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41.1 What is a heat pump? 41/3
41.2.1.3 Water-to-air
In a water-to-air heat pump heat is transferred from a
water circuit to heat an air stream. This can be viewed as
heating the air stream or alternatively, if the air is ambient,
as cooling the water circuit.
41.2.1.4 Water-to-water
In a water-to-water heat pump energy is transferred from
one water circuit to another at a higher temperature. This
gives the heat pump an advantage over a passive heat Figure 41.1 Small heat pump
41.4 Thermodynamic cycles
41.4.1 Mechanical vapour compression
cycle
The majority of heat pumps use the vapour compression
cycle, exactly the same as used in refrigeration. See
Figure 41.2.
In this type of cycle a mechanical compressor provides
the energy input into the cycle. The working fluid is
Pressure
termed the refrigerant. There are four stages to the cycle
(refer to Figures 41.2 and 41.3):-
1. Heat is absorbed from the energy source into the
evaporator. In the evaporator the refrigerant changes
from a liquid to a gas at a constant pressure. The
refrigerant is vaporized or evaporated.
2. The compressor raises the pressure and temperature
of the refrigerant. The refrigerant goes from being a
saturated gas/vapour to a super-heated vapour.
3. The heat absorbed by the refrigerant and the energy Enthalpy
added by the compressor is released from the cycle as
the refrigerant passes through the condenser. In the Figure 41.3 Pressure Enthalpy diagram of a vapour compression
condenser as energy is rejected to the heat sink at cycle
constant pressure the refrigerant changes from a super-
heated vapour back to a liquid. The gas condenses. However, practical considerations often limit their use to
4. The high pressure, high temperature liquid passes larger applications.
through an expansion device, either a valve or a capil-
lary. The pressure of the refrigerant is reduced back to 41.4. Ll Refrigerants
the lower evaporating pressure. The temperature of the
refrigerant also reduces during the expansion process. The most commonly used types of refrigerants are fluo-
The refrigerant is now a mixture of liquid and vapour rinated hydrocarbon compounds. These are either hydro-
as it passes back into the evaporator. chlorofluorocarbons (HCFCs) such as R22 or hydrofluo-
rocarbons (HFCs) such as R407c, R134a or R410a.
It is common for the cycle to be reversed so that Hydrocarbons Butane and Propane are finding use in
cooling becomes the priority, rather than the primary aim small appliances such as domestic dehumidifiers where
of heating. their flammability is not a major concern due to the low
There are many types of compressor used in this type of quantities used. Ammonia has traditionally been used in
cycle, e.g. reciprocating, screw, rotary, vane, centrifugal, large commercial and industrial applications, and systems
swing or scroll. They are usually driven by an electric using carbon dioxide are under development.
motor.
The use of compression devices driven by other forms 41.4.1.2 Legislation
of energy is possible. The most common alternatives are
the use of prime mover such as gas or diesel engines. Legislation on ozone depletion and global warming has
forced the refrigeration industry to develop equipment to
use alternative and new refrigerants.
High pressure side The production of old CFC refrigerants, such as R12,
has now been banned due to its effect on the ozone layer.
Condenser It has an ozone depletion factor (ODF) of 1. The use
of R12 for maintenance has been banned from 1 January
2001.
Although the production of HCFC R22 with an ODF
Jixpansion_ of 0.1 is not due to be phased out until 2009, European
valve equipment manufacturers will be forced to cease produc-
Compressor tion of equipment using HCFCs before 1 January 2004
at the latest. For some countries and types of equipment
earlier phase out dates apply. The use of recycled R22 for
maintenance will be allowed until 2015.
Evaporator
41.4.2 Mechanical vapour recompression
Low pressure side
Mechanical vapour recompression (MVR) heat pumps use
Figure 41.2 Vapour Compression Cycle the process fluid as the working fluid, usually in an open
or semi-open cycle. These systems often use water vapour The stages in the absorption process are:-
or steam as the working fluid.
In an open cycle vapour from an industrial process is 1. The evaporator absorbs heat from the energy source.
compressed to a higher pressure and consequently to a The energy absorbed evaporates some of the refrigerant
higher temperature. Once expanded through a nozzle or vapour from the liquid absorbent.
venturi the vapour is condensed in the same process giving 2. The vapour passes into the absorber where it is dis-
off heat. solved into the absorbent, releasing some energy and
In a semi-open cycle the heat from the compressed concentrating the solution. The heat sink fluid is usu-
vapour is transferred to the process via a heat ally passed through the absorber prior to the condenser
exchanger. in order to collect and remove this released energy.
Compared with the closed vapour compression cycle 3. Some of the solution is pumped to the generator, its
described above these systems eliminate the use of one pressure being raised to that of the condenser.
or two heat exchangers, and as the temperature difference 4. Heat is added to the generator to raise the temperature
between heat source and heat sink is low the performance of the solution and evaporate the refrigerant vapour out
of MVR systems is high. Typically COP of 10-30 can be of the solution. This reduces the concentration of the
achieved. Current MVR systems operate with heat source solution.
temperatures of 70-8O0C and deliver heat at between 110 5. The weaker solution from the generator is then passed
and 15O0C. back to the absorber, via an expansion valve to equalize
pressures. The solution in the absorber is diluted and
so can continue to absorb vapour without becoming
41.4.3 Absorption cycle saturated.
6. The high temperature, high-pressure vapour from the
The operation of the absorption refrigeration cycle is sim- generator passes into the condenser. Here the useful
ilar to the above vapour compression cycle. The evap- heat is rejected to the heat sink and the vapour is con-
orator, condenser, and expansion device serve common densed back to a saturated liquid at constant pressure.
purposes, but a heat-operated absorber and regenerator 7. The refrigerant vapour returns to the evaporator via
replace the compressor. A schematic of the absorption the expansion device, which reduces the pressure and
cycle is shown in Figure 41.4. temperature of the vapour. Prior to the collection of
In the absorption cycle the refrigerant vapour is dis- further heat from the energy source.
solved in a suitable liquid. The power required to pump
the working fluid around the cycle is less than that There are a number of practical drawbacks that limit the
required compressing a refrigerant vapour. applicability of this refrigerant cycle.
