6-19

(a) According to Table 5.2 and 6.6 we have:

8𝜋 8𝜋
𝜓(𝑟⃗) = 𝐴√ 2𝑎0 √6𝑎0 3 𝑅21 (𝑟)𝑌11 (𝜃, 𝜑) = 𝐴√ 2𝑎0 √6𝑎0 3 Ψ211 (𝑟⃗)
3 3

Thus 𝜓(𝑟⃗) is eigen function of 𝐿⃗̂⃗2 and 𝐿̂𝑧 and 𝑛 = 2, 𝑙 = 1, 𝑚 = 1

(b) Ψ211 (𝑟⃗) is normalize so

−1
8𝜋
𝐴 = (√ 2𝑎0 √6𝑎0 3 )
3

(c) According to 6.233 and 6.265 we have

1
⟨21|𝑟|21⟩ = (3 × 22 − 1 × 2)𝑎0 = 5𝑎0
2
And 𝑟2 = 22 𝑎0 = 4𝑎0

Mohammad Behtaj & Adel Sepehri

Translate by: Telegram Channel