“Ree. Maths: code ve, 137. Set No. 1 Question Booklet No. Sg) 55 17U/114/28 (i) (io be filled up by the candidate by bluefblack beik-potnt pen) om [LTTLTITI1 : it- (Sate gar) STRUCTIONS TO CANDIDATES (Use only bhiaetlack ballpoint pen = desea both ‘ies of the. Answer Sheet) 1, Rising0 tinder of ition atthe Qustion fo amen ge ens that it Sener rR ect bal a to fon notice eins sears eras ee to obtain a Dea Serial No, of OMB Auswer Sheet Day and Date 2 Dusting foose’ pape write oe lag, inside the Examination Holl except the Ad Cord its envelope. os z Shei be ainen I should not be folded or mulated. A second Answer Set ‘shall ot'l the Answer Sheet will be evaluated, 4. Write your Roll Nambor dnd ‘Statekbymber of the Answer Shest by pen in the space provided above. 5. On the font of the Atsner Shek write ri hie pa al et he pcp immer on ee No Nava Bs allowed In is of 'No., Question Dookie | ee and Seema. if any) on OMR sheet watRall No. and OMR sheet no, on the Question Book 7. 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Code Hm (18!) 17U/114/28(i) No, of Questions : 150 pedi ait dem: 150 Time :22 Hours ‘ ull Marks : 450 wore: 25 wee yoig: 450 Note :(1) Attempt as ‘many questions as you can. Each question carries 3 {Three} marks. One mark will be deducted for each incorrect answer..Zerd, mark will be awarded for each unattempted question. Sftenfte weit at ea at ar yeast ety oda wet 3 (ia) atet ar 81 ander ver oar & hig we ote wer aA! see agate mer ap arate ger err (2) If more than one alternative answers seem to be approximate to the correct answer, choose the closest one. aft cenftes Seiten ore wer See Pree adhe a, at Pevecrr wal sae Fy, ‘ (3) This paper comprises of: sections : Mathematics, Chemistry ®-Physics . Each section con! 80 questions. ze gee dM wet a ® : afr, tae Ret os Die Rar aa wee-% 50 997 FI PTO170/114/28(i) SECTION - I ws -1 MATHEMATICS afta ’ 2 vit OL. The value of a a Bote is: Y2-Virsinx Vacostx WE: 1 l 1 1 a 5 Cr Gg 3g log(S+x)~log(S—x) 02. The value of lim = ty BE) eS) an ARB: 1 2 a) 0 Qo. @ § ay = 03. The derivative of tan’ (sec x + tan x} is: tan’! (sec x + tan x) at araenerT 3 1 d —_, (4) cot x () -3 @ 3 (3) Gesinxy04. 05. 17U/114/28(i) Ife" +e’ = e**? then value of Bie: at & aor Boor ar & : 1 GF | (3) -* oF «al aanenetia®) ad ino, then value of £3 at 0=% If log g) and y=asin®, mn. value of Soy at a is: _ a x=a(cand+togtan5 aan y=asind, O=5 oe SE gra B: . a 4 ) 4 4 hp 6 = @ = A invested cone has-edepth of 40 tm. and base radius’ ere, ‘Water is potted ints it ata rate of 1.5 cm’ per minute. The rate at which the level of water in the cone is rising when. the depth is 4om. ? w omer Q) From/see @) Femjace 4) tom/oce wen seqeh 9% Gt Teak 40 Golo Ter area a FAVA 5 Foro 211.5 Bie? wie Pre at ae S Sweeny cat Bi Se eg Ar Wes + Soro A A wy F wh S aa F ast at avs: Q) Tm Botte rete (2) A Aotio Airs Fees (1) Gettngirs PTO.170/114/28() ny 07. The maximum value ot(2] is: Ax 08. 09. fan (3) or ATER ATA & : (1) ¢. log (1 + &) (2) e @ (3) ‘the largest possible area of a right angle triangle whose hypotenous is Som. is: = an? 25s 25 2 (1) 25cm’ Q) “Fem (3) Pom (4) 15 em 5 Botte woh aet eeritr Bram ar oem wag daar 2 : (1) 28 at Aoiflo (2) Pat Gortte 3) a Foto (4) 15 af Goro Ls » The value of [=~ axis : _ (tae ora 8: x+2 1) Qtan"¥x+i+e (QQ) (x41)+2Vx-1 -2log)x +2|-2tan” Ver1+c 3) Qlog!x +)+2tan Vr+1+C (4) loglx +2? + tan! Vx+1+C10. iL 12. 170/114/28(1) The value of Jz is: ify a: a se 2) gael _ @ Fre a Rte athe vase of | [aR + SEER) 3 (stam x4 GSTS) dc a er: } ' L 0) Be @ § a} 0 @) zt afl ‘The value of frei(-t) axis: > Toefl 2 {uoe(2-1) axa a B ° aod , Be (3) 0 (4) 5 "PTO,170/114/28{i) 13. 14, The area bounded by the curve y” - 2y + x =O and y-axis is : 1 4 () 3 84 units (2) 3 sa. units 8 2 (3) 334. units (4) J 89, units oH y'-2y+x-0 Tar yaa @ RY es srepft wr Fama B : () 3 at afte @) 5 ware 0) 5 wt are Fat aRe The order of differential equation y+ Be yax is: (1) not defined (2) 0 (3) 2 (4) 2 rat wotareet y= Ly deo (onde) te B : ) oer sé (2) 0 (3) 2 4) 2170/114/28() 15, The differential equation corresponding to alll circles x” + y’ - Jay = a’, is : empl gut x’ +y"-2ay= a’, Perper ey sree weltercet ST: (1) (2) -ayjremft-w 0 B y -29( SE) - any Ew =0° B ) (san (Z)+ arylee =0 S ) (x* (2) vay Bex! =0 16. The equation of curve passing through the point (0-2), given that at any point (x, y) on the curve the product of the slope of its tangent _ andy soardlinute of the point is equal to the x coordinate of the point, iss . aft wa aoe & Pact Peg ay} 1 Sas erat ter a neva (wits) _ Wen y dete: er gore , x Pkats & areae 8 ct Ry (0, -2) @ Te at ga ame ete & () y'+2°-4=0 Q) x+y7+4=0 x 2 Zay?