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Text Book:
Silicon VLSI Technology
Fundamentals, Practice and
Modeling
g
Authors: J. D. Plummer, M. D. Deal,
and
a d P. B. G
Griffin
Photolithography
g p y ((Chap.
p 1))
• Basic lithography process
– Apply
pp y pphotoresist
– Patterned exposure
– Remove photoresist regions
Light
– Etch wafer Mask
– Strip remaining photoresist
Photoresist
Deposited Film
Substrate
Film deposition Photoresist application Exposure
Etch mask
Lithography
• The ability to print patterns with submicron features
and to place patterns on a silicon substrate with
better than 0.1 um precision.
• Lithography is arguably the single most important
technology in IC manufacturing
– Gains have traditionally been paced by the development of
new lithography tools, masks, photoresist materials, and
critical dimension etch processes
• Considerations:
– Resolution
– Exposure field
– Placement accuracy (alignment)
– Throughput
– Defect density (mask, photoresist and process)
SILICON VLSI TECHNOLOGY
Fundamentals, Practice and Modeling 3 © 2000 by Prentice Hall
By Plummer, Deal & Griffin Upper Saddle River NJ
Lithography - Chapter 5
nm
DRAM Bits/ Chi p (Sampl ing) 256M 512M 1G 4G 16G 32G 64G 128G 128G
MPU Transistors/C hip (x106) 550 1100 2200 4400 8800 14,000
Fiel d Size (mm) 22x32 22x32 22x32 22x32 22x32 22x32 22x32 22x32 22x32
Exposure Tec hno logy 248 248 nm 248 nm 193nm 193nm + 193nm 193nm ??? ???
nm + RET + RET RET + RET + RET
+ H 2O + H 2O
157nm??
Data Volume/Mas k lev el (GB) 216 729 1644 3700 8326 12490
Definitions
• Critical Dimensions (CD)
– Dimensions that must be maintained
• CD Control
– About 10% of minimum feature size.
– Expressed as 3 3-sigma
sigma as three standard deviations of the
feature size population must be within the specified 10% of
the mean)
• Placement or Alignment Accuracy
• Optical Lithography used through 0.18um to 0.13 um
generation. ((described in text))
g
• X-ray, e-Beam and extreme ultraviolet are options
beyond 0.1 um.
Wafer Exposure
• It is convenient to divide the
wafer printing process into
three parts
– A: Light source,
Aerial
Image
(Surface) – B. Wafer exposure system,
– C. Resist.
Important Aspects
• Masks
– Design, Fabrication, Reuse and Maintenance
• Photoresist
– Material, material properties, develop, operation during etch
or mask process,
process post process removal
• Wafer Exposure System
– Exposure energy type, focus, linewidth/wavelength,
diff ti effects
diffraction ff t (fringing),
(f i i ) depth
d th off focus
f
• All
– Line width
– Alignment
A. Light Sources
• Decreasing feature sizes require the use of shorter wavelengths, λ.
• Traditionally mercury (Hg) vapor lamps have been used which generate
many spectral lines from a high intensity plasma inside a glass lamp
lamp.
– Electrons are excited to higher energy levels by collisions in the plasma.
– Photons are emitted when the energy is released.
– g line - λ = 436 nm ((typical
yp in 1990’s))
– i line - λ = 365 nm (used for 0.5 µm, 0.35 µm)
– Issues include finding suitable resists and transparent optical components at these
wavelengths.
Light
Source
Three types of
Optical
System exposure systems
have been used.
Mask Gap
Photoresist
Si Wafer
Diffraction (1)
• A simple example is the image formed by a small circular
aperture (Airy disk).
• N t th
Note thatt a point
i t image
i is
i formed
f d only
l if:
if
– λ → 0, d → ∞, or f → 0
1.22λ ⋅ f
R=
d 1.22 λf/d
• Diffraction is usually
y described in terms of two
limiting cases:
– Fresnel diffraction - near field (proximity and contact systems)
– Fraunhofer diffraction - far field (p
(projection
j systems)
y )
Resolution
• The denominator is defined as the numerical aperture:
NA ≡ n sin α (3)
– Where α represents the ability of the lens to collect diffracted light.
0.61 λ λ (4)
R= = k1
NA NA
• k1 is an experimental parameter which depends on the lithography
system and resist properties (≈ 0.4 - 0.8).
Depth of Focus
• While resolution can be increased by:
– decreasing k1 0.61 λ λ
– Decreasing
D i λ
R= = k1 (4)
NA NA
– increasing NA (bigger lenses)
λ λ (5)
DOF = δ = ± = ± k2
2( NA) (NA)
2 2
I MAX − I MIN
MTF = (6)
I MAX + I MIN
Intensity Intensity
at Mask on Wafer
• Typically require
1 1
IMAX
MTF > 0.5 or resist has
exposure problems
I MIN
0 0
Position Position
Spatial Coherence
Light Condensor
• Practical light sources are not point
Mask
Source Lens sources.
