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1.

Aufbau Principle Phosphorus (special) how many bonds can


2. Pauli Exclusion it make?
3. Hund’s Rule - Identify group (5A)
- Thus it needs 3 more e to reach
1.4 Development of Chemical Bonding octet.
Theory - PH3

- Carbon is tetravalent 1.5 Valence Bond Theory


- Emil Erlenmeyer proposed C-C triple
bond for acetylene
- Alexander Crum Brown – CC double
bond
- Kekule – carbon chains can double
back to form rings of atoms
- Jacobus van’t Hoff & Joseph Le Bel
---- coming in to plane
___ in the plane
Wedge – out of the plane

When bonds form = energy is released. Bc


the product is more stable (less energy)

Ionic Compounds
- Some achieve octet by gaining e or
losing e
- Ions form
- Held together by an electrostatic
attraction.
- Salts form.

Covalent Compounds
- Sharing e between atoms
- Molecules form.
- Held together by covalent bonds.
- Carbon !!

1. Lewis Structure (electron-dot


structures)
- Least electro negative center
2. Kekule strictures (Line-bond
structures)

Lone-pair electrons
- VE pairs not used for bonding

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