Practice Paper I Time Altwed: 3 Hours) General Instructions: (#) All questions are compulsory. [Macimum Marks: 70 (ii) Question mambers 1 to S are very short answer questions, carrying 1 mark each. (iii) Question numbers 6 to 12 are short answer questions, carrying 2 marks each. iv) Question numbers 13 10 24 are also short answer questions, carrying 3 marks each. (7) Question numbers 25 to 27 are tong answer questions, carrying $ marks each. (ii) Use log tables, if necessary. Use of Calculator is not permitted. « Which of the following ions is smallest, why? N*, OF" F 1 What type of magnetism is shown by a substance if magnetic moments of domains are arranged in the same diection? On adding NaOH to ammonium sulphate, a colourless gas with pungent odour is evolved which forms a blue coloured complex with Cu”* ion, Identify the gas. 1 What is meant by common ion effect? 1 ‘Why is the staggered conformation of ethane more stable than eclipsed conformation? 1 (a) State the law of constant composition. (8) Why isthe molality of solton independent of ‘temperature? 7. (@) Predict the sign of AS for the ‘lowing reaction: CaCO,(s) + Ca0{s) + CO.e) (b) State Hess's law. OR we 2 Define: (a) Standard enthalpy of formation. (b) Standard enthalpy of neutralisation. 8 Caleulte the bond order of N and N,” = 2 [Molar mass of AgBr = 188 g mol"', Atomic mass of Br = 80 g mol '] li, (a) Name the gas formed by incomplete combustion of coal. Also, write the chemical reaction in its formation. (b) Suggest a reason to why this gas is poisonous? 2 12, (ay What are CFCs? Give an example. (b) What is the harmful effect of CFC? 2 13, 10g of Ag reacts with I g of S. Calculate the mass of Ag,S formed. eee two reactants remain unreacted? If yes, wl and what would be its mass? k (Atomic mass of Ag = 108 u, $= 32 u} 14, Complete the following equations: (i) NH, + 3Cl,(excess) —> (id) (NH),Cr,0, > (i) HPO, > 15, (a) Define Hund’s rule. (b) Write the electronic configuration of (14253), Cr"(24). (c) Define Pauli’s exclusion principle. 3 16, Give reason; 3 (a) Why are cations smaller than neutral atoms? (6) Fluorine has lower electron gain enthalpy than chlorine. (©) Sulphur has lesser ionisation enthalpy than phosphorus.1. @ (@) Which of the following has minimum bond angle? H,O, CO,, NH,, CH, (6) (@) Why is-bond stronger than -bond? (ii) How many o and n-bonds are present in the following compound: No ay (14263) 18. Define the an 3 19. 20. ais (a) Critical temperature (4) Avogadro law (c) Charles’ law oR (a) What type of defect is shown by NaCl? (b) An element ‘X” [Atomic mass=40 g mot '] having fec structure has unit cell edge Tength of 400 pm. Calculate the density of x, (142=3) (a) What is the oxidation number of Cr in K,Cr,0.? (0) Balance the following equation in basic medium by ion-electron method: Zn + NO, —> Zn* + NH, (142=3) (a) What is heavy water? Calculate the molecular weight of heavy water. (b) Why should heavy water plants be near to fertilizer industry? 3 (a) Why are group 2 elements harder than group 1 elements? (b) Write balanced equations for the following: (@ KO, and HO (ii) K,O and CO, (142=3) (a) What type of isomerism is shown by cis-2-butene and trans-2-butene? (b) Why is cone. HNO, added to sodium extract (Lassaigne’s extract) before testing for halogens? (c) What is the IUPAC atielot a 24, What is the value of equilibrium constant for the following at 400 K? 2NOCI (g) == 2NOLE) + Cla(g) AH? = 77.5 kJ mol', R = 8.314 JK! mor', AS = 135 JK! mol! 3 25, (a) How will you convert the following: (i) Acetylene to Chlorobenzene i) Ethyl bromide to Ethyne (b) Give a chemical test to distinguish between hexane and hexene (c) Give reason: (i) Why does neo-pentane has lower boiling point than n-pentane? (i Dry ether is used