CONFIDENTIAL* SET 2 962/1

Class / Tingkatan : ……………… Name / Nama: ………………………………………

Identity card number: ……………… Centre number/index number :……………...............
(Nombor kad pengenalan) (Nombor pusat/angka giliran)

962/1 STPM

JABATAN PENDIDIKAN NEGERI KELANTAN

MODUL G-CAKNA

CHEMISTRY 1 STPM 2020

SET 2
One and a half hours (Satu jam setengah)

SIJIL TINGGI PERSEKOLAHAN MALAYSIA

(MALAYSIA HIGHER SCHOOL CERTIFICATE)
Instructions to candidates: For examiner‟s use
DO NOT OPEN THIS QUESTION PAPER UNTIL YOU ARE (Untuk kegunaan
TOLD TO DO SO. pemeriksa)
There are fifteen questions in Section A. For each question, four choices of Section A
answers are given. Choose one correct answer and indicate it on the Multiple-
choice Answer Sheet provided. Read the instructions on the Multiple-choice Section B
Answer Sheet very carefully. Answer all questions. Marks will not be deducted (Bahagian B)
for wrong answers.
Answer all questions in Section B. Write your answers in the spaces provided. 16
Answer any two questions in Section C. All essential working should be shown.
For numerical answers, unit should be quoted wherever appropriate. 17
Begin each answer on a fresh sheet of paper and arrange your answers in
numerical order. Section C
(Bahagian C)
Answers may be written in either English or Bahasa Malaysia.

Total
Arahan kepada calon
(Jumlah)
JANGAN BUKA KERTAS SOALAN INI SEHINGGA ANDA DIBENARKAN BERBUAT
DEMIKIAN
Ada lima belas soalan dalam Bahagian A. Bagi setiap soalan, empat pilihan jawapan diberikan.Pilih
satu jawapan yang betul dan tandakan jawapan itu pada Borang Jawapan Aneka Pilihan yang
dibekalkan. Baca arahan pada Borang Jawapan Aneka Pilihan itu dengan teliti. Jawab semua soalan.
Markah tidak akan ditolak bagi jawapan yang salah.
Jawab semua soalan dalam Bahagian B. Tulis jawapan anda di ruang yang disediakan.
Jawab mana-mana dua soalan dalam Bahagian C. Semua jalan kerja yang sesuai hendaklah
ditunjukkan. Bagi jawapan berangka, unit hendaklah dinyatakan di mana-mana yang sesuai. Mulakan
setiap jawapan pada helaian kertas jawapan yang baharu dan susun jawapan anda mengikut tertib
berangka.
Jawapan boleh ditulis dalam This
bahasa Inggeris
question atau
paper Bahasa
consists ofMalaysia.
9 printed pages
(Kertas soalan ini terdiri daripada 9 halaman bercetak )

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CONFIDENTIAL* SET 2 962/1

Section A [15 marks]

Answer all questions.

Indicate the correct answer on the Multiple-choice Answer Sheet provided.

1. Carbon-14 is radioactive and is used by archeologists in carbon dating. Which species has
both the same number of neutrons and the same number of electrons as an atom C-14 ?
A 11B-
14
B N-
16
C O2+
17 +
D F

2. Which statement is true of an emission spectrum of the hydrogen atom ?

A The spectrum is similar to that of He+ ion
B The Lyman series and the Balmer series have the same number of lines

C The first visible line has the shortest wavelength

D The ionisation energy of hydrogen atom can be determined from the continuum of the
Balmer series

An atom M has six valence electrons and forms a stable M2+ ion in an aqueous solution.
3.
What is the electronic configuration of atom M ?
A 1s22s22p63s23p4

B 1s22s22p63s23p63d54s1
C 1s22s22p63s23p63d44s2
D 1s22s22p63s23p63d64s2

In which of the following salts would you expect the bond to have the greatest ionic
4.
character ?
A LiCl B LiF
C KCl D KF

