Examination Paper, 2014 [NCT] ne allowed: 3 Hours] [Maximum Marks: 7¢ neral Instructions: 1. All questions are compulsory. 2. Marks are indicated against each question. Question number 1-5 are very short answer questions carrying 1 mark each. Question number 6-10 are short answer questions carrying 2 marks each, . Question number 11-22 are also short answer questions carrying 3 marks each, 6. Question mumber 23 is value based question carrying 4 marks. ~ Question number 24-26 are long answer questions carrying 5 marks each. 8. Use log table if necessary. Use of calculator is not allowed. . Define limiting reagent. - Write the IUPAC name and symbol for the element with atomic number 120. |. Write Van der Walls equation for ‘n’ moles of a real gas. . Predict the sign of the entropy change for the change: HO) > HO . What is the state of hybridisation of each carbon atom in C,H,? 6. Calculate the number of atoms in each of the following: - (a) 52g of He (b) 52 moles of Ar (gm. atomic mass of He = 4 g/mole) 7. How many electrons in an atom may have the following quantum numbers? awne Py (a) n=4,m,=-% (b) n=3,1=0 8. The concentration of hydrogen ion in a sample of soft drink is 3.8 < 10° M. What is its pH? (log 3.8 = 0.58) “a OR Drive the relationship between K, and K,. 9. Account for the following: (a) K,CO, cannot be prepared by Solvay process. (+) Alkali metals are not found in nature. 10. Props an potanone are the ozonolysis past of an alse, What the statu rma of the alkene? ML. (a) State Hund’s Rule. ae (6) What will be the siavelength of bal 12. (a) Write the configuration 0 (b) Draw the foie of. de «2 8 21, 22. 23. 450 Write the molecular orbital configuration of N,. Calculate its bond order and predict its magneti behaviour, - Describe the hybridization scheme in case of PCI,. Why are the axial bonds longer as compared to equitorial bonds. . (a) Calculate the total pressure in a mixture of 8 g of dioxygen (O,) and 4 g of dihydrogen (H,) confined in a vessel of 1 dm‘ at 27 °C. R = 0.083 bar dm’ K! mol ! (6) Critical temperature for CO, and CH, are 31.1 °C and -81.9 °C respectively. Which of these has stronger intermolecular forces and why? . (a) For the reaction, 2CI (g) — Cl, (g) , what are the signs of AH and AS? (b) For the reaction at 298 K, 2A + B > C. AH = 400 kJ mole! and AS = 0.2 kJ K! mole! At what temperature will the reaction becomes spontaneous? . (a) What is the oxidation number of Fe in Fe,O,? (b) Balance the equation: MnO, + Fe® — Fe® + Mn® + H Complete the following reactions: (a) Zn +NaOH > — (b) MnO, + H,0, -» (ce) Ca(HCO,), + Ca(OH), > OR How is HO, peroxide prepared industrially? Explain why it is stored in coloured wax-lined glass or plastic bottles. . Comment on the following observations: (a) The mobilities of the alkali metal ions in aqueous solution are: Li < Na’ < K’ < Rb’ < Cs* (b) Lithium is the only alkali metal which forms nitride directly. (c) A solution of Na,CO, is alkaline. Write the IUPAC name of the following. OH (a) coor 0) (©) CH ici cet ON CH=CH, (a) Arrange the following in order of property mentioned against each: : 2.9 s ( (CH),C :, CH—CH—CH,, CH CH, [Increasing stability] (ii) H—COOH, CH,COOH, Cl—CH,—COoH aceeabia eee (6) Write the name of isome: [Increasing acidie strength] rism among the following compounds: i CH,—CH,—CHO and ela, A trainee pilot was flying his plane in stratosphere. His senior advised hg in the stratosphere. Ssphere. His senior advised him not to fly the aeroplane Answer the following questions: In your opinion, why the senior pilot meat @ eo , y °F pilot advised his trainee pilot not to fly his plane in the Together with® Chemistry — XIib) te) 24. (a) (b) (a) (b) 28. (a) (b) (a) (b) s = (@) Write the possible chemical reaction affecting the stratosphere, Mention the values associated with your reply. Define Le-Chatelier’s principle, What is the effect of: () Addition of H, (ii) Removal of CO on the equilibrium: 2H,(g) + CO(g) —— = CH,OH(e) Determine the pH of 10 *.M NaOH solution. oR Explain the following with example: () Common ion effect (i) Buffer solutions Ata certain temperature and total pressure of 10° Pa, iodine vapour contains 40% by volume of I atoms: I(g) == 2I(g) Calculate K, for the equilibrium. Explain the following: (i) Lead does not form PbI,. Gi) Boron is unable to form BE,” ion. iii) [SiF is known whereas [SiCI,]* not. Complete the following reactions: (a) Zn0 + CO > (6) BH, + NH, —*> OR If the starting material for the manufacture of silicon is RSiCI,, write the structure of the product formed. Give reasons: (i) Graphite is used as lubricant. (ii) Diamond is used as abrasive. ii) All alloys are used to make aircraft body. A Which of the following compound will show cis-trans isomerism: (i) (CH,),C—CH—CH, (i) C.H,CH=CH—CH, Which isomerism is shown by following pair of compounds: CH,—COOH and HCOOCH, Complete the following reactions: () CH,—CH=CH, + HBr fae 5? (i) CH,—C1 + Na Se (iii) cae CH,—CH, SA? a OR.Examination Paper, 2015 [NCT] ____— allowed: 3 Hours] E eral Instructions: All questions are compulsory. Marks are indicated against each question. 1 xd . Question numbers 1-5 are very short answer questions carrying 1 mark each. . {. Question numbers 6-10 are short answer questions carrying 2 marks each. $. Question numbers 11-22 are also short answer questions carrying 3 marks each © 6. Question number 23 is a value based question carrying 4 marks. 7. Question numbe +s 24-26 are long answer questions carrying 5 marks each. 8. Use log tables, if necessary. Use of calculators is not allowed. 1. Write the IUPAC symbol for the element having atomic number 118, 1 2, Which of the following has maximum bond angle? 1 HO, NHy, CHy, C3Hy 3. How many atoms of magnesium are present in 96 u of Mg? 1 4. Which gas law is shown by the following graph? 1 4 PV 1_—__———» 5. Arrange the following in decreasing order of -I effect: 1 — Br, -Cl,-F 6. (i) Define Pauli’s exclusion principle. 2 (ii) Write electronic configuration of Cr (Z = 24), OR ‘The mass of an electron is 9.1 x 10°! kg. If its kinetic wn length. me 4 482 ogether wtth® Chemistry ~ XI7. For the reaction: 2A(g) + B(g) —> 2D(g) AU® = 10.5 kJ and AS® = 44.1 JK! mot, Calculate AG® for the reaction and predict whether the reaction may occur spontaneously. 2 8. Comment on the following observations: (a) The mobilities of the alkali metal ions in aqueous solution are: Lit < Nat < K* < Rb* < Cs" (b) Be and Mg do not give colour to flame, whereas other alkaline earth metals do so. 9, What happens when: (a) Sodium metal is dropped in water. (b) Sodium metal is dissolved in liquid ammonia. 2 10. Write the IUPAC name of the following: 2 (a) OH NO, (b) CH, —CH—CH,—CH CH=CH, 11. Calcium carbonate reacts with aqueous HCI to give CaCl, and CO, according to the reaction: CaCO,(s) + 2HCKag) —> CaCl,fag) + CO,(g) + H,0() What mass of CaCO, is required to react completely with 25 ml of 0.75 M HCI? [Molar Mass(g mole!) : Ca = 40, C = 12, O = 16, Cl = 35.5, H = 1] 3 12. Give a brief account for the following: (a) Anions are bigger in size than their parent atom. (b) Oxygen has lesser first ionization enthalpy than nitrogen. (c) Fluorine has less negative electron gain enthalpy than chlorine 3 13. Give the shapes of following covalent molecules using VSEPR theory: (i) PCI, (ii) CIF, (ii) XeF, 3 Latest Examination Papers | 453rh 1S. (a) In terms of Charle’s law, explain why -273°C