt ond re•i.,l'i ollaek by ucills
a. the function is e.wont:ni.Jnl 3]. [n a l1ca1 O.'lc)langcr, lloating hc·•d Is
b !he ｌｾｰｬｯ｣｡Ｍｴｲｮｳｦｭ＠ Integral af )lrovided to
ｾｮｴＩ＠ llliS finjte vnJu.,: only for s ｾ＠ a a. l1>Cililate clcMing o.f Ute cxch•ngcr
.:. ll1e ｌｮＱｬ｡ｾ･ＭｴｲｳｦＰｭ＠ Integral of b. increase Ute heat b'l>nst'e1- atCJ!

.c
""p(nt) hru! initial values onl) fou a .:. rdiew llr""'"' o:4U>Cd by lhQ'fllal
d. lh.: ·fimllllon exp(•ll is ｰｩ､ｬＮ･Ｍｷｾ＠ ｸｰ｡ｮｾｬｵ＠｣
continuous only- for s a d. .inuronsc U1u Jog moon lom>pCTllture

ce
26. A system "ilh a doubt.. pole ot lit'> origin gradient
is anstablo since the conusponding tcnn iu 32, Suc.nlS-C is a disaccharide ｣ｯ ｮｳ ｩｾｴ ｮｧ＠ or
the lime domain a. glucose md _glucose
n. ls a const-ant
ra b. glucose nnd fru<:lose
b.. grows- ･ｾＭＬ＾ｯｮｴｩＺ｡ｕｹ＠ with time. c. gluoose and ｾｯ｢､Ｎ･＠
c. grows linonrly wiU1 time d. fructose nnd gruactose
tl. aooay• lin.:nrly will\ tlmd 33. The organiil add monomer In :Nylon G6 tS
m
27. A ｾｩｮｵｳｯ､｡ ｬ＠ variation in d1.: inlnJt P""•irrg 11. $ebootc ac1d
through • linear firsl-order system b. terephtll"lllc ｾ｣ｩ､＠
a. b<lCOrnC.S moro Cllscillolor:y (frequcnc) C. •dipic 3CIIi
xa

incrooses)
d. bL'IlZnic acid
b. become.< less oscillatory ＨｩＧｮＺｱｵｾ｣ｲ＠
､･｣ｲ｡ｾｳ Ｉ＠
34. Which one of the lbllowing is noL lil!dy IIJ
be li con.<tituenl.ufvegetoble Oll!?
"· gaL< nmplificd (magnitude mcreases)
.e

:a. citric acid

d. gi>l• oUcnuatcd (magnitude decreases )
b. o!ejc •dd
28. A typical example of • physical system
t:. $I CUrie m:id
wrtll itnder·damped cllarncterislics is •
w

:t. IJ-tube m..1nometer d. glycerol

h, <prin&·loaded dil!plmlgp> v•lve 35. ·n,e gtt5 "hielt t\lntrihuk-s the ma).imtJm
'" tlte healing value or natural ga;, i•
w

.:. CSTR wiU1 .Gil!t-ord.:.1' "'ant ion

11- lhc:nnqc.ouple lttpt iruntol!'Scd in •
•. co
liq ui<l-filled U!ermowell l1. CO:
u,
w

29. ln tt manufacturing ｬｮ､ｵｾ ﾷｹＬ＠ bt'I:Jlk·el'i!!11 ｾ Ｎ＠

pOint occur. when d. (.'HI

;t. Lhe total annual ｲｾｴ｣＠ of prod11ctiOt1
equals llle •ssigned ' alue ie,',•l ,\f ＧＮｬＺﾣＱ ﾷＱ ｾ＠ $•[·1:: If{ t·!II
ll. Ihe tom I ｮｵｾｬ＠ product co&1 ･ｱｵｴｾｬｳｨ＠ Fat each of the lo llowin.!l qm:stions (36 to 52),
i<lbl ann\w I ＬＮ｝ｾ＠
four ｾｬ｣ＧｴｯｩｶＢ＠ - A. B. C 31ld D aro pmvitkd.
c.. the annual profit oquals the ｣ｾ･ｴ､＠ Indic.Jlto the corTCc( answer by writing A. R C or
value (). os appropriate. against the coiTilSpondinJI
d. Ihe llllnlllll Ｄ｡ｬｾ＠ cqUHlllhc ti:..ad C<l•Ls question num!}t:r In tho answer book. For
 J ura
questiont 53 to 55 two itclll!i are indicoled in the
lcl\-1\and column lind oil; items in !he righHmnd
column. Each item in the icll-htmcl c41umn It
closely ossoeiatod \Vith one of the· items in the
b. ( rW ' --( {!1"
righr-hnnd I.'Ohnnn. F'or ench. ＼ｴｵ･ｾｌｩｯｮ Ｌ＠ write the
nppmpriBte mnlch in t)le cQoTe.s-p<mding i)(IX in the
t,P t.., ili ...

