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Isomeroa
Isomeroa
�=𝑅𝑇/(𝑉𝑚−𝑏)−𝑎/(𝑇 〖𝑉
𝑚〗 ^2 )
�_𝟕
COMPUESTO: TOLUENO
𝑯_�
TEMPERATURA CRITICA Tc (K)
𝑏=0,125 (𝑅 𝑇�)/��
500
400
300
300
PRESION
200
100
0
0 0.2 0.4 0.6
-100
T (K) 601.64 T (K) 591.64
Vm (L/mol) P(atm) Vm (L/mol) P(atm)
0.2 377.794371 0.2 351.305577
0.23 158.635842 0.23 140.71792
0.26 90.6987966 0.26 77.2330547
�_𝟕
OLUENO
0.29 65.0450123 0.29 54.3518102
𝑯_� 0.32 54.3341341 0.32 45.5367428
591.64
0.35 49.5746396 0.35 42.1516651
40.55
0.38 47.3348784 0.38 40.9499467
0.08205746
0.41 46.1813168 0.41 40.6048304
14507.803218786
0.44 45.4819798 0.44 40.5505204
0.1496562134
0.47 44.9512782 0.47 40.5446693
0.5 44.4609705 0.5 40.4884727
0.53 43.9564759 0.53 40.3480601
0.56 43.4180652 0.56 40.1186757
0.59 42.8422769 0.59 39.8079348
0.62 42.2328474 0.62 39.4279316
0.65 41.5962667 0.65 38.9915708
0.68 40.9396317 0.68 38.5109478
0.71 40.2696573 0.71 37.9967246
0.74 39.5922712 0.74 37.4579836
0.77 38.912498 0.77 36.902298
0.8 38.2344831 0.8 36.3358922
0.83 37.5615758 0.83 35.7638268
0.86 36.8964338 0.86 35.1901795
0.89 36.2411287 0.89 34.6182092
0.92 35.597243 0.92 34.0504979
0.95 34.9659559 0.95 33.4890718
0.98 34.3481172 0.98 32.9355021
1.01 33.7443087 1.01 32.3909894
1.04 33.1548965 1.04 31.8564327
1.07 32.5800733 1.07 31.3324859
1.1 32.0198939 1.1 30.8196049
1.13 31.4743038 1.13 30.3180855
1.16 30.9431628 1.16 29.8280946
1.19 30.4262641 1.19 29.3496958
1.22 29.9233502 1.22 28.8828701
1.25 29.4341253 1.25 28.4275335
1.28 28.9582654 1.28 27.9835501
1.31 28.4954271 1.31 27.5507441
1.34 28.0452537 1.34 27.128909
1.37 27.6073811 1.37 26.7178152
1.4 27.1814415 1.4 26.3172159
1.43 26.7670673 1.43 25.9268526
1.46 26.3638934 1.46 25.5464589
1.49 25.9715597 1.49 25.1757637
1.52 25.5897122 1.52 24.8144941
1.55 25.2180047 1.55 24.4623778
1.58 24.8560995 1.58 24.119144
1.61 24.5036679 1.61 23.7845255
1.64 24.160391 1.64 23.4582595
1.67 23.8259598 1.67 23.1400884
1.7 23.5000753 1.7 22.8297603
1.73 23.1824485 1.73 22.5270299
VOLUMEN MOLAR
T (K) 581.64 T (K) 571.64 T (K)
Vm (L/mol) P(atm) Vm (L/mol) P(atm) Vm (L/mol)
0.2 324.466416 0.2 297.258501 0.2
0.23 122.53507 0.23 104.073389 0.23
0.26 63.5599951 0.26 49.6687376 0.26
0.29 43.4919651 0.29 32.4567314 0.29
0.32 36.6024893 0.32 27.5241912 0.32
551.64
Li near (551.64)
601.64
591.64
581.64
571.64
601.64
591.64
581.64
571.64
561.64
541.64
531.64
521.64
511.64
Col umn AO
�=𝑅𝑇/(𝑉𝑚−𝑏)−𝑎/
(𝑇 〖𝑉𝑚〗 ^2 )
COMPUESTO: TOLUENO
𝑏=0,125 (𝑅 𝑇�)/��
FACTOR DE COMPRENSIBILIDAD
1
2
0.5
1.5
FACTOR DE COM
0.5
0
-2 0 2
0.08205746
0.41 46.1813168 1.06902647 0.38352652 1.13887341