NA condenser
S= (8)
or often as NA projection optics
Small
degradation for
large features
s≈0.5-0.7
Diffraction effect ⇓ MTF for s→0 optical intensity decreases
Less
coherent Improvement for
light very small
Lower contrast in the aerial image features
Photoresist
• Designed to respond to incident photons by changing
their properties when exposed to light.
– Long-lived response require a chemical change
• Most resists are hydrocarbon-based materials.
– Photons break chemical nonds
Processing
• Start with clean wafer
• Spin-on
p photoresist
p
– Adhesion promoter may be required
– Viscosity and spin rate determine thickness and uniformity
– Create a film of 0.6 to 1 um depth
Df
D0 1
0.5
Df
0.5
D0 γ= (11)
Df
0.25 0.25 log10
D0
0 0
1 10 100 1 10 100
Exposure Dose (log) Exposure Dose (log)
Critical MTF
1.0
Areal Image
xposure Dose
0.75
Df
0.5
Ex
D0
0.25
0
Position
• The aerial image and the resist contrast in combination, result in the quality
of the latent image produced. (Gray area is “partially exposed” area which
determines the resist edge sharpness.)
• By analogy to the MTF defined earlier for optical systems,
systems the CMTF for
resists is defined as
D f − D 0 101 / γ − 1 (12)
CMTFresist = = 1/ γ
D f + D 0 10 + 1
• Typical CMTF values for g and i-line resists are about 0.4. Chemically
amplified DUV resists achieve CMTF values of 0.1 - 0.2.
• Lower values are better since in general CMTF < MTF is required for the
resist to resolve the aerial image.
SILICON VLSI TECHNOLOGY
Fundamentals, Practice and Modeling 20 © 2000 by Prentice Hall
By Plummer, Deal & Griffin Upper Saddle River NJ
Lithography - Chapter 5
• A slit is scanned
across the wafer
– Slit and lens system
y
minimize aberrations
– Difficult full wafer
alignment
• The
Th systems use global
l b l alignment
li -
difficult alignment on each die
• full mask difficult Æ use steppers instead
to improve overlay accuracy
– 4x to 5x mask
– Step, align, scan-slit
Measurements of Masks
• Check Masks for Features and Defects
– Scan
– Make a new mask or Correct the errors
SEM
Resist pattern Φebeam≈10nm
ρ π V3− 4 V2−3 ρ ⋅ L
ρS = = ⋅ R= = = ρS ⋅
L
t ln (2 ) I 5−6 I1−5 t ⋅ W W
I1−5
W = ρS ⋅ L ⋅
V2−3
resistor
• Th
There are severall commercially
i ll available
il bl simulation
i l ti tools
t l that
th t calculate
l l t the
th
aerial image - PROLITH, DEPICT, ATHENA. All use similar physical models.
• We will consider only projection systems.
ε (W , t ) = Re{U (W )e − jωt
} where U (W ) = C (W )e − jφ ( P ) ((14))
Generic
Source
Projection
α
x
System
y
Aperture
z
x1y1 Plane x'y' Plane
x y Plane
ε ( f , f ) = F {t(x , y )}
x y 1 1
(17)
• The light intensity is simply the square of the magnitude of the ε field, so that
I ( fx, fy )= ε (f , f )x y
2
= F {t (x1 , y1 )}
2
(18)
Mask x
• Example - consider a long
g
rectangular slit. The Fourier
w/2 t(x) z
transform of t(x) is in standard
texts and is the sin(x)/x function.
Photoresist
on Wafer
Objective
Obj ti or
Condenser Mask Projection
F{t(x)} Lens Lens
Light
Source
x
I(x')
y
Aperture
z
x1y1 Plane x'y' Plane
x y Plane
⎧ NA ⎫
⎪1 if f x2 + f y2 <
• But only a portion of the light is collected. P( f x , f y ) = ⎨ λ ⎪⎬ ((19))
• This is characterized by a pupil function: NA
⎪0 if f x2 + f y2 > ⎪
⎩ λ ⎭
• The objective lens now performs the inverse Fourier transform.
I i ( x, y ) = ε ( x, y ) 2
Microns
0
Microns
0 0
-1
-1 -1
-2
-3 -22
-2
-3 -2 -1 0 1 2 3 -2 -1 0 1 2 -2 -1 0 1 2
Microns Microns Microns
I ( x, y, z ) = I i ( x, y )I r ( x, y, z ) (22)
where Ii(x,y) is the AI intensity and Ir(x,y,z) models latent image effects.
