I "I I '

CHII!MISTRY
. ｜ｾ＠ ele<,tron """ "' ｬｩＭｯ･ｾ＠ ｾｬｯｮｧ＠ ｾ＠ >lrnoght d ｾ｡ＨＧｬ＠ ｾｮ､＠ MgO
ltnc 1m the ｾＭ､ｯｲ･｣ｴｷｮＩ＠ ofl..,gth 1 'J_ !>"'ng 5 Wh1ch ｯｮｾ＠ of ｴｨｾ＠ follo\\mg ln11lhamd«"
rc>stnoted '" the range '
ｾｲｯ｡ｮ､＠ state ""' o funclwn "
o to ' ' Its

'
,,,,.
colourle,; '1

r:;-: ' "-' -,

VI(<)-- .... "''""-- " '
<, I !
' Sm
Fu '
What o; the pmbahohr,. of fondmg the
el.,.;tnm at the rmd·JWn•t of !he hne 0 I• "1\"' ｴｬ＼Ｍｾ｡＠
2' I are on \·a"'
",, .J::. !I >< sunable for "'''""1
a rr-lxmd merlap
' ' '2
b
" ''
What" the rat1o of lhc ground smte "'"'rg_> '
<>fan cleoiMt mo< mg 1n He '"that <Jf nne
mo<mg m 1.1 !Pr.,.,-ume thai l><>lh bdm>e
hl.c h> dmgen lllll111) ·• ' " d""tmn fmm
MO< " must
0 ｾＬＧ｟｝＠

t> M
c I h/'1
d '!, I h
l \1mch ｌｾ＼ｴＭＱ＠

.'M'
"b ｉｩｾＢ＠ 2K·. 107" ｾｘ＠ - 1)[1'

11!4'- 27' IIYY' 2R _!W' .llr

"' ll,., ' 1"4' 2T lllr4X - ｸＮｾﾷ＠
II,.,
0 ll,.,. "
What IS ｴｨｾ＠
J<r
gromell' of nmogen awm m
Nil '· :--;(( lh)3 ;md N(S!(('H d,h ｭｯｬ･ｾｵＮＬ［＠
L«l -11
a Tn_gonal planar mall three cas"'
b lng<••al p>mm1dnl m allihrec '"""'
c lngonal p>r01rud!ll m NH; und
ｾＨＧｈＬＩ＠ "h1k ＱｮｧｯｾＡ＠ planar 10
"J(SHCIL);),
111 What " ｴｨｾ＠ E 1alue n1 tl>e "'JUI\ !ll""l p01nt
DO CJ. ｯｦｬｩｭｂｮｆｾﾷ＠ agam"' KMn04
A3. 114. ｣ｾＮ＠ D' IF',,, , •. "17 V and ｆＢＧｾＮＬﾷ＠ ' I 52
A2_ f'l--t. fJ_ D>
'
" A3. BT.C2. "
a M11ch k-.o !han o 77 v
"'
\lihoch p<llf of wn<c <oliJ, has ihe """" h ｜ｬｩｾＭｨ＠ ｧｲ＼ｭｾ＠ th"" I 52 V
Madelung constnnt'' ,_, ｮｾｭ］＠ n 77 v and 1 51 v
a NaCI nnd can cl ｾＱＧ｜Ｒ＠
b NaCI and car_, 11 C"""de< lhe foll<><llng ｯ＼｡ｴｾｭ･ｮ＾＠

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 <'•m<. 11'-;<J, "a h"'" on cQno !1-,SIJ, <I 1 <ml)
m<:<hUm !7 Soolid "'1""\lono pq, h.H "h1d1 .,( lilc
2 Ac..:onlJng l<t ｛ｾＱ｜ｯ＼＠ ｴｨｾｏｦＩＧＮ＠ H,S<J, 1< ｬＨｯｭＢｮｾ＠ ''
rolloot :m ｯ｣､Ｍｬ｜｟Ｌｾ＠ aold"'-'tllw.n an ac!ol a rnHi<fl<' ｂｩＭｰｶｲｾｮ､｡ｬ＠
;; [If, ' J.:F J.:llF, can be ｲｾｧｯＮｊ｣､＠ a• "" h ( >c!ahdral ｭｯｩ､Ｇｾ＠
"ood-l•o;o rooCh•>n ,_ ｓｾｵ｡ｲ｣ｩ＾Ｉ＠ OO!Uio:lal ｭｯ＾ｏ＼ｾｃ＠
\\ltid! ol 1hc >hl!cmenl• g!'on '"""'< at< J Pen ｬ｡ｧｯｮｾ＠ I ｭｯｩｾｴ｜｣＾＠
onm.:"l'' V.1oo1 ;, !he ｾﾷｫ＠ o( ｰｬＬＮﾻｨｾ＠
a 1 a<Hll onh okl"tgont''
h I anol _l ,.,\\
" It ｲ＼Ｚ､ｵ｣ｾＭｯ＠ 1
"- 2 anol.l nnh b h mcrea.,..,.
J_ 1. 2 .. ｾｯ＠
12- \\ luch nne <If lhc liolln" ong oo•di""' " nnt
ＢｾｰｯＱ｣ｊ＠ ｉｾ＠ <>C<Ur ''" I JSMJ prmotpk'
, l\,,r l!l'l • -.:ocl · llF
,, <"a< ·r, ｾｆ＠ • c.r, 21T
N.

