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Abstract. The general properties of aggregate can determine the performance and durability of
the concrete. In this study, mineralogical, petrographic, mechanical, physical and chemical
properties of the rock samples of different origin (limestone, recrystallized limestone,
dolomite, sand and gravel, tephra–phonolite, trachybasalt) were determined. Samples were
obtained from different origin rocks units and they have been classified in three different sizes
of aggregate with crushing and screening method. Grading, classification of particle, loose bulk
density, water absorption ratio, flakiness index, coefficient of Los Angeles, resistance to
freeze-loosening and alkali-silica reaction of aggregates and organic matter determination has
been determined. The rocks have been investigated in compliance with the relevant standards.
Trachybasalt and dolomite have higher particle density than other rocks. In addition, strength
and flexural strength of these rocks are higher than other rocks. Tephra–phonolite has the
lowest water absorption rate. At the same time resistance to freeze loosening of Tephra-
phonolite is lower than the other rocks. Resistance to fragmentation and the resistance to wear
of all of rocks are quite high. Sand and gravel, tephra–phonolite and trachybasalt are evaluated
in terms of alkali-silica reaction. Sand and gravel are more reactive than the other aggregates.
Organic matter content of the aggregates is low for the quality of aggregate. Also high
correlation between some properties of aggregates was observed. For example, high correlation
between compressive strength and flexural strength, water absorption and porosity, resistance
to fragmentation and the resistance to ware (Micro-Deval).
1. Introduction
Nowadays, rock and concrete are two of the most widely used building material. Rocks are used as
construction materials in two ways. One of them is decorative architectural and the other one is natural
aggregates which used as raw materials in concrete. Aggregates are granular materials, which are
obtained naturally, artificially or as recycled. It is known that mineralogy and properties of the
aggregate, which derived from naturally formed bed or crushed rock, significantly affect the strength
and stability of concrete. Strength of aggregate has an effect on the strength of concrete, especially in
high-strength one (> 50 MPa). Porosity, grade, size distribution, moisture content, shape, surface
texture, break strength, modulus of elasticity, impurities of aggregates are important for the technology
of concrete. These properties of the aggregate result from mineralogical composition of the host rock
or the features of formation [1], (Table 1).
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Published under licence by IOP Publishing Ltd 1
World Multidisciplinary Earth Sciences Symposium (WMESS 2016) IOP Publishing
IOP Conf. Series: Earth and Environmental Science 44 (2016) 022002 doi:10.1088/1755-1315/44/2/022002
In this study, mineralogical, petrographic, mechanical, physical and chemical properties of the rock
samples of different origin (limestone, recrystallized limestone, dolomite, sand and gravel, tephra–
phonolite, trachybasalt) were determined. The rocks have been investigated in compliance with the
relevant standards. High correlations between some properties of aggregates were observed.
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World Multidisciplinary Earth Sciences Symposium (WMESS 2016) IOP Publishing
IOP Conf. Series: Earth and Environmental Science 44 (2016) 022002 doi:10.1088/1755-1315/44/2/022002
Figure 1. Total alkalis vs. SiO2 diagram for the Tf and Tb rocks [17]
Chemical
K1 K2 K3 Kçt K4 Do Tf Tb
Composition (%)
SiO2 0.71 0.03 4.10 5.19 0.26 0.73 53.78 48.51
Al2O3 0.25 <0.01 0.88 0.81 0.07 - 18.50 16.85
Fe2O3 0.08 <0.04 0.44 0.54 <0.04 0.20 3.74 7.57
MgO 0.22 0.48 12.77 7.90 19.33 20.48 0.98 5.38
CaO 55.40 56.34 37.51 42.61 33.73 30.97 5.76 10.33
Na2O 0.02 <0.01 0.04 0.05 0.02 - 4.96 3.64
K 2O 0.04 <0.01 0.16 0.33 0.01 - 6.11 3.82
TiO2 0.01 <0.01 0.05 0.06 <0.01 - 0.42 1.04
P 2O 5 0.02 <0.01 0.01 0.04 <0.01 0.05 0.29 0.80
MnO <0.01 <0.01 0.01 0.05 <0.01 - 0.1 0.14
Cr2O3 <0.002 <0.002 0.004 - <0.002 - <0.002 0.01
Loss on ignition 43.2 43.1 43.8 41.58 46.2 47.51 4.29 1.23
Total 99.95 99.97 99.75 99.16 99.68 99.94 99.95 99.31
K1: Limestone, K2: Recrystallized limestone, K3: Sand and gravel, K4: Dolomite, Tf: Tephra–phonolite, Tb: Trachybasalt,
Kçt: average chemical composition of limestone [18], Do: average chemical composition of dolomite [18]
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World Multidisciplinary Earth Sciences Symposium (WMESS 2016) IOP Publishing
IOP Conf. Series: Earth and Environmental Science 44 (2016) 022002 doi:10.1088/1755-1315/44/2/022002
Flexural strength of trachybasalt rocks is the highest compared to the other tested rocks (Table 4).