ｃ ｾ ｴＮ＠ ］Ｈ Ｚｾ ＧＮ＠
11n.1wcrboo.k
!Marks: 2 20 = 401 c.

r:: t ,.lｾ＠ ｾ＠ ...

om
36. A box C4lnLiins S bnll•. 2 of whrch an: d.
defective. The pmbnbillry that none oflhe
boUs drown aJ'e doooCiive when lwo ore .jf. Velocity ofn ｾ ｭｯｬ＠ p:lrtlclc Qfdiornch.1' Dp
drBwn nt random without rq>lat.:c:ment is at " Ｑ ｬ ｩｾｴｊ ｭ ｣ｾ＠ r lrum lhe rotation• I axis of"
cyclone rotntlng nl • n •l\!luL1r Apeed co i<
"· 15f2S
civeu b)' (tJte 0 tl1er ｓｾ ＾ｊｉ＠ bois are OS peo

.c
b. 9116
stand:trd ｮｯｬｾｴＮｩ Ｉ＠
1:. 7116
d. lJS a, (D,p,-p)lllr
ｉｾ＠

ce
37. f'hc ｴｩ ｲｮｾｩ｣Ｚｬ＠ 01" S),l + yz-l at lhg point (- I'
t.l, t) is
b ( l)'cP,- p)filr'
n. 3i- Jj+3k 18 Jl
ll. 3i-3j+6k
"· P.- p)nhJ.
ra c. 4o-:i- 3k
d 4i- ;\j+6k
ｲ ｄ 18ｾ＠ ,,
S<l1urnted ｾｯｬｵｴｩｧｮ＠ ol' benz""e in wnler is ln
d. [ ｄ Ｇｾ＠ ｬ ｾｨ ﾷ＠
:"8.
m
equtltboium "ltlr A mixuore <>I' alr and f/,- Jl
ｉｾ＠ fL
""JIOUI'll Of benzene and Woter ul tOCliO
tcmllCtllture bOd ｊ ｬ＼ｃｳｾ］Ｍ Mole frntlion of -12. \Vater is Oowing :ll l ｭ Ｏｾ＠ tJtrougll a ｰ ｩ ｰ ｾ＠
ben1..ene tn liquid is 'Xn nnd the v•p11ur
xa

(cJf 10 em J.D.) "itl\ o right angle bend.

pre:<sures ol' hen.letH' and water at thc:.c The l'o l'l!c in ｎ ･ｷｴｯｮｾ＠ e:<ertoo C'1l the ｾｃｩｬ､＠
.:onclitions oro p,8 41\d 1>.w ｲｾｰｃｌＱ ｬ ｩｶ｣Ｚｾ Ｇ ﾷ＠ by the wat·cr ｩ ｾ＠
Ute ｰ｡ｲｴｾＡ＠ pressor" of b<;nzone in a1r-
vopour mL'(tU['C is
•. 10../2#
.e

;t, P•n b. S1r 2

b. sup. 9 c. s..fir.
>l, (p- - Pv"') 11]1 d. 511 ..fi
w

d. l!<np..,.. .IS, Rllte of heallrnrtsf<l Uttuugh a Jlipe ｷｾｬ＠ is

ｾＹ Ｎ＠ For lht ｲ＼ｎｴｮｩ｢ｬｾ＠ ｲｴＺｾ｣ ｴ ｩ＼ ｬ ｮ＠ A [] 28. iflht given by
w

ｴＺ＼ｾｕｩｬ｢ｮｵｭ＠ ｃＴｬ ｮ Ｎ ＬｾＱ ｮｴ＠ K is 0.05 moUnt, liJrk[T, - / 0 )

