Ln(Ct)

β-Carotene α-Carotene
t(min) 70 80 90 70 80 90
0 1.0 1.0 1.2 0.6 0.7 0.8
15 0.8 0.7 0.5 0.4 0.4 0.2
30 0.6 0.4 -0.1 0.3 0.0 -0.5
45 0.5 0.1 -0.7 0.1 -0.4 -1.2
60 0.3 -0.2 -1.4 -0.1 -0.8 -1.9

β-Carotene.
1.5

1.0 f(x) = − 0.0421 x + 1.1537

f(x)
R² ===1−− 0.012766
f(x) 0.02 x + 1 x + 1.03396
R²
R² == 0.996204622866811
1
0.5

Ln (Ct).
0.0
0 10 20 30 40 50

-0.5

-1.0

-1.5
Tíempo (T).

Cryptoxan
1.0
f(x)
f(x) == −− 0.0277
0.0244 xx ++ 0.8772
0.8353
R²
R² == 1
1
0.5

0.0
0 f(x) =10
− 0.0195
20x + 0.0817
Ln(Ct).

30 40 50
R² = 1
-0.5

-1.0

-1.5
Tiempo (T).

Lycope
1.0

0.5
f(x) == −− 0.0305
f(x) 0.0357
0.0439 xx ++ 0.3392
0.4045
0.3333
0.0 R² = 1
0 R² = 110 20 30 40 50
-0.5
Ln(Ct).

-1.0

-1.5
 1.0

0.5
f(x) == −− 0.0305
f(x) 0.0357
0.0439 xx ++ 0.3392
0.4045
0.3333
0.0 R²
R² == 1
1
0 10 20 30 40 50
-0.5

Ln(Ct).
-1.0

-1.5

-2.0

-2.5
Tiempo (T).

Provitami
7.0

6.0
f(x)
f(x) == −− 0.0381
0.0216 xx ++ 6.1202
0.0142 6.0163
6.0107
5.0 R²
R² == 1
1

4.0

Ln(Ct).
3.0

2.0

1.0

0.0
0 10 20 30 40 50
Tiempo (T).
 Cryptoxanthin Zeaxanthin Lycopene
70 80 90 70 80 90 70 80
0.1 0.8 0.9 1.3 1.3 1.4 0.3 0.4
-0.2 0.5 0.5 1.1 0.9 0.8 -0.1 -0.1
-0.5 0.1 0.0 0.8 0.6 0.3 -0.6 -0.7
-0.8 -0.3 -0.4 0.6 0.2 -0.3 -1.0 -1.2
-1.1 -0.6 -0.8 0.4 -0.2 -0.8 -1.5 -1.7

β-Carotene.
'α-Caroten
1.5

x + 1.1537 1.0
61 x + 1.03396
22866811 f(x)
0.5 f(x) == −− 0.0453
0.0253 xx ++ 0.8435
0.7326
R²
f(x)
R² ===1
1 − 0.0118 x + 0.6199
70 ºC R² = 1
Linear 0.0
(70 ºC) 0 10 20 30 40 50

Ln(Ct.)
0 30 40 50 60 70 Linear -0.5
(70 ºC)
Linear
(70 ºC) -1.0

-1.5

-2.0

-2.5
Tíempo (T).
Tiempo (T).

Cryptoxanthin. Zeaxanthi
2.0
0277
0244 xx ++ 0.8772
0.8353
1.5
f(x)
f(x) == −− 0.0367
0.0158 x + 1.3838
70 ºC
R² = 1 0.0244 x + 1.3169
1.2848
1.0 R² = 1
Linear (70 ºC)
0195
20x + 0.0817
Ln(Ct).

30 40 50 60 70 80 ºC
Linear (80 ºC) 0.5
90 ºC
Linear (90 ºC) 0.0
0 10 20 30 40 50
-0.5

-1.0
Tiempo (T). Tiempo (T).