is the lowest temperature. (b) Ca ‘ulate the total pressure in a mixture of 8g of oxygen and 4g of hydrogen confined in a sel of 1 dm? at 27°C. [Given R = 0.083 bar dm’ K! mole '] 3 OR (a) What will be the minimum pressure required to compress 500 dm? of air at 1 bar to 200 dm* at 30°C (b) Critical temperature for CO, and CH, are 31.1°C and -81,9°C respectively. Which of these has stronger intermolec forces and why’ 16. (a) State Hess’s law. (b) Give a brief note on the following thermodynamic terms. (i) Standard enthalpy of combustion. (ii) Standard enthalpy of formation. 17. (a) What is the oxidation number of Fe in FeO? (6) Balance the equation: HY + MnO; + Fe** —> Fe** + Mn®* + HO (Acidic medium) 18. (a) What causes the temporary and permanent hardness of water? (6) Explain why H,0, is stored in coloured wax lined glass or plastic bottles? 19. Account for the following: () Boron trihalides (BX,) act as lewis acid, (ii) PbCI, is a powerfull oxidising agent. (iii) Graphite acts as a good lubricant. 3 20. Complete the reactions: (i) ZnO + CO—> Gi) By, + NH, (iii) Na,B,0, + HCI + 1,0 — 21, (a) Which of the following compounds will show cs-trans isomerism and why? (0 (CH,),C=CH—CH, (ii) CH\CH=CH—CH, 454| Together octh® Chemistry — XI(>) Which isomerism is shown by following pair of compounds: CH,COOH and HCOOCH, 22. Arrange the following in order of property mentioned against each: 3 @ () (CHy)sC, CH;—CH,—CH, CH,—CH,—CHy—CH, be [Increasing stability) (i) HCOOH, CH,COOH, CH,CH,COOH [Increasing acidic strength] Hy (iii) CH,, CHy cu -CH,, CHy —C [Increasing stability) CH, ce student and his friends to start a campaign to motivate people to reduce global warming by minimising the use of outomobiles, motivating them to use bicycle, public transport oF go for carpool, which is also economical and should plant trees to increase the green cover, avoid burning of dry leaves, wood ete, but also motivated for the plantation, 23. Ramesh a sci Answer the following questions: ~ |. Name the two greenhouse gases. 2. What is global warming? 3. What values are associated with Ramesh’s campaign? 4 24. (a) Show that the circumference of Bohr’s orbit for the H-atom is an integral multiple of the de- Broglie wavelength of electron revolving around the orbit. (6) Explain that the effect of the Heisenberg uncertainty principle is significant only for motion of microscopic objects and is negligible for that of macroscopic objects. [h = 6.626 « 10 ™ Js, Mass of electron = 9.1 « 10"! kg} (c) State Hund’s Rule of maximum multiplicity 5 OR (a) The energy associated with Bobr’s first orbit is -2.18 = 10'* J atom ', What is the energy associated with fifth orbit? (6) The work function for Caesium atom is 1.9 eV. Calculate the threshold wavelength. [Given : 1 eV = 1.6 « 10°79] (c) How many subshells are associated with = 4? 25. (a) Explain the following with example: ()) Common ion effect (®) Buffer solution. Latest Examination Papers | 455s ain 40% ‘. (b) Ata certain temperature and total pressure of 10° Pa, iodine vapours contain 40% by volur of | atoms: 1,2) == 21() Calculate K,, for the equilibrium OR (a) Define solubility product. Write solubility product expression in terms of molar solubility | FeCl. (b) State Le-Chatelier’s principle. ion is 4.0, What will be the equilibrium constant for 1 (c) Equilibrium constant for the reacti reverse reaction. (d) Calculate the pH of 10° M HCI solution. 26. (a) Give the main product of the reaction: Anhy. AICI. rn CO + CH,—Cl ————> n i) Cor HO eg CH, (b) How can you convert the following: (i) Acetylene to Nitrobenzene (ii) 2-Bromopropane to 1-Bromopropane (iil) Give a chemical test to distinguish between ethene and ethane. 