5. Which of the following molecules does not have dative covalent bond present ?
A CO2 B H3O+
C O3 D NO3-

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6. Which of the following statements is true of the ideal gas equation pV=nRT ?
A The relative molecular mass increases with the increase in temperature
B The density of an ideal gas at constant pressure is proportional to the temperature
C One mole of any ideal gas occupies the same volume under the same temperature and
pressure
D The volume of a given mass of an ideal gas is doubled if its temperature is raised from
50° C to 100 ° C at constant temperature

7. Which statement about graphite is true ?

A Graphite is soft and melts easily
B Graphite is used as a liquid lubricant
C Graphite is a good conductor of electricity
D The C-C distance between the planes of hexagonal rings is shorter than the C-C
distance within those plane

A reaction occurs as follows.

8.
2P + Q → 2R

[P]

time

Which statement can be deduced from the above information ?

A The half-life of the reaction is constant
B The reaction is zero order with respect to P
C The rate equation is : Rate = k [P]2 [Q]
D The rate of reaction doubles when the concentration of P is doubled

The reaction 2 NO (g) + H2 (g) → N2O (g) + H2O (g) is second order with respect to NO
9.
and zero order with respect to H2. If the rate constant for the reaction doubles for each
10 °C rise in temperature, which of the following sets of conditions gives the lowest rate
of reaction ?
[NO] [H2] Temperature
(mol dm-3) (mol dm-3) (° C)
A 0.1 0.1 40
B 0.2 0.2 30
C 0.3 0.4 20
D 0.4 0.6 10

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10. Hydrogen peroxide and iodide ion react in the presence of hydrogen ion to produce
iodine and water to the equation:
H2O2 + 2 I- + 2 H+ → 2 H2O + I2
In the kinetic experiment of reaction above, the following graphs are obtained.

Concentration 1.0-
(mol dm-3)

H+
0.5- I-
H2O2

Time (s)
| | |
2500 5000 7500
What is the order of the reaction with respect to H2O2, I-, and H+ ?
H2O2 I- H+

A 0 1 2
B 1 1 0
C 1 1 2
D 2 1 0

The equilibrium reaction of a system is given below.

11.
2 X (g) + Y (g) 2 Z (g)
1.5 mol X and 2.0 mol Y are placed in a 2.0 dm3 container at T°C. At equilibrium,1.2 mol
Z is formed. What is the value of the equilibrium constant, Kc for the reaction at T°C?
A 0.044 mol-1 dm3 B 0.088 mol-1 dm3
C 11.4 mol-1 dm3 D 22.9 mol-1 dm3

An equilibrium system is shown below.

12.
N2O4 (g) 2 NO2 (g)
x moles of N2O4 dissociates at T K and P atm. At equilibrium, 0.2x moles of N2O4 remain
in the system. What is the value of the equilibrium constant Kp of the system ?
A 0.125 P B 0.14 P

C 7.11 P D 8.00 P

A 1.0 mol dm-3 sample of ethanoic acid is diluted with water at a constant temperature.
13.
How does the acid dissociation constant, Ka of ethanoic acid vary with dilution ?
A No change B Decrease to zero
C Increases, then becomes constant D Decreases, then becomes constant

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The solubility product of calcium carbonate is 5.03 x 10-6 mol2 dm-6 at 25 ° C. What is
14.
the mass of calcium carbonate precipitated when 50.0 cm3 of an aqueous solution of
0.100 mol dm-3 calcium chloride is added to 50.0 cm3 of an aqueous solution of 0.100
mol dm-3 potassium carbonate ?
A 0.0710 g
B 0.500 g
C 1.00 g
D 10.0 g

Two miscible liquids P and Q form an ideal solution. The vapour pressures of pure P and
15.
pure Q at 298 K are 105 kPa and 70 kPa respectively. What is the total vapour pressures
of a mixture containing 2 mole of P and 3 mole of Q at 298 K ?
A 84 kPa
B 175 kPa
C 210 kPa
D 420 kPa

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CONFIDENTIAL* SET 2 962/1

Section B

[15 marks]

Answer all questions in this section

16 a) Hydrogen cyanide, HCN is a type of gas.

i. Draw the Lewis structure of HCN. [1]

ii. State the number of σ and π bonds found in a molecule of HCN. [2]
Number of a σ bonds: …………………………………………………………...

