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PAPER - 1
INSTRUCTIONS
A. General :
1. This Question Paper contains 75 questions.
2. The question paper CODE is printed on the right hand top corner on this sheet of this booklet.
4. Blank paper, clipboard, log tables, slide rules, calculators, cellular phones, pagers and electronic gadgets
in any form are not allowed.
5. The answer sheet, a machine-gradable Objective Response Sheet (ORS), is provided separately.
8. Write your Name, Roll No. and Sign in the space provide on the back page of this booklet.
9. The ORS has CODE printed on its lower and upper Parts.
10. Make sure the CODE on the ORS is the same as that on this booklet. If the Codes do not match, ask for a
change of the Booklet.
11. Write your Roll No., Name and Name of centre and sig with pen in appropriate boxes. Do not write these
anywhere else.
12. Darken the appropriate bubbles below your registration number with HB Pencil.
13. The question paper consists of 3 parts (Chemistry, Mathematics & Physics). Each part consists of Four Sections.
14. For each question in Section–I , you will be awarded 3 marks if you darken the bubble corresponding to the
correct answer and zero marks if no bubble is darkened. There is no negative marking for incorrect
answer(s) for this this section.
15. For each question in Section–II , you will be awarded 3 marks if you darken the bubble(s) corresponding
to the correct choice(s) for the answer and zero mark if no bubbled is darkened. In case of bubbling of
incorrect answer, minus one (–1) mark will be awarded.
16. For each question in Section–III , you will be awarded 2 marks if you darken the bubble corresponding to
the correct answer and zero marks if no bubble is darkened.. In case of bubbling of incorrect answer,
minus one (–1) mark will be awarded.
17. For each question in Section–IV, you will be awarded 3 marks if you darken only the bubble corresponding
to the correct answer and zero mark if no bubble is darkened. In case of bubbling of incorrect answer,
minus one (–1) mark will be awarded.
PART–I
Atomic masses : [H = 1, D = 2, Li = 7, C = 12, N = 14, O = 16, F = 19, Na = 23, Mg = 24, Al = 27, Si = 28,
P = 31, S = 32, Cl = 35.5, K = 39, Ca = 40, Cr = 52, Mn = 55, Fe = 56, Cu = 63.5, Zn = 65, As = 75,
Br = 80, Ag = 108, I = 127, Ba = 137, Hg = 200, Pb = 207]
SECTION - I
Straight Objective Type
This section contains 10 multiple choice questions. Each question has 5 choices (A), (B), (C), (D) and (E)
for its answer, out of which ONLY ONE is correct.
1. The standard molar enthalpies of formation of cyclohexane () and benzene () at 25ºC are – 37 and +11.5
Kcal/mol respectively. The standard enthalpy of hydrogenation of cyclohexene () at 25ºC is – 28.5 Kcal/mol.
From the given data, calculate the magnitude of resonance energy of benzene :
(A) 37 Kcal/mol (B) 134 Kcal/mol (C) 54 Kcal/mol
(D) 157 Kcal/mol (E) 35 Kcal/mol
2. If two moles of a hypothetical real gas X occupy a volume of 4L at 10 atm pressure and 300 K, then which of
the following statement is correct :
(A) Gas X is less compressible with respect to an ideal gas, since attractive tendencies are dominant among
gas molecules.
(B) On applying greater pressure, the gas X will respond by increasing its volume, since repulsive tendencies
are dominant among gas molecules.
(C) As the pressure is lowered and temperature is increased, the gas X will show greater deviation from ideal
behaviour.
(D) Assuming the attractive / repulsive tendencies of gas X to be the same even at STP conditions, 1 mole of
gas X occupies a volume of 22.4 L at a pressure lower than that at STP (keeping temperature constant).
(E) The value of compressibility factor (Z) will be greater than 1 for the real gas X under the conditions given
in the question.
RESONANCE P1MT2XI090111C0-1
3. Which of the following statements is INCORRECT regarding caustic potash, KOH :
(A) It is prepared by the electrolysis of an aqueous solution of KCl.
(B) It is used for the absorption of gases like CO2, SO2 etc. in eudiometry.
(C) White phosphorus undergoes disproportionation reaction with its aqueous solution, when boiled.
(D) Commercially, it can be prepared by Le-Blanc process, but not by Solvay’s process.
(E) Its 2 moles absorb 4 moles of NO forming KNO2 , N2O and H2O.