xr
< llgl"l: '
" • Hgl',

' ｾｮ＠
\\1uoh
Jl,l) • ＬＱｾＰＡ＠
,,
tho fdlu'""g .,hom<"-"1
'"'"
•reo«:• bd.aw both Br<>llo!cd-
l.n\\!) ;<cod .1nJ a ｨ＾＼ｾ＠ """·> "' " · of Ｇ＾ｲｴｈＡｯｬｾ＠
'- Jl,<!
b_ 11("1!, ,;, .' "
'" .
"- ｾＨＩＧＬ＠ -IJ- ''·5p
$0,2" 5J.(><·lp
\\11.01 ffl lh<- f'""" ng 1"'; nl ﾷｾ＠ I""" ) " ,_ 5J-'S;-'Sp
, . rc ol 4ol·3p·l"'
b ＼ｬｓｾＭ C ln ｾＢ＠ »clohodool <<>mplc' of lig>n<l< <>n <»•"
ＧｾＢ＠ Ji,pl•<:eoi ht!k "'".' from lho1\' ＧＢｾ＠
id"ol f">'<li<>"'' tho c·t>•t.lllidol ;phllmg nf
ol-<>l'hit•l' fhr tin• cmt>pl<x " '" -'"'""
"
,,
.1,. ,,

"' ｾＺＬＧ＠ ;, 1 Ｚｾ［Ｂ＠

of ｯｨＢＧＭｾ＠ 'lakmCtt"{!J,ll,,J " ""'"''x and '
!he hg•n•l• ""' oli.pl.occol "" l'hwh "''

I( ·,n_,)
B<11<><> ｮｩｴｲｊｾ＠
!hal of ｾ［ｬｨ｡ｮ＠
fw.> a ｾ｡ｰｬｯｩｴＮＺ＠ li\,c Ia} or ,,' 'm•l_l
<!!udwo and i• • luhnCilnl < X m\1)
; ｬＧｨｾ＠
ｭＡｮ､ｾＢ＠
\\'hid\ ＬｾＭｬｨｯ＠
cloctri,.>l cnndudi,ity ,r h"'""
..ｭｾ＠ "' lh;ol "j guplnlc
;t>lomenV. ｾＧＢ＠ al!oH "·'""
12 ' ｴｯｬｮｨ･＼ｾ＠
'oml_l'
\\Inch""" of tho l(>llowmg compound• h>'
ge<>mouy
wnc"l" " 1\:o((':-.J,I''
ｾＭ I onl) h l"i\'Lf
h 1 ,,d_1 ｾ＠ ll'dCI,f·
ｾ＠ 2and.1 ol !l'J(I.'C"i'l"

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 1,\\ ｷｵｯｰｾｩｪｏｗ＠ ＨｕＭＧｾＢＱＩ＠ ＢＧｾＡＮｉｐｓ＠ '
ＡｐＮＬｾｕ＼ｉ＠ ｮｵｯｾ､ＢＧｬ＼ｪ｜ｉｐﾷｚ＠ 'II "'I 'I <· \UnlROU:icw _]{) ｕ＼ｎｐｏｊ｝ｾ＠ >ljl U< p.»n
I.\P '""'"'1''1 I' I'"" \"1'"1'"'1'1 so ＢＧｾﾷ､＠ "'"""11"1 ＢＧｾ＠ I" ｾｵｯ＠ '1"''1.1\ (,Z
"'I·(O"Cli!O nUU(d")ljd jill:>yclop-z '( l !P Ｍｾ＠ 'J'!'I I'
,,I'F;-. I' H' If,> M'H. >'I L \I '<>fr. 1ii "I\) ll I ｾ＠