Number of a π bonds: …………………………………………………………..

iii State the type of hybrid orbital of the carbon atom in HCN. [1]

…………………………………………………………………………………..

b) Explain why aluminium chloride is a covalent compound whereas aluminium

fluoride is an ionic compound. [3]

……………………………………………………………………………………….
……………………………………………………………………………………….
………………………………………………………………………………………

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17 The critical point and triple point of carbon dioxide is shown in the table below:

Point Temperature (o C) Pressure ( atm )

Critical point 31 73
Triple point -57 5

a) Using the data above, sketch the phase diagram of carbon dioxide and label it
accordingly. [2]

b) How does the freezing point of carbon dioxide change with pressure? Explain your
answer. [2]
………………………………………………………………………………………...
……………………………………………………………………………………….…

c) Carbon dioxide is stored in fire extinguishers in the liquid form. State the
temperature and pressure necessary inside these containers for the carbon dioxide to
exists in the liquid form. [2]
………………………………………………………………………………………..
………………………………………………………………………………………..
………………………………………………………………………………………..

d) Solid carbon dioxide is known as dry ice.

Explain why solid carbon dioxide sublimes at atmospheric pressure . [2]

……………………………………………………………………………………….
……………………………………………………………………………………….

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CONFIDENTIAL* SET 2 962/1

18 (a) Atom X has one electron and its mass is 1 mass of an atom of carbon-12.
Hhh hhhhhhhh 6
(i) Determine the relative atomic mass of X and write its chemical symbol. [3]

(ii) Compare the behaviour of a beam of X⁺ ions with a beam of protons in the same
magnetic field [4]

(b) Compound Y is made up of 82.35% N and 17.65% H atoms. Its mass spectrum is shown
belobelow. (relative atomic mass N=14, H=1 )

(i) Determine the chemical formula of compound Y. [3]

(ii) Identify the ions which cause the peaks at m/e =16 and m/e =18. Explain your answer.
anjjj [5]

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CONFIDENTIAL* SET 2 962/1

19 (a) Niels Bohr postulated that energy ∆E is released in the form of light when there is a
transition of electron between a higher energy level to a lower energy level.

(i) The Lyman and Balmer series in the atomic emission spectrum of hydrogen are formed
when there is a transition of electrons between energy levels. Draw an energy level diagram
that shows the formation of these two series . [4]

(ii) One of the lines in the Lyman series have a wavelength of 121.6 nm. Calculate the
energy of this transition in joules [5]

[The Planck’s constant, h, is 6.63 × 10⁻³⁴ J s and the speed of light, c, is 3.00 × 10⁸ m s⁻¹.]

(b) An atom of element X has 7 protons in its nucleus.

(i) Explain how the electron configuration of X obeys Hund’s rule. [3]

(ii) Draw the orbitals of the valence shell of X. [3]

20. (a) An organic acid , Z is a weak monoprotic acid. If the pH of a 0.10 mol dm-3 Z is 3.76
what is the value of Ka for Z ? [3]

(b) (i) Define buffer solution

(ii) Calculate the pH of the 1.0 dm3 of a buffer solution prepared by dissolving 1.0
mole of CH3COOH and 1.2 mole of CH3COONa in a sufficient amount of water.

(iii) Calculate the pH of the buffer solution in (ii) above when 0.1 mole of calcium
hydroxide , Ca(OH)2 is added to it (Ka CH3COOH= 1.8 x 10-5 M ) [6]

(c) The solubility product constant for PbCl2 is 1.60 x 10-5 . Calculate the solubility of
PbCl2 in :

(i) water at 250 C

(ii) 0.10 mol dm-3 Pb(NO3)2 at 250 C [6]