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Table 2.2 Standard pK values of some monocarboxylic acids

  
  
  

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Table 2.3 Standard pK1 and pK2 values of some dicarboxylic acids

  

  
  
  
 


Half way titration point

= pKa
8
pKa 7.2
– +
H3PO4¢ HPO4 + H

pH 4
pKa 7.2
– +
CH3COOH CH3COO + H

0
10 20
ml of 0.1 M NaOH

Fig. 2.1 pH titration curve of monocarboxylic acids

6
pk2 5.0
5

4
pk1 3.5 pk2 4.3
pH
3 Malic acid Oxalic acid

2
pk1 1.3
1 Oxalic acid

Fig. 2.2 pH titration curve of dicarboxylic acids

  

            



            
         
          
   

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