Lycopene Vitamin C
4.0
3.5 f(x)
f(x) == −− 0.0224
0.0496x xx+++3.6709
0.037 3.7041
3.641
R²
R² == 1
1
0357
0439 xx ++ 0.3392
0305 0.4045
0.3333 3.0
70 ºC
20 30 40 50 60 70 Linear (70 ºC) 2.5
80 ºC
Ln(Ct)

2.0
Linear (80 ºC)
90 ºC 1.5
Linear (90 ºC) 1.0
 4.0
3.5 f(x)
f(x) == −− 0.0224
0.0496x xx+++3.6709
0.037 3.7041
3.641
R²
R² == 1
1
0357
0439 xx ++ 0.3392
0305 0.4045
0.3333 3.0
70 ºC
20 30 40 50 60 70 Linear (70 ºC) 2.5
80 ºC

Ln(Ct)
2.0
Linear (80 ºC)
90 ºC 1.5
Linear (90 ºC) 1.0
0.5
0.0
0 10 20 30 40 50
Tiempo (T). Tiempo (T).

Provitamina A.

381
216 xx ++ 6.1202
142 6.0163
6.0107
70 ºC
Linear (70 ºC)
80 ºC
Linear (80 ºC)
90 ºC
Linear (90 ºC)

20 30 40 50 60 70
Tiempo (T).
Lycopene Vitamin C Provitamin Α
90 70 80 90 70 80 90
0.3 3.7 3.7 3.6 6.0 6.0 6.1
-0.3 3.4 3.1 2.9 5.8 5.7 5.5
-1.0 3.0 2.6 2.2 5.6 5.4 5.0
-1.6 2.7 2.0 1.4 5.4 5.0 4.4
-2.3 2.4 1.5 0.7 5.2 4.7 3.8

'α-Carotene

xx ++ 0.8435
0.7326
x + 0.6199
70 ºC
Linear (70 ºC)
0 30 40 50 60 70
80 ºC
Linear (80 ºC)
90 ºC
Linear (90 ºC)

Tiempo (T).

Zeaxanthin

7
8 x + 1.3838
4 x + 1.3169
1.2848 70 ºC
Linear (70 ºC)
80 ºC
Linear (80 ºC)
90 ºC
20 30 40 50 60 70 Linear (90 ºC)

Tiempo (T).

Vitamin C

4
6x xx+++3.6709
3.7041
3.641

70 ºC
Linear (70 ºC)
80 ºC
Linear (80 ºC)
90 ºC
Linear (90 ºC)
4
6x xx+++3.6709
3.7041
3.641

70 ºC
Linear (70 ºC)
80 ºC
Linear (80 ºC)
90 ºC
Linear (90 ºC)

20 30 40 50 60 70
Tiempo (T).
 Kinetic parameters obtained for bioactive com

Bioactive compounds T(°C) k (min¯¹) D (min) t₍₀․₅₎ (min)

β-Carotene 70 0.012766 180.3685644 54.29634816
80 0.02 115.1292546 34.65735903
90 0.0421 54.69323261 16.46430358
α-Carotene 70 0.0118 195.1343299 58.74128649
80 0.0253 91.0112685 27.39712176
90 0.0453 50.829693 15.30126226
Cryptoxanthin 70 0.0195 118.0812868 35.54600926
80 0.0244 94.36824152 28.40767133
90 0.0277 83.12581563 25.02336392
Zeaxanthin 70 0.0158 145.7332337 43.87007472
80 0.0244 94.36824152 28.40767133
90 0.0367 62.74073823 18.88684416
Lycopene 70 0.0305 75.49459321 22.72613707
80 0.0357 64.49818188 19.41588741
90 0.0439 52.45068549 15.78922963
Vilamin C 70 0.0224 102.7939774 30.94407056
80 0.037 62.23202954 18.73370758
90 0.0496 46.42308655 13.97474154
Provitamin Α 70 0.0142 162.1538798 48.81318173
80 0.0216 106.6011617 32.09014725
90 0.0381 60.43530428 18.19283938
eters obtained for bioactive compounds degradation in tree tomato juice between 70 and 90 °C