ｉｮ Ｈ ｾ Ｉ＠
ｾ ｕｴ､ ｩ ｮ Ｌｧ＠ frmn initially "2 moles of A and
zero mnles of B. how mnny moleo will nt: q
w

fmmed •t "''uilihrium7
.1 ＨＱ ＬＲＵｾ＠ f'Qr cylindim< tJf very thin wall. q C:tll be
h. (J 338 approximnll!d by
c. O.IS2 " " llrkJJ ｾ ＱｾＩ＠ 2]
<L 0.637 u. , )
ｉｮ ｾ＠
-10. Mnxwtlrs oolatiu11 cur...,.puudiug tu the ｾ＠
td<mtity.dU - TtlS I '\'dP ＾ ｾ ｦＡｊ､ｮｴ＠ ill-
2nr,k(T 1;.)
b. 'J - _,._,.__,...,'"-
(r,, - r )
 sura
2nf<(T - T0 ) b. 0,6
IJ -
>).
(r.,-r, ) e. o.s
d, 0,2
•L 2irk (T To) -18. For the liquid pbll!IU ｴＺｲｯＨｦ ､ ｾ＠ ｩｲ･ｶｾ ｳ ｩ｢ｬｴ＠
• '1 -Jr,+r,)/2]
l'll>cllon A > B, tho. corove,..ioo of A in •
44. For a coumer-cm-r.:nt ltJ:OL cKalt:tngcr wiU1 C'STR ｩｾ＠ lilund 111 be 11.3 Ill " "I'"""
T'to= 80 C. T•, = 60 C, ｔ
=50 C, and T 1, ﾷｾ＠ 1eiO<;ity of 0.1 min 1 Whnt will be the
= )0 r. and Inc tempermure ditlero1ee convcrston (or • f'FR with • space velocity
betweeu Ule IWO >lt'tmms being u.e S3111C ot0.2 mrn- 1 1 j\s•ume llint tb<l alllhe other

om
･｜ Ｇ ＰＱＧＩ｜｢ｾｲ｣＠ •long z, the direction of flo" opcpting condJtion• are the s:nne tor
cof the hC)t lluid, the temperature prolile CSTR and PFR.
ｾ Ｑ｜ｯｵｬ､＠ satisl) ;1. 0. 15
J'T " I'l b. u.:;
II. l
<I: c. (),(j

.c
J'i d. 0.9
b. - ,=II -19. Consider the oU1 O)rdcr io'C\'Ct'Sible liquid
(/z_
phose: rc•ction A- • B. Which one uf the

ce
c.
'''<1:"r • 0 f<JIIIJWing. pl<m mvolving ｨｮｬｦ Ｍｬ ｩｦｾ＠ nf the
t>:aetiun (tn.l oud the ｩｮｴｾ ｬ＠ J'dlclanl
d. i/T - () ｣ｯｮ･ｴｲ ｴ ｩ ｾ ｮ＠ Ｈｃ ＮｾｯＩ＠ givCII • str•isht Llno
ra <I: plot•
-IS, \Vall• of' a oubical oven an: ul' UJicknesa L C,..,. v.-.. lt;:t
and tbuv Ｇｾ＠ ｴｕｊｾ､･＠ of moteriol of tbeo·wol
couducti,.·iLy,. k. The lcmpcwature _i:nside the
-· lu C11o
ｾＮ＠
e, CAn"'· In t 1r.t
ｶ ｾ＠ ｉ ｴ ｾ＠

oven os I 0() C and the inside heal l:rof\Sfer

c.,., vs. In
m
d. In t 112
'
C.Qt:j]j etent '
Hi T:'ill _If u1e
1 ' W3 I"u lt:m{'trnl.ure 50. At a gt''"" va lue or E/R (J'lltio ..,r octivat.ion
enc'f8Y nod ｧｯＺｾ＠ constant). Ute t11t.io llr the
un the ｯｷｴｾｩ､ ･＠ is= held At 1S C. what ;.,. the
xa

rote oonstrutts M 500 K ond 400 K is 2 if

inside wuU l<!mp<:rature iu degn:Cl, C'l Arrhenill$ Ia\\ m used. WhAt 1-tll 1>¢ this
n. 355 mtitl il' trnn5itllln·siatc Ulouo-y ｩｾ＠ Ulled with
b. 43.7S Ｑ ｾ＠ snme VAlue of EIR!l