Generally, compressive strength and flexural strength are directly proportional (Figure 2). Density of
trachybasalt aggregate is higher than the other tested rocks. In addition, trachybasalt, dolomite,
recrystallized limestone and limestone rocks are characterized by high strength. However, tephra-
phonolite rock (40.83 MPa) is characterized by the least strength in uniaxial compressive strength
classification [19].
Figure 2. The relationship between compressive strength and flexural strength in rocks
According to the compressive strength and dry unit weight relationship [20], trachybasalt,
dolomite, sand and gravel, recrystallized limestone and limestone rocks are semi-heavy building
materials, while tephra-phonolites rock is a normal building material. Dolomite and trachybasalt have
higher loose bulk density than the other tested rocks because of their high density. The tephra-
phonolites aggregate has the highest value of water absorption (3.943%), while trachybasalt aggregate
has the lowest (0.141%) (see Table 4). Water absorption should be less than 2% for aggregate because
water absorption, shrinkage and strength have an effect on durability [21]. This may be related to
differences in the crushing and screening process. NaOH solution colour changes were observed for
determination of organic matter. The colour of the NaOH solution, which contains limestone
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World Multidisciplinary Earth Sciences Symposium (WMESS 2016) IOP Publishing
IOP Conf. Series: Earth and Environmental Science 44 (2016) 022002 doi:10.1088/1755-1315/44/2/022002
aggregates, has become a very slight yellow colour. Yellow is the color change, so it contains a very
small amount of organic material but it is not a problem for using in concrete [15].
Instead for Dolomite, Recrystallized limestone, Sand and gravel, Dolomite, trachybasalt, tephra-
phonolites aggregates weren’t observed colour change in NaOH solution. Based on [8], bars average
length changes were observed after 5, 9, 12 and 15 days. Bars that expand more than 0.20% after 15
days are potentially ASR-reactive. Bars that expand between 0.10% and 0.20% include aggregates that
are known to be potentially harmful in field performance in [8]. The change of length is 0.016% for
tephra-phonolite bars, 0.058% for trachybasalt bars and 0.131% for sand-gravel bars. As a result,
sand- gravel aggregates are potentially ASR-reactive. Mobile sulphate, derived from aggregates,
which can cause harmful effects in the concrete due to increasing sulphate content in concrete. The
acid-soluble sulphate content of the aggregates is lower than 0.2% [9]. Flatness is undesirable more
than 40% in crushed stone. It should be less than 50% for sand gravel [11]. High flatness causes the
low strength and a reduction in workability. After 500 cycles, maximum Los Angeles abrasion must
be less than 30% [22]. According to the criteria in [22], aggregates are highly resistant to
fragmentation in this study. The maximum limit is 18% for the Micro-Deval value which is given by
NCHRP (The National Cooperative Highway Research Program) [23]. Compressive strength and Los
Angeles coefficient are inversely proportional. At the same time Los Angeles coefficient and Micro-
Deval coefficient are directly proportional.
Figure 3. The relationship between a) Los Angeles coefficient and Micro- Deval coefficient, b)
Compressive strength and Los Angeles coefficient
Figure 3 shows a linear relationship between compressive strength and Los Angeles coefficient,
Micro-Deval coefficient and Los Angeles coefficient. In addition, trachybasalt and dolomite are
located in LA15, sand, gravel and limestone is located in LA20, the recrystallized limestone and
tephra-phonolites are located in the LA25 category. The thawing and freezing resistance of
trachybasalt and dolomite aggregates are higher than the others. Besides this, water absorption ratios
are low. Mass loss after freeze thawing of aggregates is <1. Aggregates are extremely durable against
freeze thawing and are located in the F1 category in [24]. Trachybasalt and dolomite are more suitable
for road, airport, runway concrete in areas where wear resistance is important.
Acknowledgement
This work was supported by the Research Fund of Süleyman Demirel University. Project
number: 1806-D-09.
References
[1] P. K. Mehta, P. J. M. Monteiro, “Concrete Microstructure, Properties, and Materials,” Third
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World Multidisciplinary Earth Sciences Symposium (WMESS 2016) IOP Publishing
IOP Conf. Series: Earth and Environmental Science 44 (2016) 022002 doi:10.1088/1755-1315/44/2/022002