+2=0 E,v. @ ty*+ @) oy i P70,170/114/28{i) 17. Solution of differential equation 2 =cos(x+y)+sin(x+y) is: aa eT W cos(x+y}rein(x+y) a ea & () 2 tan( 222) cx (2) tog tan #52 -2c (3) logft-tan(x+yj=x+C (4) tan(x+y}=e"4C 18. Solutions of differential equation 8 xsinay = x*cos’y is : TERT wit Bs xsingy=x00s?y area B®: 1 Ql) tanye"=—(-1e“+C (a) OY (x7 +1)+C 2 (3) e* tany=(x? +e" +c (4) tany=(x'+l)e"+C 19. Suppose the growth of a population is proportional to the number present. If the population of the colony double in 50 days, then population will be triple in : (1) 75 days (2) 25 lee3 days (3) as( 4) days (4) 25 1ot4(2 cays 1020. 21. 170/114/28(i} ae am Prat oa at oprdiear a gfe ax sa Gea at verde F sarge Bi aR 50 Peat A a a error ag ae &, at Peart Rat AF die ah St oR ? . : Q) 75 Ret (2) 25 igs et 3 (3) 2s(88) rex (4) 28 woe,(2) ft The angle between two diagonals of a cube is :. wr & at fepeit B te at ater a arr B: of anf @ 6° (4) 90° Ifa =10, f-2 and gi org , them value of [a3] is: AR fil=10, [b[=2 wer aber , tt fxd] a are: a), 16 @Q) 20 ~ @) 12 (aj 26 A pair of dice is thrown. If,the two numbers appearing on them are different then probability that the sum of numbers is 6, ia; SR we Ure BF A.B ale at tet oe sierra sles , at stat or at 6 aA a Brea 8: 5S 2 a ag ag of a 2 et PTO,170/114/28{1) 23. Ina hostel 60 % of students read Hindi newspaper, 40 % read English newspaper and 20 % read both Hindi and English newspapers. A student is selected at random. The probability that he read neither Hindi nor English newspaper, is : ue Berare # 60% a fet aera os ved % 40% ore sith TER Va Wea F eM 20% ot fet wen ait Set aaa Tt @ ued &1 aga ce Ba # aaa fea or 3, sa oa at mire eS aT A feat a ST aA Ga Tea F 2 1 4 2 3 Mog Qos @) 5 ag 24, There are 3 bags, each containing 5 white balls and 3 black balls, Also there are two bags each containing 2 white balls and 4 black bails. A white bal! is drawn at random. The probability that white ball is from a bag of the first group is : yet ga F Sat A Gem 3 & ae ude Aa A 5 whe ger 3 a Were Fi get go A 2 Fa F Ter ots AT FH 2 ade cen 4 att aRRat Fi cw GBS A ages Pret ont 8) ade aie aA at saterar ae SPH ora ae ge BT aT Aa AB ? 5 1 45, 8 Wg (2) 45 a 8 a a5 12170/114/28(i) 25. The standard deviation of the number of heads in a simultaneous toss of three coins is : dee pedh i peseer ierey ba EWGpr Bmore rawr (oat Sees) gar 7 3 og Q g @) 0.75 * (4) 0.87 beey ba ca 26. Thevitueot| * “(e+af |, . ao * be (a+b)! (b+ef* bac ab (c+ay) cb ar art &: ac be (a+b) (Q): abe (2) (atb+c]” (3) fatbre)* (4) 2abe(arbtc)® 27, If 'd' is a determitiatt sf square matrix A of order n, then the | determinant of its-adjoint is : awe (orgs) at at cree a at a aT a 8, ot esa SEE st UP A B= Wy @ (a a9 wma 13 P.nO,17U/114/28(i) 28. The range of the function f x) = 1- |x-2] is: was £ (x) [x-2| a ota 8: {l) (2) (1,2) 6) @) 2,1 29, If &+6=90° then maximum value of sina sinf is: ate 24-908 @ sing sing ar ofa or 2 : ayo. (2) ; (3) 0 6 fia 30. iftan = 1=% tan®, then the value of cos¢ is: 2 Vite ~ 2 af tan®= f= tand acoso AT ATT S : 2Vite 2 ecos0 { Tyecosd 2) cos0-é -ecos@ ) Trecose 4 Tyrese 81. Solution of the equation cote +coseco = V3 are : WALT cotd+cosec 0 =V3 a Bat was : ) Q=2m +5, neZ (3) @=2nn-n, neZ (4) 0=2(n+])n, neZ 14 a (2) O=2nn-5, neZ Slr33. 170/114/28(i} . Ifa and B are different complex numbers with |B|=1, then value of B~al | ft — al ** ARE a erp Prat seen ae weer B Re fpl=1, a gat ar ee Bs (0 @) 1 @) 2 (4) +2 The value of x satisfying log, jx"+ 4x + 12)= 2 are: log (ot 4x + 12) =2 Ht dase aT aT x S ay B : QQ) 2,-4 @) -1,3 @) 1-3 ) -1,-3 . If a,8 are roots of the equation x” pix+1) -c = 0, then (a+1){B+1) is equal to: ARK op WATT x partl)-c=0 B ES, A (0+1)(G+1) aT AT R: QM o¢ Q) 1te @) 1-c (4) e-1 Solution set of 1<|x-2|<3 is: 1s[x-2]83 or wqerr ea B: Q) 4,1] U{3, 5) Q) -5, 1] U[3, 5} 8) B5,-3] ey 45 Pro.170/214/28|i) 36. If the repeatition of the digits are not allowed, then numbers lying between 100 and 1000 can be formed with the digits 1, 2,3, 4 and 5 ; is: ae oleet ot gregh axa wT B, a 100 F 1000 S meq F 1,2, 3,4 TH 5 stat & wit @ aah wh Qa dent z - Q) 16 (2) 20 (3) 60 (4) 120 ‘37. If-'m’ parallel lines in the plane are intersected by a family of 'n’ parallel lines, then the number of parallelogram formed is : aft foal ard Fon aA Varail Gn’ Gare Varo aT wage ufteae at, al se cart a ART TATA agit a der s mn mn(m~-1)(n-1) Q) Qo (m-1)(n-1) mn (3) — @ F 38. Total number of words formed by 2 vowels and 3 consonants taken from 4 yowels and 5 consonants is : afte cat & 4 wd wea 5 eer 1 8 2 watt den 3 srt at SAN IE wT areal aT Gea B (y “60 (2) 120 (3) 7200 (4) 720 1639, 41. 