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Keywords: Oil palm empty fruit bunch (OPEFB); Palm oil mill effluent (POME) anaerobic sludge;
Composting; In-vessel composter; Lignocellulosic degradation
Contact information: a: Department of Process and Food Engineering, Faculty of Engineering, Universiti
Putra Malaysia, 43400 UPM Serdang, Selangor, Malaysia, MALAYSIA; b: Department of Bioprocess
Technology, Faculty of Biotechnology and Biomolecular Sciences, Universiti Putra Malaysia, 43400 UPM
Serdang, Selangor, Malaysia, MALAYSIA; c: Faculty of Plantation and Agrotechnology, Universiti
Teknologi MARA, 40450 Shah Alam, Selangor, Malaysia; d: Department of Biological Functions and
Engineering, Graduate School of Life Science and System Engineering, Kyushu Institute of Technology, 2-4
Hibikino, Wakamatsu-ku, Kitakyushu, Fukuoka 808-0916, JAPAN;
* Corresponding author: azharis@eng.upm.edu.my
INTRODUCTION
At present there are 4.69 million hectares of land planted with oil palm in
Malaysia, yielding millions of tonnes of oil palm fresh fruit bunches each year (MPOB
2009). The oil fraction in the oil palm fruits is usually in the range 18 to 22%, and the
remaining being moisture and oil palm biomass such as oil palm mesocarpfibre (MF),
palm kernel shell (PKS), and empty fruit bunches (OPEFB) are available for further
exploitation. According to Tan et al. (2010), Malaysia is currently the second largest
palm oil producer, with 406 currently active palm oil mills and a total annual processing
EXPERIMENTAL
Raw Materials
The pressed-shredded OPEFB was obtained from Seri Ulu Langat Palm Oil Mill,
(Dengkil, Selangor, Malaysia) in the size range 15 to 20 cm. Two tonnes of the
mentioned OPEFB were used in this study.
were made using a Rigaku XRD-DSC-X II diffraction system. Cu-Kα radiation (0.15418
nm) was used as radiation source, and 2θ angles were recorded using a scintillation
counter, in the 2θ interval between 10 and 40°C. The crystallinity of SiO2 pattern was
estimated using the Scherrer equation (L = K/ cos), where λ is wavelength of X-ray,
is the full width at half maximum, and is the Bragg angle). The value of was
estimated by fitting the XRD pattern obtained from analysed result.
Parameters Value
OPEFB POME Anaerobic Final Compost
Sludge
Moisture (%) 44.9 95.0 49.3
pH 5.9 7.4 7.5
C (%) 44.1 31.5 38.5
N (%) 0.6 4.7 2.8
C/N 77.7 6.7 13.8
Total solid (mg/kg) - 51750.0 -
Suspended solid (mg/kg) - 46830.0 -
Volatile solid (mg/kg) - 30820.0 -
COD (mg/L) - 60500.0 -
BOD (mg/L) 18100.0 -
Cellulose (%) 37.3 1.7 26.2
Hemicellulose (%) 27.8 5.6 15.4
Lignin (%) 16.5 53.1 33.3
Ash (%) 5.8 37.3 17.8
Compositions of Nutrients and Metal Elements
Fig. 2. Profiles for temperature and total bacterial population during the composting process
Fig. 3. Profiles for moisture, pH, and oxygen level during the composting process
Fig. 4. Profiles for nitrogen, carbon, and C/N ratio throughout composting process
Figure 4 clearly shows that the C/N ratio of OPEFB reduced significantly from 58
(at day 0) to 44 (at day 7). As mentioned earlier, this happened because of the high
temperature during the thermophilic phase in the in-vessel composter. Once the OPEFB
material was transferred to the windrow, a smaller reduction of C/N was observed as a
result of the lower operating temperature. The final C/N ratio at day 40 was calculated to
be 13.85. This is satisfactory because matured compost material usually has a C/N ratio
of 15 or less (Baharuddin et al. 2009; Hock et al. 2009).
Fig. 5. SEM micrograph (500x magnification) for the raw press shredded OPEFB (a), OPEFB
material at day 7 (b), OPEFB material at day 20 (c), and OPEFB material at day 40 (d)
(a)
(b)
Fig. 6. XRD analysis of composting process (a) and a comparison of crystal size by using
Scherrer equation (b)
(b)
Fig. 8. TG data comparison of composed OPEFB with raw OPEFB (a) and DTA data comparison
of composed OPEFB with raw OPEFB (b)
CONCLUSIONS
ACKNOWLEDGEMENTS
The authors would like to thank Universiti Putra Malaysia, FELDA Palm
Industries Sdn. Bhd., Kyushu Institute of Technology, Japan, Malaysian Technical
Development Corporation (MTDC) and UPM RUGS (9199802) for their financial and
technical support for this research.
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Article submitted: Feburary 8, 2012; Peer review completed: June 31, 2012; Revised
version received and accepted: August 3, 2012; Published: August 14, 2012.