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PAPER-3 (B.E./B. TECH.

JEE (Main) 2020


COMPUTER BASED TEST (CBT)
Memory Based Questions & Solutions
Date: 09 January, 2020 (SHIFT-1) | TIME : (9.30 a.m. to 12.30 p.m)

Duration: 3 Hours | Max. Marks: 300


SUBJECT: CHEMISTRY

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PART : CHEMISTRY
SECTION – 1 : (Maximum Marks : 80)
Straight Objective Type (lh/ks oLrqfu"B izdkj)
This section contains 20 multiple choice questions. Each question has 4 choices (1), (2), (3) and (4) for its
answer, out of which Only One is correct.
bl [k.M esa 20 cgq&fodYih iz'u gSaA izR;sd iz'u ds 4 fodYi (1), (2), (3) rFkk (4) gSa] ftuesa ls flQZ ,d lgh gSA

1. Determine wavelength of electron in 4th Bohr's orbit ?


4th cksgj d{kk esa bysDVªkWu dh rjax)Sè;Z dk fuèkkZj.k dhft, ?
(1) 4 a0 (2) 2 a0 (3) 8 a0 (4) 6 a0
Ans. (3)
Sol. 2 r = n
2
n
2× a0 = n
Z
2
4
2× a0 = n
1
 = 8 a0

2. Which of the following species have one unpaired electron each?


fuEu esa ls dkSulh Lih'kht ¼izR;sd esa½ ,d v;qfXer bysDVªkWu j[krh gSa\
(1) O2, O2– (2) O2, O2+ (3) O2+, O2– (4) O2, O22–
Ans. (3)
Sol. O2 = 1s2 *1s22s2*2s22pz22px2 = 2py2 *2px1 = 2py1

3. For Br2()
Enthalpy of atomisation = x kJ/mol
Bond dissociation enthalpy of bromine = y kJ/mole
then
(1) x > y (2) x < y (3) x = y (4) Relation does not exist
Br2() ds fy,
ijek.kfodj.k dh ,sUFksYih = x kJ/mol
czksehu dh caèk fo;kstu ,sUFksYih = y kJ/mole
rc
(1) x > y (2) x < y (3) x = y (4) dksbZ lEcU„èk ugah gksrk gS

Ans. (1)
Hatomisation = x kJ/mole ijek.kfodj.k = x kJ/mole
Br2() 2Br(g) Br2() 2Br(g)

HVap. HVap.

Sol. Br2(g)
Bond energy = y kJ/mole
Br2(g)
caèk ÅtkZ = y kJ/mole

Hatomisation = Hvap + Bond energy


Hence x > y
Hijek.kfodj.k = Hvap + caèk ÅtkZ
bl izdkj x > y

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4. Which of the following oxides are acidic, Basic Amphoteric Respectively.


fuEu esa ls dkSuls vkWDlkbM Øe'k% vEyh;] {kkjh;] mHk;èkehZ gS&
(1) MgO, P4O10, Al2O3 (2) N2O3, Li2O, Al2O3 (3) SO3, Al2O3, Na2O (4) P4O10, Al2O3, MgO
Ans. (2)
Sol. Non-metal oxides are acidic in nature
alkali metal oxides are basic in nature
Al2O3 is amphoteric.
vèkkfRod vkWDlkbM vEyh; izd`fr ds gksrs gSA
{kkjh; èkkrq vkWDlkbM {kkjh; izd`fr ds gksrs gSA
Al2O3 mHk;èkehZ gSA

5. Complex Cr(H2O)6Cln shows geometrical isomerism and also reacts with AgNO3 solution.
Given : Spin only magnetic moment = 3.8 B.M.
What is the IUPAC name of the complex.
(1) Hexaaquachromium(III) chloride
(2) Tetraaquadichloridochromium(III) chloride dihydrate
(3) Hexaaquachromium(IV) chloride
(4) Tetraaquadichloridochromium(IV) chloride dihydrate
ladqy Cr(H2O)6Cln T;kferh; leko;ork n'kkZrk gS rFkk ;g AgNO3 foy;u ds lkFk Hkh vfHkd`r gksrk gSA
fn;k gS: izpØ.k dsoy pqEcdh; vk?kq.kZ = 3.8 B.M.
ladqy dk IUPAC uke D;k gS \
(1) gsDlk,DokØksfe;e (III) DyksjkbM
(2) VsVªk,DOkkMkbZDyksjkbMksaØksfe;e (III) DyksjkbM MkbZgkbMªsV
(3) gsDlk,DokØksfe;e (IV) DyksjkbM
(4) VsVªk,DOkkMkbZDyksjkbMksaØksfe;e (IV) DyksjkbM MkbZgkbMªsV
Ans. (2)
Sol. Cr(H2O)6Cln (complex)spin = 3.8 B.M.
From data of magnetic moment oxidation number of Cr should be +3
Hence complex is Cr(H2O)6Cl3.
Complex shows geometrical isomerism therefore formula of complex is [Cr(H 2O)4Cl2]Cl2H2O.
It's IUPAC Name: Tetraaquadichloridochromium(III) chloride dihydrate
Cr(H2O)6Cln (ladqy)pØ.k = 3.8 B.M.
pqEcdh; vk?kq.kZ ds eku ls Cr dk vkWDlhdj.k vad +3 gksuk pkfg,A
bl izdkj ladqy Cr(H2O)6Cl3 gSA
ladqy T;kferh; leko;ork n'kkZrk gSA blfy, ladqy dk lw=k [Cr(H2O)4Cl2]Cl2H2O gSA
bldk IUPAC uke VsVªk,DOkkMkbZDyksjkbMksaØksfe;e (III) DyksjkbM MkbZgkbMªsV gSA

6. The electronic configuration of bivalent Europium and trivalent cerium respectively is:
(Atomic Number : Xe = 54, Ce = 58, Eu = 63)
f}la;ksth ;wjksfi;e rFkk f=kla;ksth flfj;e ds bysDVªkWfud foU;kl Øe'k% gS%
(ijek.kq Øekd : Xe = 54, Ce = 58, Eu = 63)
(1) [Xe]4f7, [Xe]4f1 (2) [Xe]4f7 6s2, [Xe]4f1
(3) [Xe]4f76s2, [Xe]4f15d16s2 (4) [Xe]4f7, [Xe]4f15d16s2
Ans. (1)
Sol. Eu2+ : [Xe]4f7
Ce3+ : [Xe]4f1

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7. Ksp of PbCl2 = 1.6 × 10–5


On mixing
300 mL, 0.134M Pb(NO3)2(aq.) + 100 mL, 0.4 M NaCl(aq.)
(1) Q > Ksp (2) Q < Ksp (3) Q = Ksp (4) Relation does not exit
PbCl2 dk Ksp = 1.6 × 10–5
300 mL, 0.134M Pb(NO3)2(aq.) + 100 mL, 0.4 M NaCl(aq.) feykus ij&
(1) Q > Ksp (2) Q < Ksp
(3) Q = Ksp (4) fdlh izdkj ds lEcUèk dk vfLrRo ugha gSA
Ans. (1)
Sol. Q = [Pb2+][Cl–]2
2
3 0 0  0 .1 3 4  1 0 0  0 .4 
 
 
400  400 
3  0 .1 3 4
  0 .1 
2

4
= 0.105 × 10–2
=1.005 ×10–3
Q > K sp

8. Which of the following can not act as both oxidising and reducing agent ?
fuEu esa ls dkSu vkWDlhdkjd rFkk vipk;d nksuks ds leku O;ogkj ugha dj ldrk gS\
(1) H2SO3 (2) HNO2 (3) H3PO4 (4) H2O2
Ans. (3)
Sol. As in H3PO4 Phosphorous is present it's maximum oxidation number state hence it cannot act as
reducing agent.
pwafd H3PO4 esa QkWLQksjl bldh mPpre vkWDlhdj.k voLFkk esa mifLFkr gSA blfy, ;g vipk;d ds leku dk;Z
ugha dj ldrk gSA

9. First Ionisation energy of Be is higher than that of Boron.


Select the correct statements regarding this
(i) It is easier to extract electron from 2p orbital than 2s orbital
(ii) Penetration power of 2s orbital is greater than 2p orbital
(iii) Shielding of 2p electron by 2s electron
(iv) Radius of Boron atom is larger than that of Be
(1) (i), (ii), (iii), (iv) (2) (i), (iii), (iv) (3) (ii), (iii), (iv) (4) (i), (ii), (iii)
Be dh izFke vk;uu ÅtkZ cksjksu dh rqyuk esa vfèkd gksrh gSA
mDr dFku ds lanHkZ esa lgh dFku@dFkuksa dk p;u dhft,sA
(i) 2p d{kd ls bysDVªkWu dk i`Fkddj.k 2s d{kd dh rqyuk esa ljy gksrk gSA
(ii) 2s d{kd dh Hksnu {kerk 2p d{kd dh rqyuk esa vfèkd gksrh gSA
(iii) 2s bysDVªkWu }kjk 2p bysDVªkWu dk ifjj{k.k gksrk gSA
(iv) cksjksu ijek.kq dh f=kT;k Be dh rqyuk esa vfèkd gksrh gSA
(1) (i), (ii), (iii), (iv) (2) (i), (iii), (iv) (3) (ii), (iii), (iv) (4) (i), (ii), (iii)
Ans. (4)
Sol. Theory Based.