as solvent in Wurtz reaction. (2+142=5) OR (a) An alkyl halide *X° (C,H,Cl) on reaction with KOH (alc) gives alkene *Y* which on reaction with water in presence of H,SO, gives *Z’. ‘2’ is also obtained from *X” by reaction with ag. KOH. Identify X, ¥, Z and write the reactions involved. (5) Complete the following reactions: @ O alae, wo © Jr, > aes 26. (a) Account for the following: (@) SiF, forms SIF, while CCl, does not form ccs (ii) PbCI, is more stable than PbCI,. (ii) SnC\, is solid, whereas SnCl, is Fiquid. (6) Complete the @ si+ cH! =eoO 27, (@) The concentration of hydrogen ion samp! ots ik 0» 10" Mt What (o wane pedi [log 4 = 0.6021) (®) What is meant by ®) Pen for reaction w&) is the +e Ag) === 2HIg) is 4. onic product wi a eerie —@ ran } == tig + Hor : sole Re prove? What is the ce effect of temperature on K, 2242418) ‘ aca ta a tswers protenstheretre, SNE . mccharee mutha wy E Bin is! : 2NH,(g) 4, What happens when PCI, is heated? 1 5. Why does thermal stability of carbonates of group 2 increase down the group? 1 6. Calculate the number of atoms in each of the following: (a) 7.85 g of Fe (Atomic mass of Fe = 56 u) (4) 4.68 mg of Si (Atomic mass of Si= 28 u) 2 7. Elements X, Y and Z have 4, 5 and 7 valence electrons respectively. (@ Write the molecular formulae of the compounds formed by these elements individually with hydrogen (b) Which of these compounds will have the highest dipole moment? 2 8 (a) When water freezes in a glass beaker, what happens to AS (system) and AS ( ing)? surrounding)’ (b) What are the possible values of g, W and AT in free expansion Baas iea pt une adiabatic process? 9. Which acid pair shown here would you ae to be (a) FCH,COOH or CICH,COOH OH 0) O or CH,COOH 2 10, (a) Which of the following compounds will ‘not exist as resonance hybrid? Give reason for your choice, CO}, CHOH, SO}, CH, (b) An alcohol (boiling point 97 °C) was mixed with a hydrocarbon (boiling pout 68 °C). Suggest a suitable method to separate them, Explain the reason for your choice. 2 OR Calculate the percentage of Cl in organic compound, 0.2175 g of which in the Carius method gave 0.5825 g of AgCl. 11. Account for the following: (i) Solid PCI, is ionic in nature. (i) Draw the srstre of H,POs, What its basicity? 2 () Why is sheen less coanttoe — eli Bp 12. (ii) NF, ——— Ohio 13. (a) What is meant by F-centre? (b) Calculate the number of unit cells in 8.1 g of Al if it crystallizes in fec structure. 3 [Atomic mass of Al = 27 g¢ mol-I} (a) What is photoelectric effect? (b) Account for the following: ( The expected electronic configuration of copper is [Ar] 3d°4s? but actually it is (Ar) 30!4s! Gi) In building up of atoms, the filling of 4s-orbitals occurs before 3d-orbitals. (14253) 15. (a) Write the electronic configuration of Cu! ion (Z = 29), (6) Calculate the de Broglie wavelength of a milligram sized object moving with 1% speed of light, Planck's constant (/1) = 6.63 < 10 kg ans : Velocity of light (c) = 3.0 10% ms! (1+2=3) 16. (a) Which of the following species will have the largest and the smallest size? Mg, Mg", Al, Al", Na, Na’, Li, Li? = Practice Papers | 438ow (b) Predict the formulae of compounds formed by the following pairs of elements: (i Silicon and Fluorine (ii) Aluminium and Phosphorus (© Arrange the following elements in increasing order of non-metallic character: B,C, Si,N,F 3 (a) Which hybrid orbitals are used by carbon in compound CH,COOH? (b) Predict the shape of PF; using VSEPR model. (c) Write one difference between a sigma bond and a pi bond. 3 (a) For the equilibrium, PCl(g) === PCI,(g) + Cly(g) at 298 K, K = 1.8 * 107. Calculate AG° for the reaction. (R = 8314 JK"! mot) (6) What will be the sign of AS for the reaction: Ng) + Og) —* 2NO(g) — Heat Give reason in support of