Professional Documents
Culture Documents
Class Xii Sample Paper Chemistry Set-Ii PDF
Class Xii Sample Paper Chemistry Set-Ii PDF
Class Xii Sample Paper Chemistry Set-Ii PDF
SEC-A
1. Write IUPAC name of the following:
(a) Nylon 6, 6
(b) Nylon 2–nylon 6
(c) Melamine polymer
(d) Nylon-6
(A) Both assertion and reason are correct statements, and reason is the correct explanation of
theassertion.
(B) Both assertion and reason are correct statements, but reason is not the correct explanation
of theassertion.
(C) Assertion is correct, but reason is wrongstatement.
(D) Assertion is wrong, but reason is correct statement.
16. Assertion : Copper sulphate can be stored in zinc vessel.
Reason : Zinc is less reactive than copper.
17. Assertion : All naturally occurring α-amino acids except glycine are optically active.
Reason : Most naturally occurring amino acids have L-configuration.
18. Assertion : Network polymers are thermosetting.
Reason : Network polymers have high molecular mass.
19. Assertion : SF6 cannot be hydrolysed but SF4 can be.
Reason : Six F atoms in SF6 prevent the attack of H2O on sulphur atom of SF6.
20. Assertion : KCN reacts with methyl chloride to give methyl isocyanide
Reason : CN– is an ambident nucleophile.
SEC-B
21. State Raoult’s Law for a solution containing volatile components. How does Raoult’s law
become a special case of Henry’s Law?
22. Write the hybridization type and magnetic behaviour of the complex [Ni(CN)4]2–. (Atomic
number of Ni = 28)
23. Draw the structure and predict the shape of
(a) XeO3 and
(b) BrF3
24. Write the chemical reaction which takes place in the following:
(a) Van Arkel method for refining zirconium
(b) Mond’s process for refining ofNickel
25. Write chemical equations to illustrate the following name bearing reaction:
(a) Finkelstein reaction
(b) Gatterman reaction
26. Show that for a first order reaction, the time required for half the change (half-life period) is
independent of initial concentration.
27. Complete the following reactions and give the names of major products:
SEC-C
28. Define the following terms:
(a) Azeotropes
(b)Osmotic pressure
(c) Colligative properties
OR
A solution of glycerol (C3H8O3) in water was prepared by dissolving some glycerol in 500 g
of water. This solution has a boiling point of 100.42 °C. What mass of glycerol was dissolved
to make this solution? (Kb for water = 0.512 K kg mol–1)
30. (a) What are the two types of emulsions and how do they differ from one another? Give one
example of each.
(b) Which one of the following electrolytes is most effective for the coagulation of Fe(OH)3
sol and why?
NaCl, Na2SO4, Na3PO4
OR
Define the following terms:
(a) Peptisation
(b) electrophoresis
(c) colloidion
31. Give mechanism of preparation of alcohols from alkenes (Acid catalysed hydration).
OR
Explain the following behaviours:
(a)Alcohols are more soluble in water than the hydrocarbons of comparable
molecular masses.
(b)Ortho-nitro phenol is more acidic than ortho-methoxy phenol.
(c)Cumene is a better starting material for the preparation of phenol.
32. The rate constant for first order reaction is 120m-1. How much time will it take to reduce the
concentration of the reaction to 80% of its initial value?
OR
For the reaction
2NO(g) + Cl2(g) → 2NOCl(g),
the following data were collected. All the measurements were taken at 263 K:
37. (a) Illustrate the following reactions giving suitable example in each case:
(i) Ammonolysis
(ii) Coupling reaction
(iii) Acetylation of amines
(b) Describe Hinsberg method for the identification of primary, secondary and tertiary
amines. Also write the chemical equations of the reactions involved.
OR
(a) Illustrate the following reactions giving suitable example in each case:
(i) Hoffmann's Bromamide degradation reaction,
(ii) Diazotization
(iii) Gabriel phthalimide synthesis.
(b) Distinguish between the following pairs of compounds:
(i) Aniline and N-methyl aniline
(ii) (CH3)2 NH and (CH2)3N.