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10. [PdFClBrI]2– Number of Geometrical Isomers = n. For [Fe(CN)6]n–6, Determine the spin only magnetic
moment and CFSE (Ignore the pairing energy)
(1) 1.73 B.M., –20 (2) 2.84 B.M., –1.60 (3) 0, –1.60 (4) 5.92 B.M., –2.40
[PdFClBrI]2– T;kfefr; leko;oh;ksa dh la[;k = n. [Fe(CN)6]n–6 ds fy;s, izpØ.k dsoy pqEcdh; vk?kw.kZ rFkk
CFSE dk eku fu/kkZfjr dhft;s (;qXeu ÅtkZ dks ux.; ekurs gq;s)
Ans. (1)
Sol. Number of Geometrical Isomers in square planar [PdFClBrI]2– are = 3
Hence, n = 3
[Fe(CN)6]3–
Fe3+ = 3d5, According to CFT configuration is t 22 g2 1 e g0 0
  n n  2 = 1.73 B.M.
C F S E  – 0 .4  0  n t 2 g  0 .6  0  n e g

= –0.40 × 5 = –2.00
Sol. oxZ leryh; [PdFClBrI]2– esa T;kfefr; leko;oh;ksa dh la[;k = 3 gSA
blfy;s, n = 3
[Fe(CN)6]3–
Fe3+ = 3d5, CFT ds vuqlkj foU;kl 221
t2g eg
00

  n n  2 = 1.73 B.M.
C F S E  – 0 .4  0  n t 2 g  0 .6  0  n e g

= –0.40 × 5 = –2.00

11. A can reduce BO2 under which conditions.


fdl ifjfLFkfr esa A, BO2 dks vipf;r dj ldrk gS

A + O2  AO2

Gf
B + O2 BO2

T(0°C) 1400°C
(1) > 1400°C (2) < 1400°C
(3) > 1200°C and (rFkk) < 1400°C (4) < 1200°C
Ans. (1)
Sol. A + BO2   B + AO2
G = –ve
Only above 1400°C
dsoy 1400°C ds Åij

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12. A   B 700 K
C
A   B 500 K
Rate of reaction in absence of catalyst at 700 K is same as in presence of catalyst at 500 K. If catalyst
decreases activation energy barrier by 30 kJ/mole, determine activation energy in presence of catalyst.
(Assume 'A' factor to be same in both cases)
700 K ij mRizsjd dh vuqifLFkfr esa vfHkfØ;k dk osx 500 K ij mRizsjd dh mifLFkfr esa vfHkfØ;k ds osx ds leku
gS ;fn mRizsjd lfØ;.k ÅtkZ vojksèk esa 30 kJ/mole ls deh djrk gSA rc mRizjs d dh mifLFkfr esa lfØ;.k ÅtkZ
dk fuèkkZj.k dhft,sA (ekuk fd 'A' dkjd nksuks ifjfLFkfr;ksa esa leku gSA)
(1) 75 kJ (2) 135 kJ (3) 105 kJ (4) 125 kJ
Ans. (1)
Sol. Kcat = K
E a1 Ea2
 
R T1 R T2
Ae = Ae
E a1 Ea2
 Ea1 = Ea2 – 30
T1 T2

Ea2  30 Ea2
=
500 700
5Ea2 = 7Ea2 – 210
210
Ea2 = = 105 kJ/mole
2
Activation energy of the catalysed reaction = 105 – 30 = 75 kJ/mole
13. A substance 'X' having low melting point, does not conduct electricity in both solid and liquid state. 'X'
can be :
,d inkFkZ 'X' de xyukad j[krk gS] Bksl rFkk æo izkoLFkk nksuks esa fo|qr dk dqpkyd gSA 'X' gks ldrk gSA
(1) Hg (2) ZnS (3) SiC (4) CCl4
Ans. (4)
Sol. CCl4  Non-conductor in solid and liquid phase.
CCl4  Bksl rFkk æo izkoLFkk esa dqpkyd gSA

NH2
14. (1) NaNO2 + HCl
(2) Cu2Br2
Br
(3) HNO3, Conc. H2SO4
The major product for above sequence of reaction is :
mijksDr vfHkfØ;k Øe es fy;s izeq[k mRikn gS&
Br Br Br
Br
O2N O 2N
(1) (2) (3) (4)
Br Br Br NO2
Br
NO2 NO2
Ans. (2)
NH2 N2+Cl– Br
Br

Sol. (1) NaNO2 + HCl (2) Cu2Br2 (3)HNO3


Br Br Conc. H2SO4 Br
Br
NO2

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15. Which of the following can give highest yield in Friedel craft reaction?
ÔfuEu es ls dkSu fÝMy&Øk¶V vfHkfØ;k es vf/kdre yfC/k ns ldrk gS\
O
NH2 OH Cl C–NH2

(1) (2) (3) (4)

Ans. (2)
Sol. Aniline form anilinium complex with lewis acid so phenol is most reactive among the given compounds
for electrophilic substitution reaction.
Sol. ,uhfyu yqbZl vEy ds lkFk ,uhfy;e ladqy cukrk gSA blfy;s fn;s x;s ;kSfxdks es ls fQukWy bysDVªkWuLusgh
izfrLFkkiu vfHkfØ;k ds izfr vf/kdre fØ;k'khy gksxkA

CH3 O
3 (1) EtMgBr/Ether H2SO4
16. H3C–CH—C–CH3
(2) H3O 
What will be the major product ?
CH3 O
3 (1) EtMgBr/bZFkj H2SO4
H3C–CH—C–CH3
(2) H3O 
fuEufyf[kr es ls eq[; mRikn gksxsa\
CH3 CH2
3 3
(1) CH3–C=C–CH3 (2) CH3–C–CH–CH3

CH2–CH3 CH2–CH3

CH3 CH3
3 3
(3) CH3–CH–C–CH3 (4) CH3–CH–C=CH2
CH–CH3 CH2–CH3

Ans. (1)
CH3 O CH3 OH CH3
3 (1) EtMgBr/Ether 3 H+/ 3
Sol. H3C–CH—C–CH3 CH3–CH—C–CH3 CH3–C=C–CH3
(2) H3O
CH2–CH3 CH2–CH3

CH3 O CH3 OH CH3


3 (1) EtMgBr/bZFkj 3 H+/ 3
Sol. H3C–CH—C–CH3 CH3–CH—C–CH3 CH3–C=C–CH3
(2) H3O
CH2–CH3 CH2–CH3

17. Which of the following is correct order for heat of combustion?


fuEufyf[kr es ls dkSulk Øe ngu dh Å"ek ds fy;s lgh gksxk&
(A) (B) (C)

(1) C > B > A (2) A > B > C (3) B > A > C (4) C > A > B
Ans. (1)

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Sol. In isomers of hydrocarbon heat of combustion depends upon their stabilities.


As the stability increases heat of combustion decreases.
Stability order > >

Sol. gkbMªksdkcZu ds leko;oh;ksa es ngu dh Å"ek muds LFkkf;Ro ij fuHkZj djrh gSA
LFkkf;Ro c<+us ds lkFk] ngu dh Å"ek es o`f) gksrh gSA
LFkkf;Ro dk Øe > >

18. Write the correct order of basicity.


{kkjh;rk dk lgh Øe fyf[k;s&

CH3 CH3 CH3 :CN: CH2=CH–CH2 CCH


C

CH3
(a) (b) (c) (d) (e)

(1) a > b > d > e > c (2) a > b > e > d > c
(2) b > a > d > c > e (4) c > e > d > b > a
Ans. (1)
Sol. Basicity is inversely proportional to electronegativity.
Sol. {kkjh;rk] fo|qr_.krk ds fo"kekuqikrh gksrh gSA

19. A, B, C, and D are four artificial sweetners.


(i) A & D give positive test with ninhydrin.
(ii) C form precipitate with AgNO3 in the lassaigne extract of the sugar.
(iii) B & D give positive test with sodium nitroprusside.
Correct option is :`
(1) A – Saccharine, B – Aspartame, C – Sucralose, D – Alitame
(2) A – Aspartame, B – Saccharine, C – Sucralose, D – Alitame
(3) A – Saccharine, B – Aspartame, C – Alitame , D – Sucralose
(4) A – Aspartame, B – Sucralose, C – Saccharine, D – Alitame
A, B, C, vkSj D ds pkj Ñf=ke e/kqjd (artificial sweetners) fuEu gSA
(i) A vkSj D fuugkbfMªu ds lkFk ldkjkRed ijh{k.k nsrk gSA
(ii) C 'kdZjk ds yslkus fu"d"kZ eas, AgNO3 ds lkFk vo{ksi nsrk gSA
(iii) B vkSj D lksfM;e ukbVªksizl
q kbM ds lkFk ldkjkRed ijh{k.k nsrk gSA
lgh fodYi gS&
(1) A – lSdjhu, B – ,sLikVsZe, C – lwØkykst, D – ,sfyVse
(2) A – ,sLikVsZe, B – lSdjhu, C – lwØkykst, D – ,sfyVse
(3) A – lSdjhu, B – ,sLikVsZe, C – ,sfyVse, D – lwØkykst
(4) A – ,sLikVsZe, B – lwØkykst, C – lSdjhu, D – ,sfyVse
Ans. (2)

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Sol. A – Aspartame

B – Saccharine

C – Sucralose

D – Alitame

(i) A & D give positive test with ninhydrin because both have free carboxylic and amine groups.
(ii) C form precipitate with AgNO3 in the lassaigne extract of the sugar because it has chlorine atoms.
(iii) B & D give positive test with sodium nitroprusside because both have sulphur atoms.