170/114/28() In the expansion of (wesy independent term of x is 405. The * value of a is : (e+) a sare x Bea we a A 40s Rade aa: Q) asd 2) aaa 8) a=s2 @) asie . Ta, b, care in AP. and x, y,2 are in G.P. then value of x yr 2 ig: AT 9, Dye CTT AM (ALP) THM x,y, 2 TATE Aeht GP) teat xeys ae? or an ® : () xyz (2) xyz (3) 1 (0 1 1 ‘The sum to 'n' terms of the series DERE EF woe ds 1 1 1 oft TS BB Ep 3 n vt rare: OQ) Vansi Q) W2nei-1 @ Aaa ) 3{vanrt-1] 17 PTO,170/114/28(1) 42. Let x be A.M. and y, z be two GMs between two positive numbers, 343 then value of ist xyz af & aarp Genel ST FARA eT (A.M) x Ter a) PITT AER oe Yo. an ma B: xyz (GMs) y aan z 8 a 3 @ 1 @ 2 9 43. Ifcircles x+y? =a’ and x°+ y’-6 x- By +9 -0 touch externally, then the value of ‘a! is : aft Ja xt yale x+y - 6x By 4+ 9-0 Th agt a arent: eet ava 8, Gia HB a2 Q -1 (3) 21 (4) 4 44, If the latus-rectum of an ellipse is one half of its minor axis, then eccentricity (e) is : aR Reet deige & vuProra at rang seb ay-srer H ord F ase 3, i dian A RA WAM E: 1 3 w 3 ao F @ 3 alg 4 1845. 47. 170/114/28(i) a Ife, and e, aré respectively the eocentricities of the ellipse Bet 2 and the hyperbola ¥~ 1, then the relation between e, and ei a . a aS e, Tare, are: dere aan aren afro EL a aan’ &, de, cere, a ame A ware: (Wy Bef 4ez=2 (2) 2s2e=3 @) 2cfrej=3 (4) ef+et=1 je ithe lines ax + 12y+1=0, bx+ 13y+ 1=O and ex+ l4y+1-0are concurrent, then a, b, c are in : Q) HP. @ ap. (3) AP. (A) abo=1 af Teng ax+ 1ay+1=0, bx+ t3y+1=0T Ht dy t 1-0 UH frgmit %, dt abc ®: (| HP. # Q GPF (3) apt (4) abo a ‘The angle between the lines whose direction cosines are given by the equations 3/+ m + 5n = 0 and 6mn—2al+ Sim - is : ae et Rersit A RagieMt (dics) wth 3l+ m+ 5n=0 wen 6mn-2nl+ Sim =O ant Pea 8, at ar tans S trey an ey & oo) a 8) oo) ow wfy 1s BT.o,17U/114/28{i) 48. If the cartesian equation of a line is 6x - 2 = 3y + 1 = 22-2, then its vector equation is : af& 6x—2= 8y +1 =22-20e Var ar aa Tier z, A sa ta ar afar ater e : @ jek} +a(i+a}+ 38) 2) # =(61+3}+28)+4(2i-j+k) $ @ (33 Livi) eafiea}sae) r(i (@) f= i-j+k}+a(i+j+k) 49, ‘The cartesian equation of the plane #=3}+ 8(i+2K)+t(-2i-j+K) is: MIT F=3j+0(i+2k)+t(-21-]+k) ar aT Toe Re (1) Qx-Sy-2+15 <0 (2) 2x+S5y+2+15=0 (3) x+2y+z24+15=0 (4) -x+2y+32+15=0 50, A variable plane which remains at a constant distance Sp from the origin cuts the coordinate axes at A, B, C then locus of the centroid of triangle ABC is : we IC BATT AT ASTTZ J Wea 3p SQA oe Ret cen B wer seat Bt A,B,C Prat Tx aheBe ae B ct Pra abe & ars at frye & = : 1 lo ae (2) (4 *L= 8) 2051, 170/114/28{i) SECTION - It we -T CHEMISTRY were fas ‘The anhydride of Ba(OH), is : Ba(QH), 7 wreRyES (Q) Bak, (2) BaoH (3) Bao (4) Bao, Which of the following is true for Br, at standard temperature and pressure ? (1) acolourless gas (2) red brown volatile liquid (3) colourless volatile liquid (4) _ yellow insulating solid AMS OMT FT era Te Br, RM ear aT B ? (1) tre Fre + Q) Bear areefier wer 8 () és averse aa B 4) der gate ate ® . Atoms of different elements with the same number of neutrons : (1) isotopes (2) isobars (9) isomers (4) isotones Fatt wet S yong, fs agrt a dow wm 8 ae: (1) aan @) nites 3) wah 4) FRR al PTO.170/114/28(i) 54. Cheese is a colloidal solution of : (1) solid in solid (2) liquid in solid (3) solid in liquid (4) gas in solid for we aetlgdl ret B Q) ate # ate aT (Q) ae 4 xa aT 3) ma oe a 44) Ga # Fe ar 5S. For the reaction’2A42 > C+D, the rate constant is 1.5*10°S". The order of the reaction is RPT QA+B 3 C+D E fa Te Rein 1ox10%s "8 1 siPBraT at atte ert : ay (2) 2 @) 0 a3 86. The rate constant of a bimolecular gas-phase reaction is found to follow the Arrhenius equation. Which of the following will result in a smaller rate constant ? (1) lowering activation energy (2) lowering temperature (3) lowering pressure 4) lowering concentration of reactants 2287, 170 /114/28(i) ws facrge Tada # afiear ar te Revie omtPraa & eee BIR aa 81 gt A ay, aay Ye Reis, wart ate : Q) aren wal y anf (2) wart # ant 8) aa F ah 4) atedat & arse a ait Of the following which one is likely to have largest value of the Parameter ‘a’ in the Vander Walls equation of state for real gases ? areata FS avecaer aac F ont aa gew val at a Pratetiac @ Peek faq offers Ser ? Ql) H, (2) Ny (3) Co, (4) NH, }. What is the orbital angular momentum quantum number (¢) of the electron that is most easily removed when ground state aluminum is ionized ? WH seer F ghey at one eet oe ot ta awa rent & arse an sar 8 suet onflen aivta wh sate veut (0) ar art eet : Q) 0 a) $ @) 2 . 