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Safety data sheet

according to 1907/2006/EC, Article 31

Issue date: 16.01.2018 Version number 1 Revision: 16.01.2018

1 Identification of the substance/mixture and of the company/undertaking

Product identifier

Trade name: GRF502

Relevant identified uses of the substance or mixture and uses advised against
No further relevant information available.
Application of the substance / the mixture Thermoplastic Conversion

Details of the supplier of the safety data sheet

Manufacturer/Supplier:
Mexichem Specialty Compounds Limited
Stephanie Works,
Chinley,
High Peak
SK23 6BT,
United Kingdom
MSCenquiries@mexichem.com

Further information obtainable from: Research and Development Laboratory

Emergency telephone number: During normal opening times: +44 1663 750 221

2 Hazards identification

Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008

GHS08 health hazard

Resp. Sens. 1 H334 May cause allergy or asthma symptoms or breathing difficulties if
inhaled.
Muta. 2 H341 Suspected of causing genetic defects.
(Contd. on page 2)
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Issue date: 16.01.2018 Version number 1 Revision: 16.01.2018

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(Contd. of page 1)

GHS07

Skin Sens. 1 H317 May cause an allergic skin reaction.

Label elements
Labelling according to Regulation (EC) No 1272/2008
The product is classified and labelled according to the CLP regulation.
Hazard pictograms

GHS08

Signal word Danger

Hazard-determining components of labelling:

FASCOM CW MAX Blowing agent
C,C'-azodi(formamide)
Hazard statements
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H317 May cause an allergic skin reaction.
H341 Suspected of causing genetic defects.
Precautionary statements
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P284 [In case of inadequate ventilation] wear respiratory protection.
P321 Specific treatment (see on this label).
(Contd. on page 3)
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Issue date: 16.01.2018 Version number 1 Revision: 16.01.2018

Trade name: GRF502

(Contd. of page 2)
P405 Store locked up.
P501 Dispose of contents/container in accordance with local/regional/national/
international regulations.
Other hazards
Results of PBT and vPvB assessment
PBT: Not applicable.
vPvB: Not applicable.

3 Composition/information on ingredients

Chemical characterisation: Mixtures

Description: Mixture of substances listed below with nonhazardous additions.

Hazardous components:
CAS: 9002-86-2 polyvinyl chloride >50-≤100%
substance with a Community workplace exposure limit
Methyl methacrylate and butyl acrylate copolymer >2.5-≤10%
substance with a Community workplace exposure limit
REAPAK B-LE/6010 >2.5-≤10%
Eye Irrit. 2, H319
FASCOM CW MAX Blowing agent ≤2.5%
Resp. Sens. 1, H334; Muta. 2, H341; Aquatic
Chronic 2, H411; Skin Sens. 1, H317
CAS: 123-77-3 C,C'-azodi(formamide) ≤2.5%
EINECS: 204-650-8 Resp. Sens. 1, H334
SVHC
123-77-3 C,C'-azodi(formamide)
(Contd. on page 4)
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Issue date: 16.01.2018 Version number 1 Revision: 16.01.2018

Trade name: GRF502

(Contd. of page 3)
Additional information:
For the wording of the listed hazard phrases refer to section 16.

4 First aid measures

Description of first aid measures

After inhalation:
Inhalation of vapours due to thermal decomposition:-
move to fresh air
oxygen or artifcial respiration if needed
consult a physcian
After skin contact:
After contact with the molten product, cool rapidly with cold water.
In case of adhesion, do not try to remove the product.
After eye contact:
Rinse opened eye for 15 minutes under running water, occasionally lifting the upper and
lower eyelids. Seek medical advice if irritation develops and persists.
After swallowing: If symptoms persist consult doctor.
Information for doctor:
Most important symptoms and effects, both acute and delayed
No further relevant information available.
Indication of any immediate medical attention and special treatment needed
No further relevant information available.
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Safety data sheet
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Issue date: 16.01.2018 Version number 1 Revision: 16.01.2018

Trade name: GRF502

(Contd. of page 4)

5 Firefighting measures

Extinguishing media
Suitable extinguishing agents:
Use fire extinguishing methods suitable to surrounding conditions.
Water spray
Special hazards arising from the substance or mixture
In case of fire, the following can be released:
Carbon monoxide (CO)
Hydrogen chloride (HCl)
Advice for firefighters
Wear self-contained breathing apparatus and protective suit (to protect skin and eyes).
In case of fire nearby, remove the bags
Protective equipment: No special measures required.

