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GLUCOPURE SENSE Page 1(15)

Substance key: 000000653207 Revision Date: 18.03.2019
Version : 1 - 0 / RA Date of printing : 14.02.2020

SECTION 1. PRODUCT AND COMPANY IDENTIFICATION

Trade Name: GLUCOPURE SENSE

Material number: 299662
Recommended use: Detergent
Producer or Importer name: Clariant Produkte (Deutschland) GmbH
Address: 65926 Frankfurt am Main
Telephone no. : +49 69 305 18000
MSDS made by: Clariant (Argentina) S.A.
Emergency phone: 00800-5121 5121

SECTION 2. HAZARDS IDENTIFICATION

GHS Classification
Short-term (acute) aquatic : Category 2
hazard

Long-term (chronic) aquatic : Category 3

hazard

GHS label elements

Signal word : Warning

Hazard statements : H401 Toxic to aquatic life.

H412 Harmful to aquatic life with long lasting effects.

Precautionary statements :
Prevention:
P273 Avoid release to the environment.
Response:
P312 Call a POISON CENTER/doctor if you feel unwell.
Disposal:
P501 Dispose of contents/ container to an approved waste
disposal plant.

Other hazards which do not result in classification

None known.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Substance / Mixture : Mixture

Chemical nature : Surfactant

solution

Components
Chemical name CAS-No. Concentration (% w/w)
D-Glucitol, 1-deoxy-1-(methylamino)-, N-(C16- 1591782-99-8 >= 50 -< 70

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18 and C18-unsatd. acyl) derivs.

SECTION 4. FIRST AID MEASURES

General advice : Remove/Take off immediately all contaminated clothing.

Get medical advice/ attention if you feel unwell.

If inhaled : If inhaled, remove to fresh air.

Get medical advice/ attention.

In case of skin contact : In case of contact, immediately flush skin with soap and plenty
of water.

In case of eye contact : In the case of contact with eyes, rinse immediately with plenty
of water and seek medical advice.

If swallowed : If swallowed do not induce vomiting,seek medical advice and

show safety datasheet or label

Most important symptoms : No symptoms known currently.

and effects, both acute and No hazards known at this time.
delayed

Notes to physician : Treat symptomatically.

SECTION 5. FIREFIGHTING MEASURES

Suitable extinguishing media : Water spray jet

Alcohol-resistant foam
Dry powder
Carbon dioxide (CO2)

Unsuitable extinguishing : High volume water jet

media

Specific hazards during : In case of fires, hazardous combustion gases are formed:
firefighting Carbon monoxide (CO)
Carbon dioxide (CO2)
Nitrogen oxides (NOx)

Specific extinguishing : Wear suitable protective equipment.

methods

Special protective equipment : Self-contained breathing apparatus

for firefighters

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, : Wear suitable protective equipment.

protective equipment and Ensure adequate ventilation.
emergency procedures

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Environmental precautions : The product should not be allowed to enter drains, water
courses or the soil.

Methods and materials for : Soak up with inert absorbent material (e.g. sand, silica gel,
containment and cleaning up acid binder, universal binder, sawdust).
Treat recovered material as described in the section "Disposal
considerations".

SECTION 7. HANDLING AND STORAGE

Advice on protection against : Observe the general rules of industrial fire protection
fire and explosion

Advice on safe handling : When used and handled appropriately no special measures
are needed

Further information on : Keep containers tightly closed in a cool, well-ventilated place.

storage conditions Handle and open container with care.

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Components with workplace control parameters

Contains no substances with occupational exposure limit values.
Personal protective equipment
Respiratory protection : Use respiratory protection in case of insufficient exhaust
ventilation or prolonged exposure
Full mask, filter A
Full mask to standard DIN EN 136
Filter class 2
The use of filter apparatus presupposes that the environment
atmosphere contains at least 17% oxygen by volume, and
does not exceed the maximum gas concentration, usually
0.5% by volume. Relevant guidelines to be considered
include EN 136/141/143/371/372 as well as other national
regulations.
Applicable national Regulations must be observed. Take note
of the limitations regarding wear-time, in conjunction with the
Regulations for the use of Respiratory Protective Equipment.

Hand protection
Break through time : 480 min
Glove thickness : 0,7 mm
Remarks : Long-term exposure Impervious butyl rubber gloves

Break through time : 30 min

Glove thickness : 0,4 mm
For short-term exposure (splash protection): Nitrile rubber
gloves.

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These types of protective gloves are offered by various

manufacturers. Please note the manufacturers´ detailed
statements, especially about the minimum thickness and the
minimum breakthrough time. Consider also the particular
working conditions under which the gloves are being used.