c. 8l.25 a Lli
.e

d. 48.2S b. 2
46. lf the $pecitic heal$ of :1 gas and o v•pour \:, 2.24
nre 0.2 ｾＮｬｩ ｫｊＡ＠ K •nd I.S kJ kg K d. u
w

re-spectively, 1111d the ltutnirul\' is 0.01. the S I. A C<mtrol ｙｾｴ･ｭ＠ hlL\ Ihe followins
lmrniil heal. in k.l/1..1! K is lransler runcltun,
w

l l , 0.31 a. I
b. 0.1Ci7 b. liS
1!. 0.017 c. 7/R
w

tL 0.215 d. • l
tbe Vapour pressw-es of l>enzene und Which of tl1e ｾｹＡ＼ ｴ｣ｭ＠ ｬｾ＾ｖＱｊＸ ｴ ｬｊ･＠ followinll
wlucnu aJ'<> 3 and Ｎ｜ Ｑ ｾ＠ alluu;phcre; lTan5fer filnctlons ｩ ｾ＠ .!<it3ble'l
rc:sp<...:tively. A liquid Iced of tlA mules of
bc'117.eni: ;md t),6 molll'l nf ｴｯｬｵ･ｮｾ＠ ;, 1
a.
vaiJ')rit.ed. Ｎ ＢＭｾｳｵｭｩｮ＠ th•t tile pl'(>dlli!ts ｾｲＢ＠ 72
in olquilibtium, the vfipout ｴｬｨｾＡ･＠ mole I
lhlction of bcn7.<.>ne ;, b. 1
s - 2.; + 3
"' ｯ Ｎ ｾ＠
 6 ufR
SECTION.
flwe Merb a-t.._ (II A 71
cxp(- 20.r) A.uJ\\'et tlfJ) ｊｖｾＮｴ ｴ＠ qot'bl.'ltle
d.
•'.,- 2, - 1 (1\·latl.,s: .5 1.5 - 751
53 Euch item gJven in the lefl-hlllld rolumn Is I
closely ajsi>Cifilt:li \ 1ith a specific ｾＨｩ Ｎ＠ l::vnluate J( 4K' -t .1').1.>· hy ltupezold•l
｣ ｨｮｲ｣ｴ＼ｾｩ
ｾ ｬｵｭｮ
Ｌ ｴｩ ｣＠ listotl in the ｲｩｊｾｨ
Ｎ＠ t.latch <!.'lch of'lhe ｩｴ･ｭ ｾ＠ Ｑｌｨ
ｬﾷｨｵｮ､＠
the
'
t'Ulc, Usc ｾ＠ J!tap •ize of 0.2. Ohlll iJ1 lite
UIJrfC$ponding ｣ ｨ｡ｲｊｴｬ｣ｩ ｾ ｴ ｬ｣Ｎ＠ error b{>nnds for this solution. ('ampule the

om
ahsohth>error of the nnmeric.1l solution hy
(\\'rile hoth aJts\\c:rs in 13nx Nn. .53)
evolualing the integral analyll.u>ll) .
A. 'l'rlnl>'J)IIrl:ni<ln htl!
tA·
I;! Control vnlve S7. Solve tb; - 6XJ•=-6x by the following
J. lnc1'ease in gam mar_gin metb<xls:
2, Phose l.ag i< proportional to fiujUC!lCY

.c
a. vnrintjon of L>i'lrnmeten
3, H)l"'rbofic b. ｾ･ｰ｡ｲｮ ｴ ｩｯｮ＠ of'\13riah les
ｾ Ｎ＠ Unslllblc rospon>c 58.