your answer, 3 (a) Two gases O, and N) are at temperature 298 K. What is the ratio of their kinetic ies? (6) A balloon is filled with hydrogen at room temperature. It will burst if pressure exceeds 0.2 bar, Ifat 1 bar pressure, the ‘gas occupies 2.27 L volume, up to what volume can the balloon be expanded? (142-3) (@) Balance the following equation by ion electron method: (acidic medium) Bi +NO, —+ Bi +NO, (b) Acellis prepared by dipping a copper rod reduction potentials of copper and nickel 4 ste 0.34V end -025 V opty cia ae eae 21. Complete the following reaction 3 (a) H, + MoO, (b) CO(g) + Hg) 2a , (c) CaO + HO > 22. (a) Write resonating structures of benzene (b) Write IUPAC name of the following ‘compound. CH,—CH—C—CH—CH I Br O CH; (o) Write structural formula of 4-chloro-2-pentene. ia OR ol (a) Why is (CH,),C® more stable than (CHy),CH"? {yates a (6) Write IUPAC name of compound: + is IL f ‘i CH,—C—CH,—CH,—CHO- (©) Name the process used to separate sugar and salt. 23. (a) Complete the following reaction and also give the type of reaction: oe oa —BS,2 + ZnBr, Br Br (5) How will you distinguish between ‘i Or erent Coat (¢) Write the major organic product produced | in the following reaction: CH;CH,CH=CH, + HBr BS, 3 (@) Define primary pollutants of the air. (b) Write the name of gas produced in ‘Mathura refineries which can damage thecl AY (if) cH) + KOH (ale,) ——> (c) How will you convert: (i) sodium benzoate to benzene? (ii) propene to 1-propanol? (1+2+2=5) OR (a) Why is iodination of methane reversible process? (b) What happens when: (i) methane is oxidised at 523 K and 100 atm in presence of Cu? (ii) ethane is heated with oxygen in presence of manganese acetate? (©) Why does iso-butane get oxidised by KMnO,? (d) Mlustrate isomerisation reaction with an example. (1424141=8) (a) Give equations for the following: (i) Preparation of CO, (ii) Basic properties of Na,CO, (iii) Formation of (b) What is dry ice? Why is it called so? How will you prepare pure sample of CO (carbon monoxide)? (342-5) OR (a) Account for the following: ( Boron forms electron deficient ‘compounds (ii) PbCI, is less: stable than SnCl,. 21, (ii) producer ga uses. Wh happens when CO, is passed through lime water (1) for short duration (2) for a lo duration? (+35) (a) Calculate pH of an aqueous solution of 1.0 M ammonium formate assum) complete dissociation (pK, of HCOOH = 3.8 and pK, of NH, =4.8) (6) State the formula of conjugate base of each of the following acids: () 1,0" (i) HS, (ii) HPO, (iv) CH,NHS (o) Arrange the following in increasing order of basicity: | Hts) ofthe Fiery Cy bit deren A sen having pH = 3. Assuming no ¢ P volume, calculate concentration of Sac ion in resulting solution. (2+3=5) Te 1 B 6COxg) + IHL; ACH? = 3266.0 KI mol"!AH 393.1 kJ mol ! Hyg)+ 5 Oxg)-+H,0():4, H = -286.0 kJ mot! 20. (a) Give an example of redox reaction (}) Balance the following redox reaction by ion- electron method (in acidic medium): (C10? + Fe +H’ —+ Cr + Fe + H,0 (14253) effect of temperature in 21. (a) Name the isotope of hydrogen in which (A) exothermic (ii) endothermic reversible neutrons are twice the number of protons. reactions? (1+2+2=5) (6) Complete the following equations: 26. (a) Draw the structure of AlCl, 4) Mg(HCOs)> + Ca(OH); —> () What happens when: (i) KI + HO, —> (14253) (i) aluminium is reacted with dil, H-SO,? OR (ii) boric acid is added to water? (a) How would you prepare a sample of ND;? (6) Give suitable reasons: (b) Which of the substances present in water (® B does not form B® ion. cause permanent hardness of water? (ii) Acidic character of dioxides of group 14 (i) In qualitative anal P acidic medium for up IL (c) State Le Chatelier’s principle. What is the (c) Name the process used for the manufacture decreases down the group. (1+2+2=5) of heavy water. 