puno<huoo ｾ＠ 'I
"'II J•> OUlU .>\"d. l.l PO-'-'<>O "'II " ＱＰｾ｟｜＠ ｾ＠ ｾ＠ n
''1'!"" (oo.u.'.l ＢＧｾ､＠ 'I' ,,: -J 1-1 JO '"I"' "II " ll"lj" ..\p "P"
0\<.U.>J ｮｵｯＮ｜ＬＭｾ＠ wn,,owdu! '
Jll
"'I'·""
Ｇｬｾｍ＠
""l""'tl'
1""1"·""1» NJI OJ.
P''" "'I'""
{]HI 010.ll.'_1 UU0.\0'*'04 "'""'"1'\1 ｾ＠
'1"""-iooJ<>.I umo;;m<>J "
i. l'\.'1..> P .II' "! J •) " '"" "
.J\-cl_ U ｾＴＱ＠ " :lu""'ll".l "'11 .1" """ 'l"''l\\ ti
HIJC ,"''1" ＧＭＢｾ Ｑ
ＱＢ＠ '"""' <po 11 '"1'":--l F
Ｈｾｉｴ＠ "") 041"'1"<171 '· ＭＧＱｾ＾ｵｙＮ､ｷ＠ ·_{
puo lOUCid•OlOllh< ｾｦｬｨｭ＠
"'"4'" ｾＧＢ＠ "-'O'!tunu '"'"' 1111" ,,jon:-; o
'lU.'IOOUl - L[
Ill ""1"'1"'"1"'"" "r"' 'II'" ﾷｾＱＢＧＮ＠ 'I
IJ<J puwm ｾＢＧｯｮﾷ＠ '·'1'":0.: r H •) o
ＬＮｾｕｉ＠ ""11"1 oop JO ll"l\l" .IOJ
" """!""" .oocl ＨｾＢ＠ ｩｵｯｰｱＱＮｾ＠ -"U. n: .I \ \1 4
.PI\ sw·n F ·' H \' •
.\")\ ｾＭＨＩ＠ 1
('FII'>II,'II- ,I
\ 01\ <it" <II 'I .J''('It'li•<.:IH ·_,!'<o'!ll•<.:l- \"
ＮＱｾ｜＠ 'IL "I • ＧｾＢｉ＠ d ＢＧｾ＠
ＢＧｾ＠ ｵｾＢ＠ umpoO< -4 ｾＧＢＡ｣ｬｩｏ＠ J<' ＧｦｬｾＢｐﾷ＠ 0111 J<> ＧｾｐＢ＠
'"-'l'"u ｾＧｦｬ＠ m ＱＧｾＢ＠ i.aJou;> ｾｱｬＢ＠ Jl"J_,
ｊｏｾ＠ ｾＱ＠ " ｾＢＧｉ＼Ａ＠ O!IJ J" ｵｯ＠ｾ '1""1.\\ w
f ｬＧｕｃｨＨｾＩ＠ 1 ".1'""" ｾｭｰ＠ ｰｵｴｾＧｬ＠ 01 I''PI \ p
'4lll'l 11, :tHI'l ｾｊＧＢ＠ ""'"4" ＱｾＢＧ＠ ''' ru .. >kt .•
ｾ＠
-"' J>rn:.n ""'P" I" >-''"'!" ' ｊｾｬ＠ u 1 '!

Ｚｾ＼＾ＢＧｎ＠ ｾｕｬ＠
"'-'!'"""'1 r·P •
\l<lJI 'Zf
'· ""'-'"'11'11
'1"'1" "''".l '"''·'" II"'
"·) ', "'II J"
ｾＢＱＴ＠ """"'.Id
ouo
ｊｾ＠ "'"'"" ""1'1 ＢＧＡｾ＾＠
'U 0! IIP 0.-! <II!"
"II IZ

ｾ＠
'·'.1 "' '"JdWoO ,(UO WJ<!J I<>U ""! :-,;.IS """r ('
•. ｉｾｐｴｵ＠ ＾ｾＡ＠ uoo (jiJOJ 411" '"IJ"''"' P"" •U!Jo_l
" !Cli\\.MMd '·"',&f,-, !<> I<PW ｾＴ＾＠ ＧｾＢｩ＠ 1"41 put !U!I .'<.) <ll WH :\,IS "'"'P!''' '
Ｉｮ＼ｾｬ＠ "I '"'lflnJ "Jl\0100 Ul ｰｾＡ＠

" pouu"J ""'ll Ｌｾｳ＠ <loop" '1"''1" IJ)•'•l !ll p:>Onp;> ﾷｾ＠ ｉｈｊｾ＠ <[
. II> 10 op<M""'"' "''<110 0 '""! '..IS qJl\\ ｜ｾｬ､ｗｯ＠
ｉＧｾ＠ ""II" " ｉｾｐｴｵ＠ "mdouJ "\: It J.'.J'm'JJ ""'"'I' " ! ｬｩｾＢＭﾷＱ＠ """\! 00 '
••d•mnu
ﾷｾＧＭＱＺ＠
ｾＢＧＱ｜＠
' '
dop-..;p ""' HJJ)<'A
,. wu '-""P ""' I!)>',] ｾＱＧＴＢ＠
.'I.JS IJI!" ,po:u 11 '''"I" '""I"' p.» ｾＭｵｊｯ＠
'""""h-r "'"!' i<l\\
""'

·tc
"l'!"·(l_) "' _, <U
;,I'"'"' 1<l I<ll< IUm""''"l ｾ＠
" "•jO.i.owuo Bu""'II"J ｾＴＱ＠ 1" ·'"" 4""1" "I II\'
_,!US
. ,P' I
',,,
ＢＧﾷｉｾＡ＠ "'"1"1'" """'"bv r
'" 'I'"P"P II"' P-"":1 o ＬＮＡＢｾＧ＠ ,QouR•"' ＱＢＭ＼ｾＡ Ｑ
-' {{j
Ｑ＠ ｾＧｉ＠ '"'I
'
ｕｏｬＡＧ＾ｊｾ＠ ﾷＧｬｕＮｾＴＱ＠ 4 "''" ｾｪ＾ｉｕｃｬＨ＠ '"'I ｾｕｬ＠ ＢＧｾ＠ I <lj "'II _ll> ｾｕ＼Ｇ＠ <(OJ ｾＧ＠ \\ ,,' '
II I" '
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 c I"' (I, !·J•pher1yl phosphinn <>than<!· I. !'hen" I
hi' idinitrngen) mol) bdenum (II J
d. bi' ｬ､ｩｮｴｲｯｧｾｊ＠ his 11. Ｒﾷ､ｩｰｨｾｮＩｬ＠ _1, {l,•ntoic' acid
ph<>>f>hinu ethane) mul) t>denum (II) ｾＭ ｅＡｨｾｬ＠ acw> ace!Uk
H<''-' ｭｾｽ＠ 'tcrooi«m>¢r< ore ｊｬ＼ｾｩ｢ｫ＠ )(lf 5. ａ｣･ｴｹｬｮｾ＠
the , ..,,,pic' (Pt\CIJ (Hr) (I) !NO,) I NIL)
(lj,(JJj ,,
Sdc"<:! tho co"""' an'""' """g ｬｨｾ＠ cmk
a. 15
gi'"" hck>":
<L ｬＮｾ｡Ａ､＾＠
b_ 1!)
b_ ＲＮｾ｡ｮ､Ｕ＠
<. 12 L. 2 and J 111>1;-