ce
5. ｬ ｵｏｊ｜ＡＳＵｾ＠ in pbaso murgin a, AI what. poinls are Ihe Cauclty·Rciman
G. ｐ｢｡ｾ･＠ ｧ ｡ｮ ｬ ｾ＠ ｩｾ＠ - 90• eq\lations satislied ror lhe fnuellon,
S4. Each of Ute methods given in the left-band F(z) xj -t i x."y 1 Whetc> i• f.(z)
column i! closely Jink"d to one> of thd
ra analytic?
items listed tn tltc right-hand column b. Compute lbc distinct cube rool5 nf
Match e.1ch method witl1 the (H).
corresponding item. 59. II is proposed to produce occt.llch::hydo by
l Write both ｡ｮ ｳｷ･ｾ＠ ul ｈｯ ｾ＠ No. 541 o;odation of ethanol m gas ph:tSe
m
A, Discounted ca•h !low C,fl, OH (g) ' 112 O:(g) - > Cl·hGIO (g) •
B. ｄｾｬｮ ｩｮ ｧ＠ balance H:zO (g)
'The ratiO of atr to elbnool in d1e fl-esh tbed
xa

I. Depred ation
2. Jluyout poriod (before it i.s mt,ed with r.:cycle stn:•m) i>
10 to !. The ｣ｾ＾ｮｶ･ｲＺｳｩｯｵ＠ Qf ｾｴｨ ｮ ｯ ｬ＠ oo •
3. l'rolit.1bitity ann lysis
single pa!s through the rc•.ctor is 25'1., l11c
-t ｓｯ ｬ ｶｬｩＡｾ＠ \loluc unrcactcd ethanol is completel) separated
.e

.5. Annuilv fi'om the TCI\Ciion products and rooycled.

(i. WClr-king ｃｊｾ ｲｬＮ｡＠ \Vital i• U1e talitl of rccy,lc stream Ill the
55. l'vlntch each rol)•mer mentioned in the left- fresh 1<.-ed ｾ ｴ ｲ･ ｭｵ ＿＠ \Vhnt i• the
w

hand ｾＱ Ｑｵｲｮ＠ wi01 Ute corrc:spouding camposititm of the QU[Iel >1re:tm. lh>m th<:-
cbc"llllenl nature listt d ln the ｲｩＡｦｬｾｨｵ ｬ＠
n:ctor in mass fr.tct·inn nnd n111fc l'rncti&?n'l
column. 60. ("nCO., ,• lurry has In be dried. l11c drier ｩ ｾ＠
w

(Write both ａｮｳｷｾ＠ in Box Ko. jS) dc•igoed l<1 l'llJilQVe 100 k& mot>litre fl<r
hour, r\ir •I 20 C ｾｴｮ､＠ 40°o refalivc:
A. Pcrs,>c:>< humidity. enters the dncr and leaves nt 65
w

B. Rnyon •c nnd 65°o rolative humidity. Whal ts Ihe

I. Pol Ｉ Ｇ ａｏｾ｣ｨ｡ｲｴ､･＠ weight rin kg) of bon.c-dty nir rcquU'ed per
L P•llyamtdc hour? Th<> ntrurnophcric pras.utt i• 103
kP:a. If the} humtdity <tfthe ntr entering the
:;. P<llyllt.'fylatc
drier c.nn bt: V:lried, whal i" t.bt: minimum
.t. Pol)ester amount of llry •ir r<:quired2 The Ｍｯｍ［ ｴＮｬｮ ｾ＠
5. Polyether for Antoine e<Juotion for vqpour pressure.
6. Pol)'lllefin of wnter Iii mni Hg may be taken ns A =
IVOii. B - 3816.#. ｾｮ ｵ＠ <: ｾ ＭＴＶ Ｎ Ｑ ｊ Ｎ＠
 "I ｴｩ ｬ ｾ＠
61 For Ute binary ｾｹｳｴ･ｭ＠ methanol (I ) and
J)cu:tcnc (2). the fC<!OlllffiOOdcJ VaiUilS ol
the Wil90n pu.mwelers ul 68 C ur" A1: =
0. L7.5 1 rmd ａｾｴ＠ - 0.3456. The vupour
T
press"'" of pur" spedos ut68 Cure Pt.. -
68.75 kl'a und P:i"' ｾ＠ 11.5.89 kPil ShQ\1
ｾ ｴ ｡ｬ＠ tho given ｳＺｹｾＱ｣ ｴ ｮ＠ cHill lorm ,UJ
ll't<!otrupe a1 68 C. ａｾｵｭＢ＠ thuJ Ute VIIJli>Ur
ll.::ltavcs liko au itle:Jl!!,U.S..
62. FI0\1 I'Ule or ｉＧｕｬｾｲ＠ llowin!l ｴ ｬｵｴ＾ｾｨ＠ a f'lJl"