4. A proton beam can undergo diffraction by crystals. Through what potential (in volts) should a beam of protons
be accelerated so that its wavelength becomes equal to 14.3 pm :
(Given : Mass of a proton = 1.66 × 10–27 Kg)
(A) 1 V (B) 4 V (C) 9 V
(D) 16 V (E) 25 V
5. The solubility of Fe(OH)3 in a buffer solution of pH = 6 is 4.32 × 10–2 mol/L. How many times is this solubility
greater than its solubility in pure water. (Ignoring the hydrolysis of Fe3+ ions)
(A) 1000 (B) 216 (C) 10
(D) 432 (E) 216000
RESONANCE P1MT2XI090111C0-2
6. The density of a mixture of O2 and N2 at NTP is 1.4 g/L. Then the partial pressure of O2 is :
(A) 0.84 atm (B) 0.68 atm (C) 0.52 atm
(D) 0.36 atm (E) 0.2 atm
8. In which of the following processes on an ideal gas, there occurs an increase in entropy of the surroundings:
(A) Reversible Isothermal expansion.
(B) Irreversible adiabatic process.
(C) Isothermal free expansion (against vacuum)
(D) Adiabatic free expansion (against vacuum)
(E) None of these
RESONANCE P1MT2XI090111C0-3
9. Total number of geometrical isomers in the given compound is :
10. The total number of isomers for the alkyne with molecular formula C3HDClBr is :
(A) 4 (B) 6 (C) 8
(D) 5 (E) 7
SECTION - II
Comprehension Type
This section contains 3 paragraphs. Based open each paragraph, there are 2 multiple choice questions.
Each question has 4 choices (A), (B), (C) and (D), out of which ONLY ONE is correct.
12. In what molar ratio, is KMnO4 getting consumed by Cu2S and CuS respectively :
(A) 4 : 3 (B) 8 : 15 (C) 2 : 9 (D) 1 : 1
RESONANCE P1MT2XI090111C0-4
Paragraph for Question Nos. 13 to 14
A mixture containing 2 moles of an ideal gas A ( = 4/3) and 4 moles of an ideal gas B ( = 5/3) is expanded
from 2 L to 8 L by a process, for which the graph of log T (y-axis) vs log V (x-axis) is a straight line with slope
1
– . The initial temperature of gas mixture is 320 K. Assuming the gas mixture to behave ideally,answer the
2
following questions :
13. Work done by the gas mixture in the above process is : (R = Gas constant)
(A) 1920 R (B) 2000 R (C) 1840 R (D) 1760 R
14. What can be said about the value of Ssystem for the above process :
(A) will be greater than zero. (B) will be less than zero.
(C) will be equal to zero. (D) nothing can be said with certainty.
16. What will be the pH of solution, when 'A' and 'C' solutions are mixed completely ?
(A) 9.5 (B) 5 (C) 10.15 (D) 8.85
RESONANCE P1MT2XI090111C0-5
SECTION - III
True & False Type
This Section Contains 4 questions. Each statement is either true (T) or false (F).
17. The number of electrons, having anticlokwise spin present in Zn2+ having n = 3, m = 1 values, is 3.
18. NCl3 does not undergo reaction with water due to non-availability of d-orbitals on N-atom.
19. Under identical conditions, a gas with lower molecular mass diffuses faster as compared to another gas with
higher molecular mass.
RESONANCE P1MT2XI090111C0-6
SECTION - IV
Integer Answer Type
21. Determine the sum of fully filled and half filled orbitals, which have number of radial nodes less than the
number of angular nodes, in ground state of Mn2+ ion.
22. Determine the sum of number of d-p bonds and number of peroxy linkages in one molecule each of Caro's
acid (H2SO5) and Marshall's acid (H2S2O8).
RESONANCE P1MT2XI090111C0-7
23. Calculate the difference between enthalpy change (H) and internal energy change (E) in Kcal for the
combustion of 1 mole of heptane () at 27ºC. Give your answer in terms of magnitude, rounding it off to
nearest whole number.
24. How many of the following compounds do not impart characteristic colour to the Bunsen flame :
NaCl , BeCl2 , KOH , BaSO4 , MgCl2 , CsCl , Na2SO4 , Mg(OH)2 , K2CO3
RESONANCE P1MT2XI090111C0-8
PART- II
SECTION - I
Straight Objective Type
This section contains 10 multiple choice questions. Each question has 5 choices (A), (B), (C), (D) and (E)
for its answer, out of which ONLY ONE is correct.