3 OR 22. (a) Arrange the following in order of the (a) Complete the following reactions: icied ngeieadl acid () Zn0 +CO—> (it) NaxCO + HCL—> aH ae era —CH —CH, ic iiGioeremee 3» CH;CH, CH; —C ae ‘1 (i) Graphite is a conductor of electricity: (ii) Gallium is smaller than aluminium. (W) CICH;COOH, FCH;COOH, BrCH;COOH, Halper ahi rectalinocitcato: o Sn a mele Coe a tee | oy geeun ectamereces oat ite the isomerism among ig a : i ic nee Gnoe! (@) Explain the following reactions with sutabe 23. (a) Write the TUPAC name of the following | (@ Decarboxylation compound: >i CHy-CH—CH,—CH—CH, a (6) What are ‘A’ and So[Main Mark Time Allowed: 3 Hour General Insiructions: AS given) Practice Paper 1 compound by heating with fur sulphuric acid? ccount for the following: (a) K,CO, cannot he prepared by Solva 1. Arrange the following in increasing order of ionic radii F,O%, Me™, Ne 2, What type of solid is SH i. / 2 Give reason. 1 ” process 3. Why does PCI; fumes In moist air: 1 a sats aint ee “A, What is the relationship between K,and Ke fu () fee ne arth m ; eS oe ) + HCl(g) 12. Write balanced equations for the reactions ‘ : 1B i between sg Amange the ftlowingin inereasing ordet ofthe eG property indicated: es ace aoe ' Bede Bsns Me {soluility tg wn | 22 Comeles the following reactions 3 i ( Mg +N 6. The density of 3 molal solation of NaCl is 1.110 g mI", Calculate the molarity of the solution. 2 (i) Cad (id) P, + 3NaOH + 31,0 — > oR 4. (a) Slate Heisenberg’ uncertainty principle 1M solution of NaNO; has density 1 25 gem”. (b) An electron has 0.1 nm uncertainty i Calculate the molality. position. ‘What will be the ‘uncertainty In [Molar mass of NaNOs is 85 ¢ mol!) 2 1. Explain the non-linear shape of HaS and oe-planar shape of PCls using valence shell ‘velocity. 1= 9.1 «10! kg t= 6.626 x 10° Js} 15, (a) Write all the four quantum numbers of (m= ‘electron pair repulsion theory. 2 an electron in the valence shell of RB(37). £8, Catenlate the enthalpy change of the following (6) Calculate the ratio of velocities of reaction: electron and proton if both have equal Hg) + Brg) —> 2HBr(g) wavelength. 3 Given that bond energy of Ha, Br2 and HBr is i435 KD mot, 192 kJ mot! and 368 kJ mol” respectively 2 9. (a) Wentify the most stable species in the following set of ions giving reason: Gu, Grypr, Cubs, &8:, (®) Waite the structural formula for the compound named 5-bromoheplancic acid. 2 10, (a) Will CCI, give white presipitate of AgCl con heating with AgNO) solution? Give reason for your answer. (b) In Kjeldahl's method, the nitrogen in organic compound is converted into which 444 | Together with® Chemistry ~ XI [m,=9.1 10" kg, m,= 1.675 * 1077 kg) 16. Aapags helena 8-7 OM SI ° (a) increasing first ionisation enthalpy. (b) increasing ‘non-metallic character. Give reason for the arrangement assigned. 3 17. Caleulate the bond order of H:°, Hes" and O2 afer writing their electronic configuration. Predict their magnetic behaviour also. 3 18 (a) Critical temperature of H,, He, O, and N, are 332 K, 5.3 K, 1583 K and 126 K respectively. Arrange them in the order of liquefication of gases.(b) How is the viscosity affected by increase in temperature? (©) Under which conditions, a gas deviates most from an ideal gas behaviour? 