There are two common fluid pairings used. In smaller
equipment the refrigerant used is ammonia and the 1. Achievable COPs are low, typically 1.2 to 1.4.
absorbent used is water. In larger equipment the refrig- 2. Equipment sizes for lithium bromide/water systems are
erant is water and a solution of lithium bromide is used large.
as the absorbent. 3. Concentrations of fluids are critical for stable operation.
4. Practical systems are complex.
5. Operating ranges are restricted by fluid pair-
Generator Condenser
ings. Lithium bromide/water systems cannot oper-
ate below freezing. Ammonia/water systems are
Heat
in Heat restricted in top temperature due to high
out pressures.
High temp
side
However, these types of systems have found success
where heat is available from a cheap source, or as waste
heat from an existing process. Some smaller gas fired
equipment has also been developed.
Absorbant
pump Flpw_ Expansion
control device
41.5 Climate change levy
The Climate Change Levy being introduced by the Gov-
Low temp ernment will oblige businesses to pay a levy on their
side energy bills. One of the aims of this legislation, along-
Heat side reducing CO2 emissions, is to provide an incentive
in for businesses to reduce their total energy usage and to
Heat look at how efficiently they use energy.
out
Absorber Evaporate Heat pumps can be beneficial in reducing energy usage
in a number of applications, and so could be helpful in
Figure 41.4 Absorption Cycle reducing the levy imposed.
41.6 Industrial applications ambient temperatures e.g. the Far East and Mediterranean
countries, the use of air-to-water heat pumps to gener-
41.6.1 Heating ate hot water for domestic and commercial/hotel use is
common.
41.6.1.1 Buildings However, hot water production when waste process
General heating for buildings using heat pumps is more water is available as a heat source can be viable, see
frequently used in Europe where district heating schemes section 41.6.4 below.
are more common. Here the higher initial capital cost
of a heat pump can be spread over a larger number of 41.6.2 Cooling
properties. These are water-to-water heat pumps, or air to The most common chillers providing chilled water to
water units often used in conjunction with low capacity industrial processes are air-cooled water-to-air heat pumps
back-up heating for the coldest periods of the year. or water-cooled water-to-water heat pumps. The cooling
In the USA air-to-air and ground source water-to- duty of these chillers is always larger than the energy
air heat pumps are commonly used in domestic heating input, the COP is greater than one.
where air distribution heating systems are the norm. This The absorption cycle can be found used in industrial
usage occurs particularly in areas where higher average chillers, particularly those of high capacity that can be
ambient temperatures allow higher heat pump COPs or driven by a waste heat source, perhaps even linked to a
where a ground source is available or a ground loop can CHP plant.
be accomodated. These units are often reverse cycle to Gas fired vapour absorption chillers are becoming
provide cooling in the summer. increasingly common. Small packaged units of 5OkW
Use in the UK is limited by the cost of available cooling capacity are available on the market.
alternative energy sources e.g. low cost gas. Here gas
fired boilers traditionally work in conjunction with a wet
radiator system. Even allowing for the inefficiencies of
41.6.3 Air conditioning
boilers the COP of a heat pump would have to be in excess Reverse cycle split air conditioning units are called 'heat
of 3 in order to give any running cost saving to fund the pumps', although the cooling only versions are also air-
higher initial cost of a heat pump, based on the present to-air heat pumps. These heating and cooling systems
differential between electrical and gas energy prices. are a viable alternative to cooling only air conditioning,
The COP of an air-to-water heat pump falls during cold eliminating the need for a separate heating system. They
weather just when the most heating is needed. A unit are finding increasing use in commercial and industrial
operating in air temperatures of 50C and producing water office buildings.
at 550C would have a COP of 2-2.5. The 'Versatemp' type water based system is a unique
The increased use of under-floor heating operating concept that has been on the market for many years. In this
at approx. 4O0C has increased the consideration given system individual reverse cycle water-to-air heat pumps
to using ground source heat pumps. With a constant are located in each room in a building. They exchange
source temperature of 10-120C the COP of the heat heat with a two-pipe water circuit providing heating or
pump remains stable at around 3-3.5. In this scenario, cooling to the space as required. This water circuit is kept
particularly where gas is not available, the viability of a constant temperature by a central heating and cooling
heat pumps for heating looks a lot more favourable. plant, which could be a reverse cycle water-to-water,
water-to-air or ground source heat pump. The system can
41.6.1.2 Hot water simultaneously provide cooling on one side of a building
exposed to solar gain and heating to the other side in
Heating hot water using heat pumps suffers similar com- shade.
parisons in the UK. In other areas of the world with higher
41.6.4 Heat recovery
Heat recovery from industrial processes is perhaps the
most under-used application for heat pumps.
Heat recovery can be from both air and water, with the
most viable heat sink being water. Water can be heated
to as high as 7O0C lending itself to direct use in heating
buildings or domestic hot water, or for preheating water
for the same or another process.
There are many situations in which dynamic heat recov-
ery using a heat pump is superior to a passive heat recov-
ery device such as a plate heat exchanger or air-to-air
cross-flow heat exchanger.