Se tienen 25 ml de NaOH que se valoran utilizando HCl 0.1M y se gastan 12.

5ml con indicador de fenolftalein

1.-Escribir el equilibrio que se establece

2.-Determinar la concentración inicial de NaOH
3.-Establecer la tabla de valoración de HCl
4.-Determinar el pH de la solución cuando se adicionan 1,2,4,6,8,10,12,12.49,14,16,18 y 20 ml de NaOH
5.-Graficar pH=f(Vad)
6.-Determinar el punto de equivalencia graficamente

1.- NaOH + HCl → H₂O + NaCl

2.- C₁= (12.5ml)(0.1M)/(25ml)= 0.05 M

V.NaOH Ml 25 [NaOH] 0.05 Kw

Vpeq 12.5 [HCL] 0.1

VOLUMEN INICIAL [OH] [H]

0 0.0500000000
0.1 0.0494023904
0.2 0.0488095238
0.3 0.0482213439
0.4 0.0476377953
0.5 0.0470588235
0.6 0.0464843750
0.7 0.0459143969
0.8 0.0453488372
0.9 0.0447876448
1 0.0442307692
1.1 0.0436781609
1.2 0.0431297710
1.3 0.0425855513
1.4 0.0420454545
1.5 0.0415094340
1.6 0.0409774436
1.7 0.0404494382
1.8 0.0399253731
1.9 0.0394052045
2 0.0388888889
 2.1 0.0383763838
2.2 0.0378676471
2.3 0.0373626374
2.4 0.0368613139
2.5 0.0363636364
2.6 0.0358695652
2.7 0.0353790614
2.8 0.0348920863
2.9 0.0344086022
3 0.0339285714
3.1 0.0334519573
3.2 0.0329787234
3.3 0.0325088339
3.4 0.0320422535
3.5 0.0315789474
3.6 0.0311188811
3.7 0.0306620209
3.8 0.0302083333
3.9 0.0297577855
4 0.0293103448
4.1 0.0288659794
4.2 0.0284246575
4.3 0.0279863481
4.4 0.0275510204
4.5 0.0271186441
4.6 0.0266891892
4.7 0.0262626263
4.8 0.0258389262
4.9 0.0254180602
5 0.0250000000
5.1 0.0245847176
5.2 0.0241721854
5.3 0.0237623762
5.4 0.0233552632
5.5 0.0229508197
5.6 0.0225490196
5.7 0.0221498371
5.8 0.0217532468
5.9 0.0213592233
6 0.0209677419
6.09999999999999 0.0205787781
6.19999999999999 0.0201923077
6.29999999999999 0.0198083067
6.39999999999999 0.0194267516
6.49999999999999 0.0190476190
6.59999999999999 0.0186708861
6.69999999999999 0.0182965300
6.79999999999999 0.0179245283
6.89999999999999 0.0175548589
6.99999999999999 0.0171875000
7.09999999999999 0.0168224299
7.19999999999999 0.0164596273
7.29999999999999 0.0160990712
7.39999999999999 0.0157407407
7.49999999999999 0.0153846154
7.59999999999999 0.0150306748
7.69999999999999 0.0146788991
7.79999999999999 0.0143292683
7.89999999999999 0.0139817629
7.99999999999999 0.0136363636
8.09999999999999 0.0132930514
8.19999999999999 0.0129518072
8.29999999999999 0.0126126126
8.39999999999999 0.0122754491
8.49999999999999 0.0119402985
8.59999999999999 0.0116071429
8.69999999999999 0.0112759644
8.79999999999999 0.0109467456
8.89999999999998 0.0106194690
8.99999999999998 0.0102941176
9.09999999999998 0.0099706745
9.19999999999998 0.0096491228
9.29999999999998 0.0093294461
9.39999999999998 0.0090116279
9.49999999999998 0.0086956522
9.59999999999998 0.0083815029
9.69999999999998 0.0080691643
9.79999999999998 0.0077586207
9.89999999999998 0.0074498567
9.99999999999998 0.0071428571
10.1 0.0068376068
10.2 0.0065340909
10.3 0.0062322946
10.4 0.0059322034
10.5 0.0056338028
10.6 0.0053370787