4 OR (a) Out of benzene and toluene, which will undergo nitration more, easily and why? > hale eae (b) Complete the following reactions: (9 CH,—CH=CH, + HBr == Organic Peroxide ary.NCT Examination Paper 2018 Time allowed: 3 Hours] [Maximum Marks: 70 General Instructions: (i) All questions are compulsory. (ii), Question number I to 5 are very short answer questions carrying 1 mark each, (iii) Question number 6 to 10 are short answer questions carrying 2 marks each. (iv) Question number 1] to 22 are also short answer questions carrying 3 marks each. (v) Qu (vi) Question number 24-26 are long answer questions carrying 5 marks each. stion number 23 is value based question carrying 4 marks. (vii) Use log table if necessary. Use of calculator is not allowed. 1. Which of the following orbitals are possible? 1 Ip, 2p 2s, 3 2. Why boron trifluorides behaves as a Lewis acid? 1 3. What is Anti-Markownikov’s Rules? 1 4, What are nucleophiles? Give one example. 1 5. Define intensive property of a system. 1 6. Calculate the concentration of HBr solution in mole I"! in a sample which has density 1.50 gL~! and mass per cent of HBr in it being 48%. 2 (Molar mass of HBr = 81 g mol!) 7. What is the number of photons of light with a wavelength of 4000 pm that provide 1 J of energy? 2 8. Explain the physical significance of van der Waals constants ‘a’ and ‘bi 2 @®9, Define: (1) Enthalpy of formation (2) Isolated system 10. Give IUPAC names of i (1) CH,—CH: =C— I OH H OH NH, (2) Or In sulphur estimation, 0.157 g of an organic compound gave 0.4813 g of BaSO,. What is the percentage of S in the compound? (Atomic mass of Ba = 137 g mol, § = 32 g mol, O= 16 g mol) z 11. Arrange the following in their increasing order of number of atoms: (i) 1 g Au (s) (Z = 197 u) (ii) 1 g Na (s) (Z = 23 u) (iii) 1 g Cl, (g) (Z = 35.5 u), 2 12. Explain (a) (i) Aufbau’s Principle (ii) Pauli’s exclusion principle (b) Write electronic configuration of Cr(Z=24) (i Out of N and O which have high first (ii) Write general electronic conf guste (iii) Define hydrogen-bonds. ; 14, (i) Determine group and block 35. (ii) Define pie (x) bonds. 13.15. Calculate the volume occupied by 8.8 g of CO, at 31.1°C and | bar pressure. (R = 0.083 bar L/K/mol) 3 16. (i) What is the shape of following molecules on the basis of VSEPR theory: 3 (1) XeF, (2) SF, (ii) Describe the change in hybridisation (if any) of the Al atom in the reaction: AICI, + Cr —> AICI; 17. The enthalpy of formation of CO(g), CO,(g), N,0,(g) and N,O(g) are —110, -393, 9.7 and 81 kJ mol respectively. Find the value of enthalpy change for the reaction: N,O,(g) + 3CO(g) —> NzO(g) + 3CO,() 3 18, (a) What causes the temporary and permanent hardness of water? (b) How does H,O, behave as a bleaching agent? 3 or How is sodium carbonate (Na,CO,,10H,0) prepared by solvay process? Write the chemical equations of the reactions involved. 19. Balance the following redox reaction in basic medium: MnO, (aq) + (aq) —> MnO{s) + 119) 20. Complete the following reactions: ( CaC, +N, — + (ii) Na,O, + HO — (ii) Ca(OH), + Cl) — 3 21. (i) Name the metal used in photoelectric cells. (ii) Why diamond is used as an abrasive? a (iii) What are allotropes?22, What happens when (i) Aluminium is treated with dilute NaOH (ii) Boric acid is added to water. (iii) Diborane is reacted with H,0. 23. In winter Jaya’s parents burn coal in Angithi to keep the room warm. One late night, they wanted to keep it with burning coal inside the room. Jaya, a science student, stopped them for doing so. They asked Jaya, why she did not agree with them? Then Jaya told them about the incomplete combustion and harmful effects of burning coal in the deficiency of oxygen. ‘Answer the following questions from above passage: (i) Name the gas formed by incomplete combustion of coal. Also write chemical reaction involved. (ii) Give reasons why this gas is poisonous? (iii) What are the values associated with Jaya’s suggestion? 