Eye protection : Depending on the risk, wear sufficient eye protection (safety
glasses with side protection or goggles, and if necessary,
face shield.)

Skin and body protection : Wear suitable protective equipment.

Protective measures : Observe the usual precautions for handling chemicals.

Avoid contact with skin and eyes.

Hygiene measures : Wash hands before breaks and at the end of workday.
Use protective skin cream before handling the product.
Take off immediately all contaminated clothing and wash it
before reuse.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : Liquid

Colour : amber

Odour : characteristic

Odour Threshold : not tested.

pH : approx. 8

Solidification point : ca. 6 °C

Boiling point : > 100 °C

Flash point : ca. 134 °C

Evaporation rate : not tested.

Flammability (solid, gas) : Not applicable

Self-ignition : Not applicable

Burning number : Not applicable

Upper explosion limit / upper : Not applicable

flammability limit

Lower explosion limit / Lower : Not applicable

flammability limit

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Vapour pressure : not tested.

Relative vapour density : not tested.

Density : ca. 1,0560 g/cm3 (20 °C)

Bulk density : Not applicable

Solubility(ies)
Water solubility : soluble

Solubility in other solvents : not tested.

Solvent: fat

Partition coefficient: n- : Not applicable

octanol/water

Auto-ignition temperature : not tested.

Decomposition temperature : > 450 °C

Heating rate: 3 K/min
Method: DSC

Viscosity
Viscosity, dynamic : ca. 800 mPa.s ( 25 °C)

Viscosity, kinematic : not tested.

Explosive properties : no data available

Oxidizing properties : Not applicable

Minimum ignition energy : not tested.

Particle size : Not applicable

SECTION 10. STABILITY AND REACTIVITY

Reactivity : See section 10.3. "Possibility of hazardous reactions"

Chemical stability : Stable under normal conditions.

Possibility of hazardous : No dangerous reaction known under conditions of normal use.

reactions

Conditions to avoid : Keep away from heat and sources of ignition.

Incompatible materials : Strong acids and oxidizing agents

Hazardous decomposition : When handled and stored appropriately, no dangerous

products decomposition products are known

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SECTION 11. TOXICOLOGICAL INFORMATION

Acute toxicity
Product:
Acute oral toxicity : Acute toxicity estimate: > 5.000 mg/kg
Method: Calculation method

Acute inhalation toxicity : Remarks: no data available

Acute dermal toxicity : Acute toxicity estimate: 4.465 mg/kg

Method: Calculation method

Components:
D-Glucitol, 1-deoxy-1-(methylamino)-, N-(C16-18 and C18-unsatd. acyl) derivs.:
Acute oral toxicity : LD50 (Rat, female): 5.000 mg/kg
Method: OECD Test Guideline 423
GLP: yes

Acute inhalation toxicity : Remarks: no data available

Acute dermal toxicity : LD50 (Rat, male and female): > 2.000 mg/kg
Method: OECD Test Guideline 402
GLP: yes

Skin corrosion/irritation
Product:
Remarks : no data available

Components:
D-Glucitol, 1-deoxy-1-(methylamino)-, N-(C16-18 and C18-unsatd. acyl) derivs.:
Species : reconstructed human epidermis (RhE)
Exposure time : 15 min
Method : OECD Test Guideline 439
Result : No skin irritation
GLP : yes

Serious eye damage/eye irritation

Product:
Remarks : no data available

Components:
D-Glucitol, 1-deoxy-1-(methylamino)-, N-(C16-18 and C18-unsatd. acyl) derivs.:
Species : Bovine cornea
Result : slight irritation
Exposure time : 4h
Assessment : No eye irritation
Method : OECD Test Guideline 437

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GLP : yes

Species : rabbit eye

Result : non-irritant
Method : OECD Test Guideline 405
GLP : yes

Respiratory or skin sensitisation

Product:
Remarks : no data available

Components:
D-Glucitol, 1-deoxy-1-(methylamino)-, N-(C16-18 and C18-unsatd. acyl) derivs.:
Test Type : Maximisation Test
Exposure routes : Dermal
Species : Guinea pig
Method : OECD Test Guideline 406
Result : Not a skin sensitizer.
GLP : yes

Germ cell mutagenicity

Product:
Germ cell mutagenicity - : No information available.
Assessment

Components:
D-Glucitol, 1-deoxy-1-(methylamino)-, N-(C16-18 and C18-unsatd. acyl) derivs.:
Genotoxicity in vitro : Test Type: Ames test
Test system: Salmonella typhimurium
Metabolic activation: with and without metabolic activation
Method: OECD Test Guideline 471
Result: negative
GLP: yes

