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Substituting, we get
Now we define the equilibrium constant KP for the
chemical equilibrium of ideal-gas mixtures as
Substituting, we find
KP = 2 x 10-160
Assumptions
1 The constituents of the mixture are ideal gases.
2 The equilibrium mixture consists of H2 and H only.
Analysis
This is a dissociation process that is significant
at very high temperatures only. For simplicity we
consider 1 kmol of H2, as shown in Fig.16–8. The
stoichiometric and actual reactions in this case
are as follows:
Analysis
This is a dissociation process that is significant
at very high temperatures only. For simplicity we
consider 1 kmol of H2, as shown in Fig. 16–8. The
stoichiometric and actual reactions in this case
are as follows:
A double-headed arrow is used for the
stoichiometric reaction to differentiate it from the
actual reaction. This reaction involves one reactant
(H2) and one product (H). The equilibrium
composition consists of 0.9 kmol of H2 (the
leftover reactant) and 0.2 kmol of H (the newly
formed product). Therefore, NH2 0.9 and NH 0.2
and the equilibrium constant KP is determined
from Eq. 16–15 to be
From Table A–00, the temperature corresponding
to this KP value is