1.

Persamaan laju reaksi

𝑃𝐻0
𝐶𝑇𝐾4[𝑃𝐴0−𝑃𝐸0 ]
𝐾𝑒𝑞
r0 = [1+𝑃𝐴0𝐾2+𝑃𝐸0𝐾9]

Keterangan :

PA0 : Tekanan parsial propane (atm)

PE0 : Tekanan parsial propylene (atm)

PH0 : Tekanan parsial hidrogen (atm)

2. Panas reaksi
C3H8 C3H6 + H2

ΔHOR(298) = ΔHfOPRODUK - ΔHfOREAKTAN

= 124,27 KJ/mol
298
ΔHREAKTAN =∫
673,15
𝐶𝑝 𝑝𝑟𝑜𝑝𝑎𝑛𝑒 𝑑𝑇

= -139,2437 KJ/mol
667,34 677,34
ΔHPRODUK =∫
298
𝐶𝑝 𝑝𝑟𝑜𝑝𝑦𝑙𝑒𝑛𝑒 𝑑𝑇 + ∫298 𝐶𝑝 𝐻2 dT
= 64.838, 11 J/mol
= 64,83811 KJ/mol
ΔH0RT = ΔH1 + ΔH298 + ΔH2
= (-139,2347+ 124,27 + 64,83811)
= 49,8734 KJ/mol = 49.874,3 J/mol
3. Konstanta kesetimbangan
T masuk reaktor = 4000C

= 673 K

Keq [atm]= (1.48 107)exp(-15403/T)

= (1.48 107)exp(-15403/673K)

= 1.700326 10-3