Test Type: Mammalian cell gene mutation assay

Test system: Chinese hamster lung cells
Metabolic activation: with and without metabolic activation
Method: OECD Test Guideline 476
Result: negative
GLP: yes
Remarks: By analogy with a product of similar composition

Genotoxicity in vivo : Test Type: In vivo micronucleus test

Species: Mouse (male and female)
Strain: NMRI
Application Route: oral (gavage)
Method: OECD Test Guideline 474
Result: negative
GLP: yes

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Germ cell mutagenicity - : In vitro tests did not show mutagenic effects, In vivo tests did
Assessment not show mutagenic effects

Carcinogenicity
Product:
Carcinogenicity - : No information available.
Assessment

Components:
D-Glucitol, 1-deoxy-1-(methylamino)-, N-(C16-18 and C18-unsatd. acyl) derivs.:
Carcinogenicity - : No information available.
Assessment

Reproductive toxicity
Product:
Reproductive toxicity - : No information available.
Assessment No information available.

Components:
D-Glucitol, 1-deoxy-1-(methylamino)-, N-(C16-18 and C18-unsatd. acyl) derivs.:
Effects on fertility : Species: Rat, male and female
Strain: wistar
Application Route: oral (gavage)
General Toxicity - Parent: NOAEL: >= 650 mg/kg body weight
General Toxicity F1: NOAEL: >= 650 mg/kg body weight
Method: OECD Test Guideline 421
GLP: yes

Effects on foetal : Test Type: Pre-natal

development Species: Rat, male and female
Strain: wistar
Application Route: oral (gavage)
Dose: 15, 150, 363 mg/kg bw milligram per kilogram
Duration of Single Treatment: 25 d
General Toxicity Maternal: NOAEL: 150 mg/kg body weight
Embryo-foetal toxicity: NOAEL: >= 363 mg/kg body weight
Method: OECD Test Guideline 414
GLP: yes

Test Type: reproductive and developmental toxicity study

Species: Rat, male and female
Strain: wistar
Application Route: oral (gavage)
Dose: 0, 125, 300, 650 mg/kg bw
Duration of Single Treatment: 54 d
Frequency of Treatment: 1 daily
General Toxicity Maternal: NOAEL: >= 650 mg/kg body weight
Embryo-foetal toxicity: NOEL: >= 650 mg/kg body weight
Method: OECD Test Guideline 421
GLP: yes

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Reproductive toxicity - : No evidence of adverse effects on sexual function and fertility,

Assessment or on development, based on animal experiments.

STOT - single exposure

Product:
Remarks : no data available

Components:
D-Glucitol, 1-deoxy-1-(methylamino)-, N-(C16-18 and C18-unsatd. acyl) derivs.:
Assessment : The substance or mixture is not classified as specific target
organ toxicant, single exposure.

STOT - repeated exposure

Product:
Remarks : no data available

Components:
D-Glucitol, 1-deoxy-1-(methylamino)-, N-(C16-18 and C18-unsatd. acyl) derivs.:
Assessment : The substance or mixture is not classified as specific target
organ toxicant, repeated exposure.

Repeated dose toxicity

Product:
Remarks : no data available

Components:
D-Glucitol, 1-deoxy-1-(methylamino)-, N-(C16-18 and C18-unsatd. acyl) derivs.:
Species : Rat, male and female
NOAEL : >= 650 mg/kg bw/day
Application Route : oral (gavage)
Exposure time : 28 d
Number of exposures : daily
Dose : 0, 125, 300 and 650 mg/kg bw
Group : yes
Method : OECD Test Guideline 407
GLP : yes
Remarks : By analogy with a product of similar composition

Aspiration toxicity
Product:
no data available

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Components:
D-Glucitol, 1-deoxy-1-(methylamino)-, N-(C16-18 and C18-unsatd. acyl) derivs.:
no data available

Further information
Product:
Remarks : The product has not been tested. The information is derived
from the properties of the individual components.

SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity
Product:
Toxicity to fish : LC50: 10 - 100 mg/l
Remarks: The data refer to the solvent

Toxicity to daphnia and other :

aquatic invertebrates Remarks: no data available

Toxicity to algae/aquatic :
plants Remarks: no data available

Toxicity to microorganisms : Remarks: not reasonable

Components:
D-Glucitol, 1-deoxy-1-(methylamino)-, N-(C16-18 and C18-unsatd. acyl) derivs.:
Toxicity to fish : LC50 (Danio rerio (zebra fish)): 2,51 mg/l
End point: mortality
Exposure time: 96 h
Test Type: semi-static test
Method: OECD Test Guideline 203
GLP: yes

Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): 1,04 mg/l
aquatic invertebrates Exposure time: 48 h
Test Type: Immobilization
Method: OECD Test Guideline 202

EC50 (Daphnia magna (Water flea)): 1,3 mg/l

Exposure time: 48 h
Test Type: Immobilization
Method: OECD Test Guideline 202

EC50 (Daphnia magna (Water flea)): > 1 mg/l

End point: Immobilization
Exposure time: 48 h
Test Type: semi-static test
Method: OECD Test Guideline 202
GLP: yes

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Toxicity to algae/aquatic
plants
Toxicity to fish (Chronic
toxicity)
Toxicity to daphnia and other
aquatic invertebrates
(Chronic toxicity)
Toxicity to microorganisms
Toxicity to soil dwelling
organisms
Plant toxicity
Sediment toxicity
Page 11(15)
Revision Date: 18.03.2019
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: EC50 (Desmodesmus subspicatus (green algae)): > 80 mg/l
End point: Growth rate
Exposure time: 72 h
Test Type: static test
Method: OECD Test Guideline 201
GLP: yes
: NOEC (Danio rerio (zebra fish)): 0,36 mg/l
Exposure time: 9 d
Test Type: semi-static test
Method: OECD Test Guideline 212
GLP: yes
: NOEC (Daphnia magna (Water flea)): 0,25 mg/l
End point: Reproduction rate
Exposure time: 21 d
Test Type: semi-static test
Method: OECD Test Guideline 211
GLP: yes
: NOEC: 1.000 mg/l
Exposure time: 28 d
Test Type: Soil
Method: OECD Test Guideline 216
GLP: yes
EC50 (activated sludge): > 5.000 mg/l
End point: Bacteria toxicity (respiration inhibition)
Exposure time: 3 h
Test Type: static test
Method: OECD Test Guideline 209
GLP: yes
: Test Type: artificial soil
NOEC (Eisenia fetida (earthworms)): 1000 mg/kg dry weight
(d.w.)
Exposure time: 56 d
End point: Reproduction
Method: OECD Test Guideline 222
GLP: yes
: NOEC: 250 mg/kg
Exposure time: 21 d
End point: emergence
Species: Brassica napus
Method: OECD Test Guideline 208
GLP: yes
: NOEC: 1000 mg/l
Duration: 28 d
Sediment: Artificial sediment
Method: OECD 216
GLP: yes
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Ecotoxicology Assessment
Chronic aquatic toxicity : Harmful to aquatic life with long lasting effects.

Persistence and degradability

Product:
Biodegradability : Remarks: Not applicable

Components:
D-Glucitol, 1-deoxy-1-(methylamino)-, N-(C16-18 and C18-unsatd. acyl) derivs.:
Biodegradability : aerobic
Inoculum: activated sludge
Concentration: 17 mg/l
Carbon dioxide (CO2)
Result: Readily biodegradable.
Biodegradation: 63 %
Exposure time: 28 d
Method: OECD Test Guideline 301B
GLP: yes

aerobic
Inoculum: activated sludge
Concentration: 895 kBq/L
Carbon dioxide (CO2)
Result: Readily biodegradable.
Biodegradation: 99 %
Exposure time: 28 d
Method: OECD Test Guideline 303A
GLP: yes

Bioaccumulative potential
Product:
Bioaccumulation : Remarks: no data available

Components:
D-Glucitol, 1-deoxy-1-(methylamino)-, N-(C16-18 and C18-unsatd. acyl) derivs.:
Partition coefficient: n- : log Pow: 3,8 (23 °C)
octanol/water pH: 5,76
Method: Regulation (EC) No. 440/2008, Annex, A.8
GLP: no

Mobility in soil
Product:
Distribution among : Remarks: no data available
environmental compartments

Components:
D-Glucitol, 1-deoxy-1-(methylamino)-, N-(C16-18 and C18-unsatd. acyl) derivs.:

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Distribution among : Medium: Soil

environmental compartments Kd: 557 ml/g
Method: OECD Test Guideline 106

Stability in soil : Radio label: yes

Method: OECD Test Guideline 307
GLP: yes

Other adverse effects

Product:
Additional ecological : The product has not been tested. The information is derived
information from the properties of the individual components.

Components:
D-Glucitol, 1-deoxy-1-(methylamino)-, N-(C16-18 and C18-unsatd. acyl) derivs.:
Results of PBT and vPvB : The substance is not identified as a PBT or as a vPvB
assessment substance.