6 Accidental release measures

Personal precautions, protective equipment and emergency procedures

Sweep up to prevent hazard of slipping.
Normal standards of industrial hygiene should be observed.
Environmental precautions:
Do not allow to enter sewers/ surface or ground water.
Avoid release into the environment
Methods and material for containment and cleaning up:
Dispose of contaminated material as waste according to item 13.
Reference to other sections
See Section 7 for information on safe handling.
(Contd. on page 6)
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Issue date: 16.01.2018 Version number 1 Revision: 16.01.2018

Trade name: GRF502

(Contd. of page 5)
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.

7 Handling and storage

Handling:
Precautions for safe handling
Provide appropriate exhaust and ventilation at machinery.
Prevent formation of dust.
Take precautionary measures against static discharges.
Do not eat, drink or smoke whilst handling the material.
Observe normal standards of industrial hygiene when handling.
Avoid inhalation of vapours and contact with skin and eyes
Provide self-contained breathing apparatus nearby.
At all stages of the operation, do not exceed the temperature at which decomposition
into toxic and corrosive products will occur.
In case of unexpected or premature stoppage of mixing or conversion machines:
- Turn off the heat source
- Wear a self-contained breathing apparatus if necessary
- Remove the product.
Information about fire - and explosion protection:
Thermal decomposition of the product may release toxic or corrosive gases.

Conditions for safe storage, including any incompatibilities

Storage:
Store in clean dry well ventilated conditions at ambient temperatures.
Keep away from sources of ignition.
(Contd. on page 7)
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Safety data sheet
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Issue date: 16.01.2018 Version number 1 Revision: 16.01.2018

Trade name: GRF502

(Contd. of page 6)
Requirements to be met by storerooms and receptacles:
Store in clean dry well ventilated conditions at ambient temperatures.
Information about storage in one common storage facility: Not required.
Further information about storage conditions: None.
Specific end use(s) No further relevant information available.

8 Exposure controls/personal protection

Additional information about design of technical facilities:

No further data; see item 7.

Control parameters
Provide ventilation of the premises - dust or vapours likely to be given off during
conversion operations.
Ingredients with limit values that require monitoring at the workplace:
9002-86-2 polyvinyl chloride
WEL Long-term value: 10* 4** mg/m³
*inhalable dust **respirable dust
Methyl methacrylate and butyl acrylate copolymer
UK HSE EH40/2000 Long-term value: 10 mg/m³
(8-hour TWA reference period) Total Inhalable Dust
123-77-3 C,C'-azodi(formamide)
WEL Short-term value: 3.0 mg/m³
Long-term value: 1.0 mg/m³
Sen
Additional information:
(Contd. on page 8)
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Issue date: 16.01.2018 Version number 1 Revision: 16.01.2018

Trade name: GRF502

(Contd. of page 7)

Exposure controls
Personal protective equipment:
General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Wash hands before breaks and at the end of work.
Respiratory protection:
In case of brief exposure or low pollution use respiratory filter device. In case of
intensive or longer exposure use self-contained respiratory protective device.
Protection of hands:
The glove material has to be impermeable and resistant to the product/ the substance/
the preparation.
Due to missing tests no recommendation to the glove material can be given for the
product/ the preparation/ the chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of
diffusion and the degradation
Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on
further marks of quality and varies from manufacturer to manufacturer. As the product is
a preparation of several substances, the resistance of the glove material can not be
calculated in advance and has therefore to be checked prior to the application.
Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective
gloves and has to be observed.
Eye protection: Product handled while hot - wear safety glasses.
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(Contd. on page 9)

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Issue date: 16.01.2018 Version number 1 Revision: 16.01.2018

Trade name: GRF502

(Contd. of page 8)

9 Physical and chemical properties

Information on basic physical and chemical properties

General Information
Appearance:
Form: Granulate
Colour: Different according to colouring
Odour: Not available.
Odour threshold: Not determined.

pH-value: Not applicable.

Change in condition
Melting point/freezing point: 150 °C (approx)
Initial boiling point and boiling range: Undetermined.

Flash point: Not applicable.

Flammability (solid, gas): Not determined.

Decomposition temperature: Beginning to decompose above 200 °C

Auto-ignition temperature: Product is not selfigniting.

Explosive properties: Product does not present an explosion

hazard.
(Contd. on page 10)
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Trade name: GRF502

(Contd. of page 9)

Explosion limits:
Lower: Not determined.
Upper: Not determined.

Vapour pressure: Not applicable.

Density: Not determined.

Relative density Not determined.
Vapour density Not applicable.
Evaporation rate Not applicable.

Solubility in / Miscibility with

water: Insoluble.
organic solvents: Slightly soluble in:
- Cyclohexanone
- Dimethylsulphoxide
- Tetrahydrofuran

Partition coefficient: n-octanol/water: Not determined.

