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(a)
As we know that according to ideal gas equation;
𝑃𝑉 = 𝑛𝑅𝑇
Where,
P is the pressure
V is the volume of the container.
N is the total number of moles of the gas and
T is the temperature in absolute scale.
R is the universal gas constant. (in S.I. units-> 8.314 JK-1mol-1)
Now, according to force – voltage analogy,
Force(F)<->Voltage(V)
Rate of change of mass(dm/dt) <->current(I)
According to Ohm’s law,
𝑑𝑚 𝐹
𝑤= = 𝑅 = (𝑉/𝑅)
𝑑𝑡
(b)
According to ideal gas equation we can write,
𝑃𝑉 = 𝑛𝑅T
=>𝑃𝑉 = (𝑚/𝑀)𝑅𝑇
𝑀𝑃𝑉
=>𝑚 = 𝑅𝑇
Now,
𝑑𝑚
𝑤=
𝑑𝑡
𝑀𝑉
𝑑𝑚 ( )𝑑𝑝
𝑅𝑇
=>𝑤 = =
𝑑𝑡 𝑑𝑡
Thus
𝑀𝑉1
( )𝑑𝑃
𝑅𝑇
= 𝑤1 − 𝑤2……………………………………………………………(4)
𝑑𝑡
𝑀𝑉2
( )𝑑𝑃
𝑅𝑇
= 𝑤2 − 𝑤3…………………………………………………………..(5)
𝑑𝑡
Substituting values of w1,w2 and w3 from (1),(2) and (3) into (4) and (5) and rearranging
we get,
𝑀𝑉1
( )𝑑𝑃1 𝑃𝑐−𝑃1 𝑃1−𝑃2
𝑅𝑇
=( )− ………………………………………………..(6)
𝑑𝑡 𝑅1 𝑅2
Also,
𝑀𝑉2
( )𝑑𝑃2 𝑃1−𝑃2 𝑃2−𝑃ℎ
𝑅𝑇
= − …………………………………………..(7)
𝑑𝑡 𝑅2 𝑅3