14507.80321879
0.44 45.4819798 1.08546397 0.40535662 1.12162712
0.1496562134
0.47 44.9512782 1.09827912 0.42794222 1.10853954
0.5 44.4609705 1.11039075 0.45029194 1.0964481
0.53 43.9564759 1.12313486 0.47189347 1.0840068
0.56 43.4180652 1.13706242 0.49249715 1.07072911
0.59 42.8422769 1.15234422 0.51199979 1.05652964
0.62 42.2328474 1.16897281 0.53038017 1.04150055
0.65 41.5962667 1.18686253 0.54766242 1.02580189
0.68 40.9396317 1.20589874 0.56389478 1.00960867
0.71 40.2696573 1.22596152 0.57913726 0.99308649
0.74 39.5922712 1.24693656 0.59345441 0.97638153
0.77 38.912498 1.26871963 0.60691108 0.95961771
0.8 38.2344831 1.29121793 0.61957008 0.94289724
0.83 37.5615758 1.31434982 0.63149094 0.92630273
0.86 36.8964338 1.33804396 0.64272926 0.90989972
0.89 36.2411287 1.36223821 0.65333654 0.8937393
0.92 35.597243 1.38687848 0.66336021 0.87786049
0.95 34.9659559 1.41191765 0.67284378 0.86229238
0.98 34.3481172 1.4373146 0.68182707 0.84705591
1.01 33.7443087 1.46303339 0.69034652 0.83216544
1.04 33.1548965 1.48904251 0.6984354 0.81763
1.07 32.5800733 1.51531428 0.70612415 0.80345434
1.1 32.0198939 1.54182429 0.71344057 0.7896398
1.13 31.4743038 1.56855098 0.72041012 0.77618505
1.16 30.9431628 1.59547525 0.72705609 0.76308663
1.19 30.4262641 1.62258009 0.73339986 0.75033944
1.22 29.9233502 1.64985036 0.739461 0.73793712
1.25 29.4341253 1.67727255 0.74525753 0.72587239
1.28 28.9582654 1.70483451 0.75080601 0.71413725
1.31 28.4954271 1.73252537 0.75612168 0.70272323
1.34 28.0452537 1.7603353 0.76121861 0.69162155
1.37 27.6073811 1.78825547 0.76610978 0.68082321
1.4 27.1814415 1.81627785 0.77080717 0.67031915
1.43 26.7670673 1.84439519 0.77532191 0.6601003
1.46 26.3638934 1.87260089 0.77966427 0.65015767
1.49 25.9715597 1.90088893 0.7838438 0.64048236
1.52 25.5897122 1.92925383 0.78786937 0.63106565
1.55 25.2180047 1.95769058 0.79174923 0.62189901
1.58 24.8560995 1.98619459 0.79549104 0.61297409
1.61 24.5036679 2.01476165 0.79910197 0.60428281
1.64 24.160391 2.04338788 0.80258869 0.59581729
1.67 23.8259598 2.07206974 0.80595743 0.58756991
1.7 23.5000753 2.10080392 0.80921403 0.5795333
1.73 23.1824485 2.1295874 0.81236393 0.57170033
Z vs Pr
2 4 6 8
Tr1 Tr2 Tr3 Tr4 Tr5 Tr6 Tr7 Tr8 Tr9 Tr10
PRESION REDUCIDA
T (K) 591.64 T (K)
Vm(L/mol) P(atm) Vm ideal Z Pr Vm(L/mol)
0.2 351.305577 0.13819443 1.44723628 8.66351609 0.2
0.23 140.71792 0.34500564 0.66665577 3.4702323 0.23
0.26 77.2330547 0.62859712 0.41361946 1.9046376 0.26
0.29 54.3518102 0.89322647 0.3246657 1.34036523 0.29
0.32 45.5367428 1.06613852 0.30014861 1.12297763 0.32