10.7 0.0050420168
10.8 0.0047486034
10.9 0.0044568245
11 0.0041666667
11.1 0.0038781163
11.2 0.0035911602
11.3 0.0033057851
11.4 0.0030219780
11.5 0.0027397260
11.6 0.0024590164
11.7 0.0021798365
11.8 0.0019021739
11.9 0.0016260163
12 0.0013513514
12.1 0.0010781671
12.2 0.0008064516
12.3 0.0005361930
12.4 0.0002673797
12.5 0.0000001
12.6 0.00026596
12.7 0.0005305
12.8 0.00079365
12.9 0.00105541
13 0.00131579
13.1 0.0015748
13.2 0.00183246
13.3 0.00208877
13.4 0.00234375
13.5 0.0025974
13.6 0.00284974
13.7 0.00310078
13.8 0.00335052
13.9 0.00359897
14 0.00384615
14.1 0.00409207
14.2 0.00433673
14.3 0.00458015
14.4 0.00482234
14.5 0.00506329
14.6 0.00530303
14.7 0.00554156
14.8 0.00577889
14.9 0.00601504
15 0.00625
15.1 0.00648379
15.2 0.00671642
15.3 0.00694789
15.4 0.00717822
15.5 0.00740741
15.6 0.00763547
15.7 0.00786241
15.8 0.00808824
15.9 0.00831296
16 0.00853659
16.1 0.00875912
16.2 0.00898058
16.3 0.00920097
16.4 0.00942029
16.5 0.00963855
16.6 0.00985577
16.7 0.01007194
16.8 0.01028708
16.9 0.01050119
17 0.01071429
17.1 0.01092637
17.2 0.01113744
17.3 0.01134752
17.4 0.0115566
17.5 0.01176471
17.6 0.01197183
17.7 0.01217799
17.8 0.01238318
17.9 0.01258741
18 0.0127907
18.1 0.01299304
18.2 0.01319444
18.3 0.01339492
18.4 0.01359447
18.5 0.0137931
18.6 0.01399083
18.7 0.01418764
18.8 0.01438356
18.9 0.01457859
19 0.01477273
19.1 0.01496599
19.2 0.01515837
19.3 0.01534989
19.4 0.01554054
19.5 0.01573034
19.6 0.01591928
19.7 0.01610738
19.8 0.01629464
19.9 0.01648107
20 0.01666667
 20.1 0.01685144
20.2 0.0170354
20.3 0.01721854
20.4 0.01740088
20.5000000000001 0.01758242
20.6 0.01776316
20.7000000000001 0.01794311
20.8000000000001 0.01812227
20.9000000000001 0.01830065
21.0000000000001 0.01847826
21.1000000000001 0.0186551
21.2000000000001 0.01883117
21.3000000000001 0.01900648
21.4000000000001 0.01918103
21.5000000000001 0.01935484
21.6000000000001 0.0195279
21.7000000000001 0.01970021
21.8000000000001 0.01987179
21.9000000000001 0.02004264
22.0000000000001 0.02021277
22.1000000000001 0.02038217
22.2000000000001 0.02055085
22.3000000000001 0.02071882
22.4000000000001 0.02088608
22.5000000000001 0.02105263
22.6000000000001 0.02121849
22.7000000000001 0.02138365
22.8000000000001 0.02154812
22.9000000000001 0.0217119
23.0000000000001 0.021875
23.1000000000001 0.02203742
23.2000000000001 0.02219917
23.3000000000001 0.02236025
23.4000000000001 0.02252066
23.5000000000001 0.02268041
23.6000000000001 0.02283951
23.7000000000001 0.02299795
23.8000000000001 0.02315574
23.9000000000001 0.02331288
24.0000000000001 0.02346939
24.1000000000001 0.02362525
24.2000000000001 0.02378049
24.3000000000001 0.02393509
24.4000000000001 0.02408907
24.5000000000001 0.02424242
24.6000000000001 0.02439516
24.7000000000001 0.02454728
24.8000000000001 0.0246988
24.9000000000001 0.0248497
25.0000000000001 0.025
 Tabulación del Ph
14.00000000
con indicador de fenolftaleina
12.00000000