Q₁₀ (70-90 °C) Zz (°C) Bioactive compounds T(°C)

1.815990732518 38.59310713 β-Carotene 70
80
90
1.959332297199 34.23390207 α-Carotene 70
80
90
1.191852684065 131.1947214 Cryptoxanthin 70
80
90
1.52406850572 54.64346844 Zeaxanthin 70
80
90
1.199726744844 126.4504811 Lycopene 70
80
90
1.488047618286 57.93177904 Vilamin C 70
80
90
1.638016664002 46.65956789 Provitamin Α 70
80
90
n 70 and 90 °C

k (min¯¹) D (min) t₍₀․₅₎ (min) Q₁₀ (70-90 °C) Zz (°C)

0.0133 173.13 52.12 1.78 39, 97
0.0198 116.29 35.01
0.0421 54.69 16.46
0.0118 195.13 58.74 1.96 34.23
0.0253 -91.01 27.4
0.0453 -50.83 15.3
0.0195 118.08 35.55 1.19 131.19
0.0244 94.37 28.41
0.0277 83.13 25.02
0.0158 145.73 43.87 1.52 54.64
0.0244 94.37 28.41
0.0367 62.74 18.89
0.0305 75.49 22.73 1.2 126.45
0.0357 64.5 19.42
0.0439 52.45 15.79
0.0224 102.79 30.94 1.49 57.93
0.037 62.23 18.73
0.0496 46.42 13.97
0.0142 162.15 48,813 1.64 46.66
0.022 104.66 31.51
0.0381 60.44 18.19
 Bioactive compounds
β-Carotene α-Carotene Cryptoxanthin Zeaxanthin
1/T (°K⁻) k (min¯¹) k (min¯¹) k (min¯¹) k (min¯¹)
0.002914177 0.012766 0.0118 0.0195 0.0158
0.002831658 0.02 0.0253 0.0244 0.0244
0.002753683 0.0421 0.0453 0.0277 0.0367

β-Carotene α-Carotene Cryptoxanthin Zeaxanthin

1/T (°K⁻) Ln(k) Ln(k) Ln(k) Ln(k)
0.002914177 -4.36096989215 -4.43965574751 -3.93734081341 -4.14774533895
0.002831658 -3.91202300543 -3.67695088325 -3.71317214668 -3.71317214668
0.002753683 -3.16770753829 -3.09444824649 -3.58632286579 -3.30497852392

0.0027 0.00275 0.0028 0.00285 0.0029 0.00295 0.0027 0.00275 0.0028

-2.8 -2.8

-3 -3
f(x) = − 4963.95831624162 x + 10.6973197376333
R² = 0.982112980079388 f(x) = − 8390.0018
-3.2 f(x) = − 2265.65342979311 x + 3.10282966883302 -3.2 R² = 0.996303023
R² = 0.991113804574843 f(x) = − 7415.5618
-3.4 f(x) = − 6139.22493120396 x + 13.6077797862117 Lycopene f(x)==0.975150465
R² − 5251.2139
R² = 0.989479961139854 -3.4
Ln(K).

Linear (Lycopene) R² = 0.999997032

-3.6 Vilamin C -3.6
f(x) = − 2192.2412
Linear (Vilamin C) R² = 0.979865620
-3.8
Provitamin A -3.8
-4 Linear (Provitamin A)
-4
-4.2
-4.2
-4.4
-4.4
1/T (K-1).
-4.6
e compounds
Lycopene Vilamin C Provitamin Α
k (min¯¹) k (min¯¹) k (min¯¹)
0.0305 0.0224 0.0142 Parámetros termodinámicos obtenidos para l
0.0357 0.037 0.0216
0.0439 0.0496 0.0381

Lycopene Vilamin C Provitamin Α

Ln(k) Ln(k) Ln(k)
-3.49002859537 -3.79869432012 -4.25451331437
-3.3326045902 -3.29683736634 -3.83506196429
-3.1258409589 -3.00376444525 -3.26754099685

