x Cp1[kJ/kg°C] Cp2[kJ/kg°C] Cp1[kJ/kmol°C] Cp2[kJ/kmol°C] Te [°C] ΔHs[kJ/kmol]

0 2.45 4.187 142.296 75.428805 100 0

0.001 2.45 4.187 142.296 75.428805 100 0
0.01 2.43 4.179 141.1344 75.284685 91.7 0
0.02 2.43 4.162 141.1344 74.97843 86.6 -188.4
0.05 2.43 4.124 141.1344 74.29386 75.7 -441.3
0.1 2.34 4.02 135.9072 72.4203 66.6 -668.7
0.15 2.34 3.894 135.9072 70.15041 63.4 -170
0.2 2.34 3.81 135.9072 68.63715 62.2 -786
0.3 2.34 3.559 135.9072 64.115385 61 -719
0.4 2.34 3.35 135.9072 60.35025 60.4 -509
0.5 2.34 3.14 135.9072 56.5671 60 -350.1
0.6 2.34 2.931 135.9072 52.801965 59.5 -252.6
0.7 2.34 2.163 135.9072 38.966445 58.9 -252.6
0.8 2.34 2.554 135.9072 46.01031 58.2 -252.6
0.9 2.34 2.387 135.9072 43.001805 57.5 -252.6
0.95 2.34 2.303 135.9072 41.488545 57 -252.6
1 2.34 2.303 135.9072 41.488545 56.5 -252.6

Cur
12000

10000

8000
Entalpía

6000

4000

2000

0
0 0.1 0.2 0.3 0
2000

0
0 0.1 0.2 0.3 0
 Cpm[kJ/kmol°C] hm [kJ/kmol] hm [kcal/kmol] Hm1 Hm2 Hm[kJ/kmol]
75.428805 7542.8805 1802.0164604138 0 48256.7805 48256.7805
75.495672195 7549.5672195 1803.6139374791 38.2602 48208.5237 48246.7839195
75.94318215 6963.98980316 1663.7177607996 381.96312 47759.9448 48141.907935
76.3015494 6419.31417804 1533.5931430169 763.92624 47247.5081 48011.43438
77.635887 5435.7366459 1298.6135615414 1909.8156 45736.1217 47645.9373
78.76899 4577.314734 1093.5340279039 3790.8816 43160.337 46951.2186
80.0139285 4902.8830669 1171.3132655406 5686.3224 40569.5999 46255.92225
82.09116 4320.070152 1032.0775364327 7581.7632 38062.092 45643.8552
85.6529295 4505.8286995 1076.4558028334 11372.6448 32987.807 44360.45175
90.57303 4961.611012 1185.3435453199 15163.5264 28049.355 43212.8814
96.23715 5424.129 1295.8404606049 18954.408 23185.305 42139.713
102.665106 5855.973807 1399.0094622295 22745.2896 18397.6386 41142.9282
106.8249735 6039.39093915 1442.828357578 26536.1712 13383.1634 39919.33455
117.927822 6610.7992404 1579.3394907545 30327.0528 9062.9862 39390.039
126.6166605 7027.85797875 1678.976056847 34117.9344 4501.40805 38619.34245
131.18626725 7225.01723325 1726.0779858689 36013.3752 2243.13773 38256.512925
135.9072 7426.1568 1774.1308232596 37908.816 0 37908.816

Curva de equilibrio

0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

Composición
0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

Composición
 Hm[kcal/kmol]
11528.6875866
11526.299374
11501.2441911
11470.0736729
11382.7553395
11216.7849873
11050.6766329
10904.4520044
10597.8431244
10323.6851737
10067.3020689
9829.16723207
9536.84709016
9410.39681781
9226.27513259
9139.59408596
9056.52826222

0.9 1
0.9 1
 86.6 0.02 -188.4 -45.009317
75.7 0.05 -441.3 -105.42788
66.6 0.1 -668.7 -159.75441
63.4 0.15 -770 -183.95528
62.2 0.2 -786 -187.77772
61 0.3 -719 -171.77123
60.4 0.4 -509 -121.60161
60 0.5 -350.1 -83.639925
59.5 0.6 -252.6 -60.346887