J7, "lo 'prepare''"· !l't(SihJ•CI>J, \\hld> P"" u

J. 4 and' ,,11)
Cnn;idcr ｕ＾ｾ＠ fnll\\\1 ing cart>
of d>CllUI'UI; ;, ｮ｣ｾＡＢ＼ｬ＠ ''
I No\lpentyl
•- ll't(NILJ,f' .,-,J KCI
, fi<"I}l
b. [PtJNihJ,f' .,-,d Nll,CI
:t. Ethyl
o. IPtCJ,J'-andNH,Cl
J. ll'tCI,I'•nJI'<Ih
18. Whm i' lhc Cr}'tal Field Stahili,minn
f'.nerg) f(TSEJ ol a li'ec l'o(IIJ ion on
ｦｯｲｭｩｮｾ＠ the !Cit'Jhe<lr.!l chi<'f<' ＢＧｾｰｩ｣Ｎ＠
ICnCJ,j'- Iin tlw "'"I' or \J '.'
().(,
" 1.2
'
',,'
m lh< tDilc•n ing .:ompound• ·

_W. "''
"M10wma1" <lbe•;c" " caust'<l b} 1
one <>I the f<tll<mmg ｾ＠
a I etmmeth) I lead
h Melhll thJihum

"'
"
"' Ill "'

" • What >< !he <WTect ><.'<juencc of 1hc

,·,ompounds gi••en ahnvo in d<'<"I'Casing
<>rdcr nlthcir S, I reacti1'11)- Ｍｾ＠
a. ·!1·111
h til II
c li·IIJ·l
J. tlt ·I -II
H. Con;icl<-t th.· l<>lltm ing 'P'""'"'-
ｉｾ＼＠ corre<l order of their dipole
momcn!.<'.'

' tV·-1·11· Ill

"' CIH)H
OJ!"
'' 111-1· ll-1\'
IV, !I I' Ill '" 0

" 111-· 11- I, IV CH

. '
(- . ..o--
·ll Whkh "m""g't the lollo\\h>g aro "'""""
a<·id,'' "
0 CH,S

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 \.\hal « ｬｨｾ＠ cnn·ccl '<llJUc!lc"t t>llhe ＧｾＢＭ＠ h ,\t.IH.t 2. I>J
Ｂ＠ｾ abmc m dccrca>lng nrdcr nf ,\2_ ＱｾＮ＠ C I. n:;
nucb,phili<il)' in tlllllijUCnu.; 91lttltcm'! 'J AI.IH\'2.
"- \'>111>1-·!V'll
h IV'•II>!!I•·I'Y
ｾｓＮ＠
I cmmnin ;, a ､ｲｵｾ＠ '"
u,cd m II"' ''""'""'"' "f
high hh\d IW"""'· ＢｾＧ＠ anJ abnormal
c V>li-·I'IV·III '"'atl fh) lhtn\

H
J_ IV•·IIl ·!1-·J-·V
\.\ lml ｩｾＭＧ［ｲ｣＠ II!C produclt >I I<Jr the ll•IIPI' ｾｧ＠
,, "''
i ' "'
m<eunn '' "·' " "'· "'
,01, '
"''- IllI "'
"-" '"' \.\ hoi ;, lhc
I " '
ｾｉ＠
_...,on

' H,, II L1
"
h
' ' , -oH

' ! <tunl ""'"""'' ,,fla) an(lihl

c II,

,, ,,
l'er<,,i,k dkd ;, " 'CI} impmt;u•t li:nl
Ｎｾ＠
OH
"r ''"' ＢｾＧ＠ ＢＧｾ＠
d"""'''l} and "'"'"
Iv
ctkn duriug !he addit"m of "I"· ·J
lhc ll>llo" ｩｮｾﾷ＠
QH
"- !lllr
b. Br..(J!J
r\
"- lll'l
,1,111
II! "'· Ｎｾ＠
l·"r the
ｾ＠
ｾｫｄｉ｣ｬＬ＠
gncn ｾｨｯｬ･Ｎ＠ "hat I> !he
Matoh I i>t·l ;elect the mcrc,ing order "' '""""it) lnwarJ,
Jch;-Jrminn''
"""""' '''""'
1hc l»h I ,. Ill , II
" 1<111<-11