3 19, When 2.0 g of propane was burnt in excess of oxygen in a bomb calorimeter at 300 K, 105 ki of heat was evolved. Calculate AH and AU of the reaction at 300 K. 3 20. (a) What is the oxidation state of each *N” in NH.NO;? (6) Balance the following equations by ion-electron method in acidic medium: (i) SO; + H’ + Cr30* —>+ Cr* + SO, + H,0 (i) MnO, + COO’ + H” —> Mn” + CO, + H,O coo (142-3) 21. (a) Name the radioactive isotope of hydrogen. (6) Complete the following reactions: @ CO@) + 2g) —24> (ii) Na,O(s) + HO) —> (142-3) OR Complete the following reactions: (a) Ca(HCO,), “> (b) CaCl, + Na,co, —> (o) KMnO, + H,SO,+H,0,—> 3 22. (a) Which of the following are aromatic in nature? (b) Draw Newman and Sawhorse projections for the eclipsed and staggered confor- mations of ethane. Which of these conformations is most stable and why? (Q2+1=3) 23. Explain the following terms: 3 (@) Acid rain (b) Green chemistry (c) Chemical Oxygen Demand (COD) m4. 25. 26. Write the IUPAC compound: cH | cH,—Cc=C | Br (a) name of the following CH,OH (0) Predict the major products of the following reactions: () CH;—CH=CH, S462, (i) CH;—CH=CH, + HBr —> (142-3) On the basis of Le Chatelier’s principle, explain how temperature and pressure can be adjusted to increase the yield of ammonia in the following reaction: N,(g) + 3H,(g) == 2NH,(g); AH = = 92.38 kJ mol! ‘What will be the effect of addition of argon to the above reaction mixture at constant volume? Calculate the pH of 10 M HCI solution. G+2=5) () OR The value of K, for the reaction 2HI(g) = Hg) + L(g) is 1 * 104. At a given time, the composition of reaction mixture is [HI] = 2 « 10° M, (H,] = 1 « 10° M and (I,] = 1 x 10° M In which direction will the reaction proceed? The ionisation of hydrochloric acid in water is given below HCI(aq) + HOW) == H,O"(aq) + Cl(ag) Label two conjugate acid-base pairs in this ionisation, (24365) Name the element of group 13 which exists in liquid state for a wide range of temperature and can be used for measuring high temperature, Which of the following is Lewis acid? AICI, MgCl, CaCl, BaCl, (a) (6) (a) (b) Practice Papers | 44521, (c) @) © (@ (b) © 0) © What is the hybridisation of orbitals of central atom in (Be(OH),?? and the geometry of the complex? Which of the following is most acidic in ‘nature: B,O,, Al,0,, Ga,O,, In,O, Why does *B’ not form BF,°? 5 oR Is borie acid, protic acid or Lewis acid? Wh: “How does the tendency to show catenation vary down the group 14? Arrange the group 13 elements in increasing order of first ionisation enthalpies. A compound *X” of boron reacts with ammonia on heating gives another ‘compound *Y’ which is called inorganic benzene. The compound *X’ can be prepared by treating BF, with LiAlH,. Identify the compounds *X’ and *Y’ and write the reactions involved. (14141425) Why does the presence of nitro group make the benzene ring less reactive towards electrophilic attack as comparison to the unsubstituted benzene ring? Explain. Convert acetylene to nitrobenzene, Classify the following into electrophiles and nucleophiles: ( HCO” (i) cr (iii) (CH,),C* (iv) CH,OH ‘What is the order of reactivity of HI, HBr, HCI with propene? —_(14142+1=5) OR (a) Arrange the following alkyl halide decreasing order of the rate of elimination reaction with alcoholic KOH: CH, — CH — CH,Br, CH,CH,Br, HCN Gis HC Hof \cH,. (d)_ Arrange the following in decreasing order of their boiling point: n-Butane, 2-Methylbutane, n-Pentane, 2,2-Dimethylpropane (e) Arrange the following in increasing order of reduction with zine and HCL RCI, RI, RBr 3Time Allowed: 3 Hours} Pra ice Paper [Maximum Mark General Instructions: As given in Practice Paper |. 1. Name the alkaline earth metal which shows diagonal relationship with aluminium, 1 2, Predict the sign of AS in the following processes: (a) He) — 2Hle) () Crystallisation of sugar 1 3, Why is second ionisation clements higher than group 2 elements? 1 4, Why does NaCl become yellow on heating with sodium 1 vapours. 5, Why does NH; has higher boiling point than | ony PH;? 6, Calculate the mole fraction of solute if molality of solute in aqueous solution is one. {Molecular weight of HO = 18 g mol] 2 7. (a) Why is H" more stable than H, ? (b) Why doall the bonds in PCI, ‘not of same bond length? 