2 a3 P.T.O,170/114/28(i) 9. Under constant current electrolysis, how many coulombs would be required to reduce 2 mol of Cu™ to metallic copper ? fret ant oe a ae ge orsaet at afar @ 2 Fret Cu” Br sna ater A aad & fee ate atta ot crraxreet ett ? (4) 2 (2) 96,500 {3) 1,93,000 (4) 3,86,000 60. The equation : AH = AU+PAV is applicable alw : (1) always (2) only for constant pressure process (3) only for constant temperature process 4] only for constant entropy process eet a= au+Pav SHAE Q) en (2) Fat Rae ate a oar + fre (3) Gaa Re ae at uber & fae (4) Baer Rere Gert aren Fare 61. Which of the following is always true for a spontaneous process ? (1) The process is exothermic (2) The internal energy of the system decreases (3) The entropy of the system increases (4) The total entropy of the system plus surroundings increases 24170/114/28(i) ere: ire & fae Pe A A aka aT Be? Q) ae srr wa Gore att & Q) Pre at ataftes cat an at (3) Praer a derht agdt & 4) Per a cat vatrer at ee cent aadt 3 . Considering 0.1 M aqueous solutions of sach of the following which solution has the lowest pH ? 0.1 M xe Peer SA ue Presfatar & foes parr ae Shem ? (1) NaCO, (2) Na,PO, @)_-Na,S (4) Nacl . The Rydberg equation predicts accurately the UV-visible spectrum of the hydrogen atom. A form of the Rydberg equation may also by used to predict the UV-visible emission for all the following except : Rest whem, eae vary & uv-aern sar at acta sere mer 8 1 Real aeet ar cH ey, Pet ah & ov. came Shae St were ax Bw 8, eae: Qo () D (3) Hee (4) Be* a5 Pro.170/114/284i) 64. At a given temperature, the forward rate constant of a one —step is 4x107M 's’. Given that the equilibrium constant is 1x10’, what is the reverse rate constant of the reaction ? Bret RA aa ana oe Gest eT ae stn Re Preis 4107's BI aft erencen feria vi07a ct, saPafrar ar Geet te Reis ert (4) 8*10°M's (2) 4x10°M's" (3) 4x107M's" (4) 8*10°M"'s' 65, The two quantum numbers +4 and 5 for the electron spin represent : (1) the rotation of the electron in clockwise and anticlockwise directions, respectively (2) the rotation of the electron in anti-clockwise and clockwise directions, respectively (3) the magnetic momentom of the electron pointing up and down respectively (4) two quantum mechanical spin states which have no classical analogue. gaat 3 aa & fee a gain dens +] ote 2 aa act Be qi) gaagrt & amen afeoned a ara gis (2) Raa H RAT: ararak a eferorat Wort a (3) aaagr & gaia gis aa at aaa Gat as HA ear at (4) A aston airs cat oreeensit Bret Hg sett aAgea ae & 26170/114/28(%) 66. Consider a He atom and a H, molecule At 25° C, the mean kinetic energy of a He atom is : {1) two times that of a H, molecule (2) the same ad that of a H, molecule (3) four times that of a H, molecule. (4) half that of a H, molecule We He Fey A as Hoy 25 cae fare vA B1 HeTeTT AT AT aks’ Gat eri: Q) Hey t aremiter Gat a a yar 2) Kory at merit eat 3 araz 8) Byory a emer oat ar are gar (4) Hay er arefeist Gant aT ara 67. The coordination number of a metal crystallizing in hep structure is : hep tae # Rreecgr &F art ag st monet den 8 : (12 - 2 4 (3) 8 (4) 6 68. For the reaction H,(g) + I,(g) = 2tl(g) the equilibrium constant Kp changes with : . (1) total pressure (2) catalyst {3) the amount of H, and [, present (4) temperature ar" PTO,170/114/28{i) safiftrar Hg) + Le) = 2Hi(e) & fire ary Feri Kp aeaat 8 ) aaa 3 ae : 2) sre a at @) Hote 1a wer Serer 4) or & arr 69. A certain buffer solution contains equal concentration X" and HX. The K for X is 10°, the pH of the buffer is : om aor Reet 4X att HXat Bizet BT BX 4 fa kK, 10” & at feet ar pH am B: a) 4 “a 7 (3) 10 4) 14 70. When 20g of napthoic acid is dissolved in 50g of benzene (kf = 1.72 K.kg.mol"), a freezing point depression of 2K is observed. The Vant Hoff factor is : ora 209 FHS ara ay oss Aeter F sow ower Si (ke 1.72 Kkgamol'), Ta Faeries A Kat wt Bet ome 1 are ens ewe: Q) 05 Qi (3) 2 @) 3 28170/114/281) 71. 