'J." 111,11-·t
Li"·l
II , Ill ' I

ｾｉ＠
ldmchlnmk
ｮＱＬｾＭＰ＠
i
(_)
tFuncli""'
t 'hai11 tmn>kr ｡ｾ･ｭ＠
cu, J -o \Y)-
,. ' N01
II
I· rce.mdical mumtoo
'
)
)
Pl;c<tki,-er
'\ntin,idunt
Cfl,--t-o -(o) oni,
'
(_ """- h>t lh< ｾＧｫＢ＠ g11cn ｡ｬｾＧＢ＠ "hal h ｴｨｾ＠
"- ,\2.11.1. ('I' j)..l '"''"'i ＬｾｊＧｲ＠ ,,r ｊ｣ｾＢＭＧｧ＠ ""u;'i'il)
"'" tud; olkalm< h: JrPI) "' ''

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 u II · Ill Cl!,' ＮｾｵｴＬ＠
hnl
"
h Ill II
"1 "\'
c Ill
d II
II
- Ill ' ______ _,_,,'
CH,
>I \\'hal arc tho pomluch 1\ Ltnd I:! m 1hc
ｉｴｾ＠ I 1<11 Ul$ fCatlo< 'll .,
ll7
,, ut,

ｾｊ［Ｍｯｈ＠
m,
" t 1l'
ｾＧＱ＠
_,t_,
CH,CH, H
' ' rH,
CH 1 !fH1 '" ｾＭ '
A );. oc," !)·" '
CH 1tlt, /, CH,(11, '
-H - Cl"
' ｾＺｈＬ＠
A ｾＭ･ｎ＠
,, ot,cH, fr

A ｈｩｾｎ＠ 1''
｡ｾｭＬ＠ '
'
A

" ' the ha"' "f

-cH -c- ,')'

CH, c
-."f--Mc
'
CH, Me
,,
fc ｾＮ｟＠ -· Ｍｾｬ Me
rmonncduuc "
'
pmdu.:r '"II be
_,,,,C; -J!Olltannl
' 3-

.)"'
The m"J(>r pwdncl '"" nne ＼ｴ｣ＭｲＬｧｾＢＧ＠
･ｾｮｴｲ｣＠
___
1.\'ll<d• "I 1ho <t"temc•E!h ｾＢ＠ ｯｬｾｮ｣＠ "'"
COITfft' 1 .__/
ｬＮＢ｡ｮ､ｊ［ｾ｜＠
',, ｾＭ｟｜｡ｮ､＠ -1 urtl) .__.r,..,t ｴｨｾ＠ ,-.,-red """'"' ＧＢｾ＠ rlw <•><k
ｾＰＱ･ｮ＠ lwhm
I ami J c•nh
' I. 1. ｾ｡ｮ､＠ 4
a I 3·4-'

' h
(
··I -'
- _; - ｾ＠
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 - ,,I ' j

55. '"
"'t"
H-

CH,
Br

"f;
H

COOH
OH

'

"

HyNxn1COOH

ｈｾ＠ H

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 _,,, .\n S,1 re!\C!!<UI al an a>ymmctr!L

"' carhon of a COmp<Jlmd

one of the IOilo" mg''
"''"!}'' £"'"' which
a -\n ｾＢｮｬｯｭ｣ｲ＠ of!hc >ubmmo
b. -\ proJucl "nh opposne upucal mtanon
c -\ ｴＱｾｬﾷ･＠ or dtastereomers
d -\ <ingle s!c>te<>"o"'"'

" In "Indo ＰＱｾ＠ <>fthc IOIIo"mg reacuon ·

' "''"'""'OJ""''
In "luch or the "'"''e nrc !lA and Ill\
d!
linal pwduo! "m>l a pnmary ;rknh()
, /'.
___ ::,. 'CHJMgBr _..,.

" I. 1 /ifld _1 " HCI-10

" 1.3and4
'
1.3:md4
"
" L2<md4
To dc01dc ahom the t<>pl<:lr}
m the"""""''"""" I and IL lhe
,,t h}dropon'
ｨｾ､ｲｯｧ･ｮ＠
"'""" """' '"""""'""!) ｯ｣ｰｬ｡ｾ､＠
sub<lrlucnl Y '" \hown bd'"'
b). " J

"
\ --J-nH "'
!lO -1-- I< R----CO\)H tc R--C--R'
' / A 'i
,. " ( ,, '"'"'""''" '
'- -----</ 0
"" - -t
,,' " ＧＢｾ＠
ＢＧｾ＠ H,O
"!10" {t) R'OH • \' 00. {til
ｾ＠

b 01 RTOOH Iii) OH
HO
IHI -'
Hp
' It I R'Lt
Wlttch moe ot' ｴｨｾ＠
c;mnm ho ＢＩｴｩＡｨｾＧ･､＠
li>ll<mtng """'1''-'und<
tr. th" Ｂ｣ｴｯﾷ､ｾ＠
!l Ｍｾｏｬ＠ " ester s; ｭｨｾｳＢ＠
ｾ＠
"
:i . .l·dtmeth} I l·!>manone
Y ·-- Oll
b :; ·moth;- I 2-pemmwne