om
65. Obuun expn:ssiuus [or ｓ｢＾ｵ､ｹﾷｳｴ｡ｾ＠
is being UIC'.JSUI\:d by usina an uriticu
toUlJ>Crulure prolilo nut! beat tmusfcr mte
ruer•r ｴｌｾ＠ sl•m u in the Gollowllig figur•
for u hollow spbencul contnhter. ｩｷｴｾ＠ ·n,_,
SU$[Oce (nt r = r,} is maintained ut T ｾ＠ T,.
and the outer Sllrlllce (at r - r,,) is
muiutained ut T - ＧＱ ｾＮ＠

.c
(,(, , 150 kg of wolcr is lo be heated in n slcom·
ｊＳｃｉＮ･ｴｾ､＠ v-ossel (r('lm 2.5 C IC> 80 C. St.:auo
ts ooutlcJU;ing ut 110 C. and the heal

ce
transfer urea ts 0.15 nl! Ｇ ｬＧｯｾ＠ h"11l trnusfer
coetlicio>nls lbr ｣ｾｵ､･ｳ｡ｴｩｯ＠ {•f steam and

a.
raWhat ts l.bc ､ ｾｲ ･｣､ｯｮ＠ ol' lluw rn tho
.
heating of wmer bv - couvecuon
Wim· C sud 500 W!nt· C ｲ ｾｳｰ･｣
, arc I00(1
ｴ ｷ･ｬｶ＠
pi l"''t ｗｲｩ ｴ ｾ＠ appropn:nc uusteadv balun<:<:
b. Dcm e an expression tbr vcloolh' C<JUilttuns 11nd liud the tlme ｾ＾Ｚｱｷｲ･､＠ for
thruugh tho c•ritic<:, ｬＺＮＭｴｾｮｩ｣･＠ n..;v ile:JUD& ｴｨｾ＠ ｗｾｴ､ｦ＠ AssWUd tllol. tll< Sfi"O[UO
rnt.o ll'r ou urdice cncl'ticicnt nJ' 0.8. hem Of Water iu tho ｩｕｾｭｪｬ＼Ｚｴ ｉＺ＠ rannc of
m
()J Don\'..: nn cxprossmn to obtam the ._.lfiU
ｩｯＱｲｾｳｴ＠ is4:18 ｾ＠ 10; Hg C. -
required IO op1pl) the \'O!!Scl con taining 67 Slnpping of ＱｬＰｩ＾ｌｾ＠ is curriod oul at a
1\'atcr as sb•"'ll In thG ｦｯｬ ｬ ｾＢｩｵｧ＠ Jigure. ｰｲｵｳｾＧ＼＾＠ o( 1.1 alms. One ml of water
xa

'J'hc cmss S<>clionol urea of tho opening at enl<l.:S U1e system aud the ratio of Ute molar
tho hu11ouo nf Ute tullk ｩ ｾ＠ u. As!nuuo that I lot ilow ｲｾ＠ uf nir -and tlllrt OJ' tho II OtU ｾ ｾ＠ 4.
< II The mlet air and Ute inlet ｷｮｴｾｲ＠ ho1•e 0. l
and ! .(1 mnlo porcu,Jt of uruo11nuu
ｎｾｐＢ｣ｴｩｶ ｬ Ｉ Ｌ＠ Th.o Mu'l'hl'te vapour pluta
T
.e

elliciency for nmmonia remtwnl ｾ＠ 50" b

at!d the HcntiS 1011 con.llimt fur mtlm(nnu
H in ｷｮｴｾｲ＠ is '2,574 -< I0 atm m3 mnl,
w