2 moles of an ideal gas expanded isothermally and reversibly from 1 litre to 10 litre at 300K. What is the enthalpy change ? ua atest Fa} 2ate, Geert aie semper seme 300 K art We 1 whet & lo che om aed Bet SFA ae Got Gade st aa B: (1) 4.98 ks QQ) 11.47kI (3) -11.47%I (4) OKs 72. Which of the following is smallest in size ? Pret § @ Reet one wad ster & ? (t) NP (2) oF a) F @) Ne’ 78. The percentage of p-character in the orbitals forming P-P bonds in P, is: Pt PePare & Pratt F p-qeay an Peery Reet Arad Bar B 7 (1) 25 (2) 33 (8) 50 (4) 75 74, The chemical composition of slag formed during the extraction of Cu is: * cud Patcr ¥ a at hr at caratrs. dato 2: (W) Cu,0 + Fes (2) Fesio, (3) CuFes, (4) Cus + Feo as PTO.170/114 /284i) 78. A solution of Na,SO, in water is electrolyzed using Pt electrodes. The products at the cathode and anode are, respectively ? Na,SO,% sata feet ar Prgaags % wer Mga orssed Hear wet 81 dete att wits oe HAM: TA GA are Sea B : (1) H,,0, 2) 0,H, (3) 0,,Na (4) 0,, 80, 76. Which of the following species is not a pseudohalide ? mH i B aia sqditengs ae 8? (1) CNO” (2) RCOO (3) OCN” (4) NNNT 77. Iron is rendered passive by treatment with concentrated : (4) HCI (2) HNO, (3) H,S0, (4) H,Po, arrest, Pitre at onan S oa set Bram mag ont 8 abe : () KCl & =) HNO,@ (@) H,S0,a (4) HPO, @ 78. The compound having a tetrahedral geometry is : Rrafatea 3 @ fou dite a aguncctia aca & ? (1) (NH(CN), (2) (aye), (3) paca)” . @) (nicl 30170 /114/28({i) 79. A metal nitrate reacts with KI to give a black precipitate which.on 81. addition of excess of KI coverts to an orange colour solution. The cation of the metal nitrate is : Wm ates eRe KIS Gre Bear a sre vay tar S ot Ka aattsen & are tr & Riera a geet set Benford ar ET R: @) He” (2). Bi* @) Per 4) Gr }. Which of the following has the maximum number of unpaired electrons ? Rreafatirt & Pret orgfne gage at den watts & ? (i) Mg” (QQ) 1 3) v" (4) Fe* ‘The formation of cyanohydrin from a ketone is an example of : (1) electrophilic addition (2) nucleophilic. addition (3) nucleophillié substitution (4) electrophilic substitution Har 8 arta a ar saree F : (1) Saenger ahr ar 2) =aerhftes- ater ar 6) BRRraR Rs ofr ar (4) gases oem a aa Pro,170/114/28{i) 82. The molecule in which the distance between the two adjacent carbon atoms is largest is : (}) ethane (2) ethene (3) ethyne (4) benzene a aadet as gerysit } dia at att fra ory A alts B ? ) Ba @) xt (3) Sag (4) ait 83. How many chinal compounds are possible on monochlorination of 2-methyl butane ? 2. frame een & abide } ovenq ore free aifret at ter Port eit ? {). 2 QQ) 4 (3) 6 (4) 8 84, Which of the following compounds does not get dissolved in concentrated H,SO, even on warming ? (1) ethene (2) benzene (3) hexane (4) aniline Rrafattad 3 8 Beer Ate, vet wet We HH PH H,S0, 7 YeaT wet 8? . () sis (2) Si @) 2 (4) Pett 32_170/124/28() 85. The reaction of toluence with chlorine in the presence eve chloride gives predominently : (1) benzoyl chloride (2) m-chlorotoluene (3) benzyl chloride - @) o-and p- chlorotoluene She adres at aoaftr F get om eer oer ara & at ger ey 3 arb: Q) Fite aires Q) m- aittergey (3) @Porr aitues @). o ap. aaeergiT 86. Chlorobenzene can be prepared by reacting aniline with : (1) hydrochloric acid * (2) cuprous chloride (3) chloroine in the presence of anhydrous AiCl, (4) ° nitrous acid followed by heating with Cucl aera ar Prater ger oe oP oper ach & - (1) BRR ore Barer Q) aque agtage & arr (3) Werage Aicl, at Seek, Faas & are 4) age UtS & art aay cucns aa ue ‘ST. The reagent with which both acetaldehyde and acetone react easily is: "8 . (1) Tollen reagent (2) Schiff reagent (3) Grignard reagent (4) Fehling reagent ae P.T.0,170/114/28(3) ae oftantes fired apr oftefesegs afte wate At A ora & afin aa & : (1) aaa orate (2) fae often (3) Beets afters 4) Seiten carats BB. The Cannizzaro reaction is not given by : (1) trimethyl acetaldehyde (2) acetaldehyde {3} benzaldehyde (4) formaldehyde Aa, Short ataiwar we wee ? () ePrergct wftreeere (Q) ofsearee 3) aanfesses (4) wafesegs 89, Hydrogenation of benzoyl chloride in the presence of Pd on BaSO, gives (1) benzyl alcohol (2) benzaldehyde (3) benzoil acid (4) phenol pache Beso sofa # antes wines & sagen a saet erat B (1) SP were Q) aneags () Fate BS (4) Rear 3417U/114/28¢) 90. When sulfonic acid and p-nitrophenol are. treated with NaHCO,, the gases released respectively are : 5 A ora She p- stern a Pour NaHCO, aut ont B, ae ot Ft Pram & ae ape: B (1) SO,, No, _. 