Sample Paper itest Pattern sh. Pa EFI 13108 Gone ral aL pees « zi mre |e é caaramnammea| Fi a ; arrears s s = . , Sane | € 2 eeeeneal + Faleca lesa conmina fos aniaEBD_7950) (© All questions ar computor. a aloe rete render enteral on ae merce (lD Secton B: Ono, 20 1027 are short ane questions and carry 2 marks cach. 9) Section C2 Qo, 28 0 34 are ong answer questions and carry 3 marks each. (0) Section DQ. 35 0 37 are ako lone answer questions and cary $ marks each ee eee eee a mark, two questions of 3 marks and all the $ questions of ive marks weightage. Yow have 10 uempe clone of he chotces in such quai (VID og tables necessary, se of calculators ot allowed. SECTION-A. Readthe given passage and ansner he questions 105 that low: ine with one carbon aon tess the ation ofalbalin politi 3s Hotinann degradation, CON + Bry /4KO—+ NH, ml or Ln i i R-C-NH, 9 R-C-NeB RCN Ge 9 RCN Co NB 1 Wich step is the ving for inthe above testion o prose in right direction 2. What athe change is carbon ein during Hoi reaction 4. Wiich ope amin i prodon! by Hofnan acon? 4 Mention he gs evolied alo with mine Hofinan reaction, Questions to Ware one word answers 6 Which one ofthe flowing has constant potential daring its operation Lesante cel daniel cel mci cll, kta cel Terai ofa rection bocca cig tines when the omcentacn ofthe single eaten X imide twiceSample Papers cas Anche equation, (2] = ep! ward and epee? 9. Write the name snd formals ofthe man or ofan 10, Incample iron bexayano Frat) how many ins wil beer hn mole ofthe ample is then ito aqueous sion Cassone complete disociation)? Questions 1 4015 rem ipl hotce questions 11, Thevolumeofgnses NI, CO, and adsorbed by one ram of chorenal ot 3K aren deo fy H>CO.>NI, (t) NIQZH,>CO, 6) NH>CO.>H, (@) CO,> NIH, 12, Thelype of isomers presenin pentamrsinenitoshrorinm (UI) ehlries (a) omic by inkae (©) ionisation (6) peterson 13, 1 emporatue increases, slubility of gs decrease’. For this situation which ofthe fllowing (Reason sendathenni @_Le-hateler’sprinepl can ho appli {3} SwemcntG)and(i)botkmecorcet ——b).Statement () ncerectonly [o)_ Statement (iis eae only (Bosh tatemet() a i acne 4 Chlorocampeund of vanadium hasonly pia magncticmomentet 1.73 BV. Thisvanada chloid has ‘he fermula &) va, » va, © va, @ vo, 15, Tranquillizes are substances se forthe extent (a) cansse @) aps (o) meal diseases physical disorder ‘Questions 161020 8) Both asvaton and reason ste eres stars Reason : The ste ofthe reaction dos not depen vpn the eanesnitaion of C 18 Assertion Reason Theresction, FeO, s) —= Fe(s)= 320, (9) sa spontancons roses 19, Assertion : Reason of SU, anSHLS inthe peetenee of FeO, ctl ves elemental Slphur Reason : $0, i reducing su, 20. Amertion: in canisation of rut, sulphur cron links ae introduced Reason: Vulansaton sa tee elitist cha cation SECTION-B The cesstanceaf 0.01 Naoution ofa srlye was found tbe 210 ohm at298K using a condusiviy traction ore metal on ra oxide ors arid cut by eating with cokeEBD_7950) 6 on hCu(NO,);,AaNO., Ha,(NO ) being elecesad beyuing inet electrodes, The ales of AG /AgsO8DV, 2g e479 With inoreesing wohags, hat willbe the sence of deposition of metalsom the cthodk™ (0) ‘Thevelucof A" far NHLCL NaDiTand NaClare 1298, 248.L amd 1264 nemo spective CCuleulaceA* or HOH son, 22. Thefellowing values frthe fst onder rate 1,= 208K, =35 7ST, 308 Kh = 140% 1 oR Following ection takes place in one te 2N0 (g)+ 044) = 2NOA() How wl bother ofthe above rection change ifthe vlums ofthe rection ves is diminished wo ‘me-thied of ts original volume? Wil there he any change inthe oder