Final JEE - Main Exam Januar y, 2020/07-01-2020/Evening Session

FINAL JEE–MAIN EXAMINATION – JANUARY, 2020

(Held On Tuesday 07th JANUARY, 2020) TIME : 2 : 30 PM to 5 : 30 PM
CHEMISTRY TEST PAPER WITH ANSWER & SOLUTION
1. Within each pair of elements of F & Cl , S & Se, 3. Among the statements(a)-(d), the incorrect ones
and Li & Na, respectively, the elements that release are-
more energy upon an electron gain are- (a) Octahedral Co(III) complexes with strong field
(1) F, Se and Na ligands have very high magnetic moments
(2) F, S and Li (b) When D0 < P, the d-electron configuration of
(3) Cl, S and Li Co(III) in an octahedral complex is t 4eg e2g
(4) Cl, Se and Na (c) Wavelength of light absorbed by [Co(en)3]3+
NTA Ans. (3) is lower than that of [CoF6]3–
ALLEN Ans. (3) (d) If the D0 for an octahedral complex of Co(III)
Sol. (i) Electron affinity of second period p-block is 18,000 cm –1, the D t for its tetrahedral
element is less than third period p-block element complex with the same ligand will be 16,000
due to small size of second period p-block element. cm–1
E.A. order : F < Cl EN
(ii) Down the group electron affinity decreases due
to size increases.
EA. order : S > Se
(1) (a) and (b) only
(3) (b) and (c) only
NTA Ans. (4)
ALLEN Ans. (4)
(2) (c) and (d) only
(4) (a) and (d) only

Li > Na Sol. (a) Co+3 (with strong field ligands)

2. The redox reaction among the following is :
eg
(1) Combination of dinitrogen with dioxygen at
D0 > p
LL
2000 K
(2) Formation of ozone from atmosphereic oxygen diamagnetic
in the presence of sunlight t2g6
(3) Reaction of H2SO4 with NaOH
(b) If D0 < p ;
(4) Reaction of [Co(H2O)6]Cl 3 with AgNO3 e g2
NTA Ans. (1) D0 < p
A

ALLEN Ans. (1)

2000 K
Sol. (i) N 2 + O2 ¾¾¾® 2NO (Re dox reaction) t2g4

during the reaction, oxidation of nitrogen take place (c) Splitting power of ethylenediamine (en) is
from 0 to 2 and reduction of oxygen take place greater than fluoride (F–) ligand therefore more
from 0 to –2. It means this reaction is redox energy absorbed by [Co(en)3]3+ as compared to
reaction. [CoF6]3–.
hv So wave length of light absorbed by [Co(en)3]3+
(ii) 3O 2 ¾¾ ® 2O 3 (Non - r e dox reaction)
is lower than that of [CoF6]3–
(iii) H2SO4 + 2NaOH ® Na2SO4 + 2H2O 4
(d) D t = D 0
(neutralization reaction) 9
(iv) [Co(H2O)6]Cl3 + 3AgNO3 so if D0 = 18,000 cm–1
® 3AgCl¯ + [Co(H2O)6](NO3)3 4
Dt = ´ 18000 = 8000 cm–1
(White ppt.) 9
Statement (a) and (d) are incorrect.

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Final JEE - Main Exam Januar y, 2020/07-01-2020/Evening Session
4. The number of possible optical isomers for the 6. Which of the following statements is correct-
complexes MA2B2 with sp3 and dsp2 hybridised (1) Gluconic acid can form cyclic (acetal/
metal atom, respectively, is : hemiacetal) structure
Note : A and B are unidentate neutral and (2) Gluconic acid is a partial oxidation product of
unidentate monoanionic ligands, respectively glucose
(1) 0 and 0 (2) 0 and 2 (3) Gluconic acid is obtained by oxidation of
(3) 0 and 1 (4) 2 and 2 glucose with HNO3
NTA Ans. (1) (4) Gluconic acid is a dicarboxylic acid
ALLEN Ans. (1) NTA Ans. (2)
Sol. (a) If the complex MA2B2 is sp3 hybridised then ALLEN Ans. (2)
the shape of this complex is tetrahedral this Sol.
H
structure is opticaly inactive due to the presence O=C COOH
of plane of symmetry. H OH H OH
A HO H ¾¾¾® HO H
Br2 / H2O
H OH H OH
M B H OH H OH
A B OH OH
Optical isomes = 0
EN
(b) If the complex MA2B2 is dsp2 hybridised then
the shape of this complex is square planar.
D-glucose