4 24. (i) Which of the following is not a Lewis acid? H,0, BF,, NH; (ji) The pH of soft drink is 3.76, Calculate the concentration of hydrogen ion in it (iii) For the given reaction: PCI(g) == PCI,(g) + Clg), AH = + 124.0 kd mol at 473 K. What will be the effect on Ke if (@) More of PCI, is added. (6) Temperature is increased? Or (0 Explain common-ion effect with example. (i Mention one application of solubility product. (iii) Calculate the pH of 0.2 M (NH,), CO, solution. Given pk, = 9.02 and pk, = 4.76. ©25. (i) Explain the following terms (a) Inductive effect (b) Carbocations (c) Position isomers. (ii) Complete the following reactions: He" (a) CHy;—-C = CH 43547 ? (b) CH,—CH,—-c1 “=, 2 Or (i) What type of isomerism is shown by pentane and 2-methy! butane? (ii) Give a chemical test to distinguish between ethene and ethane. (ii?) Convert 2-Bromopropane to 1-Bromopropane. (iv) Give a brief account for the following statements (a) n-pentane has greater boiling point than isopentane (b) CH, cannot be synthesised by Wurtz reaction. 2 26. (i) Draw cis and trans structures of hex-2-ene. Which isomer will have higher boiling point and why? (ii) Convert: Ethene to benzene (iii) What is Wurtz reaction? ‘ 2H,0(e) + 280.18) (c) Define state function, For the reaction, + Y(g) > 2F(g) AU? = -10.5 ks and AS® = 44.1 JKT Calculate AG® for the reaction and predict whether the reaction may ‘occur spontaneously. 3 (a) What is the oxidation number of *S'in HS0,? (b) Balance the following equation: Znis) 4NO3(ag) > Zn?*(ag) + NH; (aq) + H" (Acidic medium) 3 ‘of hard water by synthetic (a) Discuss the principle and method of softeni ion exchange resins. (5) Write chemical reaction to show the amphoteric nature of water. 3 Write the IUPAC name of the following: (a) ‘COOH OH ) ON, NO, OH (©) CH.—CH—CH=CH—CH,—cHO CHO20, (a) Arrange the following () -l, Br, - Cl, ~ F [De asing order of 1 effect] (i) (CH,),C, CH,—CH,, CH, —CH—CH,, CH, [Increasing order of stability] (b) Which of the following compound (s) will show cis-trans isomerism: (i) (CH,), C = CH - CH, (ii) C,H, CH = CH —CH, 3 21. Explain the followin; (a) Markounikov’s rule (b) Friedal-Craft alkylation (c) Kolbe’s electrolysis 3 22. A certain salt X, gives the following results: (a) Its aqueous solution is alkaline to litmus. (A) It swells upto a glossy material Y on strong heat (c) When cone. H,S0, is added to a hot solution of X, white crystal of an acid Z sepa out. Or asons: HINO, can be transported in aluminium container, (b) Graphite is used as lubricant (c) Diamond is used as an abrasive. In winter, Sonia’s parents burn coal in Angithi to keep the room warm. One late night, they wanted to keep angithi with buming coal inside the room. Sonia, a Science student, stopped them for doing so. They Were surprised and asked Sonia, why she did not agree with them? Then Sonia explained about the incomplete combustion and harmful effects of burning coal in the deficiency of oxygen Answer the following questions: (a) Name the gas formed by incomplete combustion of coal. Also write the chemical reaction involved. (b) Suggest a reason as to why this gas is poisonous. (c) What are the values associated with Sonia's suggestion? 