ofthe reaction wih cedced 23. ite dawn the aructues and names ofthe prods bain when D-glacme i trate with (i) acetic enbyride (i) hydryanic aid 24, tle heinfrmation asked fr the llouing polymers (a) Bakeie Matai sed fr preparation Im) PVC-Monors nit 25, Account forthe following [by Diabetic prints are advisa tae artifice sceinrs instead of natural swectners 26, Give suitable reson fr following sateen and [Ni(CO),] havent structures but not ie (a) Twocamploses nick [Ri(CN), inmagpetcbebviow (0) Squire planar compleresofM,L, ype wilh co arnatonnurbero exhibit gzemaial bomen sil raha complexes wilh sr cmpiton dot 27. Why isthe vapour pressure fan aque ston of glacone omer than that oPwate? SECTION-¢ 2K, Resistance of condsiviy cel lk-wth 01 MKCIis 10chm, he resistance ofthe sae cll when dwt 0.02 M KCI solution i 20 obs cael te conductivity and moar sont 00.02 M 29, (a) Show graphically, ow the amount of ges asorbed oma sli in physical adsorption va i) presse andi tempera (b). Name substance which sm aor plating ase: preset inSample Papers x. M. 38 a |a)Atasite low grade copper oes are eilabe, zinc anton steps at also avaiable. Which ofthe two sep willbe more suitable fr reducing the levehed copper or and why? (0) Why ace mca earbcoaes rsp frst conered ino correspumding ides i Sly ining ‘he comesponing meals? (a) Give tebe reson for flowing statement: i) Hic tren plas bates bts kept in wa bes, iy otethalg sn smpoundsaremore reece than logan (0) Complete the allowing esction: F(a3)+H,0 ()-+0, @)—> Casi he flowing as monosaccharides, dstcharides or polysxsshaides: (a) Sucrose by Frasese (@) Sarch i) Malone e) Gloss © Leese on Whot ore mloties! Neme tn classes niogencontinng ses oun in noslatde White the prods of he fllowing ations ( CH,cH,cH=CH, +I Aci, oC a on (0) Why dos emmenoysisf aly ales not ik pur amines ‘Wit eston(s) of pheno invelving 43) theclewageof O— bond, (©) thecleavage of C— OH bond. (6) thephonolmoleculeasa whole SECTION-D (a) Catia heperemtag degre of dissociation ofan elesrolyte XY, molermass~ 168) in woe, ifthe observed mar mass by messuringclvation in taling point 65.6 (0) Whats san: y bmcrtalmolceua rss folate? Discus te factors which bring aba int experimentally determined molecular masses flues sng ellie properties,EBD_7950) cs on (0) Sapo resi pre waar at 35°C S87 me. When 27.0 gostei dsl 100 gf vets (et he same emperature) vapour pressure of the solution, thus formed is 30.98 mn Hg, Caleuatethe molester mass of wate 1) Whataronoe-idel solutions? iy What ole dacs the molecular interaction ply in deciding the vapour pressure of illowing salutons? (0), Nleohot and xectone ©) Chloror and aceon 36. (a) ite chanical equation arth comerson of i) Chromiteore sodium strorate i) Pouassium pammanganateto manganese diode (0) Exp why 0) foe Mn! /ntn®* couples more postive than that or Fe Atonicnunbersof Mi =25, Fe =) 1, (Atomiemumber of iy Co ca beewilyoxsised oC (a) Completes along ®CesO3 (og) + HS) +H (0a) —> (0) Expinwhy? i) a-Blck lets have greertndncy to fem orplens thn block elements. i) _Ascompored the transition laments, Caan le have very meting point, 31. (a) Biphia why i) Daring the preperation ofrtnons davies rom aldchy dsr katones, pH of the rection iscareflly conti sco the (0) White chemical equations tose ming etions i) Gasteroan- Koch on while othe eatbonfic acids do not. Jus (a) Formic acid reduces Tle (6) Why are tiling pins a aldeles an ketones lower than those ofthe corresponding a [e) Why is benzoic asi stongor aid than acti [Give UPACrames ofthe flowing i) CH,CHCH.Coc! wy eco ot, cncn.co