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Boundary: Surface or surfaces, real or imaginary, by which either a closed or open system is
delineated from the surroundings for analysis.
Closed system: A system that does not exchange mass with its surroundings.
Open system (Control Volume): A system that exchanges mass with its surroundings.
Isolated system: A system that does not interact with the environment. Changes of conditions
in the environment have no influence on the behavior of isolated systems.
Adiabatic system: A system that has no thermal interaction between system and
surroundings. In practice, a thick layer of insulation material approximates an adiabatic wall.
The adiabatic system may experience interactions other than thermal.
Thermodynamic property: A particular property from among the larger set (see "property")
that, on the basis of experiment and experience, has been found to be important for
thermodynamic analysis.
Extensive property: One whose numerical value depends on the extent of the system. In a
homogeneous system, it is proportional to the mass of the system, e.g. volume, area, length,
energy.
Intensive property: One whose numerical value is independent of the extent of the system,
e.g. density, pressure, stress, temperature.
Energy: A quantity that has the capacity for producing a change of state in a closed system.
Work: A form of energy transfer. Work occurs when a force acts over a displacement. Work
is said to be done by a system if the sole effect external to the system can be made equivalent
to raising a weight.
Heat Transfer: Another form of energy transfer. The energy transferred between systems, or
between a system and it’s surrounding, due to a temperature difference.
Unit: The name of the arbitrary chosen element, used in assigning a numerical value to a
dimension, and adopted as a standard for reporting measurements and conducting analysis.
SI and British units used in this course. Conversion factors: See inside of book cover.
Thermodynamic equilibrium: The condition of a system such that all influences (thermal,
mechanical, chemical, etc.) which have the potential for altering its state are in balance.
Thermal equilibrium: A condition said to exist within a system or between a system and its
surroundings, or between two systems, when, despite intimate thermal contact, no change in
properties is observed.
Mechanical equilibrium: No net force exists on or in the system acting from the
surroundings or from within the system. Furthermore, no work transfers are occuring within
subsystems and all parts of the system are at rest relative to each other and the surroundings.
Typically mechanical equilibrium of a system is reached prior to thermal equilibrium after a
process has occurred.
Process: This describes the continuous series of state changes undergone by a system due to
interactions between the system and another system, between the system and its surroundings,
or due to an initial lack of equilibrium in the system that caused it to change spontaneously.
Path: The locus of states through which a system passes when going from an initial state to a
final state. For some systems, the thermodynamic state is described by only two independent
properties. Hence, the path is a trace on a plane.
Quasistatic (or quasi-equilibrium) process: A process conducted in such a manner (i.e.
slowly, without friction) that the system is at all times only infinitesimally removed from a
state of thermodynamic equilibrium.
Cycle: A process, or series of processes, in which the initial and final states are identical.
Laws: Experimental observations on systems that have been formulated into mathematical
statements.
First law of thermodynamics: The value of the net work done by or on a closed system
undergoing an adiabatic process between two given states depends solely on the end states and
not on the details of the adiabatic process. (Energy conservation statement) The change in the
total energy of a closed system during a process is equal to the heat transfer to the system
minus the work done by the system.
Mean free path (λ): The average distance a molecule moves within a gas at a constant speed
along a straight line between successive collisions.