4 ©24. (a) Whatisthe maximum number of emission ops to the ground state? (by An ion with mass number 56 contains 3 units of positive of a H-atom in 30.4% more neutrons than electrons. Assign the symbol to this ion. 4 (c) Which atoms are indicated by the following configurations? (a [Neks3y? Gi [AnBdl4s* or (a) A golf ball has a mass of 40.0 and a speed of 5 mis. If the speed can be measured within accuracy of 2%, caleulate the uncertainty in the position. (b) Out of 2s and 2p which has higher energy? (c) State Hund’s rule (a) Draw the shape of de orbital. 5 25, (a) Calculate the solubility of A,X: in pure water, assuming that neither ind of fon reacts with water. The solubility product of AsXy> Kp = LL «107%. (b) Dihydrogen gas is obtained from natural gas by partial oxidation at steam as per following endothermic reaction. CHe) + H,0(g) = COL) + 3HL9) How will the values of Kpand composition of z affected by: quilibrium mixture be @ increasing the pressure (id increasing the temperature (ii) using a catalyst? Or (a) Determine the pH of 10 8M HCI solution, (log 11 = 1.0414) () Explain common ion effect with example. (c) Mention one application of solubility product. s @ (460)26. (a) In sulphur estimation, 0.157 g of an organic compound gave 0.4813 g of BaSO,. What is the percentage of S in the compound? (At. mass of Ba = 137 g mol!, S = 32 g mol!, O = 16 g mol). (b) Sodium salt of which acid will be needed for the preparation of propane? Write chemical equation for the reaction. (c) Write the mechanism of the following reaction: NO, Conc. H,SO Hone, NO 9 ae +#H,O Or Identify A, B, C, D and E in the following sequence of reactions: 5 Red hot Fe Cl, CaC,+H,0 > A ~~ nibe — B.anty. AICI, Conc. H,SO, ANCT Examination Paper 2016 Time allowed: 3 Hours] te [Maximum Marks: 70 General Instructions: @ (a) (iii) (iv) () (vi) (vii) All questions are compulsory. Question numbers 1 to 5 are very short answer questions carrying I mark each, Question numbers 6 to 10 are short answer questions carrying 2 marks each. Question numbers 11 to 22 are also short answer questions carrying 3 marks each. 9. Question number 23 is value based question carrying 4 marks, Question numbers 24 to 26 are long answer questions carrying 5 marks each. Use log tables, if necessary. Use of calculator is not allowed. 10. In a reaction A + By —> AB), identify the limiting reagent when 2 mole of A are mixed with 3 mole of B,. 1 Write the general electronic configuration of fblock elements. 1 Define critical temperature. 1 Classify the following as Lewis acid or Lewis base: NH,* and NH, What is the oxidation number of Mn in KMnO,? (a) How many sub-shells are associated (b) How many electrons willbe present in7. Give one point to differentiate the following thermodynamic terms:2 (a) Extensive properties and intensive properties (b) Isothermal process and isobaric process. 8. Account for the following: 2 (a) K,CO, cannot be prepared by Solvay process. (b) Alkali metals are not found in nature in free state Or Write balanced equations for the reactions between: (a) Na,O, and water (b) Na,O and CO, 9. Give suitable reasons for the following: 2 (a) [SiFgP> is known whereas [SiCI,]" not. (b) Diamond is covalent, yet it has high melting point 10. (a) Whattype of isomerism is shown by pentane and 2-Methy! butane? (b) Write the name of isomerism among the following compounds: ° CH,—CH,—CHO and CH,—C—CHy LU. Calculate the concentration of nitric acid in moles per litre in a sample which has density 1.40 g ml"! and the mass percent of nitric acid in it being 69%. Molar mass of HNO; = 63 g mol! 12. Account for the following: (a) An anion is always bigger than its parent atom. (b) Chlorine (Cl) have more negative electron gain enthalpy than Fluorine (F). [Atomic no. F = 9% ca=17) (5)13. Give the shapes of following covalent molecules using VSEPR theory: 2 (a) CIF, (b) XeF, (c) ASF, 14, Compare the relative stability of the following species on the basis of molecular orbital theory and indicate their magnetic properties: 3 0F7) 0,5,0, 15. (a)_IntermsofCharle’s law, explain why 273°C is the lowest temperature? 