2)80,, NO (3) 80, co, (4)Only (@aa1).Co, 91. Which of the following bases is the strongest ? Prafaferr 7 2, waif uaet are B 2 () C,H, NH, (2) p-NO, C,H, NH, (3) m-NO,C,H,NH, . (4) C,H, CH, NB, 92. Among the following compounds, the most acidic is : () p-nitrophenol * Q) p~ hydroxy benzoic acid (3) o~hydroxy benzoic acid (4) p- toluic acid Pratattt & & aaites seer one & : Q) p- area - Q) p- sagtriesies or Gl o- REPRE (4) p> Ogg ort 93. Among the following polymers, in which one intermolecular force of attraction is the'Weakegt > (1) Polyvinyl chloride (2) natural rubber (3) nylon (4) cellulose a5 * RTO.170/114/28(i) 94. 95. Prafafted aque a art orramfs orator ae wad eect B 7 (1) tetfaanga aires Q) smrpits taC (3) RIT (@) geet ASN* reaction of an asymmetric carbon of a compound always gives : (1) an enantiomer of the substrate (2) a product with opposite optical rotation (3) a mixture of diastereoisomers (4) a single stereoisomer oe Ata & onmira aria at snatear eter Sct & (1) Bae ar Fete Q)' Prafta verre gels aren Gee () séeitehergad a Pare (4) SARetomeder gas How will you convert butane - 2 ~ one to propionic acid ? (1) Tollen reagent (2) Pehling solution 3) NaOH/L/H" & NaOH/Nal/#" ard, RH = 2- ari a shfnolites ovat TBS geet? Q) Aer attests a |) BRT fare & (3) NaQH/1,/H" (4) NaOH/Nal/H" 3696. 97. 170/114/28{) In thermodynamics, a process is called reversible when :- (1) the surroundings and the system change into each ether “ 2) there ts no boundary between the system and the surroundings 3) the surroundings are always in equilibrium with the system (4) the system changes into the surroundings spontaneously ‘sonra 3 shh are, sapere ondt one & ore = (Loe arenerer oie ct we get A oar a mae 2) arene ste dat & ete add Hare at ah F (3) mete SAR dat B ater eer gas (ara) @) a, ate & aearer & eae omer a The molecule having one unpaired electron is : Rar ony frat Baer wes organ etagr & : () No Q) ¢o (3) CN (4) 0, 98. Which of the following compounds has Sp’ hybridisation? Prafaiter 4 & aa atte sp'eieher 2 7 {1} CO, (2) -8Q, (3) N,O i4) co az P10,170/114/28(i) 99, Which of the following statements for the order of a reaction is not correct ? _ (1) The order can be determined experimentally (2) The order of the reaction is equal to the sum of the power of the concentration terms in differential rate law. {3} It is not affected by the stoichiometroic coefficients of the reactants (4) The order cannot be fractional Pre cares after a ae A eae Fer A A Bat err ah EB? ay (4 (3) 4) ae ar Peter watr & avec oe Peat oT wa B Raa le Rea F orn F Tat FA HS afer sy ante mea 8 ae cataniat & omar yore & vented et Sieh @ ate ah A oiftrs vet a aaat & 100. Of the given anions the strongest Bronsted base is : RA we GE HA Aaa wae iets Te B : () cio” (2) clo, 3) ClO, (4) clo, 38170/114/28(i) SECTION - 1 wes - mm PHYSICS Stites Power " 101. The voluines of two bodies are measured to be V,"(10.2 # 0,02)ec and V,=(6.4 t 0.01)cc. What will be difference in Volumes with error limits : (1) (38+0:01)co * (2) (3.84 0.02}ce 8) (8.8 £0.03)cc ~ A (3.8+0.04)cc & feat a sneer ar ATE V,~(10.2 + 0.02}¢8 tT V,=(6.4 + 0.02}0c «81 Sent an ora sft B dtr S avec ae: (1) 88 t0.01eRR. 2) (8.8 + 0.02; (3) (3.82 0.03y¢Rr 4) (3.84 0.04; 102.Which one is correct value of sum of the two numbers 6.75% 10? om and 4.5210" em with regards to significant figures : (Q) 72.02x10'cm =” @) 7.20216" cm (3) 72.0210" cm (4) 7.20x10? cm ants siest F viet Moet sfat orox10% @ifto men 4.52010" to aa att ad St: (1) 72.0210 2) 7202x108 dh (3) 72.02x107 Gt (4) 7.20x107 &ft ap P.T.O,170/114/28(i) 103.The velocity of particle depends upon the time ‘” according to the equation v = a + bt + c/t. What is dimension of ‘a’? aot an AT v= a+ dtto/t, WHT B age Baa +! ax Pete BI ‘a’ or Pr aa B ? air} oo br) @ bl 4) [UT] 104, The perpendicular vector of the vectors A= 2i+3}+k and B=i- jek is expressed as : aaett A=2ieajek eM B=i-j+k & waa aaex at ara fea a aT F w wl) @) qoy(tesie8) @) ypglir2iese) @ agli) 105. The velocity - time equation of a particle moving in a straight line is V = (10 + 2t + 3t}, What is the displacement of particle from the mean position at time t=1 second, if it is given that displacement is 20m at time t=O: (4) 22m QQ) 32m (3) 42m (4) 52m ce Ga Ter Beet oor a ST e aHET v= (10+ 2e+ 3e) fear By eae SRO Bee ae ay PTO eT TTT Ta Te HET HRT BAHT t20R 200 AH GT TE: uy) ge) Sate ‘(@) 42#o (4): Sho 40170/114/28(4) 106.An air bubble of radius 1 cm rises from the bottom portion through a liquid of density 1.5 gm/cm’ at a constant speed of 0.25cm/sec', If the density of air ie neglected, the coefficient of viscosity of the liquid is approximately : 1 Sho ee mr wr ay STM eet A GH GAM A 0.25 Bo /Ao LS ar/ Beto G wee Fae Hue Goer Ba ag B ore a aT et fee ore, ze aware ar Qos eae F (1) 13000 Pa-s (2) 1300 Pa-S (3) 130 Pa-S (4) 13 Pa-s. 107. An ideal gas is taken through the cycle A-» BC) A as shown in the fig. If the net heat supplied to the gas in the cycle is SJ, the work done by the gas in the process C4 is: Q) -54 () -15J a1 PTO,170/114/28() Ge aes Fa st GT ASB oC +A Praga fear are Bi aR 5 Ue Sar yt ar fear ore & at ta ara eA CAR Pear 7 arte : 5 _, 10 PIN) > Q) +53 (2) -10gH 8) -159 (4 204s 108.The work involved in breaking a bigger size spherical oil drop into n smaller size identical droplets is proportional to : we aS crane ar tetas Sa S Ge St nS oH S ws VAM Ft at ware F fear aren art organics ahr : Q) {nF -1 Q) Yh 8) dnt-1 4) Ya-1 109.A glass capillary tube of inner diameter 0.28 mm is lowered vertically into water in a vessel. The pressure to be applied on the water in the capillary tube so that water level in the tube is same as that in the vessel inNmis(T = 0.07 Nm™,P = 105Nm") 4) 10° (2) 99x10 (3). 100x10° (4) 101x10° 4217U/114/28(i) eh Bie ot aren act rece onraftar sare 0.28 Rrowte at ait a at ach 9 seater freer ore 81 aire aet Foren ee are sar ae (EAN) F Ser oer Site at FH se ar eae ada F oer or ee & aware wn (eh gs Ie T= 0.07 Bea, ag wa P= 10° Seat’) = (1) 10° (2) 99x10° (3) 10x10" =~ (4): 101«10* 110. The volume expansibility of brass and iron are 54*10°! and 36x10%;! fespectively. They are supported between rigid walls. They are heated so that they have the same rise of temperature and there is no bending. If the same thermal stress is developed in them, the ratio of Young's modulus of brass & iron will be : Sheree ie AE eT STEYR ART: 54 10° eM 36x JOM! Bi ag ar & ete carrer Bi wer are at ara ora & Pree Sra gare 7 et as sad fe wa Sita Prgltes Stes a hae ote att & a oremeta goin eer arguer er: (Ql) 2:3 (2) 3:2 @) 4s2 () 4:9 141, The specific heat capacity of a metal at low temperature (1) is given as C= 32 (T/400)". A 100 gm vessel of this metal is to be cooled from 20 K to 4 K by a special refrigetitor operating at aom temperature 27°C, The amount of work required to cool the vessel is : {1| Equal to 0.002 kj Q) gremermtan 0.148 iy (3) between 0.148. ki & 0.028 is) (4) less than 0,028 Ki 43 PTO,170/114/28(i) ep ang ar fares Sear efter ea aTTATA UE C = 32 (1/400)° fear Riga ag & 100mm & ue ade at ow Ras shay F sree aT art & amt a7 ut wrist B, 20°K 8 4K aH SST fa STAT Sada By aver wear & fa anata aed erh (1) 0.002 kj & Tae (2) 0.148 kj @ sftp (3) 0.148 kj Tar 0,028 kj & ater 7 (4) 0.028kj) @ aT 112.1f and y are coefficients of linear, superficial & volume expansion respectively, then + aR a8 ate 7 waa: tata, Sata qe sna TE Ties Fat: 1 Bo2 28. “ 1 w feb FB ow FF v2 7 a B38 113.The following are the P-V diagrams for cyclic processes for a gas. In which of this process is not heat absorbed by the gas ? Pre frat 4a & aaa wae a pv Pra a acura re 21 Peet ee H Sea ar Hager sel err? a) Pf oO e vt O vo Pe «@ Pt yy @ vf A v> oe 44170/114/23{i) 214.Two carnot engines A & B are operating between two pair of temperatures (500 K, 400 K) and (400 K, 300 K) respectively. What is the percentage difference in their efficiencies ? @ are Sr A ware A yr at aT (500 K, 400 K) aT (400 K, 300 K) 4¢ aaneet 21 ga& errensit Hofer oraz Peer & ? (1) 5% (2) 10% (3) 15% 4) 20% 115.How for does the sound wave travel in air when a tuning fork of frequency 256 Hz makes 64 vibration ? (velocity of sound in air = 320 m/sec) = () 60m 2) 7m (3) 80m (4) 90m om eats rast angit 256 eds 8 64 der A ah ain ag # Fearn x va ont ? (ag 7 ea ar Br 320 Me Ae) ; (1) 60%%e 2) 70% {3} B0Mfe (4) 90+to 116.4 wave travelling along a string is given by y (x, U = 0,005 sin (80x - 3t) where the numerical values are in SI units. What is trequency of wave in question ? (1) 0.008 Hz (2) 0.58 Bz 3} 0.48 Hz Ps 4) 0.38 He z 45 P.To,17U/114/28(i) wm Tah A alr SA AR aT TAHT y (x, 1) = 0.005 sin (80x- 34) 2, ai ctifises gee st gang A Peer Bi wer eT at oTTGhT we ? (1) 0.005 et Q) 0.58 set (3) 0.48 ee (4) 0.38 8 117. Write the equation of progressive wave propagation along the positive X.