HNO3
H
HO
Gluconic acid
(non-reducing)
COOH
OH
H
A B A B
M M H OH
A B B A H OH
(Cis-isomer) (Trans-isomer) COOH
LL
Saccharic acid
Both isomers are optically inactive due to the
7. The bond order and the magnetic characteristics
presence of plane of symmetry.
of CN– are :
Optical isomers = 0 (1) 3, diamagnetic
5. In the following reactions products(A) and (B), 1
respectively , are : (2) 2 , paramagnetic
2
A

NaOH + Cl2 ® (A) + side products (3) 3, paramagnetic

(hot and conc.) 1
(4) 2 , diamagnetic
Ca(OH)2 + Cl2 ® (B) + side products 2
NTA Ans. (1)
(dry)
ALLEN Ans. (1)
(1) NaClO3 and Ca(OCl)2
Sol. According to MOT (If z is internuclear axis)
(2) NaOCl and Ca(ClO3)2
The configuration of
(3) NaClO3 and Ca(ClO3)2
(4) NaOCl and Ca(OCl)2 CN – : s1s
2 *2 , s 2 , s*2 , p 2
, s1s 2s 2s
2 2
2p x = p 2p y , s2p z

NTA Ans. (1)

1
ALLEN Ans. (1) Bond order = (10 - 4)
2
Sol. 6NaOH + 3Cl2 ¾® NaClO3 + 5NaCl + 3H2O
(hot and conc.) (A) side product =3
–
2Ca(OH)2 + 2Cl2 ¾® Ca(OCl)2 + CaCl2 + 2H2O CN is diamagnetic due to absence of unpaired
dry (B) side product electron

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 Final JEE - Main Exam Januar y, 2020/07-01-2020/Evening Session
8. The equation that is incorrect is - 10. Two open beakers one containing a solvent and
(1) ( ) -( ) = ( ) -( )
L 0m NaBr L 0m NaI 0
Lm KBr
L 0m NaBr the other containing a mixture of that solvent with
a non volatile solute are together sealed in a
(2) ( L 0m )H O = ( L m0 )HCl + ( L m0 )NaOH - ( L m0 )NaCl
2 container. Over time -
(3) ( L 0m )KCl - ( L m0 )NaCl = ( Lm0 )KBr - ( L0m )NaBr (1) The volume of the solution does not change
and the volume of the solvent decreases
(4) ( L 0m )NaBr - ( L0m )NaCl = ( L0m )KBr - ( L 0m )KCl (2) The volume of the solution decrease and the
NTA Ans. (1) volume of the solvent increases
ALLEN Ans. (1) (3) The volume of the solution increase and the
Sol. Option (1) is incorrect. volume of the solvent decreases
According to Kohlrausch's law correct expression (4) The volume of the solution and the solvent does
is not change
(L ) 0
m NaBr
( )
- L 0m
NaI
( )
= L 0m
KBr
( )
- L 0m
KI
NTA Ans. (3)
ALLEN Ans. (3)
The other statements are correct.
Sol. The pure solvent solution will try to maintain
9. In the following reaction sequence
NH2 higher vapour pressure in the sealed container and
in return the solvent vapour molecules will

CH3
Ac2O

the major products B is -

A
Br2
AcOH
B EN condense in the solution of non-volatile solute as
it maintains an equilibrium with lower vapour
pressure. (Lowering of vapour pressure is observed
when a non volatile solute is mixed in a volatile
NHCOCH3 NHCOCH3
solvent)
Br Br
This will eventually lead to increase in the volume
(1) (2)
of solution and decrease in the volume of solvent.
LL
CH 2Br 11. A chromatography column, packed with silica gel
CH3
as stationary phase, was used to separate a mixture
NHCOCH3 NHCOCH3 of compounds consisting of (A) benzanilide (B)
COCH3 aniline and (C) acetophenone. When the column
(3) (4)
Br is eluted with a mixture of solvents, hexane : ethyl
acetate (20 : 80), the sequence of obtained
A