Sol. A – ,sLikVsZe

B – lSdjhu

C – lwØkykst

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D – ,sfyVse

(i) A vkSj D fuugkbMªhu ds lkFk ldkjkRed ijh{k.k nsrs gSa] D;ksafd nksuksa es isIVkbM cU/k ik;s tkrs gSA
(ii) C 'kdZjk ds yslkus fu"d"kZ eas, AgNO3 ds lkFk vo{ksi nsrk gS] D;ksafd bles Dyksjhu ijek.kq gksrs gSA
(iii) B vkSj D lksfM;e ukbVªksizl
q kbM ds lkFk ldkjkRed ijh{k.k nsrk gSA D;ksafd nksuksa es lYQj ijek.kq gksrs gSA

CH=O
(1) CH3MgBr O3/Zn, H2O O
20. Compound (P)
(2) H3O+ C
(P gives CH3
(3) Conc. H2SO4 +  H3C CH3
Iodoform test)
Predict the compound (P) on the basis of above sequence of the reactions?
Where compound (P) gives positive Iodoform test.

(1) (2) (3) (4)


O O O O
CH=O
(1) CH3MgBr O3/Zn, H2O O
;kSfxd (P)
(2) H3O+ C
(P vkbMksQkeZ CH3
(3) Conc. H2SO4 +  H3C CH3
ijh{k.k nsrk gSA)
mijksDr vfHkfØ;k vuqØe ds vk/kkj ij ;kSfxd (P) dh igpku dhft;sA
;gk¡ ;kSfxd (P) ldkjkRed vk;ksMksQkeZ ijh{k.k nsrk gSA

(1) (2) (3) (4)


O O O O
Ans. (2)
Sol. (1) CH3MgBr
(2) H3O+
O HO
H , 
CH=O
O
O3
C
CH3 Zn, H2O
H3C CH3

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SECTION – 2 : (Maximum Marks : 20)


 This section contains FIVE (05) questions. The answer to each question is NUMERICAL VALUE with two
digit integer and decimal upto one digit.
 If the numerical value has more than two decimal places truncate/round-off the value upto TWO decimal
places.
 Full Marks : +4 If ONLY the correct option is chosen.
 Zero Marks : 0 In all other cases
[kaM 2 ¼vf/kdre vad% 20)
 bl [kaM esa ik¡p (05) iz'u gSA izR;sd iz'u dk mÙkj la[;kRed eku (NUMERICAL VALUE) gSa] tks f}&vadh; iw.kkZad
rFkk n'keyo ,dy&vadu eas gSA
 ;fn la[;kRed eku esa nks ls vf/kd n’'keyo LFkku gS ] rks la[;kRed eku dks n'keyo ds nks LFkkuksa rd VªadsV@jkmaM
vkWQ (truncate/round-off) djsaA
 vadu ;kstuk :
 iw.kZ vad % +4 ;fn flQZ lgh fodYi gh pquk x;k gSA
 'kwU; vad % 0 vU; lHkh ifjfLFkfr;ksa esaA

21. Given a solution of HNO3 of density 1.4 g/mL and 63% w/w. Determine molarity of HNO3 solution.
?kuRo 1.4 g/mL rFkk 63% w/w ;qDr HNO3 dk ,d foy;u fn;k x;k gSA HNO3 foy;u dh eksyjrk Kkr dhft,A
Ans. 14.00
Sol. 63% w/w HNO3 solution foy;u
6 3  1 .4
M= × 1000 mole/L
63  100
M = 14 mole/L
22. Determine degree of hardness in term of ppm of CaCO3 of 10–3 molar MgSO4 (aq).
10–3 eksyj MgSO4(tyh;) foy;u dh CaCO3 ds :i esa ppm ds inksa esa dBksjrk dh ek=kk Kkr dhft,A
Ans. 100.00
Sol. 10–3 molar MgSO4  10–3 moles of MgSO4 present in 1 L solutions.
10–3 eksyj MgSO4  1 L foy;u esa mifLFkr MgSO4 ds 10–3 eksy
nCaCO  nM gSO
3 4

3
10  100
p p m ( in te rm o f C a C O 3 ) = × 106
1000
p p m ( in te rm o f C a C O 3 ) = 100 ppm

23. Determine the amount of NaCl to be dissolved in 600g H2O to decrease the freezing point by 0.2°C
Given : kf of H2O = 2 k-m–1
density of H2O() = 1 g/ml
fgekad esa 0.2°C ls deh djus ds fy, 600g H2O esa foy; fd;s x;s NaCl dh ek=kk Kkr dhft,A
fn;k gS : kf of H2O = 2 k-m–1
H2O() dk ?kuRo = 1 g/ml
Ans. 01.76
Sol. Tf = 0.2°C
Tf = ikfm
 1000
0 .2  2  2  i
5 8 .5 600
0 .2  5 8 .5  6 0 0 1 .2  5 8 .5
   = 01.76g
1000  4 40

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24. On passing a particular amount of electricity in AgNO3 solution, 108 g of Ag is deposited. What will be
the volume of O2(g) in litre liberated at 1 bar, 273K by same quantity of electricity?
AgNO3 foy;u esa fuf'pr ek=kk dh fo|qr èkkjk izokfgr dh tkrh gS rc Ag dk 108 g fu{ksfir gksrk gSA 1 bar, 273K
ij fo|qrèkkjk dh leku ek=kk }kjk O2(g) dk fdruk vk;ru yhVj esa eqDr gksxk\
Ans. 05.68
108
Sol. n  Ag
d e p o s it
  1 m o le
108
 –
Ag  e   A g
1F charge is required to deposit 1 mole of Ag
Ag ds ,d eksy fu{ksi.k ds fy, 1 F vkos'k dh vko';drk gksrh gSA
1  –
H 2 O   O 2  2H  2e
2
1
2F charge deposit   m o le
2
1
2F vkos'k fu{ksfr djrk gS   m o le
2
1
1F charge will deposit   m o le
4
1
1F vkos'k fu{ksfr djrk gS   m o le
4
nRT
VO 
2
P
1 0 .0 8 3 1 4  2 7 3 1
=  =  2 2 .7
4 1 4
vo  5 .6 7 5 L
2

25. Find percentage nitrogen by mass in Histamine ?


fgLVkfeu es nzO;eku ls ukbVªkstu dh izfr'krrk Kkr dhft;s\
Ans. 37.84
N NH2
Sol. Structure of Histamine is
NH
Molecular formula of Histamine is C5H9N3
Molecular mass of Histamine is 111
42
Percentage nitrogen by mass in Histamine =  100 = 37.84%
111
N NH2
Sol. fgLVkfeu dh lajpuk NH
fgLVkfeu dh vkf.od lajpuk C5H9N3
fgLVkfeu dh vkf.od nzO;eku 111
42
fgLVkfeu es nzO;eku ls ukbVªkstu dk izfr'kr =  100 = 37.84%
111

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PAPER-1 (B.E./B. TECH.)

JEE (Main) 2020


COMPUTER BASED TEST (CBT)
Questions & Solutions
Date: 09 January, 2020 (SHIFT-1) | TIME : (9.30 am to 12.30 pm)
Duration: 3 Hours | Max. Marks: 300
SUBJECT : MATHEMATICS

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PART : MATHEMATICS

SECTION – 1 : (Maximum Marks : 80)


Straight Objective Type (lh/ks oLrqfu"B izdkj)
This section contains 20 multiple choice questions. Each question has 4 choices (1), (2), (3) and (4) for its
answer, out of which Only One is correct.
bl [k.M esa 20 cgq&fodYih iz'u gSaA izR;sd iz'u ds 4 fodYi (1), (2), (3) rFkk (4) gSa] ftuesa ls flQZ ,d lgh gSA
1 1 1 1
1. The product 2 4 . 4 16 . 8 48 . 16128 …. to is equal to
1 1 1 1
xq.kuQy 2 4 . 4 16 . 8 48 . 16128 …. rd cjkcj gS&
1 1
(1) 2 4 (2) 2 2 (3) 1 (4) 2
Ans. (2)
1 2 3 1 1 1
  ............   ............
Sol. 24 16 48 = 24 8 16 = 2

 
2. If f'(x) = tan–1(secx + tanx), – < x< , and f(0) = 0, then f(1) is equal to :
2 2
 
;fn f'(x) = tan–1(secx + tanx), – < x< rFkk f(0) = 0, rc f(1) cjkcj gS&
2 2
1 2  1  1
(1) (2) (3) (4)
4 4 4 4
Ans. (4)
     x 
 1 – cos  x    2 sin 2    
 1  sin x   2   = tan–1  4 2 
Sol. f'(x) = tan–1 (secx + tanx) = tan–1   = tan–1 
 cos x       x  x
 sin  x    2 sin   cos   
 2    4 2 4 2
   x   x
= tan–1  tan    = 
  4 2  4 2
 x
(f'(x))dx =  dx
4 2
 x2
f(x) = x+ +c
4 4
 x2
f(0) = c = 0  f(x) = x
4 4
 1
So f(1) =
4