- direction, whose amplitude is 5 om, frequency 250 Hz and velocity 500 m sec”; eae X—ae & Ret F sari att ar aeferct fates Prear aram 5 ito, amg 250 Hz ale Ft 500 He Aare a: (1) ¥=0.05 Sin (500 t - ») (2) ¥-0.05 Bin: (100 t - x) (3) Y=0.05 Sint (500 t - x) (4) ¥=0,05 Sin * (100 t-) 118. For the give shape of vibrating wave between two ends, which onc is the expression of fundamental frequency for velocity V : fea 73 Aiea aes & angle & fart H ste 8B RA TV & fae ae arght a a aa a 4617U/114/28() 119.In open Organ pipe, the possible harmonics will generate : (1) Only odd” (2) Only Even (3) All numbers (4) Prime numbers SF gt orphaned 4, wee erie sae at : (1) Fae Fer (2) Fae ar 3) wit ver 4) wea der 120.The concept of expanding universe is based on the observation of : (1) Quasars: (2) Stark effect (3) Neutron stars (4) Doppler effect sent mets a awe Preatetan & Rerer & omer ox At ah eB : (1) aaret (2) et6 were @) =ER az (4) Sra oH 121.4 particle of mass 1. Kg ia placed in a potential field. Its potential energy is given by u = 10x’ + 5. The frequency of oscillations of the particle is given by : 1 Rear at cam Foes ce; Rafter saat Gar A cer B 1 geet Reet grat us lox? +5 fear rer Si ser & der By TERY Shh: - 0) 10 a (a) f= ) & aid Pro.“170/114/28(4) 5 122, If one mole of a monoatomic gas (r=$) is mixed with one mole of a . . 7), diatomic gas (r = 3) , the value of y for the mixture is : com orange fet (13) a ce the Reeves Ae (1-2) a oH ara at Prara one 8, Peer er y art ear er = (1.40 (2) 1.50 @) 153 (4) 3.07 128, The length of simple pendulum executing SHM is increased by 21%. The percentage increase in the time period of the pendulum of increased length is : weet onda a aed ge Ter ates wt orang 21% aes aR B 1 ators & oreferenret HF after gx Sr ast es FTE : (1) 42% (2) 10% (3) 11% (4) 21% 124.At 10°C, the Value of the density of a fixed mass of an ideal gas divided by its pressure is x At 110°C this ratio is : 10°C wee Ree wera ar seer he F sea ar Pease ma x1 110 armnt oe aw argTe eM : 383 10 283 fl) x Q) deat 8) 0% @) 3e3* 48170/114/284i) 125.A large horizontal surface moves tip and down in SHM with an amplitude of 1 cm. Ifa mass of 10 Kg (which ia placed on the Surface} is to remain. continuously iri contact with it, the maxinyum frequency of SHM will be : 18 [mga] <2 (3) |mq| <18fon¢0|>1 (4) [eel 18mg] >1 com ara ior ee BE CF ATMA TH Ge ABED THB Raga, 34 : ADCF (1) frye <1 at gp] <2 (2) emga|> 1 98" men] <1 8) {etgg| < Lc | > 2 (4) fmgl> Deere? 5217U/124/28{i) 133.When an unpolarized light of intensity I, is incident on a polarizing Sheet, the intensity of light which doea not get transmitted is : oR, Aa & sng aaa wher ee Ge arate Ser ® at aeaer O cieat Rt oe at we B ae > wy & ae wo @ & 194-The frequiency of electromagnetic wave which is best suited to observe 2 particle oF radius 3*10m tg of te oer of : () 109 He Q) 10° He (3) 10" Hz (4) 10 be, & B1 (BT 310° fo) 3 fae wad ore Sgrgany oer at ‘sgh er: 0) 10% egor 2) 10" wir 0) 10" eer (4) 10" 54 Pino,170/114/28(i) 135, The expression for electric field at Broad — Side on position is expressed as from the figure : 1_2p Pk Geer Q) Geer 1 2 . a uae (4) Zero 136.In adjoining figure, there is no deflection in the galvanometer. What is the Value of R? aigger Fare, Sedvinitee 3 ag Pra el ea B afer R ATT wat ah ? 30 R 1 210 () 9a (2) 6a (3) 30 4) 19.170/114/28(3) -187-Magnetic field at the centre of a circular loop of arca A is B. The magnetic moment of the loop will be : ‘ deer 3 cinta ay 3 Sa oe gang da ery Bei WaT sie ont er : 3 Zz Bat Bat BH apa Q) Pot @) “ (3) ae (4) syst 188.A copper wire of diameter 1.6 mm carries @ current I. The rigximum magnetic field due to this wire is 5x10“T. The value of I is : Q) 02a QQ) 05A 3) 2A @ 4a 16 Protie sane & of @ are a'r rer enter derB 1 xe are aT abrert erates a or aie Sx10° teen 8) ART aT AP she Q) 02 eae {2} 0.5 afar @) 2R fax @ 40Rer 199.4 50 om Jong bar magnet, AB és moved with a speed of 4 m sec” ina magnetic field, B = 0.017 as shown in figure, The emf generated is : D8 Od De De {) Oo1v (2) 0.02V (3) o.03V (4) 0.04V ‘ P.O,170/114/28(1) AB Ge 50 Sho oe Gass os Gas Ba B= 0.01 2a 4 4tio/@o & art & aa wer & (Ranger) cart Pret aes 5B () 4p FB Jo > FB SRE (3) dp > RR NL alepiteen Je + RB Jo > FB 3 Aro.170 /114/28() 150. The Radiowave is reflected back by the (1) Stratosphere (2) Troposphere (3) Mezosphere (4) Ionosphere Ua oer argawse & Fever AT & aati dar & ? (1) Berra @) ehrehac (3) Aeheaiae (4) ARR 60 part of atmosphere : 75,000ROUGH WorK wart “er 170/114/28(4) Rng,170 /114/28{i) ROUGH WORK wart 62ROUGH WoRK want 63 170/114/284 PTO,i. 2. 13. id. piarttrel & fore Freee pen re se FC STE SO a pane arr cage #7 & secqmnd amen ed TN TS ae agen 2 eae aT ern a a ara a al Se naar tea ci age are eve Te Fa eT are EEA TS ey ag GATT HH i) . were rT ET sn ae a 1 0 fA TE se bar act &, a ET Teed gal ah wre ote Hi RATE TT TS