<lt!\WII a; ｬｨｾ＠ l{!llo"mg

" c 4-mcth;-1 2-pent:tnone
d 2-he,anoo"

Ａ ｾＺＬ［ＧＢ＠
Amon!'- the ll>llo"tng_ wluch one v.oll h"'"
dtc highc>l dipnle mwnenl .,
homo10p10 '" I :md
ＨＢＧｾＮ＠

and <nan1WI!l)\IL rn II
"
lo;·drngon1 are di•;J,.,-eotopic Hl I ＱｾＮＭｬ｟［ＺＩ＠
I he h)cltt'!'"'" "'" homulclj>IO In I !<nd
ＬｾｲＭＮＺ＠
｣ｮ｡ｩｅ＼ｬｯｰｲｾ＠ no l!
\\lnd1 <>f lhc <Wten'"'"' ｾＢＧ＠ Bhovc" '"'""·/'-----.?
""""''"
u I unly
') "
l> 2 onl)
c _1 t>t!l}

d ｾＧＢ＠ of the abm c

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 ｾＬ｟ＮＭｎｈｏ＠

?!
ＮＭｾ＠
':
ｾＭﾢﾷ＠
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I
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ｾ＠

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64 Which one oflhe following ts ammatio 0

"'-- ---=--_.. ._
'"
/',, d
Which one of 1hc
ｾＧ＼ｏｬ､＠ ｢ｾ＠
'
tnlluom-
'

"
h
<""-",(! •h
＼Ｚｾ＠ ___j '

ＯＺｲｾ＠ ＧＭＯｾ＠

L"t-1 \\1th ｮｩｴｭｨ｣ｾ･＠ • wluene

COI'r<-'<1 """""' b Toluene ·ben?Cne
the li"' nmoloen1ene
L•<t-1
@
c Niuohen1-ene bromobenz.ene
NH1 hi!1tz£ne- ｬ＼＾ｵＭｾ･＠
d Ni!l'tlhcntene ｢ｭｮＢｾ＾｣ＮＺ･＠
en, toluene·· ｨ･ｮＷＢｾ＠
-{"fl,
Whorh one of the ｦｮｬｾＧ＼ｩｧ＠ ;:nmpnund' ｩｳｾ＠
0 NH,
1}-sugm gi1·ong an ｴ＾ｰｩ｣｡ｬｾ＠ aciJ<e penmnl
on reduct""'"

conJuganon
due to rewf«' hyper
CliO
c
A2. B4. CL DJ c
1\2, B4. n. Dl ,, CII,OH
A4. B2. 0. OJ
d ａＴＮｂｾｃｩｏｊ＠ ""
-
ｗｨｾｮ＠ " heated 11mh Ln ､ｵｾｬ＠
ｮｭｯｨｾ｣･＠
UJ.Oll
\JH_,CI rn ethanol. what is rhc maj<>r
pmdurt ftlt!nc'<l ·>

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 II, C>( ' \
J In nH>re pOl III solvent; n - > ;r•
tran01tion> e>,penence a red shit) but "
• ,. tmn,.;tions shn" blue shift
Which of the >tatcments g" en above ,,.iare
COffttt'1
a I and 1 moly
h 2 and J nnly

ｾ＠ :_';;nd.l Ｍｾ＠
{'''""('- ｾＭｭｧ＠ ｣ｯｭｰｵｲＧ＼ｾ＠
"
HO 6u

;-""\..o,
. . ./ 0
r!
!J '----=--/ ｾ＠
<'!!,Oft
Ht}_;;ffi'"
ＬＭｾ＠
'
""
CH,OH
""·-u
' ,.--"
Ho·l
cl Oll "" m
d HI
Match Los1-l with Lost-11 and select rho
wrrcet ""'""""'"'"!'the code gtW!l bclov.
the list;
ｌｴｾｬＭＱ＠

tCompc>uodl
!l H
''
HOC}(' -l' -C-CI
'
,, Clli'
CH,-{'HiD--CH,-I' H;

" n' '

H
llf-C.._H

ｔｈＬＭｾｉｬ＠
t'II,-CH 2
C'on<idet the follo,.,ing 'tatcmen"
I n > :r" tramttion " n fothtddcn I """'bor of P\lR Stgnal<l
tran,twn
' I_ 2·0tphenylethene ab;orl1; t:V light ' '
' '
at a <huner ""veleng:th. then '" t<ans"
isnmer

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J"l Ｇｉｕｏ｜ｾｲｬＤ＠ ｩｕＡＧＢｬｾ＠ .:lljl ｾｬＢＧＮＩ＠ｊ 'M!
trun1 'I'
t l\Lln < ._, ;, wruftu!r f'.-'!""J"'"''"
'I"" ( ﾷｾ＠ J"'.l "' ＡＭＧＢｾ＠ " ｾＢＡ＠ ""II"J ｾＴＧ＠
'I"" c .,
J" oun '1·".4 \\
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IJ
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1ｾＧＢｉｕｏｬＬ＠ Ｌｾ 0111 ' I<> ＧｐＡｾａ｜＠
Ｑ Ｌ＠ '
'·"''"'" ';l\- .,

'"">! ""''W · - _,J" U\OJ'>\> ·"II I"