26. The complete range of k for which the inequality kcos2x – kcosx + 1 0, x (–, ), is
1 1
(A) k < – (B) k > 4 (C) – k 4 (D) 0 k 4
2 2
1 1
(E) – k
2 2
27. If the equation 2x2 + 4xy + 7y2 – 12x – 2y + t = 0, where t is a parameter has exactly one real solution of
the form (x, y). Then value of (x + y) is equal to
(A) 3 (B) 5 (C) –5 (D) –3
(E) 0
2
28. If z is a complex number satisfying the equation |z – (1 + i)|2 = 2 and = , then the locus traced by in
z
complex plane is
(A) x – 2y – 1 = 0 (B) x + y – 1 = 0 (C) x – y + 1 = 0 (D) x + y + 1 = 0
(E) x – y – 1 = 0
RESONANCE P1MT2XI090111C0-9
n
2r 1
29. If Sn = r 4
, then S10 is equal to
r 1 2r 3 r 2
120 121 119 121
(A) (B) (C) (D)
121 120 120 122
120
(E)
119
a b c
30. If a, b, c, d, e are positive integers and matrix A = such that a + b + c + d + e = abcde, then
d 0 e
number of matrices A is equal to
(A) 16 (B) 24 (C) 40 (D) 60
(E) 48
31. BC is latus rectum of a parabola y2 = 4ax and A is its vertex. The minimum length of projection of BC on a
tangent drawn in portion of BAC is
(A) 2a (B) 2 2a (C) 2a (D) 3 2a
(E) 4 2a
RESONANCE P1MT2XI090111C0-10
32. If , and be the eccentric angles of point where a circle cuts an ellipse, then cos( + + + ) is equal
to
1
(A) 1 (B) –1 (C) 0 (D) –
2
1
(E)
2
34. If sin(sinx + cosx) = cos(cosx – sinx), then the largest possible value of sinx, is
1 16 – 2
(A) (B) 1 (C) (D)
2 4 4
1
(E)
2
RESONANCE P1MT2XI090111C0-11
35. Number of 9 lettered words that can be formed using all the letters of the word 'MEENANSHU' if alike letters
are never adjacent, is k(7!). Then k lies in the interval.
(A) [1, 5] (B) (5, 10] (C) (10, 15] (D) (15, 20]
SECTION - II
Comprehension Type
This section contains 3 paragraphs. Based open each paragraph, there are 2 multiple choice questions.
Each question has 4 choices (A), (B), (C) and (D), out of which ONLY ONE is correct.
36. a, b, c are in
(A) A.P. (B) G.P. (C) H.P. (D) none of these
RESONANCE P1MT2XI090111C0-12
Paragraph for Question Nos. 38 to 39
The line x + 2y + a = 0 intersects the circle x2 + y2 = 4 at two distinct points A and B. Another line
12x – 6y – 41 = 0 intersects the circle x2 + y2 – 4x – 2y + 1 = 0 at two distinct points C and D.
38. The values of 'a' lies in the interval
(A) (–2 5 , 2 5 ) (B) (0, 2 5 ) (C) (– 5 , 5 ) (D) (0, – 2 5 )
39. The equation of circle passing through the points A, B, C and D is
(A) 5x2 + 5y2 – 8x – 16y – 36 = 0 (B) 5x2 + 5y2 + 8x – 16y – 36 = 0
(C) 5x2 + 5y2 + 8x + 16y – 36 = 0 (D) 5x2 + 5y2 – 8x – 16y + 36 = 0
Let S be the set of first 18 natural numbers. The number of ways of selecting three numbers from S such
that
RESONANCE P1MT2XI090111C0-13
SECTION - III
True & False Type
This Section Contains 4 questions. Each statement is either true (T) or false (F).
42. Number of ways in which 4 identical balls can be kept in 7 different boxes if each box can have atmost one
ball is 35.
43. Number of ways in which 5 balls can be selected from a bag containing 5 identical and 5 different balls,
is 32.
x
44. Equation x4 – 2x2 sin2 + 1 = 0 has only one real solution.
2
45. Equation tan x = 2 tanx has no real solution.
6
RESONANCE P1MT2XI090111C0-14
SECTION - IV
Integer Answer Type
47. If the sum of all the solutions of the equation 3 cot2 + 10 cot + 3 = 0 in [0, 2] is k where k , then find
the value of k.
