Chemical Reaction Engineering Claes Diseuecion 2 Solution @) Ask Batch reactor Elementary ceacdion : order of the reaction is the same 5 thy ctoithiomedric. coefbicient of the portioulae Fpedes D Design eguation for Both reactor ta Ee fo ax °° +e where =a 2 KO_ — (Elemedary yeachon) 2 Given dota: x, = OF a> tye Lhe Xy 2095 3 2? © find k : t= Ge [* dx nS Whe -%y = keg ad Cy = Go (1- x) | Thus [ra = Kew (I~) |> t= To [* dX ° ktme (1 -X) t- 1 C dk kK ° 1-X t2 1 [i 1\ ee — nde ec a[l- Ke ‘ hae Vs, . ox las 2? Lolve for k: ¢l-- ja-xf)” where k= 05 is Te [- In [1-0 5] | he 0.09% f,-* D> Solve for t,; ta- gd J-in It-4]] where Ky 6 0.95 b= Te le [1-098] tee 2 heQ1) 2A B Liguidl - Phace Reaction Elementary reaction » -H ~ kKeqe ke 10 an te) 4 - 0.4 Fao + 5 mal a) cs7e Pesiom Equation: V_ Fay - Fa -_ ie hw Fah the. ty JROK Fhe TEN. tk ay Whee Cp = Gho(1-x) and tao = ChoVo Thus: V+ GaoVe X___ whee TV K Gao’ (1-X)* Voae. Ye ken [1-8)* C= 04d (9 5,) (92 1) (1-29)* 4-46: b) PFR Design eguation » Ve Fao ,. dX “A Vie Goo (“ dk kl* Jo (I -X)* x |. 1-x J, ae YS — aL K ro©) Batch reactor + x Deei. uation > t= Naw dx eign ep! (A J, =a where Nao = Choo ard — V2 Vo. (tanttunf volume ) x 2 = Gov J, ae “a t-2 Gro {- Ak kG Jo (-K)* tet kan ee (sar) (** 2) £2474G3) Constant volume batch rector ye? bat > Gren data 2 -G +key” and GV = dNa dé For conthant N > -1y » -ACR dt AG. ke > Plot a graph using above table and obtain equadion OF the Curve.Fi a Cavs & eae y= 0.001% -0.1252% + 4.0164 sis|z|s]slo|~ Biel > From qrph: 0.004 ¢* - 0.19526 + 4.0164 4 p.o0g - O.1252 ak -dc4 _ _ 0.0006 + 0-252 at > Finearize equation to obtain : N > Slope. Ink > intercept des - key” ie oe nincg + Ink ~ “ae> Teepove a plot of In (-24) vs. In Gy where dhe slape > indercept > In ke [Wa [aaa Per caer oof 4] ease | 2386 | 207m wo[ a0 [esos | tne | a8 ao [ass | aoase | os | aa 30 [ ae [Bows [ais | 278 goof eas | omer | ont | sone? so [ose [ome [a3 [sent Inf dca/at) vs In(Ca) as Y308939x- 2.7716 Inca > Fem above graph ‘[iy 2 04153 Ink « -2.796@4) cote. AR “ae keel® Design equation: Ve Fy, i = 7 CFTR, X_ - OF Cay = 10 mol Zc ® COTR: ig duce the volume of COTR, Vi 2 OV, oo Cay = 10 mol z >? Va = Fa, x. an k&q'* were GH = Ge (}-x) . ae = 2 [Fn A eae” (1-xy!° aria> 2(0-4) Ke (1 - 0.7)" - (-)'* oe 2 Me (-42)"" Xe 2 OF44 > 99.4% conversion 95) Consent Voleme batch rector Gp, = 2 a Abb 2 Pmin » X, 208 Meta s Ban > % 2 0-4 Find -ra=? Need ty find ke and nv “He heey” O Method 7; fasier methoel Baten reactor design eguedion > a av hue AMA = d(av) for constand volume => VGA NK alt AQ a SC er aee toda - -k { de Ca" ° Gro a tom fa 2 -KE I JV eay ren 8 a Ge... =kE Ina Ion Pp Line Cao = 4 mal 1X, 208, X,20-4 Cay = Go (1- £1) Che» Gu (1-.) (OR) 08) cee bah) (1009 Car = 0.8 wal Cae = 0-1 mol - Coe 0.2 mel (ay'" - (0.2)! = U-n)k (8) 1- (02)'* 1. n) k(@) Dp At te = 18 nin > a, = Beli end (2)"" < gon * (1a) et) 2-1)". Gen) KOI) => Divide both eguations: 1-0-2)" Then) (2) a - (oa)'"™ (Ta) (18) 1 - (02)'"* eg 7 = (oiy" 1g nz 2 > Find ky 4 - (o)'* 2 (7-2) k (1) Fe HIRES Koz ot Ly me2 Method 2+ Complicated Method Note. This methool is te show that several cotutiont Can be applied giving the same answers; however, Lome solutions gre easier than others. Batch reactor design quation » Ny, AX =: ® Constard volume: ¥ =Vo “A = Cay dk dt p> Wa = Re,* _ and - 4+ ly de dt Go “ = ke,” Where Cy = Gro(1-x) Che AX ° ae Koa’ (1-&)" x ' d oe ue net ‘ xy K Cae j aea keg tb = (« x) 1} = (ex) Kas & (1-n > AE t= Bmx > X08 and Gay ed nl “Keb, (42m) = (1) -ke (a-n) (8). (1-0-8) 4 D> AL ty 2 Rain > %+0-4 - ke, (Is) = (7-4) 2 4 -K (tn) (12) (1-09) 7 > Divide both equations: (Dar) (8) _(- 0-8)!" Lg ~K (1%) 08) 0 ae and Gay = 1 ml T3 oe) 1 (Bony 4 ved > find ke: kee) 1 4: (I-A)