TAREA 2

Encontrar α, β, η, ba, bk, Ecorr, icorr Tafel, Rp, icorr para la aleación cuya voltametría lineal se adjunta,
Tanto para tafel como para resistencia de polarización n cercano a 2, α+β=1.

Ley límite de Tafel Resistencia de polarización

Esce (mV) i (mA/cm2 Esce (mV) i (mA/cm2

-422 -0.02319 -36 -0.0400
-392 -0.02148 -34 -0.0360
-362 -0.01990 -32 -0.0320
-332 -0.01844 -30 -0.0300
-302 -0.01708 -28 -0.0280
-272 -0.01582 -26 -0.0250
-242 -0.01466 -24 -0.0230
-212 -0.01358 -22 -0.0203
-187 -0.01274 -20 -0.0185
-162 -0.01195 -18 -0.0166
-137 -0.01122 -16 -0.0148
-112 -0.01052 -14 -0.0129
-87 -0.00987 -12 -0.0111
-62 -0.00923 -10 -0.0092
-37 -0.00818 -8 -0.0074
-27 -0.00693 -6 -0.0055
-22 -0.00567 -4 -0.0037
-19 -0.00455 -2 -0.0018
-14 -0.00166 0 0.0016
-12 0.00000 2 0.0030
-10 0.00207 4 0.0060
-8 0.00463 6 0.0090
-7 0.00615 8 0.0120
-2 0.01677 10 0.0150
3 0.03518 12 0.0190
7 0.05927
11 0.09678
15 0.15517
19 0.24610
23 0.38776
27 0.60844
31 0.95226
35 1.48795
39 2.32263
43 3.62316
47 5.64960
51 8.80712
55 13.72711
63 33.33874
65 41.61761
67 51.95190
72 90.44837
cinetica de corrosion
ECUACION DE BUTLER_VOLMER
Ieta= Ia Ic

i neta i0(exp(alfanF/RT)Na-exp(-(i-(alfanF/RT))Nc))
MÉTODO APROXIMADO DE TAFEL

Datos para ánodo

Esce (mV) i (mA/cm2 ABS(i) LOG(ABS(i))

Y X XY X2
-422 -0.02319 0.023191656 -1.63466825 689.830001 2.67214028
-392 -0.02148 0.021484136 -1.66788211 653.809789 2.78183075
-362 -0.01990 0.019902335 -1.70109598 615.796744 2.89372753
-332 -0.01844 0.018436996 -1.73430984 575.790868 3.00783063
-302 -0.01708 0.017079545 -1.76752371 533.79216 3.12414006
-272 -0.01582 0.015822038 -1.80073757 489.80062 3.24265581
-242 -0.01466 0.0146571172 -1.83395144 443.816248 3.36337788
-212 -0.01358 0.013577965 -1.8671653 395.839045 3.48630627
-187 -0.01274 0.01273962 -1.89484353 354.335739 3.59043199
-162 -0.01195 0.0119530362 -1.92252176 311.448526 3.69608993
-137 -0.01122 0.0112150117 -1.95020027 267.177437 3.80328109
-112 -0.01052 0.010522445 -1.97788334 221.522934 3.91202249
-87 -0.00987 0.00987088 -2.00564414 174.49104 4.02260843
-62 -0.00923 0.009231402 -2.03473233 126.153404 4.14013565
ΣY -3283 ΣX -25.7931596 5853.60456 47.7365788
Prom Y -234.5 Prom X -1.84236854 ΣXY ΣX2
418.114611 3.40975563

Y=a+bX -421.839426
-391.881517
Sxy = ΣXY - (ΣXΣY)/n -194.891366 -361.923608
Sxx = ΣX2 - (ΣX)2/n 0.21607301 -331.9657
Syy = ΣY2 - (ΣY)2/n 175787.5 -302.007791
b = Sxy/Sxx -901.969965 -272.049882
a = Prom Y - b (Prom X) -1896.26109 -242.091973
r2 = (Sxy)2/Sxx.Syy 0.99999237 -212.134064
-187.16914
-162.204201
-137.23902
-112.269726
-87.2303116
-60.9936413
 Datos para cátodo

Esce (mV) i (mA/cm2 LOG(i)

Y2 Y X XY
178084 51 8.80712 0.94483416 48.186542
153664 55 13.72711 1.13757921 62.5668565
131044 63 33.33874 1.52294923 95.9458018
110224 65 41.61761 1.61927712 105.253013
91204 67 51.95190 1.7156014 114.945294
73984 72 90.44837 1.95640073 140.860852
58564 ΣY 373 ΣX 8.89664185 567.758359
44944 Prom Y 62.1667 Prom X 1.48277364 ΣXY
34969 94.6263932
26244
18769
12544
7569
3844
945651
ΣY2
67546.5

Y=a+bX 50.9991225
55.0004813
Sxy = ΣXY - (ΣXΣY)/n 14.683791 63.000706
Sxx = ΣX2 - (ΣX)2/n 0.70731674 65.0004588
Syy = ΣY2 - (ΣY)2/n 304.833333 67.0001365
b = Sxy/Sxx 20.7598521 71.9990949
a = Prom Y - b (Prom X) 31.3845051
r2 = (Sxy)2/Sxx.Syy 0.99999999
 X2 Y2
0.89271158 2601
1.29408646 3025
2.31937437 3969
2.6220584 4225
2.94328816 4489
3.8275038 5184
13.8990228 23493
ΣX2 ΣY2
2.3165038 3915.5
MÉTODO RESISTENCIA DE POLARIZACIÓN

Datos para ánodo

Esce (mV) i (mA/cm2

-36 -0.0400
-34 -0.0360
-32 -0.0320
-30 -0.0300
-28 -0.0280
-26 -0.0250
-24 -0.0230
-22 -0.0203
-20 -0.0185
-18 -0.0166
-16 -0.0148
-14 -0.0129
-12 -0.0111
-10 -0.0092
-8 -0.0074
-6 -0.0055
-4 -0.0037
-2 -0.0018
Datos para cátodo

Esce (mV) i (mA/cm2

0 0.0016
2 0.0030
4 0.0060
6 0.0090
8 0.0120
10 0.0150
12 0.0190