1 68.
dctemtine tltc exi t wut>t CQm[lO$i lion nnd
the exit ｮｾｲ＠ composition.
ｄｾｴ｣ｲｭｬ ｮ ｡ｴｩｬｮ＠ of c flicicnc, is omucnl in
w

plolo column design. llta -gns nod liqlllcl

rntcs arc 0 I and 11.25 kmol!s ｲｬｳｰＺｾ ｴ ｩｶ･ｬｹ Ｎ＠
6<1 ui JQfviscostrv 100 cT' IS to be pumped ns The tntcrtiwinl nnw for miL« trons.tcr is 35
w

shmvn in the Jollo\vtng figure. ·n te P'Jl" Dl-'nr ' ·ltlluJ· ·· on Ihe pl utc. Tuc t.. restdoncc
'
u:<cd cl'ery whcr., •• ol" 7 em J.D. If tho
tnl1u of both the liquid and gas in the fmth
ｯｦｇ｣ｩｾｉｃＩＧ＠ uf IIJe fttiiJIJl is 80 ''%, lind the 1.onc is 3scoonds, The liquid phose and gn.•
CJtcrsy n:qUtred for pumping. lite oil ni 20
f'h:JS(l ｭ｡ｳ ｾ＠ transfer ｾｵﾢｴｬｩ｣ｮｳ＠ are I <
uo1'hr. ｯｾｮｳｩｴｹ＠ t>l1he oil Is 800 kgnn3
10- 2 ｭ ｬ ｾ＠ und 2 ' -l (r' ｭ ｾ＠Ａ Ｂｾｐ｣ｬｩｶ･ｹ Ｎ＠
Culculuw
u, Uquid phMe ｬｕｮｳｦｾｲ＠ unitS
b. ]tiS phuse lnUlsf.n unit>
 ｾｉｬ＠ ｾ＠
c. ｦｯｾｴｲ ｾｴｲｩｰｮｧ＠ Ｎ ｬＡ ＢｯＺｮ＠ lh•tthe ｾｬｯｰ･＠ of control loop are ｮ･ｳｬｩｧ｢ｾ＠ ond dteir
the "'JUilibrlum ｾｵｲｶ｣＠
'' S ｳｴｾ､ｹＭ＼ＱＮ｜｣＠ BaiM are all equal I(! ｴｭｩｾＮ＠
d . owrull tnm•fer uniiS !!hOI• that
e Mlll'JlhNC point ･ｴｬｩｵｾﾷｮ｣Ｉ＠ a. the ｲ｣＾ｾｰｯｮｳ＠ of the c(>ntntllcJ pn..:c"
i• f>stcr U••n that uf Uoe tmconholled
69 T\\IJ purollcl lirat·ordcr reactions A • B
pmteS3, ond
and .\ (" orc t•kmg ｰｊＮＬｾ｣＠ In liiJUid pha•e
b. the n1T1ct, both JC,r cb•ugcti on the •ct
m a '' tll-m L'ed bat.:h re1ctor \Jlcr 60
mm uf opcr:IIK>n. RO •o of 1\ h•• rca.:tcd pninr ond in rhe ltl><i l'>riahle,
､｣Ｚ･ｲ｡ｾ＠ as tile P"l"ilmet.:r uf the
O\\ bile 2 1nolcs of 8 pu n1olo of C "••

om
d<tc:ctcd 1n the ］ｾｴｯｲ＠ C:okuhltc the rote ｾＰＱｴｮｬＮ｣ｲ＠ is incrca.cd..
.:on.toots k, ond k, f"" the '" 0 reoctillnJ 7J.. 1\ s'-"'nd-<ll'dcr ｰｾ＠ "1th the ll':ln<fcr
,illume dt•t no B lllld C "ere intldll) 1\mction
ｰｮＺｳ｣ｴｵｨｾ＠ I'I:.>Ctot .
70. Au isothermal plug Oo\\ ....,ctor io
KG
T ｾ＠ ,)'-2s - 3
dcsignod to sh-.:: ｾＰ＠ •. com=ion of.\ for

.c
Is eootroll.:d "lth a pmpcmonol·ullegnl
a sccond-onlcr hq111d pho•c rcocllon A • contrnUor. if ill the other lags in ｴｨｾ＠
B. Pure A at .:onccntration I l;mol;m1 is control loop :ttc ncgli!l'blo •nd Urcir
ted to th reactor ot o Oow rotc of S m1 hr ste;,dy-nate g•in• are •II equ•l to unil) ,