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2
x sin 8 x
3. The value of  sin
0
8
x  cos8 x
dx is equal to :

2 8
x sin x
 sin
0
8
x  cos8 x
dx dk eku cjkcj gS&

(1) 2 (2) 2 (3) 4 (4) 22


Ans. (2)
 
x sin 8 x (2 – x ) sin 8 x 2 sin 8 x
Sol.  sin
0
8
x  cos8 x

sin 8 x  cos8 x
dx =  sin
0
8
x  cos8 x
dx

/2 /2
sin x8
cos x8

= 2 
0
sin x  cos x
8 8

sin x  cos x
8 8 
dx = 2 1 dx = 2×
0
2
= 2

  3    3 
4. The value of cos3   . cos  + sin 3   . sin  is :
 
8  
8  
8  8 
  3    3 
cos3   . cos  + sin 3   . sin  dk eku gS&
8  8  8  8 
1 1 1 1
(1) (2) (3) (4)
2 2 2 4 2
Ans. (1)
  3      3 
Sol. cos3 8 4 cos 8 – 3 cos 8  + sin3 8 3 sin 8 – 4 sin 8 
   
   
= 4cos6 8 – 4sin6 8 – 3cos4 8 + 3sin4 8

 2  2    4         
= 4 cos 8 – sin 8   sin  cos4  sin 2 cos2  – 3  cos2 – sin2 
   8 8 8 8   8 8 

  2    1  1 1
= cos 41 – sin cos2  – 3 = 1–  =
4  8 8  2  2 2 2

1 1 2
  | adjB |
5. If the matrices A = 1 3 4 , B = adj A and C = 3A, then is equal to
|C|
1  1 3 

1 1 2
;fn vkO;wg A = 1 3 4 , B = adj A rFkk C = 3A, rc
| adjB |
cjkcj gS&
|C|
1  1 3 

(1) 72 (2) 8 (3) 16 (4) 2


Ans. (2)

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1 1 2
Sol. |A| = 1 3 4 = ((9+4) – 1(3–4) + 2(–1–3)) = 13 + 1 – 8 = 6
1 –1 3
n–12 4
| adjB | = | adjadjA | = A = A = (36)2
|C| = |BA| = 33 × 6
adjB 36  36
= =8
C 33  6

6. A circle touches the y-axis at the point (0, 4) and passes through the point (2, 0). Which of the following
lines is not a tangent to this circle ?
,d o`Ùk y-v{k dks fcUnq (0, 4) ij Li'kZ djrk gS rFkk fcUnq (2, 0) ls gksdj tkrk gSA fuEu esa ls dkSu lh js[kk bl
o`Ùk dh Li'kZ js[kk ugha gS ?
(1) 4x – 3y + 17 = 0 (2) 3x – 4y – 24 = 0
(3) 3x + 4y – 6 = 0 (4) 4x + 3y – 8 = 0
Ans. (4)

Sol. (0,4)

(2,0)

equation of family of circle o`Ùk fudk; dk lehdj.k


(x – 0)2 + (y – 4)2 + x = 0  passes xqtjrk gS (2, 0)
4 + 16 + 2 = 0   = – 10
x2 + y2 – 10x – 8y + 16 = 0
centre dsUnz (5, 4). R = 25  16 – 16 = 5
Check the options. fodYiksa dh tk¡p djsaA
Option (4)
45  34 8 24
 5
5 5

7. A spherical iron ball of 10 cm radius is coated with a layer of ice of uniform thickness that melts at a rate
of 50 cm3/min. When the thickness of ice is 5 cm, then the rate (in cm/min.) at which of the thickness of
ice decreases, is :
,d 10 cm f=kT;k okyh xksykdkj yksgs dh xsan dks cQZ dh ,d leku eksVkbZ okyh ijr ls ysi fd;k x;k gS] tks fd
50 cm3/min dh nj ls fi?kyrh gSA tc cQZ dh ijr dh eksVkbZ 5 cm gS, ml le; cQZ dh eksVkbZ ds ?kVus dh nj
(in cm/min. esa) gSA
5 1 1 1
(1) (2) (3) (4)
6 36 18 54
Ans. (3)

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Sol. Let thickness ekuk eksVkbZ = x cm


4
Total volume dqy vk;ru v = (10 + x)3
3
dv dx
= 4 (10 + x)2 ………..(i)
dt dt
dv
Given fn;k gS = 50cm3/min
dt
At x = 5cm
dx
50 = 4 (10 + 5)2
dt
dx 1
= cm/min
dt 18

8. Negation of the statement :


5 is an integer or 5 is irrational is :
(1) 5 is not an integer or 5 is not irrational (2) 5 is an integer and 5 is irrational
(3) 5 is irrational or 5 is an integer. (4) 5 is not an integer and 5 is not irrational
dFku:
5 ,d iw.kk±d gS ;k 5 vifjes; gS dk fu"ks/ku gS :
(1) 5 ,d iw.kk±d ugha gS vkSj 5 vifjes; ugha
(2) 5 ,d iw.kk±d gS vkSj 5 vifjes; gS
(3) 5 vifjes; gS ;k 5 ,d iw.kk±d gSA
(4) 5 ,d iw.kk±d ugha gS ;k 5 vifjes; ugha gSA
Ans. (4)
Sol. 5 is not an integer and 5 is not an irrational Number ~ p  q = ~ p  ~ q

5 ,d iw.kkZd ugha gS rFkk 5 ,d vifjes; la[;k ugha gS ~ p  q = ~ p  ~ q

dx
9. The integral  ( x  4) 8/7
( x  3) 6 / 7
is equal to :

(where C is a constant of integration)


dx
lekdy  ( x  4) 8/7
( x  3) 6 / 7
cjkcj gS :

(tgk¡ C ,d lekdyu vpj gS)


1/ 7 13 / 7
 x3 1  x3
(1)   C (2)    C
x4 13  x  4 
3/7 1/ 7
1 x3  x3
(3)   C (4) –   C
2 x  4 x4
Ans. (1)

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–6
x3 1

7
Sol.   dx
x  4 x  42
x3
Let  t7 ,
x4
7
dx  7t 6 dt
x  42
t
–6 6
t dt  t  c

10. If the number of five digit numbers with distinct digits and 2 at the 10th place is 336 k, then k is equal to :
;fn fofHkUu vadks okyh ik¡p vadksa dh la[;kvksa] ftudk ngkbZ dk vad 2 gS] dh la[;k 336 k gS] rks k cjkcj gS-
(1) 7 (2) 4 (3) 6 (4) 8
Ans. (4)
Sol.
2

Number of numbers la[;kvksa dh la[;k = 8 8 7 6 = 2688 = 336k k = 8

11. In an box, there are 20 cards, out of which 10 are labelled as A and the remaining 10 are labelled as B.
Cards are drawn at random, one after the other and with replacement, till a second A-card is obtained.
The probability that the second A-card appears before the third B-card is :
13 15 9 11
(1) (2) (3) (4)
16 16 16 16
,d cDls esa 20 dkMZ gSA ftuesa ls 10 ij A vafdr fd;k x;lk gS rFkk 'ka"k 10 ij B vafdr fd;k x;k gSA cDls esa
ls ;kn`PN;k ,d ds ckn ,d (izfrLFkkiuk lfgr) dkMZ rc rd fd nwljk A ls vafdr dkMZ u vk tk,A nwljs A ls
vafdr dkMZ u vk tk,A nwljs A ls vafdr dkMZ ds rhljs B ls vafdr dkMZ ls igys vkus dh izfkdrk gS :
13 15 9 11
(1) (2) (3) (4)
16 16 16 16
Ans. (4)
1 1 1 1 1 1 11
Sol. AA + ABA + BAA + ABBA + BBAA + BABA =      
4 8 8 16 16 16 16

z 1 5
12. Let z be a complex number such that = 1 and z  . Then the value of |z + 3i| is :
z  2i 2

z 1 5
ekuk z ,d ,slh lfeJ la[;k gS] fd = 1 gS rFkk z  gS] rks |z + 3i| dk eku gS&
z  2i 2
7 15
(1) 10 (2) 2 3 (3) (4)
2 4
Ans. (3)
Sol. x2 + (y–1)2 = x2 + (y+2)2
–2y + 1 = 4y + 4
1
6y = –3  y = –
2

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25 24 i
x2 + y2 =  x2 = =6  z=± 6 –
4 4 2
25 49
|z + 3i| = 6 =
4 4
7
|z + 3i | =
2

13. If for some  and  in R, the intersection of the following three planes
x + 4y – 2z = 1
x + 7y – 5z = 
x + 5y + z = 5
is a line in R3, then  is equal to:
;fn R esa fdUgha  rFkk  ds fy,] fuEu rhu leryksa
x + 4y – 2z = 1
x + 7y – 5z = 
x + 5y + z = 5
dk izfrPNsnu] R3 esa ,d js[kk gS] rks  dk eku
(1) 0 (2) –10 (3) 10 (4) 2
Ans. (3)
1 4 –2
Sol. =0 1 7 –5 =0
1 5 
(7 + 25) – (4 + 10) + (–20 + 14) = 0
3 + 9 = 0   = – 3
1 4 1
Also rFkk Dz = 0  1 7  = 0
1 5 5
1(35 – 5) – (15) + 1 (4 –7) = 0
 = 13