0.0027 0.00275 0.0028 0.00285 0.0029 0.00295

-2.8

-3
f(x) = − 8390.00187453611 x + 20.0333069788555
-3.2 R² = 0.99630302321191 β-Carotene
f(x) = − 7415.56182138913 x + 17.1960013859525 Linear (β-Carotene)
-3.4 f(x)==0.975150465601725
R² − 5251.213954914 x + 11.1556313129173
R² = 0.999997032544213 Linear (β-Carotene)
α-Carotene
-3.6
f(x) = − 2192.2412469337 x + 2.46538637388773 Linear (α-Carotene)
R² = 0.979865620780392 Cryptoxanthin
-3.8
Linear (Cryptoxanthin)
-4 Zeaxanthin
Linear (Zeaxanthin)
-4.2

-4.4

-4.6
 kb 1.38E-23 J*K-1
h 6.63E-34 J*S-1
R 8.314 J Mol-1 K
Parámetros termodinámicos obtenidos para la degradación de compuestos bioactivos en jugo de tomate de árbol entre 70 y 90 oc
T(°C) Ea (kJ mol¯¹) ΔH (kJ mol) ΔG (kJ mol¯¹) ΔS (J mol¯¹ °K)
ß-Carotene 70 61.652980983 58.800031883 108.563326961 -145.019073519
80 58.716891883 111.811431163 -150.345573494
90 58.633751883 115.061889919 -155.385207313
a-Carotene 70 69.7544755849 66.9015264849 108.787813701 -122.064074651
80 66.8183864849 112.042459845 -128.059106215
90 66.7352464849 115.299460543 -133.730453141
ß-Cryptoxanthin 70 18.226293727 15.373344627 107.354734762 -268.050095105
80 15.290204627 110.567618442 -269.793044924
90 15.207064627 113.782856677 -271.446487814
Zeaxanthin 70 43.6585928212 40.8056437212 107.955008164 -195.685165213
80 40.7225037212 111.185384876 -199.526776596
90 40.6393637212 114.418116143 -203.163300073
Lycopene 70 18.8366426153 15.9836935153 106.078575772 -262.552476343
80 15.9005535153 109.254269914 -264.34579187
90 15.8174135153 112.432318611 -266.046826644
Vitamin C 70 41.2703494412 38.4174003412 83.5972701061 -131.66215872
80 38.3342603412 84.644322371 -131.13425465
90 38.2511203412 86.2406472434 -132.14794686
Provitamina A 70 51.041516078 48.188566978 84.8976984955 -106.976924137
80 48.105426978 86.2245977464 -107.940452409
90 48.022286978 87.0370490839 -107.434289153

Datos encontrados.
 Thermodynamic parameters obtained for bioactive compounds degradation in tree tomato ju
árbol entre 70 y 90 oc
Bioactive compounds T(°C) Ea (kJ mol¯¹) ΔH (kJ mol)
ß-Carotene 70 59.5 56.95
80 56.86
90 56.78
a-Carotene 70 69.75 67.2
80 67.12
90 67.03
ß-Cryptoxanthin 70 18.23 15.67
80 15.59
90 15.51
Zeaxanthin 70 43.66 41.1
80 41.02
90 40.94
Lycopene 70 18.84 16.28
80 16.2
90 16.12
Vitamin C 70 41.27 38.72
80 38.63
90 38.55
Provitamin Α 70 51.67 49.11
80 49.03
90 48.95

Datos obtenidos del articulo para su comparacion.

nds degradation in tree tomato juice between 70 and 90 oc

ΔG (kJ mol¯¹) ΔS (J mol¯¹ °K)

108.23 -149.46
110.3 -151.32
111.23 -149.94
108.57 -120.57
109.58 -120.25
-111.01 -121.1
107.14 ,-266,56
109.69 -266.46
112.5 -267.08
107.74 -194.19
109.69 -194.44
111.65 -194.71
105.87 -261.06
108.57 -261.57
111.11 -261.57
106.75 -198.25
108.47 -197.74
110.74 -198.78
108.05 -171.74
109.99 -172.63
111.53 -172.35

para su comparacion.