CH3 CH3 compounds :

NTA Ans. (1) (1) (B), (C) and (A) (2) (C), (A) and (B)
ALLEN Ans. (1) (3) (A), (B) and (C) (4) (B), (A) and (C)
O NTA Ans. (2)
NH2 NH–C–CH3 ALLEN Ans. (2)
O O O
CH3–C–O–C–CH3
¾¾¾¾¾¾® O
Sol. + Me–C–OH
Sol. (A) Benzanilide ® Ph–NH–C–Ph (µ = 2.71 D)
CH3 CH3 (B) Aniline ® Ph–NH2 (µ = 1.59 D)
(A) Br2/ACOH
O
O (C) Acetophenone ® Ph–C–CH3 (µ = 3.05 D)
NH–C–CH3
Dipole moment : C > A > B
Br
Hence the sequence of obtained compounds is (C),
(A) and (B)
CH3
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Final JEE - Main Exam Januar y, 2020/07-01-2020/Evening Session
12. Consider the following reactions : 14. Among the statements (a) - (d), the correct ones
anhyd.AlCl3 are -
(a) + Cl
(a) Decomposition of hydrogen peroxide gives
Cl Cl dioxygen
anhyd.AlCl3 (b) Like hydrogen peroxide, compounds , such
+ Cl2 Cl Cl
(b) dark
as KClO 3 , Pb(NO 3 ) 2 and NaNO 3 when
(excess)
Cl Cl heated liberated dioxygen
(c) + CH2=CH–Cl
anhyd.AlCl3
CH=CH2 (c) 2-Ethylanthraquinone is useful for the
industrial preparation of hydrogen
(d) + CH2=CH–CH 2Cl
anhyd.AlCl3
CH2–CH=CH2 peroxide.
Which of these reactions are possible ? (d) Hydrogen peroxide is used for the manufacture
(1) (a) and (d) (2) (b) and (d) of sodium perborate
(3) (a) and (b) (4) (b) , (c) and (d) (1) (a), (b) and (c) only
NTA Ans. (2) (2) (a) and (c) only
ALLEN Ans. (2) (3) (a), (b) , (c) and (d)
Cl (4) (a), (c) and (d) only
anhydrous NTA Ans. (3)
Sol. (a) + ¾¾¾®No reaction

(b) + Cl2
AlCl

anhyd. AlCl
¾¾¾¾®
3

dark
3

Cl

Cl
EN Cl
Cl

Cl
ALLEN Ans. (3)
Sol. (a) H 2 O2 ® 2H2 O + O2
D
(b) KClO3 ¾¾¾
MnO2
3
® KCl + O2
2
1
Cl Pb ( NO3 )2 ¾¾D
® PbO + 2NO 2 + O2
(electrophilic substitution) 2
D 1
(c) + CH2=CH–Cl
AlCl3
No reaction NaNO3 ¾¾ ® NaNO2 + O2
LL
2
O2(air)

AlCl3
(c) 2-ethylanthraquinol 2-ethylanthraquinone + H2O 2
H2/Pd
(d) + CH2=CH–CH2–Cl ¾¾® (d) 2H3BO3 + 2NaOH + 2H2O2
¾® Na2[B2(O2)(OH)4] + 4H2O
–CH2–CH=CH2 All statements are correct