14. The number of real roots of the equation, e4x + e3x – 4e2x + ex + 1 = 0 is :
lehdj.k e4x + e3x – 4e2x + ex + 1 = 0 ds okLrfod ewyksa dh la[;k gS&
(1) 3 (2) 1 (3) 4 (4) 2
Ans. (2)
Sol. Let ex = t  (0, )
Given equation nh xbZ lehdj.k
t4 + t3 – 4t2 + t + 1 = 0
1 1
t2 + t – 4 + + =0
t t2
 2 1   1
t   + t   – 4 = 0
 
 t2   t

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1
Let t + =
t
(2 – 2) +  – 4 = 0
2 +  – 6 = 0
2 +  – 6 = 0
 = – 3, 2  =2  ex + e–x = 2
x = 0 only solution

15. Let f be any function continuous on [a, b] and twice differentiable on (a, b). If for all x  (a, b), f'(x) > 0
f (c )  f (a )
and f"(x) < 0, then for any c  (a, b), is greater than
f (b)  f (c )
ekuk f dksbZ Qyu gS tks fd [a, b] esa larr rFkk (a, b) esa nks ckj vodyuh; gSA ;fn lHkh x  (a, b) ds fy,
f (c )  f (a )
f'(x) > 0 rFkk f"(x) < 0 gSa] rks fdlh Hkh c  (a, b), fuEu esa ls fdlls cM+k gS ?
f (b)  f (c )
bc c a ba
(1) 1 (2) (3) (4)
c a bc ba
Ans. (3)
Sol. Lets use LMVT for x [a,c]
f (c ) – f (a )
= f'() ,   (a,c)
c–a
also use LMVT for x  [c,b]
f (b) – f (c )
= f'() ,   (c,b)
b–c
 f ''(x) < 0  f '(x) is decreasing
f '() > f '()
f (c ) – f (a ) f (b) – f (c )
>
c–a b–c
f (c ) – f (a ) c–a
> ( f(x) is increasing)
f (b) – f (c ) b–c

Hindi. LMVT dk mi;ksx djus ij x [a,c] ds fy;s


f (c ) – f (a )
= f'() ,   (a,c)
c–a
LMVT dk mi;ksx djus ij x  [c,b] ds fy;s
f (b) – f (c )
= f'() ,   (c,b)  f ''(x) < 0  f '(x) âkleku gS
b–c
f '() > f '()
f (c ) – f (a ) f (b) – f (c )
>
c–a b–c
f (c ) – f (a ) c–a
> ( f(x) o/kZeku gS)
f (b) – f (c ) b–c

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1
16. If for all real triplets (a, b, c), f(x) = a + bx + cx2 ; then  f ( x) dx is equal to :
0
1
;fn lHkh okLrfod f=kdksa (a, b, c) ds fy,, f(x) = a + bx + cx2 gS] rks  f ( x ) dx cjkcj gS&
0

1  1  1  1 
(1) f (0)  f   (2) f (1)  3f  
3  2  3  2 
1  1    1 
(3) f (0)  f (1)  4f   (4) 23f (1)  2f  
6  2    2 

Ans. (3)
1

 
1 bx 2 cx 3 b c
Sol. a  bx  cx dx = ax +
2
+ =a+ +
0 2 3 2 3
0

f(1) = a + b + c
f(0) = a
 1 b C
f  = a + +
2 2 4
  1    b c 
Now
1
 f 1  f 0  4f    =
1
 a  b  c  a  4 a     =
1
6a  3b  2c  = a + b + c
6   2  6   2 4  6 2 3

10 10
17. Let the observations xi(1  I  10) satisfy the equations, i1
( x i  5)  10 and  ( x  5)
i1
i
2
 40 . If  and

 are the mean and the variance of the observations, x 1 – 3, x2 – 3, …… x10 – 3, then the ordered pair
() is equal to :
10 10
ekuk izs{k.k xi(1  I  10) lehdj.kksa  ( x  5)  10 rFkk  (x  5)
i1
i
i1
i
2
 40 dk larq"V djrs gSA ;fn  rFkk 

izs{k.kksa x1 – 3, x2 – 3, …… x10 – 3 ds Øe'k% ek/; rFkk izlj.k gSa] rks Øfer ;qXe () cjkcj gS&
(1) (3, 3) (2) (3, 6) (3) (6, 6) (4) (6, 3)

Ans. (1)
x i – 5
Sol. Mean ek/; (xi – 5) = 1   = {Mean ek/; (xi – 5)} + 2 = 3
10
xi – 5 xi – 5
2
 = var pfjrk (xi – 5) = – 3
10 10

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x2 y2 x2 y2
18. If e1 and e2 are the eccentricities of the ellipse,   1 and the hyperbola,  1
18 4 9 4
respectively and (e1, e2) is a point on the ellipse, 15x2 + 3y2 = k, then k is equal to
x2 y2 x2 y2
;fn e1 rFkk e2 Øe'k% nh?kZo`Ùk   1 rFkk vfrijoy;   1 dh mRdsanzrk,¡ gS rFkk (e1, e2) nh?kZo`Ùk
18 4 9 4
15x2 + 3y2 = k ij fLFkr ,d fcUnq gSa, rks k dk eku gS&

(1) 14 (2) 15 (3) 16 (4) 17


Ans. (3)
4 7 7
Sol. e1 = 1 = =
18 9 3
4 13 13
e2 = 1 = =
9 9 3
 7   13 
15e12  3e22  k  k = 15    3   k = 16
9  9 

19. Let C be the centroid of the triangle with vertices (3, –1), (1, 3) and (2, 4). Let P be the point of
intersection of the lines x + 3y – 1 = 0 and 3x – y + 1 = 0. Then the line passing through the points C
and P also passes through the point
ekuk 'kh"kks± (3, –1), (1, 3) rFkk (2, 4) okys f=kHkqt dk dsanzd C gSA ekuk js[kkvksa x + 3y – 1 = 0 rFkk 3x – y + 1 = 0
dk izfrPNsnu fcUnq P gS] rks fcUnqvksa C rFkk P ls xqtjus okyh js[kk] fuEu esa ls fdl fcUnq ls Hkh xqtjrh gSA
(1) (7, 6) (2) (–9, –7) (3) (9, 7) (4) (–9, –6)
Ans. (4)
Sol. D (2,2)
 1 2
Point of intersection P  – , 
 5 5
equation of line DP
8x – 11y + 6 = 0
Sol. D (2,2)

izfrPNsn fcUnq P  – , 
1 2
 5 5
js[kk DP dk lehdj.k 8x – 11y + 6 = 0

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 sin(a  2)x  sin x


 ; x0
 x
20. If f(x) =  b ; x0
 ( x  3 x 2 )1/ 3  x1/ 3
 ; x0
 x4 / 3
is continuous at x = 0, then a + 2b is equal to :
 sin(a  2)x  sin x
 ; x0
x
;fn f(x) =  b ; x0
 ( x  3 x 2 )1/ 3  x1/ 3
 ; x0
 x4 / 3
x = 0 ij larr gSa, rks a + 2b dk eku gS&
(1) 1 (2) 0 (3) –2 (4) –1
Ans. (2)
Sol. LHL = a + 3
f(0) = b
 1 
 1  3h3 – 1 
RHL = lim 
h0 
 1
h 
 
 a = –2
b=1
 a + 2b = 0

SECTION – 2 : (Maximum Marks : 20)


 This section contains FIVE (05) questions. The answer to each question is NUMERICAL VALUE with two
digit integer and decimal upto one digit.
 If the numerical value has more than two decimal places truncate/round-off the value upto TWO decimal
places.
 Full Marks : +4 If ONLY the correct option is chosen.
 Zero Marks : 0 In all other cases
[kaM 2 ¼vf/kdre vad% 20)
 bl [kaM esa ik¡p (05) iz'u gSA izR;sd iz'u dk mÙkj la[;kRed eku (NUMERICAL VALUE) gSa] tks f}&vadh; iw.kkZad
rFkk n'keyo ,dy&vadu eas gSA
 ;fn la[;kRed eku esa nks ls vf/kd n’'keyo LFkku gS ] rks la[;kRed eku dks n'keyo ds nks LFkkuksa rd VªadsV@jkmaM
vkWQ (truncate/round-off) djsaA
 vadu ;kstuk :
 iw.kZ vad % +4 ;fn flQZ lgh fodYi gh pquk x;k gSA
 'kwU; vad % 0 vU; lHkh ifjfLFkfr;ksa esaA

21. The number of distinct solutions of the equation, log1/2|sinx| = 2 – log1/2 |cosx| in the interval [0, 2], is
lehdj.k, log1/2|sinx| = 2 – log1/2 |cosx| ds varjky [0, 2] esa fHkUu gyksa dh la[;k gS
Ans. 8
Sol. log1/2 |sinx| = 2 – log1/2 |cosx|
log1/2 |sinx cosx| = 2

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1
|sinx cosx| =
4
1
sin2x = ±
2

1
2

1  2

2

Number of solution gyksa dh la[;k = 8.

