1. What amount of energy (kJ) is released in the combustion of 5.8 g of C 4H10(g)?

2C4H10(g) + 13O2(g) ⃗ 8CO2(g) + 10H2O(l); ΔH ∘ = – 5756 kJ

(A) 575.6 (B) 287.8 (C) 182 (D) 57.56

2. Based on the values of B.E. given,

Δf H ∘
of N2H4(g) is:
Given: N–N = 159 kJ mol–1; H–H = 436 kJ mol–1

N ¿ N = 941 kJ mol–1; N–H = 398 kJ mol–1

(A) 711 kJ mol–1 (B) 62 kJ mol–1 (C) – 98 kJ mol–1 (D) – 711 kJ mol–1

1. Calculate
Δf H ∘ in (kJ/mol) for Cr2O3 from the
Δr G∘ and the S ∘ values provided at 27°C
∘
4Cr (s)+3O2 ( g) ⃗ 2Cr 2 O3 (s); Δ r G =−2093 .4 kJ/mol
S ∘( J/ K mol ) : S ∘(Cr , s) =24 ; S∘(O2 , g)=205; S ∘(Cr 2 O3 , s) =81

(A) – 2258.1 kJ/mol (B) – 1129.05 kJ/mol (C) – 964.35 kJ/mol (D) None of these

2. Two mole of an ideal gas is expanded irreversible and isothermally at 37°C until its volume is doubled and 3.41 kJ
heat is absorbed from surrounding. ΔS total (system + surrounding) is:
(A) – 0.52 J/K (B) 0.52 J/K (C) 22.52 J/K (D) 0

1. The solubility of Na2SO4, BeSO4, MgSO4 and BaSO4 in water follow the order:
(A) BaSO4 > BeSO4 > MgSO4 > Na2SO4 (B) Na2SO4 > BeSO4 > MgSO4 > BaSO4

(C) BeSO4 > MgSO4 > BaSO4 > Na2SO4 (D) MgSO4 > BeSO4 > Na2SO4 > BaSO4

1. Given the correct order of initials T or F for following statements. Use T if statements is true and F if it is false:
(I) (CH3)2P(CF3)3 is non-polar and (CH3)3P(CF3)2 is polar molecule
^
(II) CH3 P CH3 bond angles are equal in (CH3)3 P(CF3)2 molecule

(III) PF3 will be more soluble in polar solvent than SiF 4

(A) T T F (B) F F T (C) F F F (D) F T T

2. Select the correct statement:

(A) HSO5– ion has one S—O—H linkage
(B) Number of B—O—B linkages in Borax is equal to number of P—O—P linkages in P 4O10
(C) Hybridization of both sulphur in H2S2O5 (pyrosulphurous acid) is same but oxidatioin state of both sulphur are
different
(D) Tetra-polyphosphoric acid has four P—O—P and no P—P linkage

2. The correct order of the strength of H-bonds is:

(A) H… F > H … O > H…N (B) H…N > H…O > H…F

(C) H...O > H...N > H...F (D) H...F > H...N > H...O