'.'1!1!« ,00 ''' IUML!I\\
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(\\\) ""-'1110<). '· ''""'"J '
I • ＮＬｾ＠
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- 'IU,W,l)UIIii"WIH)I .,Ill\\: ·p
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rd '"'I PI """
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pu -·'W,ll , .i
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· \\

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Pl'll!"-"'1\ -, ＱＢＭＧ｜ｦｬｾｕｉ＠
1"-'4\>W .!.ljUll S '<I

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(111"-'I)OUWl!lR ｾ｜ｪｬ＠ Ｇｾ＠ 1"->IJIOW <pjtJ" U(J u
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i:OI'I'"'P" pull l>j<l!JI rr ''l""a" ""I ._,
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I"""" ＧＡｾＴ＠ '1"1 ｾＱ＠ ｾＧＢｉ＠ '1'"1"' " ｾＧｬＡＮｊ＠
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' l!' '\ UOI)OII!1j ｾＱ＼Ｇ＾＠ ""4

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 At _in3 K. the vapmtr I""""'" ＼＾ｦｨｾＢＧ＠ '' c Jl•xtfJ'M
liS Tnrr and that nf eydolt¢,ane" 122 d 10>.10-'M
Ton Ｑ｜Ｎ＼ｓｵｭｾ＠ ideal behavwur_ what Will QS l'hc lt10la1 C<HidULiivll)' of OPI ｾ＠
be the ＢＧｾ＠ pressure of a >nlutiun f"' CH,COOH(a<'l at 2Y8 K" I 1•5 mS m'mol
v.h1ch the• mule ihtt1nn of benzene " 0 25'' 1
What is the K nfth< ll<id ., {Gi'"'' '<''
o 118 J'nrr WtmSm'n>ol-'t
b II" l'mt a IS.!xiO-'
" tzr, rorr b 184xto-'
d 121 Torr L I 8·1 ' ](r'
q_; Whot "'II he 1he number of pf>""''· J "'''"""l'thcabolc
comp<meom and degree> of frcc'<l"m qq What o; the ･ｬ＼Ｚｳｮｾ＠ pntcnna
'""PL'<liVcly uf the &wlmpot umturc nl' doctrode tn wh><h c<>ncen
""'"" a1td eohan"l "' I !I altlt "' ･ｾｭｬｩ｢ｮｊＧ＠
2Md 2
' '
b 2 and l
'
' 2 and fl
',, ' ,,
1 and I
What would l>e tho vapour t"es.wre of
"atcr at ｟ｬｾ＠ - C 111 IO'-• aqu«l!J& snluUnn nf
, •
＾ｒＢｃｾ＼ＮｬＦｭｊＧ＠
ｾＧＢｉＡ＠ 'ap<rur P"'''"'" nl" ""'"' ot tOO " nsed to

124 mm
'h 12 2 mm "
31 S mm
,,' _ll ｾ＠ mm ｜ｬ･ｲｾＧＢＭ＠
''"" mtrate
chlnncle
Cak1unt nmate ""'''"' "' ''"w' a; AOUIT<nt of .1 ,\ po."mg thnmgh ,;her

Ca(NOl), o" Ca1 ' < :'NO) nitrote 'olutinn (or :!li numn"'. dep""" ｾ＠ g
nl" "I""' What " 1he elecuochenncal
Elevau<'n of h(}lling roml
equn alent ｯｦＢｾＧ＠ in gm C'
shtms tl> oh5<'TVe<l molar
a I II x llf 1
aga1n>1 '" nnrmal mobr t
b I II x to-'
\-\dlhclhc f'
ｾ＠ I II X It!-'
ｭｴｲ｡ｾ＠ ''
d I I I ' HI_,
'b ll "" 102 The emf of tile ｾ･ｬ＠ /n.J:n' (0 I \1\11 Mg'

" 117'
d 1r
ＧＢｾ＠ '*' (0 I MJi MQ is found to mcrease h1 ()(101
\K' If ｾｦ＠ of thos cell at :!j"(' is I b \'.
Wal "-nuld be cnohul py of the cell rcactl!lll' 1
1\'h"l ' molm•h <>f a '"'"""" " ＮｬＨＬｾｩＴｊ＠
n " I g of S<l<iamt hydro-xide in !51!
ｾ＠ .lt.6.114,1
< .]\1286)
d 251286)
In the hulwgen--exvgen tioel cell "h1ch
I) ' catal;" " u>ed ,, a!!<\,k '"''d '1
0]
a f-ine!,· di"dcd platinum"' palladtum
'!7 Wh•t i> ｴｾ｣＠ cnnccntronnn ol' nxygen at
h \l!XIUfc <lf CoO and plaiJ15!!!15
:!IJ''C and a r•rnnl P"'"""' of 1121 aim
opplymg Henr,--' b" c<tua!wn'' j(i"·en that c M1xtme Ｌｾﾷ｣ｌｊｏ＠ and patlll<l•um
Hem>· s ctm"ant k I ,18 x ]IT' m()le' l-' d :-.,, catalntl.> requrred
art!l I I I 04 rhc ralc equatir>n on rhe b""' nf follo"mg
21JX Itt' M data li.>r a gaseml> rcactton ,,, ' ｾｬ＠ - 2AB
',, 2<lX llf'M
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 <'e>(l\
d A3_ B4. C. Dl Rea""' IR) Elevauon nl' hcl!lmg
I 1.1 !l>e wagullti"" of lUll ml "f CL>ll"•dnl fl<""' t>
numflers of ＾ｲ･｣ｾｳ＠
"""'""\ｾｲ＼ｬｰｯｴｷｮ｡＠
presonl in rhe solulton
to the
,ulutJon nf g"ld '' compktely ｰｲｯｶ｣ｮｴｾｬ＠ ｾＩﾷ＠
1ile "ddmo11 ol' II;:-; ｾ＠ ol' X 10 11 hefore a B,,,h ·\ and R •re tndlv>dually !rue and
flrlditi<m ,,r I ml nf IIJ'o "•Cl "->IHIJ<>n R" the ootTe<t "'planm1on of·\
\\-'hot" ｴｨｾ＠ gold number of X b ll<Jth A and Rare ｬｏ､ｩＬｵｾ｜Ｇ＠ lfuo anJ
I) J_<,
,,' 250
R '-' tht• corr<..:t "-'planut"'n
< A '-' l<ue but R ;, litloe
'''·"