22. The projection of the line segment joining the points (1, –1, 3) and (2, –4, 11) on the line joining the
points (–1, 2, 3) and (3, –2, 10) is :
fcUnqvksa (1, –1, 3) rFkk (2, –4, 11) dks feykus okys js[kk[k.M dk fcUnqvksa (–1, 2, 3) rFkk (3, –2, 10) dks feykus
okyh js[kk ij iz{ksi gS
Ans. (8)
Sol. Let A(1, –1, 3), B(2, –4, 11)
AB  î  3 ĵ  8k̂
C(–1, 2, 3), D(3, –2, 10)
CD  4 î  4 ĵ  7k̂

AB . CD  4  12  56  72
projection of AB on CD = =  
 8
| CD |  16  16  49  9

23. The coefficient of x4 in the expansion of (1 + x + x2)10 is…


(1 + x + x2)10 ds izlkj esa x4 dk xq.kkad gS
Ans. 615
10!
Sol. General term egÙke in x+2
! ! !
for coefficient of x4 dk xq.kkad   + 2 = 4
10!
 = 0,  = 4 ,  = 6  = 210
6!4!0!
10!
 = 1,  =2,  = 7  = 360
7!2!1!
10!
 = 2,  = 0,  = 8  = 45
8!0!2!
Total dqy= 615

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24. If for x  0, y = y(x) is the solution of the differential equation,


(x + 1)dy = {(x + 1)2 + y – 3}dx, y(2) = 0, then y(3) is equal to :
;fn x  0 ds fy, y = y(x), vody lehdj.k
(x + 1)dy = {(x + 1)2 + y – 3}dx, y(2) = 0, dk gy gS] rks y(3) dk eku gS
Ans. (3)
 y3
 1  x   
dy
Sol. 
dx  1 x 

y  1  x  
dy 1 3

dx 1  x  1  x 
1
 dx d  y 
I.F. = e 1 x 
1 3
     1
1  x  dx  1  x  1  x 2
 x  31  x  + c
y 1
1 x
 3 
y = (1+x)  x   c   at x = 2, y = 0 0 = 3 (2+1+c) c = –3 at x = 3 , y=3
 1  x  
  
25. if the vectors, p  (a  1) î  aĵ  ak̂, q  a î  (a  1) ĵ  ak̂ and r  a î  aĵ  (a  1)k̂, (a  R) are coplanar
   
and 3(p. q)2   | r  q |2  0 , then the value of  is :
  
;fn lfn'k p  (a  1) î  aĵ  ak̂, q  a î  (a  1) ĵ  ak̂ rFkk r  a î  aĵ  (a  1)k̂, (a  R) leryh; gSa rFkk
   
3(p. q)2   | r  q |2  0 gS] rks  dk eku gS&
Ans. 1
a 1 a a
1
Sol. a a 1 a = 0  a + 1 + a + a = 0 a=–
3
a a a 1
 2 1 1
P = î – ĵ – k̂
3 3 3
 1
Q = (– î  2 ĵ – k̂ )
3
 1
R = (– î – ĵ  2k̂ )
3
  1 1
P.Q = (– 2 – 2 + 1) = –
9 3
i j k
  1 1 1 i jk
R × Q = – 1 2 – 1 = (i(4 – 1) – j(–2 – 1) + k (1 + 2)) = (3i + 3j + 3k) =
9 9 9 3
–1 –1 2
  1  2 1    2
RQ = 3  RQ = 3( P.Q )2 –  R  Q = 0
3 3
1 1
3. – . = 0   = 1
9 3

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PAPER-1 (B.E./B. TECH.)

JEE (Main) 2020


COMPUTER BASED TEST (CBT)
Memory Based Questions & Solutions
Date: 09 January, 2020 (SHIFT-1) | TIME : (9.30 a.m. to 12.30 p.m)

Duration: 3 Hours | Max. Marks: 300


SUBJECT: PHYSICS

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PART : PHYSICS

Single Choice Type (,dy fodYih; izdkj)

This section contains 20 Single choice questions. Each question has 4 choices (1), (2), (3) and (4) for its
answer, out of which Only One is correct.
bl [k.M esa 20 ,dy fodYih iz'u gSaA izR;sd iz'u ds 4 fodYi (1), (2), (3) rFkk (4) gSa] ftuesa ls flQZ ,d lgh gSA

1. Kinetic energy of the particle is E and it's De–Broglie wavelength is . On increasing it's KE by E, it's

new De–Broglie wavelength becomes . Then E is
2
,d d.k ftldh xfrt ÅtkZ E rFkk Mh&czkXyh rjaxnS/;Z  gSA bldh xftt ÅtkZ esa E dh o`f) djus ij mldh

u;h Mh&czksXyh rjaxnS/;Z gks tkrh gSA rc E gksxk&
2
(1) 3E (2) E (3) 2E (4) 4E
Ans. (1)
h 1
Sol. =  
2(KE)m KE

 KE f
=
/2 KEi

4KEi = KEf
 E = 4KEi – KEi = 3KE = 3E

hc 5
2. The dimensional formula of is
G

hc 5
dk foeh; lw=k gksxk&
G

(1) Momentum (2) Energy (3) Force (4) Pressure


(1) laosx (2) ÅtkZ (3) cy (4) nkc
Ans. (2)
Sol. [ML2T–2]
[hc] = [ML3T–2]
[c] = [LT–1]
[G] = [M–1L3T–2]

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3. Two immiscible liquids of refractive index 2 and 2 2 are filled with equal height h in a vessel. Then
apparent depth of bottom surface of the container given that outside medium is air:

nks v?kqyu'khy nzo ftudk viorZukad 2 rFkk 2 2 gS] dks ,d ik=k esa leku h Å¡pkbZ rd Hkjk tkrk gSA rc gok

ls crZu ds isans dks ns[kus ij mldh vkHkklh Å¡pkbZ gksxh&

3 2h 3h 3h 3h
(1) (2) (3) (4)
4 4 2 4 2
Ans. (1)
Sol.

1 = 2 h

2 = 2 2 h

h h h 3 3 2h
d=  d=  =
2 2 2 2 2 4

4. Three identical solid spheres each having mass 'm' and diameter 'd' are touching each other as shown
in figure. Calculate ratio of moment of inertia about an axis (perpendicular to plane of paper) passing
through point P and B as shown in figure. Given P is centroid of triangle ABC.
fn;s x;s fp=k vuqlkj rhu ,d leku Bksl xksys ftudk nzO;eku 'm' rFkk O;kl 'd' gS] dks ,d nwljs ds lEidZ esa j[kk
tkrk gSA rks iznf'kZr fcUnq P rFkk B ls xqtjus okyh v{k ¼ry ds yEcor~½ ds lkis{k tM+Ro vk?kwZ.k dk vuqikr D;k
gksxk ¼fn;k gS % fcUnq P, ABC dk dsUnzd gSA½

d
A B

(1) 13 / 23 (2) 11/19 (3) 7/9 (4) 13/11


Ans. (1)

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 2  d 2  d   13
2
Sol. M.I about P ds ifjr% tM+Ro vk?kq.kZ = 3  M    M   = Md2
 5  
2  3   10

 2  d 2 2 2  d
2
23
M.I about B ds ifjr% tM+Ro vk?kq.kZ = 2  M    M  d   M   = Md2
 5  2   5  2  10

13
Now ratio ¼vc vuqikr½ =
23

5. A solid sphere having radius R and Uniform charge density has a cavity of radius R/2 as shown in

EA
figure. Find the ratio of magnitude of electric field at point A and B i.e. .
EB

fp=kkuqlkj ,d Bksl xksyk ftldh f=kT;k R rFkk ml ij ,d leku vkos'k ?kuRo gSA blds vUnj R/2 f=kT;k dh
EA
xqgk gS] rc fcUnq A rFkk B ij fo|qr {ks=kkssa ds ifjek.k esa vuqikr dk eku gksxk&
EB

B
A R/2
R/2
R

18 11 9 9
(1) (2) (3) (4)
19 17 17 19
Ans. (3)
Sol. For a solid sphere Bksl xksys ds fy,

r
E=
3 0

R
EA =
2(3 0 )

R
EA 
6 0

Electric field at point ¼fcUnq B ij fo|qr {ks=k dh rhozrk½ B = EB = E1A + E2A

R
E1A = Electric Field Due to solid sphere of radius R at point B =
3 0

R
E1A = R f=kT;k ds Bksl xksys ds dkj.k fcUnq B ij fo|qr {ks=k dh rhozrk =
3 0

E2A = Electric Field Due to solid sphere of radius R/2 (which having charge density –)

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E2A = R/2 f=kT;k ds Bksl xksys (ftldk vkos'k ?kuRo –gS) ds dkj.k fcUnq B ij fo|qr {ks=k dh rhozrk

KQ
' 4 R
=– =–
9R 2 54 0

R R 17R
EB = E1A + E2A = – =
3 0 54 0 54 0

EA 9

EB 17

6. Consider an infinitely long current carrying cylindrical straight wire having radius 'a'. Then the ratio of
a
magnetic field at distance and 2a from axis of wire is.
3
a
,d vUkUr yEcs /kkjkokgh csyukdkj lh/ks rkj fd f=kT;k 'a' gSA rc v{k ls rFkk 2a nwjh ij pqEcdh; {ks=k dk
3

vuqikr gksxk&
3 2 1 4
(1) (2) (3) (4)
5 3 2 3
Ans. (2)
Sol.

A
a/3
B
2a

a
 0i
 0ir 3 =  0 i a =  0i
BA = =
2a 2 2a 2 a 2 6 6a

 0i
BB =
2(2a)

BA 4 2
= =
BB 6 3

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7. Find current in the wire BC.

rkj BC esa /kkjk Kkr djks&

1 B 2

4 C 3

20

(1) 1.6A (2) 2A (3) 2.4A (4) 3A

Ans. (2)

Sol.