10.00000000

8.00000000
18 y 20 ml de NaOH
6.00000000

4.00000000

2.00000000

0.00000000
0 50 100 150 200 250 300

Yamile Márquez García

1E-14

PH
12.69897000
12.69374796
12.68850457
12.68323931
12.67795165
12.67264107
12.66730700
12.66194888
12.65656616
12.65115823
12.64572449
12.64026434
12.63477715
12.62926227
12.62371905
12.61814681
12.61254486
12.60691249
12.60124898
12.59555359
12.58982553
12.58406405
12.57826832
12.57243752
12.56657081
12.56066731
12.55472611
12.54874631
12.54272694
12.53666703
12.53056557
12.52442153
12.51823384
12.51200139
12.50572305
12.49939765
12.49302397
12.48660078
12.48012676
12.47360061
12.46702093
12.46038630
12.45369524
12.44694623
12.44013769
12.43326797
12.42633538
12.41933815
12.41227446
12.40514240
12.39794001
12.39066522
12.38331592
12.37588987
12.36838477
12.36079820
12.35312766
12.34537054
12.33752409
12.32958546
12.32155166
12.31341958
12.30518596
12.29684735
12.28840019
12.27984070
12.27116493
12.26236873
12.25344774
12.24439734
12.23521271
12.22588873
12.21642000
12.20680082
12.19702517
12.18708664
12.17697848
12.16669348
12.15622401
12.14556193
12.13469857
12.12362468
12.11233037
12.10080506
12.08903739
12.07701518
12.06472533
12.05215370
12.03928502
12.02610280
12.01258913
11.99872454
11.98448783
11.96985586
11.95480325
11.93930216
11.92332190
11.90682856
11.88978452
11.87214792
11.85387196
11.83490413
11.81518517
11.79464798
11.77321603
11.75080164
11.72730360
11.70260429
11.67656589
11.64902553
11.61978876
 11.58862083
11.55523478
11.51927462
11.48029130
11.43770714
11.39076142
11.33842392
11.27925022
11.21112488
11.13076828
11.03268608
10.90657831
10.72932116
10.42712840
7.00000000
3.57518784492766
3.27531135454181
3.10037054511756
2.97657921864011
2.88081359228079
2.80277372529198
2.73696532289745
2.68010878697668
2.63008871492821
2.5854607295085
2.54519461951353
2.50852971897129
2.47488837328737
2.44382156564747
2.41497334797082
2.38805677473994
2.36283714564218
2.33912004527212
2.31674262087275
2.29556709996248
2.27547589119159
2.25636782594091
2.2381552360561
2.22076165397514
2.20411998265593
2.18817102464937
2.17286228892548
2.15814701479889
2.14398336721165
2.13033376849501
2.11716433974292
2.10444443090531
2.09214622321199
2.08024439096509
2.06871581236946
2.05753932110878
2.04669549196614
2.03616645503959
2.0259357340944
2.01598810538413
2.00630947390701
1.99688676457586
1.98770782619545
1.97876134648011
1.97003677662256
1.96152426415409
1.95321459302596
1.94509912999945
1.93716977656422
1.92941892571429
1.92183942300478
1.91442453139022
1.90716789941238
1.90006353236175
1.89310576608534
1.88628924315453
1.87960889114242
1.87305990279043
1.86663771787036
1.86033800657099
1.85415665425782
1.84808974747217
1.84213356105052
1.83628454625823
1.83053931984333
1.82489465392597
1.81934746664826
1.81389481351683
1.80853387937736
1.80326197096667
1.79807650999306
1.79297502670067
1.78795515387769
1.78301462127235
1.77815125038364
1.77336294959717
1.7686477096389
1.76400359932235
1.75942876156666
1.75492140966517
1.75047982378578
1.74610234768613
1.74178738562779
1.73753339947538
1.73333890596728
1.72920247414608
1.7251227229375
1.72109831886778
1.71712797390997
1.71321044345063
1.7093445243689
1.70552905322055
1.70176290452019
1.69804498911538
1.69437425264687
1.69074967408932
1.68717026436784
1.68363506504531
1.68014314707653
1.67669360962486
1.67328557893785
1.66991820727819
1.66659067190694
1.66330217411578
1.66005193830565
1.65683921110906
1.65366326055364
1.65052337526456
1.64741886370379
1.64434905344404
1.64131329047563
1.63831093854445
1.63534137851929
1.63240400778714
1.6294982396749
1.62662350289605
1.6237792410212
1.6209649119711
1.61817998753111
1.61542395288594
1.61269630617374
1.60999655805858
1.60732423132032
1.60467886046115
1.60205999132796