13. Identify the correct labels of A, B and C in the 15. For the following reactions :
CH3CH2CH2Z + Br–
A

following graph from the options given below: ks

tion
B stitu
A — S ub
C CH3CH2CH2 Br + Z
ke
no. e lim
i n at
of i on
CH3CH=CH2 + HZ + Br –
molecules where
CH3
speed – – —
Z = CH3CH2O (A) or H 3C–C–O (B),
Root mean square speed (Vrms) ; most probable
speed (Vmp) ; Average speed (Vav.) CH3
(1) A – Vrms ; B –Vmp ; C – Vav ks and ke , are , respectively, the rate constants for
(2) A – Vav ; B –Vrms ; C – Vmp ks
(3) A – Vmp ; B –Vrms ; C – Vav the substitution and elimination, and m = , the
ke
(4) A – Vmp ; B –Vav ; C – Vrms correct options is -
NTA Ans. (4)
(1) mB > mA and ke(B) > ke(A)
ALLEN Ans. (4)
(2) mB > mA and ke(A) > ke(B)
æ 2RT ö æ 8RT ö æ 3RT ö
Sol. Vmp ç =
ç ÷ < Vav çç =
÷ ÷ < Vrms çç =
÷ ÷ (3) mA > mB and ke(B) > ke(A)
è M ø è pM ø è M ÷ø
(4) mA > mB and ke(A) > ke(B)
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 Final JEE - Main Exam Januar y, 2020/07-01-2020/Evening Session
NTA Ans. (3) 18. The ammonia (NH3) released on quantitative
ALLEN Ans. (3) reaction of 0.6 g urea (NH 2 CONH 2 ) with
Sol. sodium hydroxide (NaOH) can be neutralized
Ks CH3–CH2–CH2–Z by :
CH3–CH2–CH2–Br + Z (1) 100 ml of 0.1 N HCl
Ke (2) 200 ml of 0.4 N HCl
CH3–CH=CH 2 + HZ + Br– (3) 100 ml of 0.2 N HCl
(A) CH3–CH2–O – = Z ¾® (4) 200 ml of 0.2 N HCl
NTA Ans. (3)
(B) O =Z
ALLEN Ans. (3)
(B) with more steric crowding forms elimination
Sol. NH2CONH2 + 2NaOH ® Na2CO3 + 2NH3
product compared to substitution.
10 mmoles 20mmoles
Ke(B) > Ke(A)
Hence, NH3 will require 20 meq.
K (B) K (A)
µB = s < µA = s 19. In the following reaction squence, structures of A
K e (A) K e (A)
and B, respectively will be :
16. The refining method used when the metal and the
impurities have low and high melting temperatures,
respectively, is -
(1) zone refining
(2) liquation
(3) vapour phase refining
EN O
HBr
D
CH2Br
A
Na
Ether
(intramolecular Product) B

(4) distillation OH
OH
NTA Ans. (2) Br
ALLEN Ans. (2) (1)
&
LL
Sol. Liquation method is used when the melting point CH2Br
of metal is less compare to the melting point of
Br
the associated impurity. CH2Br
17. The correct order of stability for the following OH
(2) &
alkoxides is : CH2Br O
O– O– O–
O2N
A

NO2 NO2 Br Br
(A) (B) (C)
(3)
OH
(1) (C) > (B) > (A) &
CH2Br O
(2) (C) > (A) > (B)
(3) (B) > (C) > (A)
OH
(4) (B) > (A) > (C) OH
Br
NTA Ans. (1) (4)
&
CH2Br
ALLEN Ans. (1)
Sol. (C) > (B) > (A) NTA Ans. (4)
ALLEN Ans. (4)

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Final JEE - Main Exam Januar y, 2020/07-01-2020/Evening Session

O OH Sol. 4NaCl + K2Cr2 O7 + 6H2SO4

Sol.
HBr Br ¯
¾®
CH2–Br CH2– Br 2CrO2Cl2 + 4NaHSO4 + 2KHSO4 + 3H2O
(A) (A)
Na/ether
CrO2Cl2 + 4 NaOH ¾® Na2CrO4 + 2NaCl + 2H2O
OH (B)
Na2CrO4 + 2H2SO4 + 2H2O2
¯
20. For the reaction
CrO5 + 2NaHSO4 + 3H2O
2H2(g) + 2NO(g) ® N2(g) + 2H2O(g)
(C)
the observed rate expression is,
A = CrO2Cl2
rate = kf[NO]2[H2]. The rate expression of the
B = Na2CrO4
reverse reaction is :
C = CrO5
(1) kb[N2][H2O]2/[NO] (2) kb[N2][H2O]
Total number of atom in A + B + C = 18
(3) kb[N2][H2O]2 (4) kb[N2][H2O]2/[H2] 22. 3g of acetic acid is added to 250 mL of
NTA Ans. (4) 0.1 M HCl and the solution made up to 500 mL.
ALLEN Ans. (4)