1 2
4i/5 B 3i/5



i i/5 4 C 2i/5 3

20

4 6
Reff =  = 2
5 5

20
i=
2

= 10A

4i 3i i
I= –   = 2A
5 5 5

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8. Two electromagnetic waves are moving in free space whose electric field vectors are given by
  
E1  E0 ĵ cos( kx  t ) & E2  E0k̂ cos( ky  t ) . A charge q is moving with velocity v = 0.8 c ĵ . Find the

net Lorentz force on this charge at t = 0 and when it is at origin.



eqDr vkdk'k esa nks fo|qr pqEcdh; rajxsa xfr dj jgha gSA ftuds fo|qr {ks=k Øe'k% E1  E0 ĵ cos( kx  t ) vkSj
 
E2  E0k̂ cos( ky  t ) ds vuqlkj fn;k x;k gSA ,d vkos'k q osx v = 0.8 c ĵ ls xfr dj jgk gSA tc ;g vkos'k

ij t = 0 rFkk ewyfcUnq ij gksrk gS] rc bl ij dqy ykWjsUt cy gksxkA

(1) qE0 (0.4 î  0.2 ĵ  0.2k̂ ) (2) qE0 (0.8 î  ĵ  0.2k̂ )

(3) qE0 (0.6 î  ĵ  0.2k̂ ) (4) qE0 (0.8 î  ĵ  k̂ )

Ans. (2)

Sol. Magnetic field vectors associated with this electromagnetic wave are given by

fo|qr pqEcdh; rjax ds laxr pqEcdh; {ks=k lfn'k

 E  E
B1  0 k̂ cos (kx – t) & B 2  0 î cos (ky – t)
c c
   
F  qE  q( V  B)

    
 q(E1  E2 )  q( V  (B1  B2 ))

   
by putting the value of E1 , E 2 , B1 & B 2 ds eku j[kus ij

The net Lorentz force on the charged particle is vkosf'kr d.k ij dqy yksjast cy



F  qE0 0.8 cos( kx  t )î  cos( kx  t ) ĵ  0.2 cos( ky  t )k̂ 
at t = 0 and at x = y = 0

t = 0 rFkk x = y = 0 ij


F  qE0 [0.8 î  ĵ  0.2k̂]

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9. Two ideal di-atomic gases A and B. A is rigid, B has an extra degree of freedom due to vibration. Mass

m
of A is m and mass of B is . The ratio of molar specific heat of A to B at constant volume is :
4

nks f}ijek.kq vkn'kZ xSl A rFkk B gSA A n`M+ gSA rFkk B dEiu dh otg ls vfrfjDr Lora=krk dh dksfV j[krh gSA A

m
dk nzO;eku m vkSj B dk nzO;eku gSA rc fu;r vk;ru ij A dk B ls eksyj fof'k"V Å"ek dk vuqikr gksxkA
4

7 5 5 5
(1) (2) (3) (4)
9 9 11 7

Ans. (4)
5R
Sol. Molar heat capacity of A at constant volume =
2
5R
A dh eksyj fof'k"V Å"ek /kkfjrk fu;r vk;ru ij =
2
7R
Molar heat capacity of B at constant volume =
2
7R
B dh eksyj fof'k"V Å"ek /kkfjrk fu;r vk;ru ij =
2
(C v ) A 5
Dividing both Hkkx nsus ij, 
(C v )B 7

10. An ideal liquid (water) flowing through a tube of non uniform cross section area at A and B are 40 cm 2
and 20 cm2 respectively. If pressure difference between A & B is 700 N/m2 then volume flow rate is :
,d vkn'kZ nzOk (ikuh), ,d vleku {ks=kQy dh uyhdk ls cg jgk gS ftldk A rFkk B ij {ks=kQy Øe'k% 40 cm2
rFkk 20 cm2 gSA ;fn A vksj B ds chp esa nkc dk vUrj 700 N/m2 gS] rks vk;ru izokg nj crkb;s &

(1) 2732 cm3 /s (2) 2142 cm3/s (3) 1832 cm3/s (4) 3218 cm3/s
Ans. (1)

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Sol. using equation of continuity lkaR;rk dh lehdj.k ls

40 VA = 20 VB

  2VA = VB

Using Bernoullies equation cjuksyh lehdj.k ls

1 2 1
PA + VA = PB + VB2
2 2

1
 PA – PB = ( VB2  VA2 )
2

1  V2 
 P = 1000 VB2  B 
2  4 

3 VB2
 P = 500 ×
4

( P)  4 (700)  4
 VB = = m/s
1500 1500

Volume flow rate vk;ru izokg nj = 20 × 100 × VB = 2732 cm3/s

11. A screw gauge advances by 3mm in 6 rotations. There are 50 divisions on circular scale. Find least

count of screw gauge ?

,d LØw xst 6 pØ.k ij 3mm vkxs c<+rk gSA o`Ùkh; iSekus ij 50 Hkkx gSA LØw xst dk vYirekad Kkr djks&

(1) 0.002 cm (2) 0.001 cm

(3) 0.01 cm (4) 0.02 cm

Ans. (2)

3
Sol. Pitch fip = = 0.5 mm
6

0.5 mm 1
L.C. = = mm = 0.01 mm = 0.001 cm
50 100

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12. A telescope of aperture diameter 5m is used to observe the moon from the earth. Distance between the

moon and earth is 4 × 105 km. Determine the minimum distance between two points on the moon's

surface which can be resolved using this telescope. (Wave length of light is 5893 Å.

5m O;kl ds }kjd ;qDr nwjn'khZ dk iz;ksx i`Foh ls pUnzek dks ns[kus ds fy, djrs gSA i`Foh rFkk pUnzek ds e/; nwjh

4 × 105 km gSA nwjn'khZ dh lgk;rk ls pUnzek ij foHksfnr fd;s tk ldus okys nks fcUnqvksa ds e/; U;wure nwjh

yxHkx fdruh gksxh ¼ izdk'k dh rjaxnS/;Z 5893 Å gSA½

(1) 60 m (2) 20 m (3) 600 m (4) 200 m

Ans. (1)

Sol.


 = 1.22
a

distance nwjh = O1O2 = d


= 1.22 d
a

1.22  5893 1010  4  108


distance nwjh = O1O2 =  57.5 m
5

 answer from options fodYiks ds vk/kkj ij mÙkj = 60m

(minimum distance U;wure nwjh)

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13. A particle of mass m is revolving around a planet in a circular orbit of radius R. At the instant the particle

 m V
has velocity V , another particle of mass moving at velocity collides perfectly in-elastically with
2 2
the first particle. The new path of the combined body will take is
(1) Circular (2) Elliptical
(3) Straight line (4) Fall directly below on the ground
m nzO;eku dk d.k ,d xzg ds pkjks vksj R f=kT;k dh o`Ùkkdkj d{kk esa pDdj yxk jgk gSA bl le; d.k dk osx

 m V
V gSA nzO;eku dk vU; d.k osx ls xfr djrk gqvk igys d.k ls iw.kZ vizR;kLFk VDdj djrk gSA la;qDr
2 2
oLrq dk u;k iFk gksxk &
(1) o`Ùkkdkj (2) nh?kZo`Ùkkdkj

(3) ljy js[kk (4) lh/kk uhps dh rjQ tehu ij fxj tk;sxk

Ans. (2)
Sol. Conserving momentum laosx laj{k.k ls:

m v  m
+ mv =  m   v f
2 2  2

5mV 5V
vf = =
3m 6
4
2
vf < vorb (= v) thus the combined mass will go on to an elliptical path
vf < vorb (= v) vr% la;qDr nzO;eku nh?kZo`Ùkkdkj iFk ij xfr djsxkA

  v v
14. Two particles of same mass 'm' moving with velocities v 1 = v î and v 2 = î  ĵ collide in-elastically.
2 2

Find the loss in kinetic energy.

  v v
leku nzO;eku 'm' ds nks xfr'khy d.kks ds osx Øe'k% v 1 = v î rFkk v 2 = î  ĵ gSA nksuksa vizR;kLFk :i ls
2 2

Vdjkrs gSA xfrt ÅtkZ esa gkfu Kkr djks&

mv 2 5mv 2 mv 2 3mv 2
(1) (2) (3) (4)
8 8 4 8

Ans. (1)

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Sol. Conserving momentum laosx lja{k.k ls

v v 
mv î + m  î  ĵ  = 2m (v1î  v 2 ĵ)
 2 2 

on solving gy djus ij

3v v
v1 = and v 2 =
4 4

Change in K.E. xfrt ÅtkZ esa ifjorZu

1 1 v  
2 1  9v 2 v 2  
 mv 2  m 2   –  (2m)  
 2 2 2    2  16 16 
 

3mv 2 5mv 2 mv 2
= – =
4 8 8

 
15. Three waves of same intensity (I0) having initial phases 0, , rad respectively interfere at a point.
4 4

Find the resultant Intensity

 
leku rhozrk (I0) dh rhu rjaxksa dh izkjfEHkd dyk Øe'k% 0, , jsMh;u gSA rhuksa ,d fcUnq ij O;frdj.k mRiUu
4 4

djrh gSA budh ifj.kkeh rhozrk Kkr djksA

(1) I0 (2) 0 (3) 5.8 I0 (4) 0.2 I0

Ans. (3)

) /4 A
Sol. )
/4

Ares =  2  1A
Ires = 2  1 I 2
0

= 3  2 2  I = 5.8 I
0 0s

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16. Particle moves from point A to point B along the line shown in figure under the action of force.
 