SECTION 13. DISPOSAL CONSIDERATIONS

Disposal methods
Waste from residues
: Product should be taken to a suitable and authorized waste
disposal site in accordance with relevant regulations and if
necessary after consultation with the waste disposal operator
and/or the competent Authorities

Contaminated packaging : Packaging that cannot be cleaned should be disposed of as

product waste

SECTION 14. TRANSPORT INFORMATION

MERCO not restricted

IATA not restricted
IMDG not restricted
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable for product as supplied.

SECTION 15. REGULATORY INFORMATION

Safety, health and environmental regulations/legislation specific for the substance or

mixture
Apart from the data/regulations specified in this chapter, no further information is available
concerning safety, health and environmental protection.

Control of precursors and essential chemicals for the : Not applicable

preparation of drugs.

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International Regulations

SECTION 16. OTHER INFORMATION

Further information
Other information : Observe national and local legal requirements

Full text of other abbreviations

AICS - Australian Inventory of Chemical Substances; ANTT - National Agency for Transport by
Land of Brazil; ASTM - American Society for the Testing of Materials; bw - Body weight; CMR -
Carcinogen, Mutagen or Reproductive Toxicant; CPR - Controlled Products Regulations; DIN -
Standard of the German Institute for Standardisation; DSL - Domestic Substances List (Canada);
ECx - Concentration associated with x% response; ELx - Loading rate associated with x%
response; EmS - Emergency Schedule; ENCS - Existing and New Chemical Substances (Japan);
ErCx - Concentration associated with x% growth rate response; ERG - Emergency Response
Guide; GHS - Globally Harmonized System; GLP - Good Laboratory Practice; IARC -
International Agency for Research on Cancer; IATA - International Air Transport Association; IBC
- International Code for the Construction and Equipment of Ships carrying Dangerous Chemicals
in Bulk; IC50 - Half maximal inhibitory concentration; ICAO - International Civil Aviation
Organization; IECSC - Inventory of Existing Chemical Substances in China; IMDG - International
Maritime Dangerous Goods; IMO - International Maritime Organization; ISHL - Industrial Safety
and Health Law (Japan); ISO - International Organisation for Standardization; KECI - Korea
Existing Chemicals Inventory; LC50 - Lethal Concentration to 50 % of a test population; LD50 -
Lethal Dose to 50% of a test population (Median Lethal Dose); MARPOL - International
Convention for the Prevention of Pollution from Ships; n.o.s. - Not Otherwise Specified; Nch -
Chilean Norm; NO(A)EC - No Observed (Adverse) Effect Concentration; NO(A)EL - No Observed
(Adverse) Effect Level; NOELR - No Observable Effect Loading Rate; NOM - Official Mexican
Norm; NTP - National Toxicology Program; NZIoC - New Zealand Inventory of Chemicals; OECD
- Organization for Economic Co-operation and Development; OPPTS - Office of Chemical Safety
and Pollution Prevention; PBT - Persistent, Bioaccumulative and Toxic substance; PICCS -
Philippines Inventory of Chemicals and Chemical Substances; (Q)SAR - (Quantitative) Structure
Activity Relationship; REACH - Regulation (EC) No 1907/2006 of the European Parliament and of
the Council concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals;
SADT - Self-Accelerating Decomposition Temperature; SDS - Safety Data Sheet; TCSI - Taiwan
Chemical Substance Inventory; TDG - Transportation of Dangerous Goods; TSCA - Toxic
Substances Control Act (United States); UN - United Nations; UNRTDG - United Nations
Recommendations on the Transport of Dangerous Goods; vPvB - Very Persistent and Very
Bioaccumulative; WHMIS - Workplace Hazardous Materials Information System

This information corresponds to the present state of our knowledge and is intended as a general
description of our products and their possible applications. Clariant makes no warranties, express
or implied, as to the information's accuracy, adequacy, sufficiency or freedom from defect and
assumes no liability in connection with any use of this information. Any user of this product is
responsible for determining the suitability of Clariant's products for its particular application.
Nothing included in this information waives any of Clariant's General Terms and Conditions of
Sale, which control unless it agrees otherwise in writing. Any existing intellectual/industrial
property rights must be observed. Due to possible changes in our products and applicable
national and international regulations and laws, the status of our products could change. Material
Safety Data Sheets providing safety precautions, that should be observed when handling or
storing Clariant products, are available upon request and are provided in compliance with
applicable law. You should obtain and review the applicable Material Safety Data Sheet

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information before handling any of these products. For additional information, please contact
Clariant.

AR / EN

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