UJI LINIARITAS KURVA KALIBRASI

x-Value f(x)-Value
Kurva Kalibrasi
Linear Calibration y = a*x + b
Std. Nr. ng/mL counts b= 34.736
300.000
a= 38.872
1 0.000 10.340 Residual standard deviation 24.389
2 1.000 98.800 250.000
3 3.000 159.000

4 5.000 205.000 Quadratic Calibration y = c*x2 + b*x + a

200.000
5 7.000 277.000 c= -3.423
6 b= 61.257

y
7 150.000 a= 5.758
8 Residual standard deviatio #NAME?
9 100.000
10
Linearity test-Mandel (99%)
50.000
Test Value 9.732
Critical Value 12.246
0.000 Optimal Model? Linier
0.000 1.000 2.000 3.000 4.000
x
5.000 6.000 7.000 8.000

Residual plot
Residual ei

12.0000
10.0000
8.0000
6.0000
4.0000
2.0000
0.0000
0.5 1 1.5 2 2.5 Standard
3 no.3.5 4 4.5 5 5.5
 Calibration and process data for the determination of Test data

method

Calibration data measured at

x y_1
mg/L Area / 1000 Process data of a calibration function ... of 1. ord ... 2. order
value 1 0.000 10.340 Testing linearity: regression 2. Ordnung is not significantly better
value 2 1.000 98.800 correlation coefficient 0.978 c= -3.423
value 3 3.000 159.000 slope 3.191 b= 34.736 b= 61.257
value 4 5.000 205.000 intercept 9.250 a= 38.872 a= 5.758
value 5 7.000 277.000 residual standard deviation s(y) = 24.389 s(y) = 16.864
value 6 0.000 0.000 process standard deviation s(x0) = 0.702 s(x0) = 0.335
value 7 0.000 0.000 process variation coefficient V(x0) = 0.439 E= 50.302
value 8 0.000 0.000 58.400

value 9 0.000 0.000 auxiliary value for the determination of x_P y_P = 87.376 t(95%, single-sided) 1.86

value 10 0.000 0.000 testing value to secure the lower range limit x_P = 2.741 t(95%, single-sided) 1.86
number mean MDL = LC XN = 2.175 t(99%, single-sided) 2.90
10 1.600 75.014 detection limit (DIN 32645) XE = 4.350 t(99%, double-sided) 3.36
quantitation limit (DIN 32645) XB = 8.700
k= 3
Calibration function 1.O: y 38.872 + 34.736 x

Confidence
Data Factor of Results interval for Standard uncertainty
Sample results
no. Area / 1000 dilution mg/L ± mg/L rel. in % e.g. double probe
lowest 10.34 -0.821379 1 -0.821 ± 1.430 1.4305 ### M= 2
mean 75.01 1.0404749 1 1.040 ± 1.373 1.3727 131.9% Standard relative expanded

highest 0.00 -1.11905 1 -1.119 ± 1.446 1.446 ### uncertainty S.U. S.U.
1 5.00 -0.975109 1 -0.975 ± 1.438 1.4383 ### 0.5931 -60.8% 1.186
2 1 ±
3 1 ±
4 1 ±
5 1 ±
6 1 ±
7 1 ±
8 1 ±
9 1 ±
10 1 ±

300.000

Calibration
250.000
Area / 1000

200.000

150.000

-----
----- regression
regression curve
curve
100.000 -----
----- confidence
confidence interval
interval

50.000

0.000 2 2
0 1 2 3 4 mg/L5 6 7 8 9 10

463243689.xls Data