SILICON VLSI TECHNOLOGY
Fundamentals, Practice and Modeling 32 © 2000 by Prentice Hall
By Plummer, Deal & Griffin Upper Saddle River NJ
Lithography - Chapter 5
ATHENA Simulation
• Calculation of light intensity
distribution in a photoresist layer
during exposure using the ATHENA
simulator.
0
• A simple structure is defined with a
photoresist layer covering a silicon
0.4
substrate which has two flat regions
and a sloped sidewall.
Microns
0.8
• Th
The simulation
i l i shows
h the
h photo-
h
M
Photoresist Exposure
• The light incident is primarily absorbed by the PAC
which is uniformly distributed in the resist.
– Note: this analysis neglects standing wave effects
• Resist bleaching:
– PAC becomes more transmissive as it becomes exposed,
exposed as
the PAC converts to carboxylic acid
• M
Modeling:
d li The
Th probability
b bili off absorptionb i iis
proportional to the light intensity and the absorption
coefficient.))
= −α ( z , t ) ⋅ I (23)
dI
dz
Exposure Model
• The absorption coefficient depends on the resist properties and
on the PAC
α resist = A ⋅ m + B (24)
where A and B are resist parameters (first two “Dill” parameters)
with A the absorption coefficient of bleached and B nonbleached
resist. Defining the percentage of unexposed resit
m=
[PAC ]
(25)
[PAC ]0
• m is a function of time (m=1 unexposed t=0, m=0 fully exposed)
and is given by (with C another “Dill” parameter
dm
= −C ⋅ I ⋅ m (26)
dt
• Substituting (24) into (23)
(23), we have:
(27)
= −( A ⋅ m( z , t ) + B ) ⋅ I
dI
dz
• Eqns.
Eqns (26) and (27) are coupled equations which are solved
simultaneously by resist simulators.
SILICON VLSI TECHNOLOGY
Fundamentals, Practice and Modeling 35 © 2000 by Prentice Hall
By Plummer, Deal & Griffin Upper Saddle River NJ
Lithography - Chapter 5
Transmittance
Source
0.75
0.5
T
T0
Light
Detector 0.25
Photoresist Baking
• A postt exposure bbake
k isi sometimes
ti used
d prior
i tto d
developing
l i th the resist
i t pattern.
tt
• This allows limited diffusion of the exposed PAC and smoothes out standing wave
patterns.
• Generally this is modeled as a simple diffusion process (see text).
0 0
0.4 04
0.4
Microns
Microns
0.8 0.8
1.2 1.2
⎧
⎪0 . 006 (
exp E1 + E 2 m + E3 m)2
if m > − 0 . 5
E2 ⎫
E3 ⎪⎪
⎪ (28)
R ( x, y , z ) = ⎨ ⎬
⎛ ⎞
⎪ 0.006 exp⎜ E1 + 2 (E2 − 1)⎟
E
otherwise ⎪
⎪⎩ ⎜ ⎟ ⎪⎭
⎝ E3 ⎠
where R is the local developing rate and m is the local PAC after
exposure. E1, E2 and E3 are empirical constants.
k ⋅ k ⋅ C ⋅ [PAC ]
n
In steady state F1=F2 and F1 = F2 = D R D
k D + k R ⋅ [PAC ]
n
D
But the rate is then r=F1=F2
and CD
CS
k D ⋅ C D ⋅ (1 − m )
n
r= + rmin F1 F2
+ (1 − m )
kD n
k R ⋅ [PAC ]0 F3
n
Developing Model
0 0
0.4 0.4
ons
Micro
Microns
0.8 0.8
1.2 1.2
• E
Examplel off the
h calculation
l l i off a developed
d l d photoresist
h i layer
l using
i theh
ATHENA simulator. The resist was exposed with a dose of 200 mJ cm-2,
a post exposure bake of 45 min at 115 ˚C was used and the pattern was
developed for a time of 60 seconds, all normal parameters. The Dill
development model was used.
Future Trends
• Optical lithography will be extendible to the 65 nm
generation (maybe further ).
• Beyond that, there is no general agreement on which
approach to use.
• Possibilities include ee-beam,
beam e e-beam
beam projection
(SCALPEL), x-ray and EUV.
• New resists will likelyy be required
q for these systems.
y
• Projection Optics
– Light Sources: 248–193 nm (KrF and ArF excimer lasers)
• Immersion Optics: use a fluid instead of air
• Extreme Ultraviolet Lithography (EUVL)
• Resolution Enhancement Technology (RET)
• Absorbance Modulation Optical Lithography (AMOL)
• Electron and Ion Beam Lithography
• X-ray Lithography
• Nanoimprint
a o p t Technology
ec o ogy