48. If is the imaginary cube root of unity, then find the number of ordered pairs of integers (a, b) such that
|a + b| = 1.
RESONANCE P1MT2XI090111C0-15
49. The line 3x + 6y = k intersect the curve 2x2 + 2xy + 3y2 = 1 at two distinct points A and B. The circle on AB
as diameter passes through the origin. The sum of possible values of k is
50. Let A be the set of all 3 × 3 skew symmetric matrices whose entries are either –1, 0 or 1. If there are exactly
three 0's three 1's and three (–1)'s, then the number of such matrices, is
RESONANCE P1MT2XI090111C0-16
PART - III
SECTION - I
Straight Objective Type
This section contains 10 multiple choice questions. Each question has 5 choices (A), (B), (C), (D) and (E)
for its answer, out of which ONLY ONE is correct.
51. A tube of length open at only one end is cut into two equal halves. The sixth overtone frequency of piece
closed at one end equals to sixth overtone frequency of piece open at both ends. The radius of cross–
section of tube is :
5
(A) (B) (C)
12 72 24
5 5
(D) (E)
24 48
5
52. In given figure, speed of A & D is m/sec as shown and speed of
8
B with respect to A is 1 m/sec., find speed of c in vertical direction.
(assume strings remains tight)
19 65
(A) 3 m/sec. (B) m/sec. (C) m/sec.
5 20
RESONANCE P1MT2XI090111C0-17
53. A non–uniform rope of length hangs from a ceiling. Mass per unit length of rope () changes as = 0ey,
where y is the distance along the string from its lowest point. Then graph between square of velocity of wave
and y will be best represented as :
(D) (E)
54. A cubical box is filled 50% with water and is open from upper part then it is
fixed on a moving cart with an acceleration 'a' on an fixed inclined as shown
in figure. Value of a for which water will not come out from cube:
g
(A) (B) g (C) 2g
2
(D) 3g (E) All of these
(SPACE FOR ROUGH WORK)
RESONANCE P1MT2XI090111C0-18
55. A monkey of mass 'm' climbs–up on a rope with relative acceleration
g
upward. Rope is wrapped on a uniform circular ring of mass 8m and
2
there is no slipping between ground and ring. If initial distance between
monkey and pulley is then how much time it will take to reach to the
pulley. (Assume ring is sufficiently far from pulley) : (Neglect size of monkey
for calculation, pulley and rope are ideal)
5 10
(A) 2 g (B) g (C) g
2
(D) g (E) None of these
56. A metal block of area 0.10 m2 is connected to a 0.020 kg mass via a string that
passes over an ideal pulley as shown in figure. A liquid with a film thickness of
0.30 mm is placed between the block and the table. When system is released
the block moves to the right with a small constant speed of 0.090 ms–1, then
coefficient of visocity of liquid is :
10 20
(A) × 10–3 Pa s (B) × 10–3 Pa s (C) 10–2 Pa s
3 3
40
(D) × 10–3 Pa s (E) 6 × 10–3 Pa s
3
57. Extension in a uniform rod of length l, mass m, cross section radius r and young’s
modulus Y when is suspended at one of its end.
mg 2m g mg
(A) 2 (B) 2 (C)
3 r Y r Y r 2 Y
mg 5m g
(D) (E) (SPACE FOR ROUGH WORK)
2r 2 Y 2r 2 Y
RESONANCE P1MT2XI090111C0-19
58. 0.056 kg of nitrogen is enclosed in a vessel at a temperature of 27ºC. How much heat has to be transferred
to the gas to double the most probable speed of its molecules. (R = 2 cal/mol.k)
(A) 4500 cal (B) 9000 cal (C) 18000 cal
(D) 5000 cal (E) None of these
59. A gas has molar heat capacity C = 24.9 J mol–1 k –1 in the process P2T = constant. Then (R = 8.3 J/mol k)
(A) Gas is monoatomic (B) Gas is diatomic (C) Gas is triatomic
(D) Atomicity of gas is 4 (E) Data insufficient
60. A small ball of mass m is released from height h on a wedge having circular
track as shown in figure. Find the normal force on ball due to wedge just after
it enters in circular track.(Assume it enters at point P tangentially and all
surfaces are smooth)
2mgh 4 mgh 4mgh
(A) (B) (C)
R 3 R R
mgh
(D) (E) zero
2R
SECTION - II
Comprehension Type
This section contains 3 paragraphs. Based open each paragraph, there are 2 multiple choice questions.