0
0 0.02 0.04 0.06 0.08 0.1 0.12 0.14 0.16
-20
-40
f(x) = -69.9820750637 ln(x) - 317.8675004998
-60 R² = 0.9983321841 0
-80 0.15 0.2 0.25 0.3 0.35 0.4 0.45 0.5 0
-20
Column E
-100
Logarithmic (Column E) -40
-120
-60
f(x) = 342.992976253x - 262.22
-140 R² = 0.9778570092
-80
-160
-100
-180
-120
-200
-140
-160
-180
-200
 0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7
-20

-40

-60

-80

-100

-120

-140

-160
5 0.2 0.25 0.3 0.35 0.4 0.45 0.5 0.55 0.6 0.65
-180

-200
f(x) = 342.992976253x - 262.2246643413
R² = 0.9778570092
Column E
Linear (Column E)
 20 2.22 0.53036457
31.8 2.26 0.53992068
65.6 2.34 0.55903292
93.3 2.43 0.58053419
100

0.59

0.58
f(x) = 1.40039170734785E-06x^2 + 0.0005070784x +
0.57 R² = 0.9966652106

0.56

0.55
Column
0.54 Polyno
0.53

0.52

0.51

0.5
10 20 30 40 50 60 70 80 90 100
734785E-06x^2 + 0.0005070784x + 0.5207045036
6

Column C
Polynomial (Column C)

0 70 80 90 100
x Cpm[kJ/kg°C] Cpm[kcal/kg°C] Tem [°C] Mm[Kg/Kmol] ΔHs[kJ/kmol] ΔHs[kcal/kmol]
0 4.187 1.0002866835 100 18.015 0
0.01 4.179 0.9983754599 91.7 18.41565 4.3998096154
0.02 4.162 0.9943141096 86.6 18.8163 -188.4 -45.0093172153
0.05 4.124 0.9852357972 75.7 20.01825 -441.3 -105.4278751971
0.1 4.02 0.9603898896 66.6 22.0215 -668.7 -159.7544077596
0.15 3.894 0.930288117 63.4 24.02475 -770 -183.9552773663
0.2 3.81 0.9102202685 62.2 26.028 -786 -187.7777246882
0.3 3.559 0.8502556262 61 30.0345 -719 -171.7712265278
0.4 3.35 0.800324908 60.4 34.041 -509 -121.6016054279
0.5 3.14 0.7501552869 60 38.0475 -350.1 -83.6399254623
0.6 2.931 0.7002245688 59.5 42.054 -252.6 -60.3468870945
0.7 2.763 0.6600888719 58.9 46.0605 -252.6 -22.127
0.8 2.554 0.6101581538 58.2 50.067 12.172
0.9 2.387 0.5702613598 57.5 54.0735 46.471
0.95 2.303 0.5501935114 57 56.07675 63.6205
1 2.1468 0.5128768694 56.5 58.08 80.77

Diagrama entalpía-
13000

12000

11000

10000

9000

8000
Entalpía[Kcal/Kmol]

7000

6000

5000

4000

3000

2000

1000

0
0 0.1 0.2 0.3 0.4 0

Compos
1000

0
0 0.1 0.2 0.3 0.4 0

Compos
 hm[Kcal/Kmol] Hm[Kcal/Kmol]
1799.6985 11526.375315
1690.37152919 11501.21977785
1575.217152267 11476.0642407
1387.580249677 11400.59762925
1248.784040805 11274.8199435
1233.030883009 11149.04225775
1285.815733193 11023.264572
1385.985932319 10771.7092005
1523.927550289 10520.153829
1628.852071289 10268.5984575
1691.764131827 10017.043086
1768.669983217 9765.4877145
1790.11147814 9513.932343
1819.542589362 9262.3769715
1822.245147439 9136.59928575
1740.0768 9010.8216

agrama entalpía-composición

0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

Composición
0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

Composición
 0 4.187
0.01 4.179
0.02 4.162
0.05 4.124
0.1 4.02
0.15 3.894
0.2 3.81
0.3 3.559 4.5
0.4 3.35 4 f(x) = - 2.0504531375x + 4.1973049214
0.5 3.14 R² = 0.998187766
3.5
0.6 2.931
0.7 2.713 3
0.8 2.554 2.5
0.9 2.387 Co
2 Li
0.95 2.303
1.5

0.5

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
+ 4.1973049214

Column B
Linear (Column B)

5 0.6 0.7 0.8 0.9 1