ce
fhc rotc conJilont for the rcoctoon ｾ＠ • find the rciJtiou bet\Veetl tliC pam meta'S of
•poctliod ｯｰ｣ｴＺｾ ｵｮ ｳ＠ tcmpCI'llturc os 0.3 tltc conlroUcr. that •bould be sJfi..fied for
m ｾｭ ｯｬ＠ h \\1ten the reactor " !1Cil,.11)
1
the control sys1om to b •bblc.
operotcd ｢ｾＮ＾･､＠ on th-" dotugn. it ｷｵｾ＠ found
ＷｾＮ＠ A new cquiJllDcnl m•dc of uutcriol A
ra tbot 30 "• of ｬＱｾ＠ utitiot re.1ct"r 11\:h.-ed ••
o Ｑ｜ｯｬﾷｭｾ･､＠ reactOr while ｕＱｾ＠ remaining
co<ts, po•t in<t• llation. k.• 3 lokhs o.nd ls
expc.::ted to have a scup volue of lll"o of
l!ehavcd as a plug llow ｲ･｡ｾｴｬ＠ C'alculatc Ulis cost at Ute ｾｮ ､＠ of a U!cful life of I 0
the cumt.'1'Kivu ()bCflint.:d in ｾ ｵ ｾＮＺ ｈ＠ a ｲ｣［ＬｾｉＮｏ Ｎ＠
m
ｹ･ｯｴｾＮ＠ Simibr oquiprncnt made of maluriol
71 F11r an c;wthunlllc rca<:hon A • U, !>0 H ｣ｲｮｾｴｳ＠ Rs. 1.5 l•kh<. but i• likely to hn\'1!
lonol of U oo·o to be: pt•oduccd ｷｨｾ＠ no Nl!mp value, ａＵｾｵｭ･＠ !lUll both lypCll uf
ｯｾｨｬ｣ｶｩｮｧ＠ or
90 "• conwr•ion 1\ rn ｾ＠ Ute equipment coulU b<' replaced nt a CONL
xa

IS<Jihermnl bnl..:h rca..:tllr operated AI 300 1\ thol is 20 "'• more thon the original v• luo.
'l'he ｲ｣［ｯｾｴｵｮ＠ h li1 l!c ｾｴｵｮ･ ､＠ "ith pure A at On the basi• of equal capitollzod C<J•b thr
tbc cllncc:utralll/!1 ol' J() i.IUOJ/ml bollt typCJ of the equipment. cstimnt.: whot
Ddcnninc tho \'Oiumc nf the reodnr, !llwuld. be the u.•eful life for equipment
dur:llion of tho: ｢｡ｴｾｨ＠
.e

upcrounn ond the: modo of motc:riol B. The compan) hn• tu

totol lldl rerno1•cd during lite ｾｯｴｨ･ｭｬ＠ ｰｾＩ＠ •n onnuol int.:n::<l on the in\C'I!menl at
opcrotion. ll1c heal of the I'Cllotion at SOO • rule of 15 •,.,
K Ill - 40 ｾｊ＠ mol of A ｲｾ｣ｴ､＠ Follull inl! 75. thethcmll:lll n:.ctitm
w

Write nlcnll
additional infonnohon L< 0\'aobble to Ｈｳｴｯｩｾｨｭ｣ｲｫｊｬｹ＠ l>olooccd) ror \be
､ｾｴＺｉＧｄｩｮ＠ the: onlcr and r•lc conlit4nl of
manufacture of each of the ｦｯｴｬ＼ｾ＠ tn8
the n:•c:tion Laboro\(>0 ＼ＡＮｾｰＺｩｮｬｊ＠
chetnic31s
w

""nduclcd •t Stl() 1- with I. kmol m1 UliUal

ｃｏｮ｣ｴｾｬＧＺｩｯ＠ of pure A \hO\\ .:d lhot lO"o •· 'm}iacetalc from ethylene
wd\ co11.1o i. ｯ｢ｬｵＱｾ､＠ in 20 milL "hllc b llTC3 from ammoni:t
w

500o corwmiun " ot-U.incd ｩｮｾ＠ mon llu: .:. <fl "'"c Jiom ｴｨｾ＠ I ｾ･ｮ＠
I'C.1CIIOII " '"-'p<:<:ICd IO l!c C:llht:t lir<l 01' d. caustk soda from brine
Sec<JOO 1)1\ICI
c. tripk ｾｵｰ･ｲ＠ phtlSpbatc from r'""'(lllate
72 A pmponionol .:onuollcr " us.:d fo. the rod..
couttOI of • f111Hmlcr i\'11'""· If the
dynllllucs of >II tltc nu..:r' un1t. in tho