Sol. K eq =
k f [ N 2 ][ H 2O ]
=
k b [ H 2 ]2 [ NO ]2
2
EN To 20 mL of this solution
1
2
mL of 5 M NaOH

is added. The pH of the solution is _____.

[Given : pKa of acetic acid = 4.75, molar mass
At equilibrium rf = rb of acetic acid = 60 g/mol, log3 = 0.4771]
Neglect any changes in volume
[ N ][ H 2O ]
2

k f [ H 2 ][ NO ] = k b 2
2
NTA Ans. (5.22 to 5.24)
[H2 ]
LL
[Given] ALLEN Ans. (5.22 or 5.23)
Sol. 3gm Acetic Acid + 250 ml 0.1 M HCl +Water
Hence, rate expression for reverse reaction. ¾¾® made to 500 ml solution.
[ N ][ H 2O ] Þ 500 ml solution has25 meq of HCl
2

= kb 2 50 meq of CH3COOH
[H2 ] \ 20ml solution has 1 meq of HCl
A

21. Conside the following reactions : 2 meq of CH3COOH

NaCl + K2Cr2O7 + H2SO4(Conc.) ® (A) + Side
æ 1 ö
products We have added 2.5 meq. of NaOH ç 5M, ml ÷
(A) + NaOH ® (B) + Side product è 2 ø
(B) + H2SO4(dilute) + H2O2 ® (C) + Side Finally , NaOH & HCl are completely consumed
product and we are left with 0.5 meq of CH3COOH
The sum of the total number of atoms in one and 1.5 meq of CH3 COONa
molecule each of (A), (B) and (C) is 1.5
NTA Ans. (18.00 to 18.00) pH = pKa + log
0.5
ALLEN Ans. (18.00) = 4.75 + log 3 = 4.75 + 0.4771
= 5.2271

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 Final JEE - Main Exam Januar y, 2020/07-01-2020/Evening Session

The standard heat of formation ( D f H 298 ) of 25. The number of sp2 hybridised carbons present
0
23.
ethane in (kJ/mol), if the heat of combustion in "Aspartame" is ________.
of ethane, hydrogen and graphite are –1560, NTA Ans. (9.00 to 9.00)
–393.5 and –286 kJ/mol, respectively is ALLEN Ans. (9.00)
_______
NTA Ans. (–192.00 to –193.00)
ALLEN Ans. (–192.5) O O O
Sol. HO–C–CH 2–CH–C–NH–CH–C–OCH
Sol. 2C(graphite) + 3H 2 (g) ¾¾ ® C 2H 6 (g) 2
sp 2
sp
2 3
sp
NH 2 CH2
DfH (C2H6) = 2DHcomb (Cgraphite) + 3 DHcomb(H2)
2
6 sp carbon
– DHcomb (C2H6)
= – ( 286 ´ 2 ) - ( 393.5 ´ 3) - ( -1560 )
= -572 – 1180.5 + 1560 = -192.5 kJ/mole no. of sp2–carbon ® 9
24. The flucculation value of HCl for arsenic sulphide
sol. is 30 m mole L–1. If H2SO4 is used for the
flocculation of arsenic sulphide, the amount, in

(molecular mass of H2SO4 = 98 g/mol)

NTA Ans. (0.36 to 0.38)
ALLEN Ans. (0.36 or 0.37)
EN
grams, of H2SO4 in 250 ml required for the above
purpose is ______.

Sol. 1 L solution requires 30 m.mol HCl

250 ml sol. will require 7.5 m.mol HCl
or 3.75 m.mol H2SO4
LL
3.75 ´ 98
Þ gm H2SO4
1000
= 0.3675 gm H2SO4
A