akubiharcom Code : 231201 B.Tech 2nd Semester Exam., 2015 ENGINEERING CHEMISTRY Time : 3 hours Pull Marks : 70 Instructors W The marks are indicated i the right-hand margin (H) There are NINE questions in dus paper (i) Attempr FIVE questions in al (ty) Question ois compulsory A. Fill in the blanks/answer any seven questions 2714 (a) SO ml of water sample require 1'5 ml {AM /50 HC! solution using methyi orange Indicator. The temporary hardnces of water is — ppm (©) Natural rubber is polymer of — (9 Terviene is condensation polymer of and (d)- Arrange hydrogen ens, LPO, water gas land biogas in increasing order of their calorie value. (fo) Aluminium vessels are used to store cone. HNO. Explain. ‘Aki5—2770/899 ‘akubihar.comto fy fi a 2 fo) fo) a ARIS 270/529 (2) akubihar.com Woy is boiling point of water increases when KC! adiled? hede end amall uneds area Large results in intense corrosion, Explain Arrange in increasing order of freezing Point of O-1 M solution of acetic acid, Rlucese, sodium chloride What is power alcohol? Woy are brass utensils tinned? scribe the principle of ime-aoda process of softening of water Give chemical reaction Invelved during softening of water. What are advantages and disadvantages A water sample containing the following in eg fitre + CaQICO4!3 MgHCO yl =14-6 Ccoleutate the amoant of line and soda requited for softening 1G ro? water, 7 {Continued} akubihar.com fa o fat oy 0 (3) What i fue gas? How is analysis of fe gas done by Orsat’s apparatus? What is the elgnifieance of the fue gas analysis, A coat sample contains following percentage composition by weight © +60, H-6, 028, Neo Find the minimum amount of omgen and air by weight for complete combustion of 1 ke of cook Also calculate the weight of air i 15% excess alr is cupped (air containe 23% Og by weight Derive Nemst equation and discuss its application Calculate the em£. of a concentration cell at 25°C consisting two Ag electrode immersed in a soluion of Ag’ of 0-01 Sf and 0-001 A concentratien. For a cet reaction 24a"? 20° 3B at 298 K the equilibrium constant is 2-0%10%, Calculate £° cell AK1S~2770/529 ae 2(4) akubihar.com (5) 8. la) Define degree of polymerization ib) Exp polrmezats 3 8. (@ Explain caustic embrittlement in boiler M} Explain the tree radical polymerization and ow it eat be prevented s mechanism 3 What are the catises of boiler corrosion? © What is glass wansition temperature? — 4 O Niger can we ler eorvouon Be (d} Werte the preparation and uses of prevented? 5 1 neoprene and fi) nylon 6,6. 4 (0) What are the causes of— 1) scale formation; ©. (@ Discuss — the mechanism of fn) priming and foaming? + slectrochemical corresion, 3 A) What are the factors that eect the rate 9. Write short notes on ss of corrosion? 4 fa) Waterline corrotion (2 How is corrosion prevented by cathodic revices core ton protection? 3 e fo) Gctare mumber fd) What is percentage of iron rusted Fe,05-24,0) when its weight (fd) Colligasve properties sncreased by 25%? ‘ 7. fa Deduce the relationship berween the we boiling point elevation of @ solution and mole fraction of dissolved solute . Expkun the terms hypertonic, isotonic BBR hypotone solutions 4 seubih (& Av 100°C the vapour presture of akubihar.com solution of 45 g of salute in 108 g water fe 722 men, Find the boiling point ofthe solution (Ky of HjO=0:52 and water Vapour pressure at 100°C 1s 760mm). 4 (Conanued) Akis-2770/829 AK15—2770/529