Each question has 4 choices (A), (B), (C) and (D), out of which ONLY ONE is correct.
RESONANCE P1MT2XI090111C0-20
61. Beat frequency observed by the driver corresponding to sound waves reflected from wall-1 and wall-2 (reflected
waves corresponding to waves directly coming from source) :
vc 2v c vc 4v c
(A) f (B) f (C) f (D) f
v v 2v v
62. Consider the sound wave observed by the driver directly from car has a wavelength 1 and the sound wave
1 2
after reflection from wall-1 observed by the driver has wavelength 2 then is :
1 2
vc 2v c vc 4v c
(A) (B) (C) (D)
v v 4v v
63. Minimum value of impulse P so that disc climbs up on the surface CD without loosing contact at point C :
3 3 1
(A) m gR (B) 2m gR (C) m gR (D) m gR
2 2 2
64. Find the friction force on sphere just after minimum impulse is imparted in previous question :
mg mg (SPACE FOR ROUGH 2WORK)
mg
(A) (B) (C) (D) 3mg
3 2 3 3
(SPACE FOR ROUGH WORK)
RESONANCE P1MT2XI090111C0-21
Paragraph for Question Nos. 65 to 66
Consider one mole of an ideal monoatomic gas is inside a fixed, perfectly insulating cylindrical vessel at
temperature T and piston is at equilibrium initially as shown in figure. Now a particle of mass m strikes
horizontally to piston of same mass at mid–point of piston and sticks to piston. Initially temperature
mv 2
T= , where R is universal gas constant) (Neglect heat loss through piston, assume that velocity is so
R
small that change in the the temperature of gas due to motion of piston is simultaneous in whole volume)
(friction is absent everywhere)
65. Ratio of maximum temperature and minimum temperature of gas during motion of piston :
(A) 1 (B) 7 : 6 (C) 7 : 5 (D) 6 : 7
66. Assume whole system is placed in gravity free room, and in previous question, particle strikes elastically
then find ratio of maximum temperature to minimum temperature during motion of piston :
(A) 4 : 3 (B) 3 : 4 (C) 2 : 1 (D) 1 : 2
(SPACE FOR ROUGH WORK)
RESONANCE P1MT2XI090111C0-22
SECTION - III
True & False Type
This Section Contains 4 questions. Each question is either true (T) or false (F).
67. More heat is required to change temperature of an ideal gas, at constant pressure than at constant volume
by same amount.
68. A rigid body rolls up inclined plane without sliding. The friction force on it may be downwards.
69. A string is carrying sinusoidal wave. Consider a small segment of string then total energy of this small
segment is conserved.
70. When a ball strikes a fixed horizontal surface at angle with vertical and rebounds at with same angle with
vertical then it must be an elastic collision.
SECTION - IV
Integer Answer Type
71. A uniform string of length , fixed at both ends is vibrating in its 2nd overtone. The maximum amplitude
is 'a' and tension in string is 'T', if the energy of virbation contained between two consecutive nodes is
K a 2 2T
then 'K' is :
8
(SPACE
(SPACE FOR
FOR ROUGH
ROUGH WORK)
WORK)
RESONANCE P1MT2XI090111C0-23
72. A tall glass jar has a small hole of radius 0.06 mm at its bottom, x
is the approximate depth upto which the jar can be lowered vertically
x
in water before water enters into it through the hole. Find in cm.
10
(Surface Tension of water = 0.06 N/m) (g = 10 m/s2 , density of
water = 1000 kg/m3) (Assume drop of water becomes
hemispherical before water enters in jar)
73. 4 gms of steam at 100°C is added to 20 gms of water at 46°C in a container of negligible mass.
Assuming no heat is lost to surrounding, If the mass of water in container at thermal equilibrium is 5.5x
(in gms) then 'x' is : Latent heat of vaporisation = 540 cal/gm. Specific heat of water = 1 cal/gm-°C.
RESONANCE P1MT2XI090111C0-24
75. Initially a small block is in equilibrium and at a height 10m from ground as shown. At t = 0, block explodes in
two equal parts. One part collides with the ground at t = 1 sec and sticks to ground at the position just below
the initial equilibrium position and another part remains held with spring, then find the amplitude of oscillations
of the block held by spring.
RESONANCE P1MT2XI090111C0-25
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shall abide by them. filled in by the Candidate.
-------------------------------- --------------------------------
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