F  x î  yĵ . Determine the work done on the particle by F in moving the particle from point A to point B.

,d d.k fcUnq A ls B rd fp=kkuqlkj ,d js[kk ds vuqfn'k cy F  x î  yĵ ds izHkko esa xfr djrk gSA rc d.k dks

fcUnq A ls B rd xfr djkus ds fy, cy F }kjk fd;k x;k dk;Z gksxkA
y

B (0, 1)

x
A (1, 0)

1
(A) 1J (2) J (3) 2J (4) 3J
2
Ans. (1)
 
Sol. W  F. ds
= (x î  yĵ).(dxî  dyĵ)
0 1
= 
1
 xdx  ydy0
0 1
x2 y2  1  1
=   =  0      = 1J
2
1
2
0
 2 2

17. For the given P-V graph for an ideal gas, chose the correct V- T graph. Process BC is adiabatic.
,d vkn'kZ xSl dk P-V xzkQ fn;k x;k gSA rc lgh V-T xzkQ D;k gksxkA izØe BC :)kss"e gSA
P
B

A C
V
V V C
C

(1) (2)
A A
B
B
T T
V V
C B

(3) (4)
A B A C

T T

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Ans. (1)
Sol. For process A – B izØe ds fy,; Volume is constant vk;ru fu;r gS;

PV = nRT ; as P increases cM+rk gS; T increases cM+rk gS

For process B – C izØe ds fy,;

PV = Constant fu;r;

 TV–1 = Constant fu;r

For process C – A izØe ds fy,; pressure is constant nkc fu;r gS

V = kT

  
18. Given p   î  3 ĵ  2k̂ and r  î  3 ĵ  5k̂ . Find vector parallel to electric field at position r
 
[Note that p . r  0 ]
  
fn;k gS f}/kzqo p   î  3 ĵ  2k̂ vkSj r  î  3 ĵ  5k̂ rc fLFkfr r ij fo|qr {ks=k ds lekUrj lfn'k Kkr djksA
 
[fn;k gS p . r  0 ]

(1) î  3 ĵ  2k̂ (2) 3 î  ĵ  2k̂ (3)  3 î  ĵ  2k̂ (4)  î  3 ĵ  2k̂


Ans. (1)
 
Sol. Since p . r  0
 
E must be antiparallel to p
 
E , p ds izfrlekUrj gksxk
 
So , E  (p)

where  is a arbitrary positive constant


tgk¡ dksbZ ,d /kukRed fu;rkad gS

Now A = a î  bĵ  ck̂

vc A = a î  bĵ  ck̂
 
A || E

a b c
  k
 3  2

so blfy, A  k( î  3 ĵ  2k̂ )

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19. Which of the following statements are correct for moving charge as shown in figure.
fn;s x;s fp=k esa xfr'khy vkos'k ds fy;s uhps fn;k x;k dkSulk dFku lR; gS&
y B0
q E0
A v

a
q
x
B
2a
2v

3  mv 2 
(A) Magnitude of electric field E0 
4  qa 

3 mv 3
(B) Rate of work done at point A is
4 a
(C) Rate of work done by both fields at point B is zero.
(D) Change in angular momentum w.r.t. origin is 2maV

3  mv 2 
(A) fo|qr {ks=k dk ifjek.k E0 
4  qa 

3 mv 3
(B) fcUnq A ij dk;Z dh nj
4 a

(C) nksuks {ks=kksa }kjk fcUnq B ij dk;Z dh nj 'kwU; gSA

(D) ewy fcUnq ds ifjr% dks.kh; laosx esa ifjorZu 2maV gSA

(1) A, B, C are correct (lgh gS)

(2) A, B, C, D are correct (lgh gS)

(3) A, B are correct (lgh gS)

(4) B, C, D are correct. (lgh gS)

Ans. (1)
Sol. (A) by work energy theorem dk;Z ÅtkZ izse; ls
1 1
W mag + W ele = m(2v )2  m( v )2
2 2
3
0 + qE02a= mv 2
2

3 mv 2
E0 =
4 qa

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(B) Rate of work done at A = power of electric force


A ij dk;Z dh nj = fo|qr cy dh 'kfDr

= qE0V

3 mv 3
=
4 a
dw
(C) at B,  0 for both forces
dt
dw
B ij,  0 , nksuksa cyks ds fy;s
dt

(D) L  (m2v2ak̂ )  (mvak̂ )

L  3mva

20. Photons of wavelength 6556 Å falls on a metal surface. If ejected electrons with maximum K.E. moves
in magnetic field of 3 × 10–4 T in circular orbit of radius 10–2m, then work function of metal surface is
,d /kkfRod lrg ij rjaxnS/;Z 6556 Å dk ,d QksVkWu vkifrr gSA ;fn mRlftZr bysDVªkWu ftldh vf/kdre xfrt
ÅtkZ gS] ,d pqEcdh; {ks=k 3 × 10–4 T esa ftldh f=kT;k 10–2m ds o`Ùkkdkj d{k esa xfr djrk gSA rc /kkfRod lrg
dk dk;ZQyu Kkr djks &
(1) 1.8 eV (2) 0.8 eV (3) 1.1 eV (4) 1.4 eV
Ans. (3)
Sol. KEmax = E – 
12400
= – (in eV)
(in Å )

2mKE
r=
eB

r 2 e 2B 2
KEmax = (in J)
2m

r 2 eB2
= (in eV)
2m

12400 r 2 eB2
= –
6556 2m
= 1.1 eV

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Numerical Value Type (la[;kRed izdkj)

This section contains 5 Numerical value type questions.


bl [k.M esa 5 la[;kRed izdkj ds iz'u gSaA

21. A rod of length 1 m is released from rest as shown in the figure below.
fn;s x;s fp=kkuqlkj 1 m yEch NM+ dks fojke ls NksM+k tkrk gS

 = 1m

30°
s

If of rod is n at the moment it hits the ground, then find n.

tc NM+ /kjkry ls Vdjkrh gS rc mldk dksf.k; osx  n gSA rc n dk eku gksxkA
Ans. 15

 1 m 2 2
Sol. mg sin 30  
2 2 3
Solving
2 = 15

  15

22. If reversible voltage of 100 V is applied across an inductor, current in it reduces from 0.25A to 0A in

0.025ms. Find inductance of inductor (in mH).

,d izsjDro ds fljksa ij 100 V dk izfrorhZ foHko yxk;k tkrk gSA ;fn /kkjk 0.25A ls 0A rd 0.025ms eas de

gksrh gSA rc izsjdRo dk LoiszjdRo (mH esa) gksxhA

Ans. 10

L(0.25)
Sol. 100 =  103
0.025

 L = 100 × 10–4 H

= 10 mH

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23. A wire of length  = 3m and area of cross section 10–2cm2 and breaking stress 48×107N/m2 is attached
with block of mass 10kg. Find the maximum possible value of angular velocity with which block can be
moved in circle with string fixed at one end.
,d rkj ftldh yEckbZ  = 3m rFkk vuqizLFk dkV dk {ks=kQy 10–2cm2 gS rFkk Hkatu izfrcy 48×107N/m2 gSA
blls ,d 10kg nzO;eku dk xqVdk tqM+k gqvk gSA rc jLlh ds nwljs tM+or~ fljs ds ifjr% o`fÙk; xfr ds nkSjku
xqVds dk vf/kdre laHko dksf.k; osx D;k gks rkdh rkj VwVs ughaA
Ans. 4 rad/s

3m
10kg
Sol.
T
=   ..........(1)
A
T = m2 ..........(2)
Solving
 = 4 rad/s

24. Position of a particle as a function of time is given as x 2 = at2 + 2bt + c, where a, b, c are constants.
Acceleration of particle varies with x –n then value of n is.
,d d.k dh fLFkrh le; ds :i esa x2 = at2 + 2bt + c, ds vuqlkj fn xbZ gSA tgk¡ a, b, c fu;rkad gSA ;fn d.k dk
Roj.k x–n ds vuqlkj ifjorhZr gksrk gS rc n dk eku gksxkA
Ans. n=3
Sol. x2 = at2 + 2bt + c
2xv = 2at + 2b
xv = at + b
v2 + ax = a
2
 at  b 
ax = a   
 x 

a(at2  2bt  c )  (at  b)2


a
x3

ac  b2
a
x3
a x–3

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25. In the given circuit both diodes having zero forward resistance and built-in potential of 0.7 V. Find the
potential of point E in volts.
fn;s x;s ifjiFk esa nks Mk;ksM+] ftudk vxz vfHkurh izfrjks/k 'kwU; gS vkSj vojks/kh foHko 0.7 V gS rc fcUnq E dk foHko
oksYV esa gksxkA
A E C

Vin=12.7V Vin=4V

B F D
Ans. 12
Sol.
A E C
12.7 V 4V

B D

Let VB = 0
Right diode is reversed biased and left diode is forward biased
ekuk VB = 0
nka;k Mk;ksM+ Ik'p vfHkurh rFkk cka;k Mk;ksM+ vfHkurh esa gSA
 VE = 12.7 – 0.7
= 12 Volt

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