Viscosity:
Dynamic: Not applicable.
Kinematic: Not applicable.
Other information No further relevant information available.
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Trade name: GRF502

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10 Stability and reactivity

Reactivity No further relevant information available.

Chemical stability
Thermal decomposition / conditions to be avoided:
No decomposition if used according to specifications.
Store away from moisture and heat to maintain the technical properties of the product.
Keep at temperatures below 40°C
Avoid contact with acetal resins - possible violent reaction at elevated temperatures.
Possibility of hazardous reactions No dangerous reactions known.
Conditions to avoid No further relevant information available.
Incompatible materials: No further relevant information available.
Hazardous decomposition products:
Hydrochloric acid.
Carbon Oxides.

11 Toxicological information

Information on toxicological effects

Acute toxicity Based on available data, the classification criteria are not met.
Primary irritant effect:
Skin corrosion/irritation Based on available data, the classification criteria are not met.
Serious eye damage/irritation
Based on available data, the classification criteria are not met.
Respiratory or skin sensitisation
May cause allergy or asthma symptoms or breathing difficulties if inhaled.
(Contd. on page 12)
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(Contd. of page 11)

May cause an allergic skin reaction.
CMR effects (carcinogenity, mutagenicity and toxicity for reproduction)
Germ cell mutagenicity
Suspected of causing genetic defects.
Carcinogenicity Based on available data, the classification criteria are not met.
Reproductive toxicity Based on available data, the classification criteria are not met.
STOT-single exposure Based on available data, the classification criteria are not met.
STOT-repeated exposure
Based on available data, the classification criteria are not met.
Aspiration hazard Based on available data, the classification criteria are not met.

12 Ecological information

Toxicity
Aquatic toxicity: No further relevant information available.
Persistence and degradability No further relevant information available.
Behaviour in environmental systems:
Bioaccumulative potential No further relevant information available.
Mobility in soil No further relevant information available.
Other information: Not biodegradable on the basis of its structure.
Additional ecological information:
General notes:
Water hazard class 1 (German Regulation) (Self-assessment): slightly hazardous for
water
Do not allow undiluted product or large quantities of it to reach ground water, water
course or sewage system.
Results of PBT and vPvB assessment
PBT: Not applicable.
(Contd. on page 13)
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vPvB: Not applicable.
Other adverse effects No further relevant information available.

13 Disposal considerations

Waste treatment methods

Recommendation
Must not be disposed together with household waste. Do not allow product to reach
sewage system.
Must be disposed of or incinerated in accordance with local regulations.

Uncleaned packaging:
Recommendation: Disposal must be made according to official regulations.

14 Transport information

UN-Number
ADR, IMDG, IATA not regulated
UN proper shipping name
ADR, IMDG, IATA not regulated
Transport hazard class(es)

ADR, IMDG, IATA

Class not regulated
Packing group
ADR, IMDG, IATA not regulated
Environmental hazards: No
(Contd. on page 14)
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Special precautions for user Not applicable.
Transport in bulk according to Annex II
of Marpol and the IBC Code Not applicable.
UN "Model Regulation": not regulated

15 Regulatory information

Safety, health and environmental regulations/legislation specific for the

substance or mixture

Directive 2012/18/EU
Named dangerous substances - ANNEX I None of the ingredients is listed.

National regulations:

Other regulations, limitations and prohibitive regulations

Substances of very high concern (SVHC) according to REACH, Article 57
123-77-3 C,C'-azodi(formamide)
Chemical safety assessment:
A Chemical Safety Assessment has not been carried out.

16 Other information
This information is based on our present knowledge. However, this shall not constitute a
guarantee for any specific product features and shall not establish a legally valid
contractual relationship.
(Contd. on page 15)
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Trade name: GRF502

(Contd. of page 14)

Relevant phrases
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H341 Suspected of causing genetic defects.
H411 Toxic to aquatic life with long lasting effects.

Department issuing SDS: Research and Development Laboratory.

Contact: Mexichem Specialty Compounds Limited, Stephanie Works.
Abbreviations and acronyms:
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement
concerning the International Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
GHS: Globally Harmonised System of Classification and Labelling of Chemicals
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
PBT: Persistent, Bioaccumulative and Toxic
SVHC: Substances of Very High Concern
vPvB: very Persistent and very Bioaccumulative
Eye Irrit. 2: Serious eye damage/eye irritation – Category 2
Resp. Sens. 1: Respiratory sensitisation – Category 1
Skin Sens. 1: Skin sensitisation – Category 1
Muta. 2: Germ cell mutagenicity – Category 2
Aquatic Chronic 2: Hazardous to the aquatic environment - long-term aquatic hazard – Category 2
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