3 (b) Calculate the total pressure in a mixture of 8 g of dioxygen and 4 g of dihydrogen confined in a vessel of | dm? at 27° C [R = 0.083 bar dm? K! mol] 16. (a) For the reaction, 2C(g) —+ Cl,(g), what are the signs of AH and AS? 3 (b) For the reaction at 298 K, 2A + B—> C. AH = 400 kJ mol”! and AS = 0.2 kJ K"! mol"! At what temperature will the reaction becomes spontaneous? 17. Balance the following redox reaction in basic medium: (Write steps of any one method used) 3 MnO," (aq) + (aq) —> MnO4(s) + 15(s) 18. (a) Name the different salts that cause permanent hardness of water. (Any two) 3 (4) How do we obtain demineralised water from hard water after passing it from synthetic ion exchange resins? Give reactions.19. (a) Mention two similarities in the behaviour of Be and Al to show that they have diagonal relationship 3 (b) What is the biological importance of Na in our body? 20. What happens when: 3 (a) Borie acid is added to water, (>) Al is treated with dil. NaOH. (c) BF, is treated with NH,. 21. Write the IUPAC names of the following: 3 (a) 1S a OH NH, (b) ©) oe S Or (a) Identify the reagent shown underlined as electrophile or nucleophile: CH,COOH + OH ——> CH,COO™ + H,0. (6) On complete combustion of 0.246 g of an organic compound gave 0.198 g of CO, and 0.1014 g of HO. Determine the percentage composition of carbon and hydrogen in the compound. 22. Complete the following reactions: 3 Peroxide (a) CH;—CH=CH, + HBr —“"*~? Dry ether (6) CH,—Cl + Na —~——+? ile. KOH. (c) CH;—CH—CH,—CH, a ®23; 24. A factory was started near a village. Suddenly the presence of irritating varpours in the villag factory for such problems. After reading the above paragraph, answer the following questions:4 (a) Explain what could have happend? (b) Give chemical reactions for the support of your explanation. fe Mention the values shown by the student in the above paragraph. (a Write the electronic configuration of Cr(Z = 24). Why is it different from the expected configuration? () The mass of an electron is 9.1 = 10! kg and its kinetic energy is 3 = 10°J. Calculate its wavelength. lc Which of the following orbitals is not possible and why? 2d, 2s, 3p, 3s Or (a) Calculate the wavelength and frequency of limiting line of Lyman series (Rydberg constant = 109677 em”!), (>) Give quantum numbers for electrons with highest energy in sodium atom (Z = 11). tc Which of the following sets of quantum number are not possible? Give reasons: () n= 1,1=0, m,=0, m, = -12 (ii) n= 0,1 = 0, m, = 0, m, = ~1/2(b) (c) (a) (6) 26. (a) (b) equilibrium constant for te eel Sle onan Determine the pH of 10°* M HCI solution taking into account the H' produced by water also. (log 11 = 1.0414) Or At certain temperature and total pressure of 10° Pa, iodine vapour contains 40% by volume of | atoms: 1g) — 2I@) Calculate K,, for the equilibrium. What is the effect of: (i) Addition of H, (ii) Removal of CO ‘on the equilibrium: 2H,(g) + CO(g) == CH,OH(g) Mention one application of solubility product. Propanal and pentan-3-one are the ozonolysis product of an alkene. What is the structural formula of the alkene? Give the main products of the reactions: S @ CO +cH,—c1 Ss ci) Cage ae + H,0 cH,(a) (b) (c) Or An alkyl halide (A) of formula C,H, 3Cl on treatment with alcoholic KOH give two isomeric alkenes (B) and (C) (C,H,)). Both alkenes on hydrogenation give 2, 3-Dimethy] butane. Predict the structure of A, B and C. Why does benzene show electrophilic substitution easily? Name the compound that will be required to obtain butane using Kolbe’s electrolysis process.