!l A"foiWh!!!R"ITU C
'cl '"' '" ,\,enwn t'\) Calomel elec1rnde
•dcre11cc "lcc1rnde and """"m
'\"onion (>\) Si('l, ""' lower bmhng
rmim than en, <pann!'h- ><>luhle ""I' or
Ken>O!I IRI l'hero " a p,- d, <'!Vet lap '"luti<111 11f" Ｍ＼ｴ＾ｬｵｨｾ＠ '"It oJf
lw!Wet!n (']and S1. lhu' makmJ; S1-Ci lwnd R•a<on {R)
le.s polar
o B<nh '\ and II are •ndi"'d"oll)- true and a Both -\ and R are ,
R ;, the correct c'planatln>J nl'.-\
b Bmh A and R are ind•l'idtJall) trw ""d b
R is the c<>tr<''" cxplanaii<>J! nl" .>,
c _.>, i, true ｾｵｴ＠ R tS fol<e
d .'\ ;, lioii": hu1 R « ln•e "' R "true
•\osertion Ｑｾ＠ ｄｾＧＢｬｯｮ＠ of I -\) ll)·drnly"" nf ｾｴｨＺ＾＠ I acetate
'" seccmda,-, and lerna,_ nlcohols cc ol- acid " a ｾｯ｣ｴｩＢＧ＠
-heft'll$ m preoencc ul' albh, 11 1> a
of fir<t
eonc<'tltratc>J H,SO, re>UII> on
sepa'"lion ()[ "" mwlllhk liquiJ ,,r
action ""'""d orde•
Oo•ltn¥ poinT Re.son IRI •\cod onl1 act" "" " catoln1
Reason

oeiJ
,, ,, .,
'. il
wher<"'l,, dlkali oc1' a; moe of Ihe re"ctant>
a Bolh A and R '"" mdtv•dually !rue und
R" Ihe correct c'plan•IJ<m of A
h<>Fiiow, ' ,, "'
n !1oth ,\ and R are
h Both A anJ R arc •ndi"duoll) true and
R" the corrc'<-1 explananon <>I" A
Ri,!hc 1 c A Ｂｴｮｾ＠ hm R" false
0 B<>th ,\ and R ol .\ " 1111 '" h>Jt R " 1ruo
IW ·''-'"""'" 1M For the ｦｯｬｷｩｮｾ＠
ｰｨ＼ｩＡｬ､ｾｭ｣｡＠ ､ｾ｣ｴｬｮｰｭｊｏ＠ of HI
' Hl ｾｈ＠
,1,:1d' 'hO'-' H · HI ---. H, t
10 polar soh-ont'
1>1 -----.1,
lii'Utenon beha>e5 ｬｩｾ･＠ a 1he quanlllm y1eld "onl1 '
Reason (RI I atC'm '' relan1el; 11nrea<t!lc
A ond Rare md"uh•olh !nte ond and d<"'-' not ｰ｡ｮｾｲＱｬｯ＠ in tho chain
R '' ll!e C<'flOCI cxplan•tion of'\ prHp;lgatinn O!ep
Bnth ·\ ond R "'" 11!dil•d,.all\· 1r>1e Mnd a Bmh .\ and R ore ｭ＼ｨｩ｣ｬｾ｡ｹ＠ Ｂｾ＠ an<l
R ;, ohe cooect C\planati"'' of,>, R" 1he C(lf!eel e'planon"n o( ,\
L A" ln10 bul R ;, fal>e b ｦｬ＼ｾｨ＠ ,\ and R ore l!ldlvoduall\ m•e m1d
d A "fal>c• htll K ''true R ;, ｴｨｾ｣ＢＬＭＧ＠ e'planatlon <>1- <\
,\,.;emon ti\1 The ho•litlg poom of ill ｾＱ＠ c A" true hut R IS lill<e
urea 'olunon "less Ihan thai of ll I \1 KCI <I ｜ｬ＾ｃＱＬｾｨｩｒｓｔｮｏ＠
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