2 8. For the equilibrium: 2NOCKg) == INO(g) + Clg) The value of K. = 3.75 x 10° at 1069 K. Calculate K, at this temperature. (R = 0.083 bar litre K! mol ') 2 oO (a) What is meant by hydrolysis of salt? {b) State Le Chatelier’s principle. 6. (a)_ Arrange the following in decreasing order of stability: ° e (CH,—CH—CH,» CH;—CH—OCH,: CH,—CH —CH,—OCH; (b)_ Write the correct representation involving heterolytic fission of CH;—Br. 10. How will you test the presence of (#) nitrogen i) sulphur in organic compound? Wite the chemical reactions involved. 2 11.) Why is F, more reactive than Cl? i) Which group has lowest ionisation enthalpy. 2 iy? 12, @ Why are noble gases bigger than (ii) Which is the most electronegative element? How does electronegativity Vary down the group? 2 13. (i) Why is NH, more basic than PH,” (ii) Name the best reducing agent in group ‘reason. n= 6 level drops to ground state? (++1=3) 16. (a) Which of the following is linear molecule? HO, COs, NH, CHy What is meant by dipole moment? Why do BeF, and BF, have zero dipole moment? (142-3) 17. An element exists as bee lattice with cell edge Jength 288 pm. Calculate the molar mass if ts density is 7.2 g em 3 oO (b) (a) What are ideal gases? (b) Total pressure of gaseous mixture of 2.8 g of N,, 3.2 g of O, and 0.5 g of H, is 4.5 atm, Calculate the partial pressure of each gas. (14+2=3) 18. (a) ‘A reaction between ammonia and BF, is given below: i :NH, + BF, —> H,N:BF, Identify the acid and base in this reaction. Which theory i? (4) Calculate the volume of water required 10 dissolve | gof AgCl to get saturated solution, (K,, of AgCl = 1.69 = 10) : Practice Papers | 447 sine19. (a) What is the oxidation state of “Cr° in 7. (8) Balance the following ionie equations by ion-electron a $0; + HY Mn? c+ +H — Oe "S00" so Cr, + HS +H — +S (ii) Cr,0?> + HyS ae onde) 20. (a) Calculate the molarity of HO, labelled as 10 volume of H,0,. (b) Give one use of H,0,. (2+1=3) 21, Give reason: its 3 (a) RbO, is paramagnetic in nature (b) Lithium does not form peroxides and superoxides. (6) Li,CO, decomposes on heating, whereas ‘other alkali metal carbonates do not decompose. 22. (a). Which of the following has dipole moment and why? 2,2-Dimethylpropane, trans-Pent-2-ene, cis-Hex-2-ene, 2,2,3,3-Tetramethylbutane (b) Why does —NO, group present on benzene ring deactivate and m-di in electrophilic substitution reaction? (c) What are free radicals? How are they formed? 3 23. Complete the following reactions: 3 @) CH, —GH— CH, — CH, a + KOH (ale) —> (b) CHBr, + Zn(dust) —Y2 | CHBr, (©) CH,CH,OH 248. 5 Te eT 1. How ee apply green chemistry for the (a) To control photochemical (b) To avoid use of halogenated solvents in dry-cleaning and chlorine in bleachin (6) To reduce use of synthetic detergents. 4 25, (a) How will you carry out followin, conversions? - (@) Ethyne to 14 (i) Bentene wo hotoph (ii) Benzene to Toluene 448 | Together with” Chemisnry — xy (ii) CH=CH, + HO ——> (b) Why does nitration of benzene with HNO, need the us? of conc. H,SO,” (c) Convert I-hexene to -hexyne G+l+15) (a) The AS,,, and AH,,, of liquid hydrogen fluoride are 25.7 J K' mol ' and 7.53 kJ mol ', respectively. Find its boiling point (b) State and explain the third law of thermodynamics. (c) Why is AH? of an element in elementary state taken as zero? (2+2+19S) OR (a) Calculate the value of the equilibrium constant of the following reaction at 298 K Hg) + L(g) == 2HI(g); AH = +51,88 kJ mot! 'S°[H,@)] = 130.6 JK mot !, S°L@)] = 116.73 J K* mot, S*[HI(g)] = 206.27 JK! mor! () State and explain the first law of (a) wn me (a) Why can CCI, not be hydrol (8) The dipole momen of CO; toro, wt © Borie acid is aprotic acid, why? ( is i trols sayht eee ee fe) Act, is Lewis acid, why? &